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    • 11. 发明授权
    • Semiconductor device having a multi-layer metal contact
    • 具有多层金属接触的半导体器件
    • US5355020A
    • 1994-10-11
    • US910894
    • 1992-07-08
    • Sang-in LeeJeong-in HongJong-ho Park
    • Sang-in LeeJeong-in HongJong-ho Park
    • H01L23/52H01L21/027H01L21/285H01L21/3205H01L21/768H01L23/485H01L23/522H01L23/532H01L23/48
    • H01L21/76843H01L21/0276H01L21/28512H01L21/76855H01L21/76858H01L21/76864H01L21/76877H01L21/76879H01L23/485H01L23/53223H01L23/53271H01L2924/0002
    • A wiring layer of a semiconductor device having a novel contact structure is disclosed. The semiconductor device includes a semiconductor substrate, an insulating layer having an opening (contact hole or via) and a first conductive layer formed on the insulating layer which completely fills the opening. The first conductive layer does not produce any Si precipitates in a subsequent heat-treating step for filling the opening with the first conductive layer material. The semiconductor device may further include a second conductive layer having a planarized surface on the first conductive layer. This improves subsequent photolithography. An anti-reflective layer may be formed on the second conductive layer for preventing an unwanted reflection during a photo lithography process. The semiconductor device preferably includes a diffusion barrier layer under the first conductive layer and on the semiconductor substrate, on the insulating layer, and on the inner surface of the opening which prevents a reaction between the first conductive layer and the semiconductor substrate or the insulating layer. A method for forming the wiring layer is also disclosed. Providing a semiconductor device with the wiring layer reduces the leakage current by preventing an Al spiking. Since the first conductive layer undergoes a heat-treatment step at a temperature below the melting point, while flowing into the opening and completely filling it with the first conductive layer material, no void is formed in the opening. Good semiconductor device reliability is ensured in spite of the contact hole being less than 1 .mu.m in size and having an aspect ratio greater than 1.0.
    • 公开了具有新型接触结构的半导体器件的布线层。 半导体器件包括半导体衬底,具有开口(接触孔或通孔)的绝缘层和形成在绝缘层上的完全填充开口的第一导电层。 在随后的用第一导电层材料填充开口的热处理步骤中,第一导电层不产生任何Si沉淀物。 半导体器件还可以包括在第一导电层上具有平坦化表面的第二导电层。 这改善了随后的光刻。 可以在第二导电层上形成抗反射层,以防止在光刻工艺期间不期望的反射。 半导体器件优选地包括在第一导电层下方,半导体衬底上的绝缘层上的扩散阻挡层,以及防止第一导电层与半导体衬底或绝缘层之间的反应的开口内表面 。 还公开了一种用于形成布线层的方法。 提供具有布线层的半导体器件通过防止Al尖峰来减少泄漏电流。 由于第一导电层在低于熔点的温度下经历热处理步骤,同时流入开口并用第一导电层材料完全填充,因此在开口中不形成空隙。 尽管接触孔的尺寸小于1μm,纵横比大于1.0,仍然保证良好的半导体器件的可靠性。
    • 13. 发明授权
    • Method for manufacturing thin film using atomic layer deposition
    • 使用原子层沉积制造薄膜的方法
    • US06270572B1
    • 2001-08-07
    • US09371709
    • 1999-08-09
    • Yeong-kwan KimSang-in LeeChang-soo ParkSang-min Lee
    • Yeong-kwan KimSang-in LeeChang-soo ParkSang-min Lee
    • C30B2502
    • H05B33/04C23C16/44C23C16/45527C23C16/45561H01L21/02381H01L21/0254H01L21/0262H01L21/02631H01L21/31604H01L21/31691
