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11. 发明授权

US06733922B2 Carbonaceous material and lithium secondary batteries comprising same 有权
标题翻译：含碳材料和包含其的锂二次电池
公开(公告)号：US06733922B2
公开(公告)日：2004-05-11
申请号：US10087247
申请日：2002-03-01
申请人： Keiko Matsubara , Toshiaki Tsuno , Kyou-Yoon Sheem
发明人： Keiko Matsubara , Toshiaki Tsuno , Kyou-Yoon Sheem
IPC分类号： H01M458
CPC分类号： H01M4/40 , H01M4/362 , H01M4/366 , H01M4/405 , H01M4/587 , Y10T428/29 , Y10T428/2918 , Y10T428/30
摘要： Disclosed is a carbonaceous material comprising a graphite particle having a 002 plane interval d002 of less than 0.337 nm as measured by the X-ray wide angle diffraction method; a complex particle disposed and distributed in the vicinity of the surface of the graphite particle, the complex particle comprising silicon and carbon and having a particle size smaller than that of the graphite particle; and an amorphous carbon layer with a plane interval d002 of more than 0.37 nm, the amorphous carbon layer being a polymer layer and being coated on the graphite particle and the complex particle, wherein the complex particle comprises a Si particulate, a conductive carbon material disposed and distributed in the vicinity of the surface of the Si particulate, and a rigid carbon material layer coated on the Si particulate and the conductive carbon material, the Si particulate being composed of a crystalline Si phase. The carbonaceous material has a high harge-discharge capacity and improved cycle-life characteristics.
摘要翻译：公开了一种含有通过X射线广角衍射法测定的具有小于0.337nm的002平面间隔d 002的石墨颗粒的碳质材料; 配置并分布在石墨颗粒表面附近的复合颗粒，所述复合颗粒包含硅和碳，并且具有比石墨颗粒小的粒度; 以及平面间隔d002大于0.37nm的无定形碳层，所述无定形碳层为聚合物层并被涂覆在所述石墨颗粒和所述复合颗粒上，其中所述复合颗粒包含Si颗粒，所述导电碳材料设置并分布在Si颗粒的表面附近，以及涂覆在Si颗粒和导电碳材料上的刚性碳材料层，Si颗粒由晶体Si相组成。含碳材料具有高的排气能力和循环寿命特性。

12. 发明授权

US07326497B2 Graphite-containing composition, negative electrode for a lithium secondary battery, and lithium secondary battery 有权
标题翻译：含有石墨的组合物，锂二次电池用负极和锂二次电池
公开(公告)号：US07326497B2
公开(公告)日：2008-02-05
申请号：US10327752
申请日：2002-12-23
申请人： Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku , Kyou-Yoon Sheem
发明人： Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku , Kyou-Yoon Sheem
IPC分类号： H01M4/58 , H01M4/88 , H01M4/00
CPC分类号： H01M4/583 , H01B1/24 , H01M4/133 , H01M4/1393 , H01M4/625 , H01M10/0525 , Y10T29/49108 , Y10T29/49115
摘要： Disclosed is a negative electrode for a lithium secondary battery which is prepared by mixing graphite powder with a binder. The negative electrode comprises graphite with an intensity ratio I(110)/I(002) of 0.5 or more wherein I(002) is an X-ray diffraction peak intensity I(002) at a (002) plane and I(110) is an X-ray diffraction peak intensity I(110) at a (110) plane The negative electrode for a lithium secondary battery has enhanced discharge capacity and cycle life characteristics.
摘要翻译：公开了通过将石墨粉末与粘合剂混合而制备的锂二次电池用负极。负极包括强度比I（110）/ I（002）为0.5以上的石墨，其中I（002）为（002）面的X射线衍射峰强度I（002），I（110）是（110）面的X射线衍射峰强度I（110）锂二次电池用负极具有增强的放电容量和循环寿命特性。

13. 发明授权

US06869730B2 Electrode material, method for preparing same, electrode, and battery comprising same 有权
标题翻译：电极材料，其制备方法，电极和包含该电极的电池
公开(公告)号：US06869730B2
公开(公告)日：2005-03-22
申请号：US10251671
申请日：2002-09-20
申请人： Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku , Kyou-Yoon Sheem
发明人： Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku , Kyou-Yoon Sheem
IPC分类号： H01M2/02 , H01M4/02 , H01M4/58 , H01M4/60 , H01M4/62 , H01M4/66
CPC分类号： H01M4/13 , H01M2/0222 , H01M4/0404 , H01M4/043 , H01M4/587 , H01M4/621 , H01M4/622 , H01M4/661 , H01M10/052
摘要： Disclosed are an electrode material, a method for its preparation, an electrode comprising the electrode material and a battery comprising the same. The electrode material comprises a binder comprising a water-soluble conductive polymer and a water-soluble polymer, and an active material.
摘要翻译：公开了电极材料，其制备方法，包括电极材料的电极和包含该电极材料的电池。电极材料包括含有水溶性导电聚合物和水溶性聚合物的粘合剂和活性材料。

