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11. 发明申请

US20070112135A1 Polymer mixture and the utilization thereof for injection molded parts 有权
标题翻译：聚合物混合物及其注塑部件的应用
公开(公告)号：US20070112135A1
公开(公告)日：2007-05-17
申请号：US10575477
申请日：2004-09-01
申请人： Michael Wicker , Klaus Schultes , Klaus Albrecht , Werner Hoess , Mona Rueppel , Eric Reinheimer , Wolfgang Fuchs , Tony Halblaender
发明人： Michael Wicker , Klaus Schultes , Klaus Albrecht , Werner Hoess , Mona Rueppel , Eric Reinheimer , Wolfgang Fuchs , Tony Halblaender
IPC分类号： C08L67/02
CPC分类号： C08L33/062 , B29C45/0001 , B29K2033/08 , B29L2031/3005 , C08L35/00 , C08L51/003 , C08L2666/04
摘要： The invention relates to a polymer mixture based on the (meth)acrylate (co)polymer components a), b), c), and/or d) according to claim 1, where a test specimen produced from the polymer mixture simultaneously has the following properties: I. a tensile modulus (ISO 527) of at least 2600 MPa, II. a Vicat softening point VSP (ISO 306-B50) of at least 109° C., III. an impact strength (ISO 179-2D, flatwise) of at least 17 kJ/m2, and IV. a melt index MVR (ISO 1133, 230° C./3.8 kg) of at least 1.5 cm3/10 min. The invention further relates to injection mouldings and to the use of the polymer mixture for producing injection-moulded parts.
摘要翻译：本发明涉及基于根据权利要求1的（甲基）丙烯酸酯（共）聚合物组分a），b），c）和/或d）的聚合物混合物，其中由聚合物混合物同时制备的试样具有以下性质：I.至少2600MPa的拉伸模量（ISO 527），II。维卡软化点VSP（ISO 306-B50）至少为109℃，III。至少17kJ / m 2的冲击强度（ISO179-2D，平坦化），和IV。至少1.5cm 3 / 10min的熔体指数MVR（ISO 1133,230℃，3.8kg）。本发明还涉及注射成型品以及聚合物混合物用于生产注模部件的用途。

12. 发明授权

US07371795B2 Polymer mixture and the utilization thereof for injection molded parts 有权
标题翻译：聚合物混合物及其注塑部件的应用
公开(公告)号：US07371795B2
公开(公告)日：2008-05-13
申请号：US10575477
申请日：2004-09-01
申请人： Michael Wicker , Klaus Schultes , Klaus Albrecht , Werner Hoess , Mona Rueppel , Eric Reinheimer , Wolfgang Fuchs , Tony Halblaender
发明人： Michael Wicker , Klaus Schultes , Klaus Albrecht , Werner Hoess , Mona Rueppel , Eric Reinheimer , Wolfgang Fuchs , Tony Halblaender
IPC分类号： C08L33/00 , C08L33/08 , C08K5/00
CPC分类号： C08L33/062 , B29C45/0001 , B29K2033/08 , B29L2031/3005 , C08L35/00 , C08L51/003 , C08L2666/04
摘要： The invention relates to a polymer mixture based on the (meth)acrylate (co)polymer components a), b), c), and/or d) according to claim 1, where a test specimen produced from the polymer mixture simultaneously has the following properties: I. a tensile modulus (ISO 527) of at least 2600 MPa, II. a Vicat softening point VSP (ISO 306-B50) of at least 109° C., III. an impact strength (ISO 179-2D, flatwise) of at least 17 kJ/m2, and IV. a melt index MVR (ISO 1133, 230° C./3.8 kg) of at least 1.5 cm3/10 min. The invention further relates to injection mouldings and to the use of the polymer mixture for producing injection-moulded parts.
摘要翻译：本发明涉及基于根据权利要求1的（甲基）丙烯酸酯（共）聚合物组分a），b），c）和/或d）的聚合物混合物，其中由聚合物混合物同时制备的试样具有以下性质：I.至少2600MPa的拉伸模量（ISO 527），II。维卡软化点VSP（ISO 306-B50）至少为109℃，III。至少17kJ / m 2的冲击强度（ISO179-2D，平坦化），和IV。至少1.5cm 3 / 10min的熔体指数MVR（ISO 1133,230℃，3.8kg）。本发明还涉及注射成型品以及聚合物混合物用于生产注模部件的用途。

