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11. 发明申请

US20100298492A1 METHOD FOR PRODUCING AQUEOUS POLYMER DISPERSION 有权
标题翻译：生产水性聚合物分散体的方法
公开(公告)号：US20100298492A1
公开(公告)日：2010-11-25
申请号：US12303859
申请日：2007-06-19
申请人： Lambertus Manders , Ilshat Gubaydullin , Wolfgang Gaschler
发明人： Lambertus Manders , Ilshat Gubaydullin , Wolfgang Gaschler
IPC分类号： C08F2/16
CPC分类号： C08F6/003
摘要： A process for preparing an aqueous polymer dispersion using flush water.
摘要翻译：使用冲洗水制备聚合物水分散体的方法。

12. 发明申请

US20090270577A1 PRESSURE-SENSITIVE ADHESIVE COMPRISING A C10 ALKYL (METH)ACRYLATE 审中-公开
标题翻译：包含C10烷基（甲基）丙烯酸酯的压敏粘合剂
公开(公告)号：US20090270577A1
公开(公告)日：2009-10-29
申请号：US12441536
申请日：2007-10-22
申请人： Cornelis Petrus Beyers , Wolfgang Gaschler , Dieter Urban
发明人： Cornelis Petrus Beyers , Wolfgang Gaschler , Dieter Urban
IPC分类号： C08F220/10
CPC分类号： C09J133/08 , C08F2220/1891 , C09J2201/606
摘要： A pressure-sensitive adhesive comprising a synthetic polymer binder, wherein the polymer has been synthesized from 10% to 100% by weight of a C10 alkyl (meth)acrylate and the alkyl group of the C10 alkyl (meth)acrylate has a propyl group as substituent (referred to subsequently as C10 alkyl (meth)acrylate).
摘要翻译：一种包含合成聚合物粘合剂的压敏粘合剂，其中聚合物已经由10重量％至100重量％的（甲基）丙烯酸烷基酯合成，并且（甲基）丙烯酸C10烷基的烷基具有丙基作为取代基（以下称为（甲基）丙烯酸C10烷基酯）。

13. 发明申请

US20080153974A1 Process for Preparing an Aqueous Addition-Polymer Dispersion 审中-公开
标题翻译：制备水性加成聚合物分散体的方法
公开(公告)号：US20080153974A1
公开(公告)日：2008-06-26
申请号：US11816028
申请日：2006-02-23
申请人： Wolfgang Gaschler , Thomas Danner , Andreas Bauder , Steffen Funkhauser , Christoph Hamers
发明人： Wolfgang Gaschler , Thomas Danner , Andreas Bauder , Steffen Funkhauser , Christoph Hamers
IPC分类号： C08L31/04 , C08L33/08 , C08L33/10 , C08L25/04 , C08L27/08 , C08L23/18 , C08L27/06
CPC分类号： C08F2/16 , B01F3/0811 , B01F5/0682 , B01F5/0691 , C08F2/24
摘要： A process for preparing an aqueous polymer dispersion by free-radically initiated emulsion polymerization using an aqueous monomer miniemulsion which is obtained by passing an aqueous crude monomer emulsion through at least one microporous membrane having an average pore diameter≦1000 nm.
摘要翻译：一种通过使用水性单体细乳液通过自由基引发的乳液聚合制备水性聚合物分散体的方法，其通过使粗水单体乳液通过至少一个平均孔径<= 1000nm的微孔膜获得。

