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    • 11. 发明授权
    • Triazine derivative dye transfer inhibitors, washing products containing the same and uses therefor
    • 三嗪衍生物染料转移抑制剂,含有相同用途的洗涤产品
    • US08263541B2
    • 2012-09-11
    • US12064107
    • 2006-08-05
    • Josef PenningerBirgit Gluesen
    • Josef PenningerBirgit Gluesen
    • C11D3/37C11D7/18C11D3/00D06L1/04
    • C11D3/349C11D3/0021
    • Washing products which comprise a dye transfer inhibitor selected from the group consisting of triazine derivatives of the general formulae I, II, III and combinations thereof: T(NH—Ar(SO3Na)a)bHalc  (I) X(NH-T(NH—Ar(SO3Na)a)eHalf)2  (II) X(NH-T(NH—Ar(SO3Na)d—NH-T(NH—Ar(SO3Na)a)Hal)Hal)2  (III) wherein T represents a 1,3,5-triazinyl residue; each Ar independently represents a naphthalene or benzene moiety; X represents a divalent hydrocarbyl moiety selected from the group consisting of linear or branched C1-20 hydrocarbon groups which may optionally include one or more —N(H)— carbon chain interruptions, stilbene groups and biphenyl groups which may optionally be mono- or poly-SO3Na-substituted; each Hal independently represents a halogen selected from the group consisting of chlorine, bromine, and iodine; each of a and d independently represents 1, 2 or 3; b and c each represent 1 or 2 such that b+c=3; e represents 1 or 2 and f represents 0 or 1 such that e+f=2; and wherein the triazinyl residue substituents are located at the 2, 4 and 6 positions of the 1,3,5-triazinyl residue.
    • 包含选自通式I,II,III的三嗪衍生物及其组合的染料转移抑制剂的洗涤产品:T(NH-Ar(SO 3 Na)a)b氢化(I)X(NH-T(NH -Ar(SO3Na)a)eHalf)2(II)X(NH-T(NH-Ar(SO3Na)d-NH-T(NH-Ar(SO3Na)a)Hal)Hal)2(III)其中T表示 1,3,5-三嗪基残基; 每个Ar独立地表示萘或苯部分; X表示选自直链或支链C 1-20烃基的二价烃基部分,其可以任选地包括一个或多个-N(H) - 碳链中断,二苯乙烯基团和联苯基团,其可任选地是单或多 -SO 3 Na-取代的 每个Hal独立地表示选自氯,溴和碘的卤素; a和d各自独立地表示1,2或3; b和c各自表示1或2,使得b + c = 3; e表示1或2,f表示0或1,使e + f = 2; 并且其中三嗪基残基取代基位于1,3,5-三嗪基残基的2,4和6位。
    • 12. 发明申请
    • COLOUR-PROTECTING LAUNDRY DETERGENT COMPOSITION
    • 彩色保护洗衣洗涤剂组合物
    • US20090069210A1
    • 2009-03-12
    • US12282610
    • 2007-02-08
    • Josef PenningerBirgit Glusen
    • Josef PenningerBirgit Glusen
    • C11D3/28
    • C11D3/28C11D3/0021
    • Detergent compositions comprising a color transfer inhibitor and optionally surfactant(s), the color transfer inhibitor comprising one or more compounds selected from the group consisting of triazine derivatives corresponding to general formulae I and II: T(NH—Ar(CO2M)a)bHalc  (I) X—NH—CH2CH2—(NY—CH2CH2—)nNH—X  (II) wherein T represents a 1,3,5-triazinyl group; Ar represents a phenyl group; each M independently represents a substituent selected from the group consisting of H, Na, Li, and K; each Hal independently represents a halogen selected from the group consisting of Cl, Br, and I; each a independently represents 1, 2 or 3; b and c each represent 1 or 2 wherein b+c=3; each X represents a T(NH—Ar(CO2M)a)bHalc−1 group; each Y independently represents H or X; and n represents a number of 0 to 50, and uses therefor in washing and treating dyed and/or undyed textiles.
