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    • 11. 发明授权
    • Fuel composition containing an aromatic amide detergent
    • 含有芳香族酰胺洗涤剂的燃料组合物
    • US5336278A
    • 1994-08-09
    • US61377
    • 1993-05-13
    • Paul E. AdamsRichard M. LangeStephen H. Stoldt
    • Paul E. AdamsRichard M. LangeStephen H. Stoldt
    • C10L1/10C10L1/18C10L1/183C10L1/188C10L1/19C10L1/198C10L1/22C10L1/223C10L1/23
    • C10L1/183C10L1/1985C10L1/2235C10L1/231
    • A fuel composition comprising a major amount of a normally liquid fuel and a minor amount of at least one compound of the general formula ##STR1## wherein each Ar is independently an aromatic group having from 4 to about 30 carbon atoms and from 0 to 3 optional substituents selected from the group consisting of amino, hydroxy- or alkyl- polyoxyalkyl, nitro, aminoalkyl, carboxy or combinations of two or more of said optional substituents, each R is independently a hydrocarbyl group, R.sup.1 is H or a hydrocarbyl group, R.sup.2 and R.sup.3 are each, independently, H or a hydrocarbyl group, R.sup.4 is a monovalent terminating group, each m is independently 0 or an integer ranging from 1 to about 10, x ranges from 0 to about 8, and each Z is independently OH, lower alkoxy, (OR.sup.5).sub.b OR.sup.6 or O.sup.- wherein each R.sup.5 is independently a divalent hydrocarbyl group, R.sup.6 is H or hydrocarbyl and b is a number ranging from 1 to about 30 and c ranges from 1 to about 3, y is a number ranging from 1 to about 10 and wherein the sum m+c does not exceed the number of valences of the corresponding Ar available for substitution and at least one A is independently an amide or an amide-containing group. In one embodiment, (I) is present in an amount effective to provide total fuel intake system cleanliness in a port fuel injected internal combustion engine.
    • 一种燃料组合物,其包含主要量的常规液体燃料和少量至少一种通式为(I)的化合物,其中每个Ar独立地为具有4-30个碳原子的芳基和0 至3个选自氨基,羟基或烷基 - 聚氧基烷基,硝基,氨基烷基,羧基或两个或多个所述任选取代基的组合的任选取代基,每个R独立地为烃基,R 1为H或烃基 ,R 2和R 3各自独立地为H或烃基,R 4为一价末端基团,各m独立地为0或1至约10的整数,x为0至约8,Z各自独立地为 OH,低级烷氧基,(OR 5)bOR 6或O-,其中每个R 5独立地为二价烃基,R 6为H或烃基,b为1至约30的数,c为1至约3,y为 数字范围从1到大约10,其中s 嗯m + c不超过相应的可用于取代的Ar的化合价数,并且至少一个A独立地是酰胺或含酰胺基团。 在一个实施方案中,(I)以有效提供在燃料喷射的内燃机的燃油进口系统清洁度的有效量存在。
    • 16. 发明授权
    • Fuel compositions containing N-substituted perahydro-s triazines
    • 燃料组合物含有N-取代的全氢三嗪
    • US5830243A
    • 1998-11-03
    • US927734
    • 1997-09-11
    • Thomas J. WolakDaniel T. DalyKurt F. WollenbergWilliam D. AbrahamPaul E. AdamsMitchell M. Jackson
    • Thomas J. WolakDaniel T. DalyKurt F. WollenbergWilliam D. AbrahamPaul E. AdamsMitchell M. Jackson
    • C07D251/04C08G65/32C10L1/22C10L1/232C10L10/00C10L10/04
    • C10L1/232C10L1/221C10L10/04
    • The present invention is directed to a composition made by reacting A) an aldehyde of 1 to 12 carbon atoms or a reactive equivalent thereof; and B) at least one etheramine represented by the formula R.sup.2 �O(CH.sub.2 CH(R)O).sub.n --R.sup.1 --NH.sub.2 !.sub.y(I) wherein each n is a number from 0 to about 50; each R is selected from the group consisting of hydrogen, hydrocarbyl groups of 1 to about 16 carbon atoms, and mixtures thereof; each R.sup.1 is selected from the group consisting of a hydrocarbylene group containing 2 to about 18 carbon atoms and a group represented by the formula ##STR1## wherein both R.sup.6 and R.sup.7 are hydrocarbylene groups of about 3 to about 10 carbon atoms and p is a number from 1 to 4; y is 1, 2, or 3; and each R.sup.2 is a hydrocarbyl group having a valence of y and containing 1 to about 50 carbon atoms when y is 1 and 1 to about 18 carbon atoms when y is 2 or 3; y is 1, 2, or 3; provided that when n is zero, y is 1. The reaction product can include a N-substituted perhydro-s-triazine represented by the formula ##STR2## Fuel additives containing these compositions are useful in reducing intake valve deposit and do not contribute to the increase in combustion chamber deposit in port fuel injected engines.
    • 本发明涉及通过使A)1至12个碳原子的醛或其活性当量反应而制备的组合物; 和B)由式R 2 [O(CH 2 CH(R)O)n -R 1 -NH 2] y(I)表示的至少一种醚胺,其中每个n为0至约50的数; 每个R选自氢,1至约16个碳原子的烃基,及其混合物; 每个R 1选自含有2至约18个碳原子的亚烃基和由下式表示的基团:其中R 6和R 7均为约3至约10个碳原子的亚烃基,p为数 从1到4; y为1,2或3; 当y为2或3时,当y为1和约1至约18个碳原子时,每个R 2为价数为y且含有1至约50个碳原子的烃基; y为1,2或3; 条件是当n为0时,y为1.反应产物可包括由下式表示的N-取代的全氢-s-三嗪:含有这些组合物的燃料添加剂可用于减少进气阀沉积物,并且不对 增加港口燃油喷射发动机的燃烧室沉积。