14. 发明授权

US09296957B2 Use of hyperbranched polyesters and/or polyester amides for separating oil-in-water emulsions 有权
标题翻译：使用超支化聚酯和/或聚酯酰胺分离水包油乳液
公开(公告)号：US09296957B2
公开(公告)日：2016-03-29
申请号：US12682019
申请日：2008-10-02
申请人： Bernd Bruchmann , Andreas Eichhorn , Marcus Guzmann , Wolfgang Gaschler
发明人： Bernd Bruchmann , Andreas Eichhorn , Marcus Guzmann , Wolfgang Gaschler
IPC分类号： C08G63/02 , C08G63/42 , C08G63/668 , C10G33/04 , B01D17/04 , B01D17/00 , C08G69/44 , C08G83/00
CPC分类号： C10G33/04 , B01D17/047 , B01D17/10 , C08G63/668 , C08G69/44 , C08G83/005
摘要： A nondendrimeric hyperbranched polyester and/or polyesteramide which comprise alkenyl-substituted succinic acid units as demulsifiers for splitting oil-water emulsions, especially crude oil emulsions. In particular, the succinic acid is substituted with alkenyl groups containing 16 to 20 carbon atoms. Also, nondendrimeric hyperbranched polyesters or polyesteramides which comprise alkenyl-substituted succinic acid units, wherein the alkenyl group has from 16 to 20 carbon atoms. In addition to the alkenyl-substituted succinic acid units, the nondendrimeric hyperbranched polyester contains, as further units, at least trifunctional alcohols having been alkoxylated with an average of from 3 to 12 ethylene oxide units.
摘要翻译：包含链烯基取代的琥珀酸单元作为用于分裂油水乳液的破乳剂的非分支超支化聚酯和/或聚酯酰胺，特别是原油乳液。特别地，琥珀酸被含有16〜20个碳原子的烯基取代。另外，包含烯基取代的琥珀酸单元的非支链多支链聚酯或聚酯酰胺，其中烯基具有16至20个碳原子。除了链烯基取代的琥珀酸单元之外，非离聚超支化聚酯还含有至少三官能醇，其平均具有3-12个环氧乙烷单元被烷氧基化。

15. 发明申请

US20110247746A1 USE OF SYNTHETIC ADHESIVES IN THE MANUFACTURE OF CORRUGATED FIBERBOARD 有权
标题翻译：合成胶粘剂在腐蚀性纤维板的制造中的应用
公开(公告)号：US20110247746A1
公开(公告)日：2011-10-13
申请号：US13083028
申请日：2011-04-08
申请人： Karl-Heinz SCHUMACHER , Gledison Fonseca , Rabie Al-Hellani , Wolfgang Gaschler , Ellen Krüger , Andrea Herold , Hildegard Stein , Oliver Hartz , Hubertus Kröner
发明人： Karl-Heinz SCHUMACHER , Gledison Fonseca , Rabie Al-Hellani , Wolfgang Gaschler , Ellen Krüger , Andrea Herold , Hildegard Stein , Oliver Hartz , Hubertus Kröner
IPC分类号： B31F1/20 , B32B37/12
CPC分类号： B31F1/2809 , B29C53/22 , C08F212/08 , C08F220/06 , C08F222/04 , C09D103/02 , C09J125/14 , D21H17/36 , D21H17/37 , D21H27/10 , Y10T156/1016 , Y10T156/1025 , C08L35/06 , C08F2220/1825 , C08F218/08 , C08F2220/1891 , C08F222/02 , C08F236/10 , C08F2/38 , C08F2/22
摘要： Described is the use of synthetic adhesives in the manufacture of corrugated fiberboard at relatively low temperatures and high lineal speeds. The corrugated fiberboard includes a corrugated sheet of paper and a flat linerboard and the corrugation of the corrugated sheet of paper is produced at paper temperatures below 95° C. and at a lineal speed above 150 m/min. The production of the corrugation of a corrugated sheet of paper is immediately followed by a continuous operation in which a preferably unheated corrugated board adhesive is applied and the corrugated sheet of paper is adhered to at least one first linerboard. The corrugated board adhesive used is an aqueous adhesive dispersion based on at least one synthetic, dispersed polymer having preferably more than 40% by weight solids content, selected from acrylate copolymers, copolymers of vinylaromatics and conjugated aliphatic dienes and vinyl acetate-alkylene copolymers, wherein the glass transition temperatures of the polymers are above 20° C. and (preferably at least 5° C.) below the surface temperature of the corrugated sheet of paper to which they are applied.
摘要翻译：描述了在相对低的温度和较高的线速下制造瓦楞纸板的合成粘合剂的用途。瓦楞纸板包括波纹纸和平板纸板，波纹纸的波纹在低于95℃的纸张温度下以高于150米/分的线速度产生。波纹纸的波纹的生产紧随其后是连续操作，其中施加优选不加热的波纹板粘合剂，并且波纹纸粘附到至少一个第一衬板。使用的波纹板粘合剂是基于至少一种合成的分散聚合物的水性粘合剂分散体，其具有优选大于40重量％的固体含量，选自丙烯酸酯共聚物，乙烯基芳族化合物和共轭脂族二烯的共聚物和乙酸乙烯酯 - 亚烷基共聚物，其中聚合物的玻璃化转变温度高于其应用它们的波纹纸的表面温度的20℃以下（优选至少5℃）。

