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11. 发明申请

US20080016752A1 Method for high energy density biomass-water slurry 审中-公开
标题翻译：高能密度生物质 - 水泥浆的方法
公开(公告)号：US20080016752A1
公开(公告)日：2008-01-24
申请号：US11879456
申请日：2007-07-16
申请人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
发明人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
IPC分类号： C10L1/10
CPC分类号： C10J3/00 , C10B53/02 , C10J2300/09 , C10L1/326 , C10L5/44 , C10L9/00 , C10L9/086 , Y02E50/10 , Y02E50/14 , Y02E50/30 , Y02P20/145
摘要： An energy efficient process for converting biomass into a higher carbon content, high energy density slurry. Water and biomass are mixed at a temperature and under a pressure that are much lower than in prior processes, but under a non-oxidative gas, which enables a stable slurry to be obtained containing up to 60% solids by weight, 20-40% carbon by weight, in the slurry. The temperature is nominally about 200° C. under non-oxidative gas pressure of about 150 psi, conditions that are substantially less stringent than those required by the prior art.
摘要翻译：一种将生物质转化为较高碳含量，高能量密度浆料的节能工艺。水和生物质在比现有方法低得多的温度和压力下进行混合，但是在非氧化性气体下进行混合，这使得能够获得含有高达60重量％固体，20-40重量％在浆料中。在约150psi的非氧化性气体压力下，温度基本上不如现有技术所要求的那样苛刻的条件下约为200℃。

12. 发明授权

US08771388B2 Method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor 有权
标题翻译：使用蒸汽加氢气化反应器和水煤气变换反应器从含碳原料生产富含甲烷的燃料气体的方法
公开(公告)号：US08771388B2
公开(公告)日：2014-07-08
申请号：US12783228
申请日：2010-05-19
申请人： Joseph M. Norbeck , Chan Seung Park , Arun S K Raju
发明人： Joseph M. Norbeck , Chan Seung Park , Arun S K Raju
IPC分类号： C01B3/00 , C01B3/24 , B01J7/00
CPC分类号： C01B3/12 , C01B2203/0283 , C01B2203/04 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/06 , C01B2203/0805 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/148 , C01B2203/84 , C10G1/06 , C10G2/30 , C10J3/00 , C10J2300/0916 , C10J2300/0946 , C10J2300/0966 , C10J2300/0973 , C10J2300/1659 , C10J2300/1662 , C10J2300/1807 , C10K1/004 , C10K3/04 , C10L3/08 , C10L3/102 , Y02E50/32 , Y02P20/145
摘要： A method for producing high levels of methane based on a combination of steam hydrogasification and a shift reactor is provided. Hydrogen produced by the shift reactor can be recycled back into the steam hydrogasifier.
摘要翻译：提供了一种基于蒸汽加氢气化和转移反应器的组合生产高含量甲烷的方法。由转换反应器产生的氢气可以再循环回到蒸汽加氢气化器中。

13. 发明申请

US20120210631A1 Commingled Coal and Biomass Slurries 有权
标题翻译：混合煤炭和生物质泥浆
公开(公告)号：US20120210631A1
公开(公告)日：2012-08-23
申请号：US13400883
申请日：2012-05-09
申请人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
发明人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
IPC分类号： C10L1/32
CPC分类号： C10B53/02 , C10J3/00 , C10J2300/0903 , C10J2300/0916 , C10J2300/093 , C10J2300/0973 , C10L1/326 , C10L5/44 , C10L9/00 , C10L9/086 , Y02E50/10 , Y02E50/14 , Y02E50/30
摘要： An energy efficient process for converting biomass into a higher carbon content, high energy density slurry. Water and biomass are mixed at a temperature and under a pressure that are much lower than in prior processes, but under a non-oxidative gas, which enables a stable slurry to be obtained containing up to 60% solids by weight, 20-40% carbon by weight, in the slurry. The temperature is nominally about 200° C. under non-oxidative gas pressure of about 150 psi, conditions that are substantially less stringent than those required by the prior art. In another embodiment, the biomass water slurry can be mixed with a coal water slurry to further optimize the carbon content and pumpability of the biomass shiny.
摘要翻译：一种将生物质转化为较高碳含量，高能量密度浆料的节能工艺。水和生物质在比现有方法低得多的温度和压力下进行混合，但是在非氧化性气体下进行混合，这使得能够获得含有高达60重量％固体，20-40重量％在浆料中。在约150psi的非氧化性气体压力下，温度基本上不如现有技术所要求的那样苛刻的条件下约为200℃。在另一个实施方案中，生物质水浆可以与煤水浆混合，以进一步优化生物质的碳含量和可泵性。