13. 发明授权

US06906142B2 Molding materials exhibiting an improved low-temperature impact resistance 失效
标题翻译：具有改善的耐低温冲击性的成型材料
公开(公告)号：US06906142B2
公开(公告)日：2005-06-14
申请号：US10415100
申请日：2001-10-22
申请人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
发明人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
IPC分类号： C08F265/04 , C08F285/00 , C08L25/12 , C08L33/08 , C08L33/12 , C08L51/00 , C08L51/08 , C08L55/02 , C08L33/04 , C08L33/18 , C08L33/20 , C08L35/02 , C08L43/00
CPC分类号： C08L51/003 , C08F265/04 , C08F285/00 , C08L25/12 , C08L33/08 , C08L33/12 , C08L51/08 , C08L51/085 , C08L55/02 , C08L2666/02 , C08L2666/04
摘要： The invention relates to an impact-modified moulding composition which has particularly high impact resistance at low temperatures (−20° C., −40° C.). This low-temperature impact resistance is achieved by using a silicone elastomer.
摘要翻译：本发明涉及在低温（-20℃，-40℃）下具有特别高的抗冲击性的冲击改性模塑组合物。这种低温耐冲击性通过使用有机硅弹性体来实现。

14. 发明授权

US06890993B2 PMMA molding materials exhibiting an improved low-temperature impact resistance 失效
标题翻译：具有改善的耐低温冲击性的PMMA成型材料
公开(公告)号：US06890993B2
公开(公告)日：2005-05-10
申请号：US10415106
申请日：2001-10-22
申请人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
发明人： Klaus Schultes , Michael Wicker , Werner Hoess , Klaus Albrecht , Hans-Juergen Kress
IPC分类号： C08L25/12 , C08L33/08 , C08L33/12 , C08L51/08 , C08L27/10 , C08L33/04 , C08L33/18 , C08L35/02 , C08L43/00
CPC分类号： C08L25/12 , C08L33/08 , C08L33/12 , C08L51/085 , C08L2666/02
摘要： The invention relates to an impact-modified molding composition which has particularly high impact resistance at low temperatures (−20° C., −40° C.). This low-temperature impact resistance is achieved by using a silicone elastomer.
摘要翻译：本发明涉及在低温（-20℃，-40℃）下具有特别高的抗冲击性的冲击改性模塑组合物。这种低温耐冲击性通过使用有机硅弹性体来实现。