    • A thin film manufacturing method is provided. The method includes the step of chemically adsorbing a first reactant on a substrate by injecting the first reactant into a chamber in which the substrate is loaded. Physisorbed first reactant on the chemically adsorbed first reactant is removed by purging or pumping the chamber. After the first reactant is densely chemically adsorbed on the substrate by re-injecting the first reactant into the chamber, the physisorbed first reactant on the dense chemisorbed first reactant is removed by purging or pumping the chamber. A second reactant is chemically adsorbed onto the surface of the substrate by injecting the second reactant into the chamber. Physisorbed second reactant on the chemisorbed first reactant and the second reactant is removed by purging or pumping the chamber. A solid thin film is formed by chemical exchange through densely adsorbing the second reactant onto the substrate by re-injecting the second reactant into the chamber. According to the present invention, it is possible to obtain a precise stoichiometric thin film having a high film density, since the first reactant and the second reactant are densely adsorbed and the impurities are substantially removed by pumping or purging
    • 提供薄膜制造方法。 该方法包括通过将第一反应物注入到其中负载衬底的室中来在基底上化学吸附第一反应物的步骤。 化学吸附的第一反应物上的物理吸附的第一反应物通过清洗或泵送室来除去。 在第一反应物通过将第一反应物重新注入室中密集地化学吸附在基材上之后,通过清洗或泵送室来去除致密化学吸附的第一反应物上的物理吸附的第一反应物。 通过将第二反应物注入到室中,将第二反应物化学吸附到基底的表面上。 化学吸附的第一反应物和第二反应物上的物理吸附的第二反应物通过清洗或泵送室来除去。 通过将第二反应物重新注入到室中,将第二反应物密集地吸附到基底上,通过化学交换形成固体薄膜。 根据本发明,可以获得具有高膜密度的精确化学计量薄膜,因为第一反应物和第二反应物被密集吸附并且通过泵送或清除基本上除去杂质
    • 14. 发明授权
    • Method of forming metal nitride film by chemical vapor deposition and method of forming metal contact of semiconductor device using the same
    • 通过化学气相沉积形成金属氮化物膜的方法和使用其形成半导体器件的金属接触的方法
    • US06197683B1
    • 2001-03-06
    • US09156724
    • 1998-09-18
    • Sang-bom KangChang-soo ParkYun-sook ChaeSang-in Lee
    • Sang-bom KangChang-soo ParkYun-sook ChaeSang-in Lee
    • H01L2144
    • H01L21/76843C23C16/34C23C16/45553H01L21/28562H01L21/28568H01L21/76804H01L28/91
    • A method of forming a metal nitride film using chemical vapor deposition (CVD), and a method of forming a metal contact of a semiconductor device using the same, are provided. The method of forming a metal nitride film using chemical vapor deposition (CVD) in which a metal source and a nitrogen source are used as a precursor, includes the steps of inserting a semiconductor substrate into a deposition chamber, flowing the metal source into the deposition chamber, removing the metal source remaining in the deposition chamber by cutting off the inflow of the metal source and flowing a purge gas into the deposition chamber, cutting off the purge gas and flowing the nitrogen source into the deposition chamber to react with the metal source adsorbed on the semiconductor substrate, and removing the nitrogen source remaining in the deposition chamber by cutting off the inflow of the nitrogen source and flowing the purge gas into the deposition chamber. Accordingly, the metal nitride film has low resistivity and a low content of Cl even with excellent step coverage, and it can be formed at a temperature of 500° C. or lower. Also, a deposition speed, approximately 20 Å/cycle, is suitable for mass production.
