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11. 发明授权

US5473020A Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use 失效
标题翻译：聚合物结合的配体，聚合物结合的金属茂，催化剂体系，制备和用途
公开(公告)号：US5473020A
公开(公告)日：1995-12-05
申请号：US268425
申请日：1994-06-30
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00 , C08F8/40
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

12. 发明授权

US5492975A Polymer bound metallocenes 失效
标题翻译：聚合物结合金属茂
公开(公告)号：US5492975A
公开(公告)日：1996-02-20
申请号：US455382
申请日：1995-05-31
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

13. 发明授权

US5492973A Polymer bound ligands 失效
标题翻译：聚合物结合的配体
公开(公告)号：US5492973A
公开(公告)日：1996-02-20
申请号：US454764
申请日：1995-05-31
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

14. 发明授权

US6124414A Fluorenyl-containing polymeric metallocene catalyst systems 失效
标题翻译：含芴基聚合金属茂催化剂体系
公开(公告)号：US6124414A
公开(公告)日：2000-09-26
申请号：US48395
申请日：1998-03-26
申请人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
发明人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： A catalyst system comprising an organoaluminoxane cocatalyst and a polymeric fluorenyl-containing metallocene prepared from a polymer resulting from the polymerization of a 2-vinylfluorene compound or the alkylation of a fluorene compound.
摘要翻译：一种包含有机铝氧烷助催化剂和由由2-乙烯基芴化合物聚合得到的聚合物或芴化合物的烷基化制备的聚合芴基茂金属的催化剂体系。

15. 发明授权

US6057410A Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use 失效
公开(公告)号：US6057410A
公开(公告)日：2000-05-02
申请号：US48392
申请日：1998-03-26
申请人： Helmut G. Alt , Peter Schertl , Bernd Peifer , Syriac J. Palackal , M. Bruce Welch
发明人： Helmut G. Alt , Peter Schertl , Bernd Peifer , Syriac J. Palackal , M. Bruce Welch
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04 , C08F32/08 , C08F30/08 , C08F30/10
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： Polymeric ligands, polymeric metallocenes, and processes for preparing same are provided. The process for preparing polymeric metallocenes comprises reacting a polymeric ligand, a transition metal compound, and an alkali metal compound. In one embodiment, a process for preparing polymeric ligands comprises reacting at least one bridged cyclopentadienyl-type monomer and an initiator under polymerization conditions. In another embodiment, a polymeric ligand is represented by the formula [Q'].sub.n, wherein Q' is a unit containing at least one bridged cyclopentadienyl-type group and wherein n is 1-5000. In another embodiment, a polymeric metallocene is represented by the formula [Q"MX.sub.m ].sub.n, wherein Q" is a unit containing at least one fluorenyl-type group, M is a transition metal, each X is individually a hydrocarbyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 12 carbon atoms, an aryloxy group containing 6 to 20 carbon atoms, a halide, or hydride, m is 2 or 3, and wherein n is 1-5000. Other aspects of the present invention include a catalyst system comprising the polymeric metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.

16. 发明授权

US6040402A Polymeric ligands, polymeric metallocenes, catalyst systems, preparation, and use 失效
标题翻译：聚合物配体，聚合金属茂，催化剂体系，制备和用途
公开(公告)号：US6040402A
公开(公告)日：2000-03-21
申请号：US48390
申请日：1998-03-26
申请人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
发明人： Bernd Peifer , Syriac J. Palackal , M. Bruce Welch , Helmut G. Alt , Peter Schertl
IPC分类号： C07C13/00 , C07F17/00 , C08F4/44 , C08F4/639 , C08F4/64 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F30/04 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C07F17/00 , C08F4/63912 , C08F4/65925 , Y10S526/943
摘要： A polymerization process comprising contacting at least one olefin under polymerization conditions with a catalyst composition produced by combining an organoaluminoxane cocatalyst and a polymeric metallocene catalyst prepared by (1) forming a fluorine-containing polymer by (a) polymerizing a 2-vinyl fluorenyl compound or (b) polymerizing a fluorenyl compound by reacting it with chloro methyl methyl ether in the presence of zinc dichloride or aluminum trichloride; (2) reacting the fluorenyl-containing polymer with an alkali metal compound; and (3) reacting the product of step (2) with a transition metal-containing compound.
摘要翻译：一种聚合方法，包括使聚合条件下的至少一种烯烃与通过组合有机铝氧烷助催化剂和通过（1）通过（a）聚合2-乙烯基芴基化合物或（a）形成含氟聚合物而制备的聚合金属茂催化剂制备的催化剂组合物接触，（b）在二氯化锌或三氯化铝的存在下使芴基化合物与氯甲基甲基醚反应; （2）使含芴基的聚合物与碱金属化合物反应; 和（3）使步骤（2）的产物与含过渡金属的化合物反应。