14. 发明授权

US06855459B2 Electrode for rechargeable lithium battery, method of preparing same and rechargeable lithium battery having the same 有权
标题翻译：可充电锂电池用电极，其制备方法及可充电锂电池
公开(公告)号：US06855459B2
公开(公告)日：2005-02-15
申请号：US10463859
申请日：2003-06-18
申请人： Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku , Kyou-Yoon Sheem
发明人： Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku , Kyou-Yoon Sheem
IPC分类号： H01M4/62 , H01M10/052 , H02J7/00
CPC分类号： H01M4/62 , H01M4/0404 , H01M4/621 , H01M10/052
摘要： An electrode for a rechargeable lithium battery includes a current collector and an active material layer formed on the current collector. The active material layer includes an active material, a binder and a water-soluble polymer. The binder is a copolymer of (metha)acrylic acid and (metha)acrylic alkylester, and an amorphous polypropylene homopolymer or an amorphous copolymer of propylene and a C2 to C8 olefin.
摘要翻译：用于可再充电锂电池的电极包括集电器和形成在集电器上的活性材料层。活性物质层包括活性物质，粘合剂和水溶性聚合物。粘合剂是（甲基）丙烯酸和（甲基）丙烯酸烷基酯的共聚物，和无定形聚丙烯均聚物或丙烯与C 2〜C 8烯烃的无定形共聚物。

15. 发明授权

US06767669B2 Negative electrode for lithium rechargeable batteries and lithium rechargeable batteries 有权
标题翻译：锂可充电电池和锂可充电电池的负极
公开(公告)号：US06767669B2
公开(公告)日：2004-07-27
申请号：US09925355
申请日：2001-08-08
申请人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
发明人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
IPC分类号： H01M448
CPC分类号： H01M4/133 , H01M4/131 , H01M4/1393 , H01M4/364 , H01M4/587 , H01M10/0525 , H01M2004/021 , H01M2004/027
摘要： A negative electrode for a lithium rechargeable battery includes a carbon material in which lithium intercalation occurs, and at least one metallic oxide selected from yttrium oxide, cerium oxide, and titanium oxide.
摘要翻译：锂二次电池用负极包括发生锂嵌入的碳材料和选自氧化钇，氧化铈和氧化钛中的至少一种金属氧化物。

16. 发明授权

US08048568B2 Negative active material for rechargeable lithium battery and rechargeable lithium battery 有权
标题翻译：可充电锂电池和可充电锂电池的负极活性物质
公开(公告)号：US08048568B2
公开(公告)日：2011-11-01
申请号：US10752297
申请日：2004-01-06
申请人： Kyou-Yoon Sheem , Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku
发明人： Kyou-Yoon Sheem , Keiko Matsubara , Toshiaki Tsuno , Akira Takamuku
IPC分类号： H01M4/58
CPC分类号： H01M10/052 , H01M4/134 , H01M4/386 , H01M2004/021
摘要： Disclosed is a negative active material for a rechargeable lithium battery including ultra-fine particles comprising an element which is capable of alloying with lithium. The particles have a diameter of 1 nm to 200 nm, a Raman shift of 480 cm−1 to 520 cm−1 measured by Raman Spectroscopy, and a full width at half-maximum of 10 cm−1 to 30 cm−1.
摘要翻译：公开了一种用于可再充电锂电池的负极活性材料，其包括包含能够与锂合金化的元素的超细颗粒。粒子的直径为1nm〜200nm，通过拉曼光谱法测定的拉曼位移为480cm -1〜520cm -1，半值最大值为10cm -1〜30cm -1。