    • 提供了使用化学气相沉积(CVD)形成金属氮化物膜的方法,以及使用其形成使用其的半导体器件的金属接触的方法。 使用其中使用金属源和氮源作为前体的化学气相沉积(CVD)形成金属氮化物膜的方法包括以下步骤:将半导体衬底插入淀积室中,使金属源流入沉积物 通过切断金属源的流入并将净化气体流入沉积室,去除沉积室中残留的金属源,切断净化气体并使氮源流入沉积室以与金属源反应 吸附在半导体衬底上,并且通过切断氮源的流入并将净化气体流入沉积室来除去留在沉积室中的氮源。 因此,即使具有优异的阶梯覆盖,金属氮化物膜也具有低电阻率和低的Cl含量,并且可以在500℃或更低的温度下形成。 此外,沉积速度约为每秒的一个循环,适合批量生产。
    • 16. 发明授权
    • Methods of forming integrated circuit capacitors using metal reflow
techniques
    • 使用金属回流技术形成集成电路电容器的方法
    • US6001660A
    • 1999-12-14
    • US969672
    • 1997-11-13
    • Young-soh ParkSang-in LeeCheol-seong HwangDoo-sup HwangHag-Ju Cho
    • Young-soh ParkSang-in LeeCheol-seong HwangDoo-sup HwangHag-Ju Cho
    • C23C14/14C23C14/58H01L21/02H01L21/28H01L21/768H01L21/822H01L21/8242H01L27/04H01L27/108H01G7/06
    • H01L28/60H01L21/76882
    • Methods of forming integrated circuit capacitors include the steps of forming an electrically insulating layer on a face of a semiconductor substrate and then patterning the electrically insulating layer to define a contact hole therein. A barrier metal layer is then formed in at least a portion of the contact hole. A lower electrode metal layer is then formed on the barrier metal layer and then planarized by reflowing the lower electrode metal layer at a temperature greater than about 650.degree. C. in a nitrogen gas ambient, to define a lower capacitor electrode. A layer of material having a high dielectric constant is then formed on the lower capacitor electrode. An upper capacitor electrode is then formed on the dielectric layer, opposite the lower capacitor electrode. The dielectric layer may comprise Ba(Sr, Ti)O.sub.3, Pb(Zr, Ti)O.sub.3, Ta.sub.2 O.sub.5, SiO.sub.2, SiN.sub.3, SrTiO.sub.3, PZT, SrBi.sub.2 Ta.sub.2 O.sub.9, (Pb, La)(Zr, Ti)O.sub.3 and Bi.sub.4 Ti.sub.3 O.sub.12. According to one embodiment of the present invention, the step of patterning the electrically insulating layer comprises patterning the electrically insulating layer to define a contact hole therein that exposes the face of the semiconductor substrate. The step of forming a barrier metal layer also preferably comprises depositing a conformal barrier metal layer on sidewalls of the contact hole and on the exposed face of the substrate. The barrier metal layer may be selected from the group consisting of TiN, CoSi, TaSiN, TiSiN, TaSi, TiSi, Ta and TaN.
    • 形成集成电路电容器的方法包括以下步骤:在半导体衬底的表面上形成电绝缘层,然后对电绝缘层进行构图以在其中限定接触孔。 然后在接触孔的至少一部分中形成阻挡金属层。 然后在阻挡金属层上形成下电极金属层,然后通过在氮气环境中在大于约650℃的温度下回流下电极金属层来平坦化,以限定较低的电容器电极。 然后在下部电容器电极上形成具有高介电常数的材料层。 然后在电介质层上形成上电容器电极,与下电容器电极相对。 介电层可以包括Ba(Sr,Ti)O3,Pb(Zr,Ti)O3,Ta2O5,SiO2,SiN3,SrTiO3,PZT,SrBi2Ta2O9,(Pb,La)(Zr,Ti)O3和Bi4Ti3O12。 根据本发明的一个实施例,图案化电绝缘层的步骤包括图案化电绝缘层以限定其中露出半导体衬底的表面的接触孔。 形成阻挡金属层的步骤还优选包括在接触孔的侧壁上和基底的暴露面上沉积保形阻挡金属层。 阻挡金属层可以选自TiN,CoSi,TaSiN,TiSiN,TaSi,TiSi,Ta和TaN。
    • 18. 发明授权
    • Semiconductor device having a multi-layer contact structure
    • 具有多层接触结构的半导体器件
    • US5939787A
    • 1999-08-17
    • US929419
    • 1997-09-15
    • Sang-in Lee
    • Sang-in Lee
    • H01L21/28C23C14/06C23C14/24H01L21/768H01L23/522H01L23/532H01L23/48H01L29/43
    • H01L21/76856H01L21/76843H01L21/76846H01L21/76877H01L21/76882H01L23/532H01L2924/0002Y10S257/915
    • A semiconductor device and manufacturing method thereof having a diffusion barrier layer formed on a semiconductor wafer, whose surface region is provided with a silylation layer, wherein the silylation layer is formed on the diffusion barrier layer which is formed on the semiconductor wafer, by a plasma process using silicon hydride or by a reactive sputtering method using SiH.sub.4. When the metal layer is formed on the silylation layer, the wettability between the diffusion barrier layer and the metal is enhanced and large grains are formed, thereby increasing the step coverage for the contact hole of the metal layer or for the via hole. Additionally, when heat treatment is performed after the metal layer is formed on the silylation layer, the reflow characteristic of the metal layer becomes good, to thereby facilitate the filling of the contact hole or the via hole easy. When the wiring layer is thus formed, the metal wiring having good reliability can be obtained and the subsequent process is rendered unnecessary.