15. 发明申请

US20070122624A1 Multilayered film made of (meth)acrylate copolymer and polycarbonate 有权
标题翻译：由（甲基）丙烯酸酯共聚物和聚碳酸酯制成的多层薄膜
公开(公告)号：US20070122624A1
公开(公告)日：2007-05-31
申请号：US10577954
申请日：2004-09-15
申请人： Klaus Schultes , Michael Wicker , Klaus Albrecht , Mona Rueppel , Gabriele Dassinger , Eric Reinheimer
发明人： Klaus Schultes , Michael Wicker , Klaus Albrecht , Mona Rueppel , Gabriele Dassinger , Eric Reinheimer
IPC分类号： B32B27/36
CPC分类号： B32B27/08 , B32B27/18 , B32B27/20 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2369/00 , C08L33/10 , C08L69/00 , Y10T428/249921 , Y10T428/31504 , Y10T428/31507 , Y10T428/31786 , C08L2666/04
摘要： The invention relates to a multilayered film comprising at least one upper layer a), a middle layer b) made of (meth)acrylate copolymer, and a supporting layer c) made of polycarbonate. Upper layer a) contains a light-stability agent and is made of a (meth)acrylate copolymer that, together with the polycarbonate of supporting layer c), can form partially compatible mixtures. A test piece, which is made from a mixture consisting of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate, has a breaking elongation (ISO 527-2) of at least 75% at 23° C. The middle layer b) contains a colorant and, optionally, a light-stability agent and is made from an identical or different (meth)acrylate copolymer that, together with the polycarbonate of supporting layer c), can form partially compatible mixtures. A test piece, which is made from a mixture consisting of 20% by weight of (meth)acrylate copolymer and 80% by weight of polycarbonate, has a breaking elongation (ISO 527-2) of at least 75% at 23° C., and the supporting layer c) is made of polycarbonate that, optionally up to 30% by weight of the material of the layers, can contain a) and b). The invention also relates to the production and uses of the multilayered film and to partially compatible polymer mixtures consisting of (meth)acrylate copolymer and polycarbonate.
摘要翻译：本发明涉及包含至少一个上层a），由（甲基）丙烯酸酯共聚物制成的中间层b）和由聚碳酸酯制成的支撑层c）的多层膜。上层a）含有光稳定剂，并且由（甲基）丙烯酸酯共聚物制成，其与支撑层c）的聚碳酸酯一起可以形成部分相容的混合物。由20重量％的（甲基）丙烯酸酯共聚物和80重量％的聚碳酸酯组成的混合物制成的试件在23℃具有至少75％的断裂伸长率（ISO 527-2）中间层b）包含着色剂和任选的光稳定剂，并且由相同或不同的（甲基）丙烯酸酯共聚物制成，其与支撑层c）的聚碳酸酯一起可以形成部分相容的混合物。由20重量％的（甲基）丙烯酸酯共聚物和80重量％的聚碳酸酯组成的混合物制成的试件在23℃具有至少75％的断裂伸长率（ISO 527-2），并且支撑层c）由聚碳酸酯制成，任选地，多至30重量％的层的材料可以含有a）和b）。本发明还涉及多层膜和由（甲基）丙烯酸酯共聚物和聚碳酸酯组成的部分相容的聚合物混合物的制备和用途。

16. 发明申请

US20050124761A1 Core-shell structured silicone rubber graft polymers, impact-resistant modified molding compounds and molded bodies and method for producing the same 审中-公开
标题翻译：核壳结构硅橡胶接枝聚合物，耐冲击改性模塑料及成型体及其制造方法
公开(公告)号：US20050124761A1
公开(公告)日：2005-06-09
申请号：US10501467
申请日：2003-01-14
申请人： Klaus Schultes , Reiner Mueller , Werner Hoess , Klaus Albrecht
发明人： Klaus Schultes , Reiner Mueller , Werner Hoess , Klaus Albrecht
IPC分类号： C08F283/12 , C08F285/00 , C08L25/12 , C08L33/06 , C08L51/08 , C08L83/04 , B32B27/08 , B32B27/14
CPC分类号： C08F285/00 , C08F283/12 , C08L25/12 , C08L51/085 , Y10T428/2989 , Y10T428/2995 , C08L2666/24
摘要： The invention relates to core-shell structured silicone rubber graft polymers that comprise a core a) from a silicium-organic polymer that corresponds to the general formula (R2SiO2/2)x.(RSiO3/2)y.(SiO4/2)z, wherein x=0 to 99.5 mole %, y=0.5 to 100 mole %, z=0 to 50 mole %, wherein R is the same or different and represents alkyl or alkenyl groups having 1 to 6 C atoms, aryl groups or substituted hydrocarbon groups and at last one shell c) from an organic polymer. The silicone rubber graft copolymers are obtained by producing the organic shell c) by radical polymerization at a temperature of not more than 65° C. and adding the initiator in at least two portions to the reaction vessel, with a further addition at least 2 minutes after start of the polymerization.
摘要翻译：本发明涉及核壳结构的硅橡胶接枝聚合物，其包含与通式（R2SiO2 / 2）x。（RSiO3 / 2）y。（SiO4 / 2）z相对应的硅 - 有机聚合物的芯a），其中x = 0〜99.5摩尔％，y = 0.5〜100摩尔％，z = 0〜50摩尔％，其中R相同或不同，表示具有1〜6个碳原子的烷基或烯基，芳基或取代烃基和最后一个壳c）来自有机聚合物。硅橡胶接枝共聚物通过在不高于65℃的温度下通过自由基聚合制备有机壳c）而获得，并将引发剂在至少两份中加入到反应容器中，再加入至少2分钟开始聚合后。