14. 发明授权

US08741000B2 Commingled coal and biomass slurries 有权
标题翻译：混合煤和生物质泥浆
公开(公告)号：US08741000B2
公开(公告)日：2014-06-03
申请号：US13400883
申请日：2012-05-09
申请人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
发明人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
IPC分类号： C10L1/32 , C10L8/00
CPC分类号： C10B53/02 , C10J3/00 , C10J2300/0903 , C10J2300/0916 , C10J2300/093 , C10J2300/0973 , C10L1/326 , C10L5/44 , C10L9/00 , C10L9/086 , Y02E50/10 , Y02E50/14 , Y02E50/30
摘要： An energy efficient process for converting biomass into a higher carbon content, high energy density slurry. Water and biomass are mixed at a temperature and under a pressure that are much lower than in prior processes, but under a non-oxidative gas, which enables a stable slurry to be obtained containing up to 60% solids by weight, 20-40% carbon by weight, in the slurry. The temperature is nominally about 200° C. under non-oxidative gas pressure of about 150 psi, conditions that are substantially less stringent than those required by the prior art. In another embodiment, the biomass water slurry can be mixed with a coal water slurry to further optimize the carbon content and pumpability of the biomass slurry.
摘要翻译：一种将生物质转化为较高碳含量，高能量密度浆料的节能工艺。水和生物质在比现有方法低得多的温度和压力下进行混合，但是在非氧化性气体下进行混合，这使得能够获得含有高达60重量％固体，20-40重量％在浆料中。在约150psi的非氧化性气体压力下，温度基本上不如现有技术所要求的那样苛刻的条件下约为200℃。在另一个实施方案中，生物质水浆料可以与煤水浆料混合以进一步优化生物质浆料的碳含量和可泵送性。

15. 发明授权

US08435448B2 Sensor for measuring syngas ratio in the high temperature and pressure condition 失效
标题翻译：用于在高温和高压条件下测量合成气比的传感器
公开(公告)号：US08435448B2
公开(公告)日：2013-05-07
申请号：US12756407
申请日：2010-04-08
申请人： Chan Seung Park , Colin E. Hackett , Joseph M. Norbeck
发明人： Chan Seung Park , Colin E. Hackett , Joseph M. Norbeck
IPC分类号： G01N31/10 , G01N27/16 , G01N33/00
CPC分类号： G01N27/18 , G01N33/0013 , G01N33/004 , Y10T436/204998 , Y10T436/205831 , Y10T436/208339 , Y10T436/22
摘要： An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.
摘要翻译：气体分析装配和方法。组件包括用于催化气体样品组分的催化剂室，产生一种或多种气体物质作为产物。产品隔室接收气体种类，并且隔室内的感测元件感测一种或多种气体种类的量。将该量与含有非催化气体样品的参考室中存在的相同气体物质的量进行比较，提供通过催化产生的气体种类的量。使用该值，基于催化反应的化学计量来计算气体样品中气体组分的含量。在优选实施例中，用于分析的气体是用于燃料生产的工艺气体，并且催化剂是催化一氧化碳和水与氢气和二氧化碳的反应的高温变换催化剂。

