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11. 发明授权

US3390200A Production of aromatic hydrocarbons by hydrodealkyaltion and hydrogenolysis 失效
标题翻译：通过氢化和氢解生产芳烃
公开(公告)号：US3390200A
公开(公告)日：1968-06-25
申请号：US48982965
申请日：1965-09-24
申请人： LUMMUS CO
发明人： SZE MORGAN C
IPC分类号： C07C4/00 , C07C4/16 , C07C4/26 , C07C15/00 , C07C15/04
CPC分类号： C07C15/04 , C07C4/00 , C07C4/16 , C07C4/26 , C07C15/00 , C10G47/00 , C10G47/22 , Y10S585/905

12. 发明授权

US3879481A Production of vinyl chloride 失效
标题翻译：生产氯乙烯
公开(公告)号：US3879481A
公开(公告)日：1975-04-22
申请号：US9503070
申请日：1970-12-04
申请人： LUMMUS CO
发明人： SZE MORGAN C , RIEGEL HERBERT
IPC分类号： C01G3/05 , C01G3/06 , C07C21/06 , C07C21/02
CPC分类号： C01G3/06 , C01G3/05 , C07C21/06
摘要： Process for producing vinyl chloride wherein ethane and/or ethylene and chlorine and/or hydrogen chloride are contacted in a first reactor with a melt including a multivalent metal chloride in its higher and lower valence state and the oxychloride of the metal; e.g., cuprous and cupric chloride and copper oxychloride, to produce a chlorinated hydrocarbon effluent, including vinyl chloride, ethyl chloride, dichloroethane and other chlorinated hydrocarbons. The ethyl chloride is recycled to the first reactor and the dichloroethane is dehydrochlorinated in a second reactor to vinyl chloride by contact thereof with a melt of a multivalent metal chloride in the higher and lower valence state. Either all or a portion of the other chlorinated hydrocarbons are burned to produce a combustion effluent including chloride and/or hydrogen chloride, which is contacted in a third reactor with molecular oxygen and the melt containing a multivalent metal chloride in its higher and lower valence state, whereby chlorine and/or hydrogen chloride are absorbed from the effluent by addition of chlorine to the melt and in addition the oxychloride is produced. The melt from the third reactor is employed in the first reactor.
摘要翻译：制备氯乙烯的方法，其中乙烷和/或乙烯和氯和/或氯化氢在第一反应器中与包含其更高和更低价态的多价金属氯化物的熔体和金属的氯氧化物接触; 例如亚铜和氯化铜和氯氧化铜，以产生氯化烃流出物，包括氯乙烯，氯乙烷，二氯乙烷和其它氯代烃。将乙基氯循环到第一反应器中，并将二氯乙烷在第二反应器中脱氯化氢，通过与更高和更低价态的多价金属氯化物的熔体接触而进行氯乙烯。全部或部分其他氯代烃被燃烧以产生包括氯化物和/或氯化氢的燃烧流出物，其在第三反应器中与分子氧接触，并且熔体含有其更高和更低价态的多价金属氯化物，由此通过向熔体中加入氯而从流出物中吸收氯和/或氯化氢，此外产生氯氧化物。在第一反应器中使用来自第三反应器的熔体。

13. 发明授权

US3869518A Acetaldehyde production 失效
公开(公告)号：US3869518A
公开(公告)日：1975-03-04
申请号：US18378871
申请日：1971-09-27
申请人： LUMMUS CO
发明人： SZE MORGAN C , WANG RUEY H
IPC分类号： C07C47/07 , B01J27/00 , C07C17/152 , C07C17/154 , C07C45/00 , C07C45/30 , C07C67/00 , C07C45/02
CPC分类号： C07C17/154 , C07C17/152 , C07C45/30 , C07C21/06 , C07C47/06
摘要： Acetaldehyde is produced from ethane by contacting ethane in the absence of added chlorine or hydrogen chloride with a molten mixture of the higher and lower valent form of a multivalent metal chloride and the oxychloride of the metal, such as a mixture of cuprous chloride, cupric chloride and copper oxychloride, in the presence of ethylene and ethyl chloride and optionally also vinyl chloride. Acetaldehyde is produced with no net production of ethyl chloride and ethylene, and if vinyl chloride is present, no net production of vinyl chloride.