    • 包含颜色转移抑制剂和任选的表面活性剂的洗涤剂组合物,所述颜色转移抑制剂包含一种或多种选自对应于通式I和II的三嗪衍生物的化合物:<?in-line-formula description =“In “公式”end =“lead”?> T(NH-Ar(CO2M)a)bHalc(I)<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in -line-formula description =“In-line Formulas”end =“lead”?X-NH-CH2CH2-(NY-CH2CH2-)nNH-X(II)<?in-line-formula description =“In-line 式“end =”tail“?>其中T表示1,3,5-三嗪基; Ar表示苯基; 每个M独立地表示选自H,Na,Li和K的取代基; 每个Hal独立地表示选自Cl,Br和I的卤素; 每个独立地代表1,2或3; b和c各自表示1或2,其中b + c = 3; 每个X表示T(NH-Ar(CO 2 M)a)b Halc-1基团; 每个Y独立地表示H或X; n表示0〜50的数,用于洗涤和/或未染色染色纺织品。
    • 13. 发明授权
    • Detergents or cleaning agents comprising a water-soluble building block system and a cellulose derivative with dirt dissolving properties
    • 包含水溶性结构单元系统和具有污垢溶解性能的纤维素衍生物的洗涤剂或清洁剂
    • US07316995B2
    • 2008-01-08
    • US11200678
    • 2005-08-10
    • Josef Penninger
    • Josef Penninger
    • C11D3/06C11D3/10C11D3/08C11D3/36
    • C11D3/3942C11D3/0026C11D3/0036C11D3/225C11D11/00C11D11/0017C11D17/0039D06M15/09D06M2200/00
    • A builder-containing laundry detergent or cleaning composition comprising: (1) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 5% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (2) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise only water-soluble builders.
    • 1.一种含助洗剂的洗衣洗涤剂或清洁组合物,其包含:(1)水溶性助洗剂块,其包含:a)5重量%至35重量%的柠檬酸,碱金属柠檬酸盐,碱金属碳酸盐, 和/或碱金属碳酸氢盐,b)至多5重量%的模量为1.8至2.5的碱金属硅酸盐,c)至多2重量%的膦酸和/或碱金属磷酸盐, d)至多50重量%的碱金属磷酸盐,和e)至多10重量%的聚羧酸多元醇,其中组分b),c),d)和e)中的至少两种以大于0的量存在 重量%,和(2)可释放污垢的烷基或羟烷基纤维素衍生物。 当纤维素衍生物用于仅包含水溶性助洗剂的洗衣洗涤剂或清洁组合物中时,具有特别明显的作用。
    • 18. 发明申请
    • Bleach-containing laundry detergents or cleaning compositions comprising water-soluble builder system and soil release-capable cellulose derivative
    • 含漂白剂的洗衣洗涤剂或包含水溶性助洗剂体系和可释放污垢的纤维素衍生物的清洁组合物
    • US20060035801A1
    • 2006-02-16
    • US11200679
    • 2005-08-10
    • Josef Penninger
    • Josef Penninger
    • C11D3/20
    • C11D3/225C11D3/0026C11D3/0036C11D3/3942C11D17/0039D06M15/09D06M2200/00
    • A builder-containing laundry detergent or cleaning composition is comprised of: (1) alkali metal percarbonate; (2) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 10% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (3) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise alkali metal percarbonates and contain only water-soluble builders.
    • 含有助洗剂的洗衣洗涤剂或清洁组合物包括:(1)碱金属过碳酸盐; (2)水溶性助洗剂块,其包含:a)5重量%至35重量%的柠檬酸,碱金属柠檬酸盐,碱金属碳酸盐和/或碱金属碳酸氢盐,b) 至多10重量%的模量为1.8至2.5的碱金属硅酸盐,c)至多2重量%的膦酸和/或碱金属磷酸盐,d)至多50重量%的碱金属 磷酸盐和e)高达10重量%的聚羧酸多酯,其中组分b),c),d)和e)中的至少两种以大于0重量%的量存在,和(3)污垢释放 可能的烷基或羟烷基纤维素衍生物。 当纤维素衍生物用于洗衣洗涤剂或包含碱金属过碳酸盐并且仅含水溶性助洗剂的清洁组合物中时,纤维素衍生物的具有污垢释放作用特别明显。