16. 发明授权

US07619012B2 Method and apparatus for steam hydro-gasification in a fluidized bed reactor 有权
标题翻译：流化床反应器中蒸汽加氢气化的方法和装置
公开(公告)号：US07619012B2
公开(公告)日：2009-11-17
申请号：US11879267
申请日：2007-07-16
申请人： Joseph M. Norbeck , Chan Seung Park , Surinder P. Singh
发明人： Joseph M. Norbeck , Chan Seung Park , Surinder P. Singh
IPC分类号： C07C27/00
CPC分类号： C01B3/34 , C01B2203/0233 , C01B2203/062 , C01B2203/0838 , C01B2203/1241 , C01B2203/148 , C01B2203/84 , C10G2/32 , C10J3/005 , C10J3/463 , C10J3/503 , C10J2300/093 , C10J2300/0966 , C10J2300/0973 , C10J2300/1659 , C10K3/00 , Y02E20/18 , Y02E50/32
摘要： A method and apparatus for converting carbonaceous material to a stream of methane and carbon monoxide rich gas by heating the carbonaceous material in a fluidized bed reactor using hydrogen, as fluidizing medium, and using steam, under reducing conditions at a temperature and pressure sufficient to generate a stream of methane and carbon monoxide rich gas but at a temperature low enough and/or at a pressure high enough to enable the carbonaceous material to be fluidized by the hydrogen. In particular embodiments, the carbonaceous material is fed as a slurry feed, along with hydrogen, to a kiln type reactor before being fed to the fluidized bed reactor. Apparatus is provided comprising a kiln type reactor, a slurry pump connected to an input of the kiln type reactor, means for connecting a source of hydrogen to an input of the kiln type reactor; a fluidized bed reactor connected to receive output of the kiln type reactor for processing at a fluidizing zone, and a source of steam and a source of hydrogen connected to the fluidized bed reactor below the fluidizing zone. Optionally, a grinder can be provided in the kiln type reactor.
摘要翻译：一种通过在流化床反应器中使用氢气作为流化介质，并且在还原条件下在足以产生的温度和压力下使用蒸汽加热碳质材料，将含碳材料转化为甲烷和一氧化碳富含气流的方法和装置一种富含甲烷和一氧化碳的气体，但在足够低的温度和/或足够高的压力下使含碳材料能够被氢气流化。在具体的实施方案中，碳质材料在加入到流化床反应器之前作为浆料进料以及氢气供入到窑式反应器中。提供了包括窑式反应器，连接到窑式反应器的输入端的浆料泵的装置，用于将氢源连接到窑式反应器的输入端的装置; 连接以接收在流化区处理的窑式反应器的输出的流化床反应器，以及连接到流化床下方的流化床反应器的蒸汽源和氢源。任选地，可以在窑式反应器中提供研磨机。

17. 发明申请

US20080031809A1 Controlling the synthesis gas composition of a steam methane reformer 审中-公开
公开(公告)号：US20080031809A1
公开(公告)日：2008-02-07
申请号：US11489298
申请日：2006-07-18
申请人： Joseph M. Norbeck , Chan Seung Park
发明人： Joseph M. Norbeck , Chan Seung Park
IPC分类号： C01B3/24
CPC分类号： C01B3/38 , C01B2203/0233 , C01B2203/04 , C01B2203/062 , C01B2203/0805 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/148 , C01B2203/84 , C10G2/30 , C10G2300/1003 , C10G2300/1011 , C10G2300/42 , C10G2300/807 , C10J3/00 , C10J2300/0916 , C10J2300/0946 , C10J2300/0966 , C10J2300/0973 , C10J2300/1659 , C10J2300/1807 , C10K1/024 , C10K1/143 , C10K1/16 , C10K1/165 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： A method for controlling the synthesis gas composition obtained from a steam methane reformer (SMR) that obtains its feedstock as product gas directly from a steam hydro-gasification reactor SHR). The method allows control of the H2/CO syngas ratio by adjusting the hydrogen feed and the water content of feedstock into a steam hydro-gasification reactor that supplies the SMR. The steam and methane rich product gas of the SHR is generated by means of hydro-gasification of a slurry of carbonaceous material and water. The mass percentages of the product stream at each stage of the process are calculated using a modeling program, such as the ASPEN PLUS™ equilibrium process. By varying the parameters of solid to water ratio and hydrogen to carbon ratio, a sensitivity analysis can be performed that enables one determine the optimum composition of the slurry feedstock to the SHR to obtain a desired syngas ratio output of the SMR. Thus one can adjust the hydrogen feed and the water content of feedstock into the SHR that supplies the SMR to determine the syngas ratio output of the SMR.