17. 发明授权

US06733546B2 Method of preparing an anode material for lithium secondary battery 有权
标题翻译：锂二次电池负极材料的制备方法
公开(公告)号：US06733546B2
公开(公告)日：2004-05-11
申请号：US10460082
申请日：2003-06-11
申请人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
发明人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
IPC分类号： H01M458
CPC分类号： H01M4/587 , H01M4/366 , H01M10/052 , Y10T29/49108
摘要： The present invention provides anode material consisting of anode active material having a great charge-discharge capacity, a high charge-discharge efficiency, a flat discharge curve and good charge-discharge cycle properties, and provides the anode material for a lithium secondary battery consisting of being coated with an amorphous metal compound formed by a metal capable of alloying with lithium on at least one part of the surface of a carbon material capable of absorbing and releasing lithium ion.
摘要翻译：本发明提供了具有充放电容量大，充放电效率高，平放电曲线充放电循环性好的负极活性物质构成的负极材料，提供了由二次电池组成的锂二次电池在能够吸收和释放锂离子的碳材料的表面的至少一部分上涂覆由能够与锂合金化的金属形成的无定形金属化合物。

18. 发明授权

US06589696B2 Negative active material for rechargeable lithium battery and method of preparing same 有权
公开(公告)号：US06589696B2
公开(公告)日：2003-07-08
申请号：US09882449
申请日：2001-06-14
申请人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
发明人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
IPC分类号： H01M458
CPC分类号： H01M4/58 , H01M2/32 , H01M4/02 , H01M4/04 , H01M4/366 , H01M4/587 , H01M4/62 , H01M4/625 , H01M6/10 , H01M10/0431 , H01M10/0525 , H01M2004/021 , H01M2004/027
摘要： Disclosed is a negative active material for a rechargeable lithium battery that includes graphite particles, silicon micro-particles attached on the graphite particles and a carbon film partially or totally coated on the graphite particles.

19. 发明授权

US06797434B1 NEGATIVE ACTIVE MATERIAL FOR RECHARGEABLE LITHIUM BATTERY, ELECTRODE FOR RECHARGEABLE LITHIUM BATTERY, RECHARGEABLE LITHIUM BATTERY AND METHOD OF PREPARING NEGATIVE ACTIVE MATERIAL FOR RECHARGEABLE LITHIUM SECONDARY BATTERY 有权
标题翻译：用于可充电锂电池的负极活性材料，可充电锂电池的电极，可充电的锂电池及其制备用于可充电的锂二次电池的负极活性材料的方法
公开(公告)号：US06797434B1
公开(公告)日：2004-09-28
申请号：US09672287
申请日：2000-09-28
申请人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
发明人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
IPC分类号： H01M458
CPC分类号： H01M4/485 , H01M4/0471 , H01M4/0473 , H01M4/13 , H01M4/587 , H01M10/0525 , H01M2004/027 , H01M2300/0025
摘要： Disclosed is a negative active material for a rechargeable lithium battery exhibiting a high charge and discharge capacity, high charge and discharge efficiency, good discharge curve flatness, good charge and discharge cycle characteristics and high packing density. The negative active material includes a product made by agglomerating particles of a mixture of a carbonaceous material and an amorphous metal compound. The carbonaceous material is a material into or from which lithium is intercalated or deintercalated, and the amorphous metal compound is able to make an alloy with lithium.
摘要翻译：公开了一种具有高充放电能力，高充放电效率，良好的放电曲线平坦度，良好的充放电循环特性和高填充密度的可再充电锂电池的负极活性材料。负极活性材料包括由碳质材料和无定形金属化合物的混合物的附聚颗粒。碳质材料是锂嵌入或脱嵌的材料，并且非晶态金属化合物能够与锂形成合金。

20. 发明授权

US06641955B1 Anode material for lithium secondary battery, an electrode for lithium secondary battery and a lithium secondary battery 有权
标题翻译：锂二次电池用阳极材料，锂二次电池用电极和锂二次电池
公开(公告)号：US06641955B1
公开(公告)日：2003-11-04
申请号：US09670888
申请日：2000-09-28
申请人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
发明人： Keiko Matsubara , Toshiaki Tsuno , Sang-Young Yoon
IPC分类号： H01M458
CPC分类号： H01M4/587 , H01M4/366 , H01M10/052 , Y10T29/49108
摘要： The present invention provides anode material consisting of anode active material having a great charge-discharge capacity, a high charge-discharge efficiency, a flat discharge curve and good charge-discharge cycle properties, and provides the anode material for a lithium secondary battery consisting of being coated with an amorphous metal compound formed by a metal capable of alloying with lithium on at least one part of the surface of a carbon material capable of absorbing and releasing lithium ion.
摘要翻译：本发明提供了具有充放电容量大，充放电效率高，平放电曲线充放电循环性好的负极活性物质构成的负极材料，提供了由二次电池组成的锂二次电池在能够吸收和释放锂离子的碳材料的表面的至少一部分上涂覆由能够与锂合金化的金属形成的无定形金属化合物。

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