17. 发明授权

US5492978A Process for preparing catalyst system 失效
标题翻译：制备催化剂体系的方法
公开(公告)号：US5492978A
公开(公告)日：1996-02-20
申请号：US455488
申请日：1995-05-31
申请人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , M. Bruce Welch , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

18. 发明授权

US5492985A Polymerization processes 失效
标题翻译：聚合工艺
公开(公告)号：US5492985A
公开(公告)日：1996-02-20
申请号：US455306
申请日：1995-05-31
申请人： Bernd Peifer , Helmut G. Alt , Syriac J. Palackal
发明人： Bernd Peifer , Helmut G. Alt , Syriac J. Palackal
IPC分类号： C08F4/642 , C07F17/00 , C08F4/58 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/646 , C08F4/656 , C08F4/657 , C08F4/685 , C08F8/00 , C08F8/42 , C08F10/00
CPC分类号： C08F8/42 , C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922
摘要： A polymer bound ligand represented by the formula QM(R).sub.m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R).sub.m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R).sub.m ZY.sub.n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyciopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.
摘要翻译：提供由式QM（R）m表示的聚合物结合配体及其制备方法，其中Q是聚苯乙烯，M是Si，C，Ge，Sn，P或N，每个R是至少一个 R是环戊二烯基型化合物，m为2或3，所述方法包括使金属化聚苯乙烯和有机卤化物化合物反应，其中聚苯乙烯用碱金属进行金属化，其中所述有机卤化物由式XM（R ）m，其中X是卤化物。本发明的其它方面包括由式QM（R）mZYn表示的聚合物结合金属茂及其制备方法，其中Z为过渡金属，Y为卤化物，甲基，氢或环戊二烯基型基团，并且n为2或3.本发明的其它方面包括包含聚合物结合的茂金属和有机铝氧烷的催化剂体系，其制备方法和使用该催化剂体系的聚合方法。

19. 发明授权

US5744666A Process for preparing an alkynyl fulvene group containing compound and said compound 失效
标题翻译：制备含炔基富烯基的化合物和所述化合物的方法
公开(公告)号：US5744666A
公开(公告)日：1998-04-28
申请号：US760886
申请日：1996-12-06
申请人： M. Bruce Welch , Bernd Peifer , Helmut G. Alt
发明人： M. Bruce Welch , Bernd Peifer , Helmut G. Alt
IPC分类号： B01J31/22 , C07F17/00 , C08F4/639 , C08F4/6392 , C08F10/00 , C08F110/02 , C07C13/00 , C07C13/465 , C07C15/12 , C07C45/00
CPC分类号： B01J31/1616 , B01J31/143 , B01J31/2295 , C07F17/00 , C08F10/00 , B01J21/08 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F110/02 , C08F4/63912 , C08F4/63916 , C08F4/6392 , Y10S526/943 , Y10S585/922
摘要： A process for preparing an alkynyl fulvene group containing compound and said compound is provided. Said process comprises reacting an alkynyl ketone compound with a cyclopentadienyl-type compound.
摘要翻译：提供了制备含炔基富烯基的化合物和所述化合物的方法。所述方法包括使炔基酮化合物与环戊二烯基型化合物反应。

20. 发明授权

US5631203A Metallocene compounds and preparation thereof containing terminal alkynes 失效
标题翻译：茂金属化合物及其含有末端炔烃的制备方法
公开(公告)号：US5631203A
公开(公告)日：1997-05-20
申请号：US434807
申请日：1995-05-04
申请人： M. Bruce Welch , Helmut G. Alt , Bernd Peifer
发明人： M. Bruce Welch , Helmut G. Alt , Bernd Peifer
IPC分类号： B01J31/22 , C07F17/00 , C08F4/639 , C08F4/6392 , C08F10/00 , C08F110/02 , B01J31/00 , C07F9/00 , C08F4/02 , C08F30/04
CPC分类号： B01J31/1616 , B01J31/143 , B01J31/2295 , C07F17/00 , C08F10/00 , B01J21/08 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , C08F110/02 , C08F4/63912 , C08F4/63916 , C08F4/6392 , Y10S526/943 , Y10S585/922
摘要： Metallocene compounds and processes for preparing such metallocene compounds are provided. Such processes for preparing such metallocene compounds comprise reacting an alkynyl ligand, an alkali metal compound, and a transition metal-containing compound.
摘要翻译：提供茂金属化合物和制备这种金属茂化合物的方法。制备这种金属茂化合物的这种方法包括使炔基配体，碱金属化合物和含过渡金属的化合物反应。

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