16. 发明授权

US07332565B2 Method for the reduction of the residual monomer content in aqueous polymer dispersions 失效
标题翻译：降低水性聚合物分散体中残留单体含量的方法
公开(公告)号：US07332565B2
公开(公告)日：2008-02-19
申请号：US10552994
申请日：2004-04-13
申请人： Mubarik Mahmood Chowdhry , Wolfgang Gaschler
发明人： Mubarik Mahmood Chowdhry , Wolfgang Gaschler
IPC分类号： C08F6/00
CPC分类号： C08F6/006
摘要： A method for reducing the amount of residual monomer in aqueous polymer dispersions by aftertreatment with an initiator system comprises aftertreating the aqueous polymer dispersion with addition of an initiator system essentially comprising a) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of an inorganic salt of persulfuric acid, b) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of a methyl ketone, and c) optionally, catalytic amounts of a metal ion which is able to exist in a plurality of valence states.
摘要翻译：通过用引发剂体系进行后处理来减少聚合物水分散体中的残余单体的量的方法包括：通过加入引发剂体系对聚合物水分散体进行后处理，该引发剂体系基本上包含a）基于所用总单体量的0.001至5重量％制备聚合物分散体，过硫酸的无机盐，b）基于用于制备聚合物分散体的总单体量为0.005-5重量％的甲基酮，和c）任选的催化量的能够以多个价态存在的金属离子。

17. 发明授权

US07282545B2 Method for producing aqueous styrene-butadiene polymer dispersions III 有权
标题翻译：制备苯乙烯 - 丁二烯聚合物水分散体的方法III
公开(公告)号：US07282545B2
公开(公告)日：2007-10-16
申请号：US10491283
申请日：2002-09-30
申请人： Wolfgang Gaschler , Volker Schaedler , Lambertus Manders , Thomas Wirth , Hubertus Kroener
发明人： Wolfgang Gaschler , Volker Schaedler , Lambertus Manders , Thomas Wirth , Hubertus Kroener
IPC分类号： C08F2/22 , C08F2/24 , C08F2/38
CPC分类号： C08F212/08 , C08F236/10 , C08F2/22
摘要： A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms, which is selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from α-methylstyrene dimer comprises including at least 30% of the hydrocarbon HC in the initial charge to the polymerization vessel and supplying the remainder of the hydrocarbon HC to the polymerization reaction in the course of that reaction.
摘要翻译：一种通过自由基水性乳液聚合制备含40至80重量％苯乙烯作为单体M1的单体混合物M，20至60重量％的作为单体M2的丁二烯的丁二烯聚合物水分散体的方法，和0至40重量％，基于100重量％的单体，除了苯乙烯和丁二烯之外的烯键式不饱和共聚单体M3，通过单体进料技术，在0.05至0.5重量％的存在下，基于100重量％至少一种具有6至20个碳原子的烃HC的重量，其选自从氢原子形成戊二烯基或1-苯基烯丙基和由α-甲基苯乙烯二聚体构成的化合物包括至少30 在初始加入到聚合容器中的烃HC的％，并且在该反应过程中将剩余的烃HC供应到聚合反应中。