17. 发明申请

US20060175735A1 Method for the production of light-diffusing moulded items with excellent optical characteristics 有权
标题翻译：用于生产具有优异光学特性的光漫射模制品的方法
公开(公告)号：US20060175735A1
公开(公告)日：2006-08-10
申请号：US10546241
申请日：2004-03-02
申请人： Werner Hoess , Arne Schmidt , Klaus Albrecht , Klaus Schultes
发明人： Werner Hoess , Arne Schmidt , Klaus Albrecht , Klaus Schultes
IPC分类号： C08K7/16 , B29C45/00
CPC分类号： B29C70/585 , B29C45/0013 , B29K2033/12 , C08K7/16 , C08L25/04 , C08L33/10 , C08L83/00 , C08L2205/22 , C08L2666/02
摘要： The invention relates to an injection moulding method for the production of a complex, high optical quality light-diffusing moulded item. The moulding material used comprises a matrix made of polymethyl(meth)acrylate and spherical plastic particles whose particle size ranges from 1-24 μm and the concentration thereof ranges from 0.05-30 wt.-% in relation to the weight of the polymethyl(meth)acrylate. The spherical particles exhibit a refractive index differential in relation to the polymethyl(meth)acrylate matrix of 0.01 0.2.
摘要翻译：本发明涉及一种用于生产复杂的高光学质量的光漫射模制品的注塑方法。使用的成型材料包括由聚甲基（甲基）丙烯酸甲酯和粒径为1-24μm的球形塑料颗粒制成的基质，其浓度相对于聚甲基（甲基）丙烯酸酯的重量为0.05-30重量％）丙烯酸酯。球形颗粒表现出相对于0.01±0.2的聚甲基（甲基）丙烯酸酯基质的折射率差。

18. 发明申请

US20060147714A1 Core and shell particle for modifying impact resistance of a mouldable poly (meth) acrylate material 失效
标题翻译：用于改善可塑聚（甲基）丙烯酸酯材料的耐冲击性的核和壳颗粒
公开(公告)号：US20060147714A1
公开(公告)日：2006-07-06
申请号：US10539509
申请日：2003-10-18
申请人： Klaus Schultes , Reiner Mueller , Andreas Spiess , Klaus Albrecht , Werner Hoess
发明人： Klaus Schultes , Reiner Mueller , Andreas Spiess , Klaus Albrecht , Werner Hoess
IPC分类号： B32B1/00
CPC分类号： C08L51/003 , C08F265/04 , C08F285/00 , C08L33/12 , C08L33/20 , C08L35/06 , C08L51/04 , C08L55/005 , C08L55/02 , Y10T428/2998 , C08L2666/02 , C08L2666/24
摘要： The present invention relates to a core-shell particle which has a core, a first shell and, where appropriate, a second shell, where: i) the core encompasses, based on its total weight, at least 75.0% by weight of (meth)acrylate repeat units; ii) the first shell has a glass transition temperature below 30° C.; iii) the second shell present where appropriate encompassed, based on its total weight, at lest 75.0% by weight of (meth)acrylate repeat units; iv) the first shell encompasses, based on its total weight, the following constituents; E) from 92.0 to 98.0% by weight of (meth)acrylate repeat units and F) from 2.0 to 8.0% by weight of styrenic repeat units of the general formula (I) where the radicals R1 to R6 are defined according to the Description and the percentages by weight of E) and F) give a total of 100.0% by weight, v) the radius of the core-shell particle inclusive of any second shell present, measured by the Coulter method, is in the range from above 160.0 to 240.0 nm. The present invention further relates to a process for preparing core-shell particles, to a moulding composition comprising core-shell particles, and to the use thereof.
摘要翻译：本发明涉及一种具有芯，第一壳和适当的第二壳的核 - 壳颗粒，其中：i）芯基于其总重量包含至少75.0重量％的（甲基））丙烯酸酯重复单元; ii）第一壳的玻璃化转变温度低于30℃; iii）适当地包含的第二壳基于其总重量至少为75.0重量％的（甲基）丙烯酸酯重复单元; iv）第一壳基于其总重量包含以下组分; E）为92.0〜98.0重量％的（甲基）丙烯酸酯重复单元，F）2.0〜8.0重量％的通式（I）的苯乙烯重复单元，其中R 1〜根据描述定义R 6，并且E）和F）的重量百分比总计为100.0重量％，v）包含任何第二壳的核 - 壳颗粒的半径存在，通过库尔特法测量，在160.0至240.0nm之间的范围内。本发明还涉及一种制备核 - 壳颗粒的方法，涉及包含核 - 壳颗粒的模塑组合物及其用途。