18. 发明申请

US20080021119A1 Operation of a steam methane reformer by direct feeding of steam rich producer gas from steam hydro-gasification 审中-公开
标题翻译：通过从蒸汽加氢气化直接进料富含蒸汽的生产气体来运行蒸汽沼气重整器
公开(公告)号：US20080021119A1
公开(公告)日：2008-01-24
申请号：US11489308
申请日：2006-07-18
申请人： Joseph M. Norbeck , Chan Seung Park
发明人： Joseph M. Norbeck , Chan Seung Park
IPC分类号： C07C27/06
CPC分类号： C01B3/38 , C01B32/40 , C01B2203/0233 , C01B2203/062 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/14 , C01B2203/148 , C01B2203/84 , C10G1/002 , C10G2300/1003 , C10G2300/1011 , C10G2300/807 , C10G2400/26 , C10J3/00 , C10J2300/093 , C10J2300/0966 , C10J2300/0973 , C10J2300/1659 , C10J2300/1853 , C10K1/024 , C10K1/143 , C10K1/16 , C10K1/165 , C10K3/00 , Y02E50/32 , Y02P30/20
摘要： An improved, economical alternative method to supply steam and methane to a steam methane reformer (SMR) is accomplished by a combination of procedures, wherein product gas from a steam hydro-gasification reactor (SHR) is used as the feedstock for the SMR by removing impurities from the product stream from the SHR with a gas cleanup unit that operates substantially at process temperatures and pressures and is located between the SHR and SMR.
摘要翻译：向蒸汽甲烷重整器（SMR）提供蒸汽和甲烷的改进的，经济的替代方法是通过以下步骤完成的，其中将来自蒸汽加氢气化反应器（SHR）的产物气体用作SMR的原料，通过除去来自SHR的产物流中的杂质具有基本上在工艺温度和压力下操作并位于SHR和SMR之间的气体净化单元。

19. 发明授权

US09493721B2 Method to produce methane rich fuel gas from carbonaceous feedstocks using a steam hydrogasification reactor and a water gas shift reactor 有权
标题翻译：使用蒸汽加氢气化反应器和水煤气变换反应器从含碳原料生产富含甲烷的燃料气体的方法
公开(公告)号：US09493721B2
公开(公告)日：2016-11-15
申请号：US13496296
申请日：2010-09-22
申请人： Arun S K Raju , Chan Seung Park , Joseph M. Norbeck
发明人： Arun S K Raju , Chan Seung Park , Joseph M. Norbeck
IPC分类号： C01B3/36 , C10L3/08 , C10J3/00 , C10K1/00 , C10K3/04
CPC分类号： C10L3/08 , C01B2203/0283 , C01B2203/04 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/84 , C10J3/00 , C10J2300/0916 , C10J2300/092 , C10J2300/093 , C10J2300/0966 , C10J2300/0973 , C10K1/004 , C10K3/04 , Y02P20/145
摘要： A method for producing high levels of methane based on a combination of steam hydrogasification and a shift reactor is provided using carbonaceous material. Hydrogen produced by the shift reactor can be recycled back into the steam hydrogasifier.
摘要翻译：使用含碳材料提供了基于蒸汽加氢气化和转移反应器的组合生产高含量甲烷的方法。由转换反应器产生的氢气可以再循环回到蒸汽加氢气化器中。

20. 发明授权

US08118894B2 Commingled coal and biomass slurries 有权
标题翻译：混合煤和生物质泥浆
公开(公告)号：US08118894B2
公开(公告)日：2012-02-21
申请号：US12286165
申请日：2008-09-29
申请人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
发明人： Joseph M. Norbeck , Chan Seung Park , Andres Aguirre
IPC分类号： C01B3/36 , C10J3/00 , C10J3/46
CPC分类号： C10B53/02 , C10J3/00 , C10J2300/0903 , C10J2300/0916 , C10J2300/093 , C10J2300/0973 , C10L1/326 , C10L5/44 , C10L9/00 , C10L9/086 , Y02E50/10 , Y02E50/14 , Y02E50/30
摘要： An energy efficient process for converting biomass into a higher carbon content, high energy density slurry. Water and biomass are mixed at a temperature and under a pressure that are much lower than in prior processes, but under a non-oxidative gas, which enables a stable slurry to be obtained containing up to 60% solids by weight, 20-40% carbon by weight, in the slurry. The temperature is nominally about 200° C. under non-oxidative gas pressure of about 150 psi, conditions that are substantially less stringent than those required by the prior art. In another embodiment, the biomass water slurry can be mixed with a coal water slurry to further optimize the carbon content and pumpability of the biomass slurry.
摘要翻译：一种将生物质转化为较高碳含量，高能量密度浆料的节能工艺。水和生物质在比现有方法低得多的温度和压力下进行混合，但是在非氧化性气体下进行混合，这使得能够获得含有高达60重量％固体，20-40重量％在浆料中。在约150psi的非氧化性气体压力下，温度基本上不如现有技术所要求的那样苛刻的条件下约为200℃。在另一个实施方案中，生物质水浆料可以与煤水浆料混合以进一步优化生物质浆料的碳含量和可泵送性。

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