18. 发明授权

US07196146B2 Method for producing aqueous styrene-butadiene polymer dispersions II 失效
标题翻译：制备苯乙烯 - 丁二烯聚合物水分散体的方法II
公开(公告)号：US07196146B2
公开(公告)日：2007-03-27
申请号：US10491336
申请日：2002-09-30
申请人： Lambertus Manders , Thomas Wirth , Wolfgang Gaschler , Hubertus Kroener
发明人： Lambertus Manders , Thomas Wirth , Wolfgang Gaschler , Hubertus Kroener
IPC分类号： C08F2/22 , C08F236/10
CPC分类号： C08F236/10 , C08F2/22
摘要： A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC having 6 to 20 carbon atoms selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and α-methylstyrene dimer comprises raising, at a point in time when at least 70% of the monomers to be polymerized have been supplied to the polymerization reaction, the concentration of butadiene in the monomer feed for a period of at least 1% of the total feed time by at least 10% by weight, based on monomers in the feed.
摘要翻译：一种通过自由基水性乳液聚合制备含40至80重量％苯乙烯作为单体M1的单体混合物M，20至60重量％的作为单体M2的丁二烯的丁二烯聚合物水分散体的方法，和0至40重量％，基于100重量％的单体，除了苯乙烯和丁二烯之外的烯键式不饱和共聚单体M3，通过单体进料技术，在0.05至0.5重量％的存在下，基于100重量％至少一种选自氢原子取代氢原子形成戊二烯基或1-苯基烯丙基和α-甲基苯乙烯二聚体的化合物的至少一种具有6至20个碳原子的烃HC的单体重量包括在至少70％的待聚合的单体已经被供应到聚合反应中，单体进料中丁二烯的浓度至少为总进料时间的1％，至少为10重量％，基于m 饲料中的异构体。

19. 发明申请

US20060058478A1 Method for radical polymerisation in the presence of a chain transfer agent 失效
标题翻译：在链转移剂存在下自由基聚合的方法
公开(公告)号：US20060058478A1
公开(公告)日：2006-03-16
申请号：US10534388
申请日：2003-12-01
申请人： Wolfgang Gaschler
发明人： Wolfgang Gaschler
IPC分类号： C08F4/04
CPC分类号： C08F2/38
摘要： Process for free-radical polymerization in the presence of a regulator which, following free-radical H-abstraction to form an aromatic system, eliminates a free-radical leaving group which starts a new free-radical chain.
摘要翻译：在自由基H取代形成芳族体系的调节剂存在下进行自由基聚合的过程消除了开始新的自由基链的自由基离去基团。

20. 发明授权

US09650745B2 Oil-in-water emulsions 有权
公开(公告)号：US09650745B2
公开(公告)日：2017-05-16
申请号：US14116577
申请日：2012-05-09
申请人： Claudius Kormann , Wolfgang Gaschler , Christian Holtze
发明人： Claudius Kormann , Wolfgang Gaschler , Christian Holtze
IPC分类号： B01D19/04 , D21H21/12 , D21C3/28
CPC分类号： D21H21/12 , B01D19/0404 , D21C3/28
摘要： The invention relates to oil-in-water emulsions based on fatty alcohols and mono- or diesters of glycerol and the use thereof as antifoams or deaerators for aqueous compositions. The oil phase of the emulsions according to the invention consists to at least 95% by weight of the following constituents: a) 40 to 95% by weight, based on the total weight of the oil phase, of a mixture of at least two alcohols as component A, consisting of: a1) at least one alkanol having 12 to 30 carbon atoms as component A1, a2) at least one mono- or diester of glycerol with at least one fatty acid having 14 to 24 carbon atoms as component A2; b) 0.1 to 10% by weight, based on the total weight of the oil phase, of at least one further component B, which is selected from esters of C12-C36-alkanecarboxylic acids with polyglycerol, amides of C12-C36-alkanecarboxylic acids with alkylenediamines or oligoalkyleneamines, and esters of C12-C36-alkanecarboxylic acids with C12-C36-alkanols, and mixtures thereof, c) 4.9 to 50% by weight, based on the total weight of the oil phase, of at least one further component C, which is selected from organic substances which are liquid at 50° C. and 1013 mbar, at atmospheric pressure have a boiling point above 200° C., and at 25° C. and 1013 mbar have a solubility in water of less than 0.1 g/l.

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