19. 发明授权

US09067389B2 Transparent plastic composite 有权
标题翻译：透明塑料复合材料
公开(公告)号：US09067389B2
公开(公告)日：2015-06-30
申请号：US12300408
申请日：2007-03-14
申请人： Werner Hoess , Michael Zietek , Michael Enders , Christian Eberle , Sven Schroebel , Klaus Albrecht , Rudolf Blass , Klaus Schultes , Arne Schmidt
发明人： Werner Hoess , Michael Zietek , Michael Enders , Christian Eberle , Sven Schroebel , Klaus Albrecht , Rudolf Blass , Klaus Schultes , Arne Schmidt
IPC分类号： B32B27/18 , B32B27/40 , B32B27/30
CPC分类号： B32B27/18 , B32B27/30 , B32B27/308 , B32B27/40 , Y10T428/31576
摘要： The invention describes a transparent plastics composite composed of PMMA and TPU with excellent mechanical properties.
摘要翻译：本发明描述了由具有优异机械性能的PMMA和TPU组成的透明塑料复合材料。

20. 发明申请

US20110015317A1 POLY(METH)ACRYLIMIDE HAVING IMPROVED OPTICAL AND COLOR PROPERTIES, PARTICULARLY UNDER THERMAL LOAD 有权
标题翻译：具有改进的光学和颜色特性的聚（甲基）丙烯酰亚胺，特别是在热负载下
公开(公告)号：US20110015317A1
公开(公告)日：2011-01-20
申请号：US12922627
申请日：2009-02-27
申请人： Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
发明人： Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
IPC分类号： C08K5/5313
CPC分类号： C08K5/5313 , C08L33/24
摘要： Process for preparing moulding materials MM with improved optical and colour properties, consisting of a polymer PM which contains units of the formula I in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder, in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for colour stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups. Shaped bodies obtainable by the process, especially light waveguides, have a low tendency to yellowing under thermal stress, coupled with a low haze, and also a stable and high transparency.
摘要翻译：用于制备具有改进的光学和颜色特性的成型材料MM的方法由包含式I的单元的聚合物PM组成，其中R 1和R 2各自为氢，甲基和R 3为氢，C 1 -C 18烷基，C 5 -C 8 - 环烷基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳基-C 1 -C 4 - 烷基，其中这些基团可以被三取代的基团选自C1-C4-烷氧基和卤素，在酰亚胺化反应中制备已知本身在反应性挤出机中，其中在完成酰亚胺化反应时，将一种或多种对颜色稳定有效的还原磷化合物P的量加入到聚合物PM中，其特征在于磷化合物是有机磷化合物 OP选自由式II的化合物组成的组，其中R 4和R 5各自独立地为氢或可被C 1 -C 4 - 烷基和/或C 5 -C 8 - 环烷基直接五取代的芳香族6元环。通过该方法可获得的成形体，特别是光波导，在热应力下具有低的黄变倾向，并伴有低雾度，并且还具有稳定和高透明度。

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