    • 一种半导体器件及其制造方法,其具有形成在半导体晶片上的扩散阻挡层,其表面区域设置有甲硅烷基化层,其中所述甲硅烷基层通过等离子体形成在形成在半导体晶片上的扩散阻挡层上 使用硅氢化物或通过使用SiH 4的反应溅射法进行。 当在甲硅烷基层上形成金属层时,扩散阻挡层和金属之间的润湿性增强,并且形成大的晶粒,从而增加金属层或通孔的接触孔的阶梯覆盖。 此外,当在甲硅烷基层上形成金属层之后进行热处理时,金属层的回流特性变好,从而易于使接触孔或通孔的填充。 当这样形成布线层时,可以获得具有良好可靠性的金属布线,并且不需要随后的处理。
    • 19. 发明授权
    • Method for manufacturing a multi-layer wiring structure of a
semiconductor device
    • 半导体装置的多层布线结构的制造方法
    • US5851917A
    • 1998-12-22
    • US625114
    • 1996-04-01
    • Sang-in Lee
    • Sang-in Lee
    • H01L21/285H01L21/441H01L21/48H01L21/768H01L23/485H01L23/522H01L23/532H01L21/28
    • H01L21/76838H01L21/76843H01L21/76856H01L21/76862H01L21/76876H01L21/76877H01L23/485H01L23/53223H01L2924/0002Y10S257/915
    • A wiring structure of semiconductor device and a method for manufacturing the same which fills up a contact hole of below one half micron. An insulating layer is formed on a semiconductor substrate, and a contact hole or a via hole is formed in the insulating layer. On the insulating layer, a first metal is deposited via a CVD method to form a CVD metal layer or a CVD metal plug filling up the contact hole. Then, the thus-obtained CVD metal layer or the CVD metal plug is heat-treated in a vacuum at a high temperature below the melting point of the first metal, thereby planarizing the surface thereof the CVD metal layer. A second metal is deposited via a sputtering method on the CVD metal layer or on the CVD metal plug to thereby form a sputtered metal layer. The contact hole is filled up with the first metal by the CVD method and then a reliable sputtered metal layer is deposited via a sputtering method. The wiring layer can be used for the semiconductor device of the next generation.
    • 半导体器件的布线结构及其制造方法,其填充低于一半微米的接触孔。 绝缘层形成在半导体衬底上,并且在绝缘层中形成接触孔或通孔。 在绝缘层上,通过CVD法沉积第一金属,以形成填充接触孔的CVD金属层或CVD金属塞。 然后,将如此获得的CVD金属层或CVD金属插塞在低于第一金属的熔点的高温下在真空中进行热处理,从而平坦化其CVD金属层的表面。 通过溅射法在CVD金属层或CVD金属插塞上沉积第二种金属,从而形成溅射金属层。 通过CVD法将接触孔填充第一金属,然后通过溅射法沉积可靠的溅射金属层。 布线层可用于下一代的半导体器件。