14. 发明授权

US3865886A Production of allyl chloride 失效
标题翻译：生产烯丙基氯
公开(公告)号：US3865886A
公开(公告)日：1975-02-11
申请号：US37161573
申请日：1973-06-20
申请人： LUMMUS CO
发明人： SCHINDLER HARVEY D , SZE MORGAN C , RIEGEL HERBERT
IPC分类号： C07C17/087 , C07C17/10 , C07C17/154 , C07C17/25 , C07C21/067 , C07C21/04
CPC分类号： C07C21/067 , C07C17/087 , C07C17/10 , C07C17/154 , C07C17/25 , Y10S260/42 , C07C19/01
摘要： Propane is chlorinated in the presence of a molten salt to allyl chloride and other chlorinated C3 hydrocarbons. Isomers of allyl chloride are hydrochlorinated to dichloropropanes, and dichloropropane is dehydrochlorinated to allyl chloride and its isomers. Hydrogen chloride generated in the dehydrochlorination is recycled to the hydrochlorination and dehydrochlorination steps.
摘要翻译：丙烷在熔盐存在下氯化成烯丙基氯和其他氯化C3烃。将烯丙基氯的异构体氢氯化为二氯丙烷，二氯丙烷脱氯化为烯丙基氯及其异构体。在脱氯化氢中产生的氯化氢被循环到氢氯化和脱氯化氢步骤。

15. 发明授权

US3637895A Dehydrogenation process using molten copper chlorides and oxychloride mixtures 失效
标题翻译：使用氯化铜和氧化物混合物的脱氢方法
公开(公告)号：US3637895A
公开(公告)日：1972-01-25
申请号：US3637895D
申请日：1968-10-23
申请人： LUMMUS CO
发明人： RIEGEL HERBERT , SCHINDLER HARVEY D , SZE MORGAN C , BROOKS MAURICE E
IPC分类号： C07C5/333 , B01J23/00 , C07B61/00 , C07C1/00 , C07C5/44 , C07C11/02 , C07C13/02 , C07C17/00 , C07C67/00 , B01J11/78 , C07C5/20 , C07C11/04
CPC分类号： C07C17/357 , C07C5/44 , Y02P20/584 , C07C21/06 , C07C25/28
摘要： PROCESS FOR DEHYDROGENATING A FEED CONTAINING EITHER AN ALKANE, CYCLOALKANE, MONO-HALO SUBSTITUTED DERIVATIVE THEREOF, OR ALKYL SUBSTITUTED AROMATIC HYDROCARBON WHEREIN THE FEED IS CONTACTED WITH A MELT CONTAINING A MULTIVALENT METAL HALIDE IN BOTH ITS HIGHER AND LOWER VALENCE STATE, SUCH AS A MIXTURE OF CUPRIC AND CUPROUS CHLORIDE. IN ACCORDANCE WITH A PREFERRED EMBODIMENT, THE MELT IS PREVIOUSLY CONTACTED WITH AN OXYGEN CONTAINING GAS TO PRODUCE THE CORRESPONDING OXYHALIDE OF THE METAL, WHEREBY THE REACTION MAY BE EFFECTED ON A CONTINUOUS BASIS.

16. 发明授权

US3456622A Stack gas cleaning process 失效
标题翻译：堆积气清洗工艺
公开(公告)号：US3456622A
公开(公告)日：1969-07-22
申请号：US3456622D
申请日：1967-07-24
申请人： LUMMUS CO
发明人： THORNTON JAMES F , SZE MORGAN C
IPC分类号： B01D47/00 , F22B37/48 , C10K1/00 , F28G1/00
CPC分类号： B01D47/00

17. 发明授权

US3450784A Hydrogenation of benzene to cyclohexane 失效
公开(公告)号：US3450784A
公开(公告)日：1969-06-17
申请号：US3450784D
申请日：1966-09-22
申请人： LUMMUS CO
发明人： REILLY JAMES W , SZE MORGAN C
IPC分类号： B01J8/04 , C07C5/10 , C07C13/18
CPC分类号： B01J8/0453 , C07C5/10 , C07C2601/14 , Y10S585/91 , Y10S585/914 , C07C13/18

18. 发明授权

US3429804A Two-stage hydrotreating of dripolene 失效
标题翻译：二阶段加氢脱水
公开(公告)号：US3429804A
公开(公告)日：1969-02-25
申请号：US3429804D
申请日：1965-05-25
申请人： LUMMUS CO
发明人： SZE MORGAN C , BAUER WILLIAM V
IPC分类号： C10G45/32 , C10G65/06 , C07C3/42 , C07C5/16
CPC分类号： C10G65/06 , C10G45/32

19. 发明授权

US3929811A Production of pyridine nitriles and carboxylic acids 失效
标题翻译：生产吡啶腈和羧酸
公开(公告)号：US3929811A
公开(公告)日：1975-12-30
申请号：US46388274
申请日：1974-04-25
申请人： LUMMUS CO
发明人： GELBEIN ABRAHAM P , SZE MORGAN C , PAUSTIAN JOHN E
IPC分类号： C07D213/80 , B01J23/00 , B01J35/10 , B01J37/04 , C07B61/00 , C07D213/79 , C07D213/803 , C07D213/82 , C07D213/84
CPC分类号： C07D213/803 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J37/04 , C07D213/84
摘要： Mono-and di-lower alkyl substituted pyridines can be converted to pyridine nitriles by reaction with ammonia, in the substantial absence of free oxygen, and in the presence of a transition metal oxide catalyst. Intermediate products can be recycled to the nitrile production step. The nitrile can be converted to the carboxylic acid by; aqueous hydrolysis, in the presence of ammonia or ammonium salts, at temperatures between about 200*F and 450*F. Ammonia is stripped from the hydrolysis mixture by passing a stripping gas through the mixture. In a preferred embodiment, the hydrolysis and stripping are performed simultaneously and continuously, with the hydrolysis mixture and stripping gas moving countercurrently to each other.
摘要翻译：单 - 和二 - 低级烷基取代的吡啶可以通过与氨反应，在基本上不含游离氧的情况下，并且在过渡金属氧化物催化剂的存在下，转化成吡啶腈。中间产品可以回收到腈生产步骤。腈可以通过转化成羧酸; 在约200°F至450°F之间的温度下，在氨或铵盐存在下水解水解。通过使汽提气体通过混合物，从水解混合物中除去氨。在优选的实施方案中，水解和汽提气体相互逆流地进行水解和汽提，同时且连续地进行。

20. 发明授权

US3922147A Hydrolysis reactor 失效
标题翻译：水解反应器
公开(公告)号：US3922147A
公开(公告)日：1975-11-25
申请号：US45819974
申请日：1974-04-05
申请人： LUMMUS CO
发明人： SZE MORGAN C , LUBEROFF BENJAMIN J
IPC分类号： B01D3/38 , C07C51/08 , B01D47/12 , B01J10/00 , C07C63/26
CPC分类号： C07C51/08 , B01D3/38 , C07C63/26
摘要： Apparatus for hydrolysis of a phthalonitrile and stripping of ammonia from the reaction products comprising a vertical reactor divided by a substantially horizontal baffle into upper and lower reaction chambers, with a draft tube extending from the lower portion of the lower reaction chamber to the upper portion of the upper reaction chamber. The nitrile to be hydrolyzed, together with water is introduced into the lower chamber, and after reaching the lower portion of this chamber is forced upwards by autogenous pressure through the draft tube to the upper chamber, in which ammonia is stripped from the hydrolysis mixture by steam or other suitable inert gas.
摘要翻译：用于水解邻苯二甲腈和从反应产物中除去氨的装置，包括由基本上水平的挡板分隔成上反应室和下反应室的垂直反应器，其中引流管从下反应室的下部延伸到下反应室的上部上反应室。待水解的腈与水一起被引入下室，并且在达到该室的下部之后，通过自给压力将其通过引流管向上压到上部室，在上部室中，从水解混合物中除去氨蒸汽或其他合适的惰性气体。

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