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11. 发明授权

US09272255B2 Combustion device that produces hydrogen with the re-use of captured CO2 有权
标题翻译：燃烧装置，通过重新利用捕获的二氧化碳产生氢气
公开(公告)号：US09272255B2
公开(公告)日：2016-03-01
申请号：US11886135
申请日：2006-03-29
申请人： Jean-Xavier Morin , Corinne Beal , Silvestre Suraniti
发明人： Jean-Xavier Morin , Corinne Beal , Silvestre Suraniti
IPC分类号： B01J8/24 , B01J8/06 , C01B3/38 , C01B3/48 , F23C10/10 , F23C13/00 , F23C99/00 , F23L7/00
CPC分类号： B01J8/067 , B01J2208/00176 , B01J2208/00212 , B01J2208/00309 , B01J2208/0053 , B01J2219/00006 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0238 , C01B2203/0283 , C01B2203/0805 , C01B2203/0838 , C01B2203/1241 , F23C10/10 , F23C13/00 , F23C99/00 , F23C2900/03002 , F23C2900/99008 , F23L7/007 , Y02E20/322 , Y02E20/344 , Y02E20/346
摘要： The combustion device according to the invention produces gases containing CO2 and water vapor and comprises a circulating fluidized bed reaction chamber (1, 2), a separator (10, 20), heat recovery means of which a part is situated in a dense fluidized bed (12, 12a, 22), wherein the part located in the bed of the heat recovery system(s) is composed of catalyst tubes (120, 120a, 220) through which a gas mixture flows. The gas mixture is composed of natural gas and/or naphtha or refinery gas or two or more of these gases. The gas undergoes reformation which converts it into a synthesis gas containing hydrogen. The fact of the catalyst tubes being situated in the dense fluidized bed made up of ashes from the combustion allows the catalyst to be reheated in a homogenous manner and the reforming reaction of the natural gas mixture to be stimulated.
摘要翻译：根据本发明的燃烧装置产生含有CO 2和水蒸气的气体，并且包括循环流化床反应室（1,2），分离器（10,20），热回收装置，其部分位于致密流化床（12,12a，22），其中位于热回收系统的床中的部件由气体混合物流过的催化剂管（120,120a，220）组成。气体混合物由天然气和/或石脑油或精炼气体或这些气体中的两种或更多种组成。气体经历重整，将其转化为含氢的合成气。催化剂管位于由燃烧的灰分构成的致密流化床中的事实允许催化剂以均匀的方式再次加热，并且天然气混合物的重整反应被刺激。

12. 发明授权

US08171893B2 Oxygen-producing oxycombustion boiler 有权
标题翻译：生产氧气的氧化锅炉
公开(公告)号：US08171893B2
公开(公告)日：2012-05-08
申请号：US10590357
申请日：2005-02-22
申请人： Jean-Xavier Morin , Corinne Beal , Silvestre Suraniti
发明人： Jean-Xavier Morin , Corinne Beal , Silvestre Suraniti
IPC分类号： F23C10/18
CPC分类号： F23C10/04 , F23C10/18 , F23L7/007 , Y02E20/322 , Y02E20/344
摘要： The boiler of the invention has a circulating fluidized bed, uses solid fuels and the oxygen obtained by high temperature oxygen production membranes, and is characterized in that the membranes are placed in the bed. These membranes are, for example, of the OTM (Oxygen Transport Membranes) type. Since the membranes operate at over 700° C., their positioning in the outer bed is ideally selected because the temperature of the solids circulating in the outer bed is between 750 and 900° C. This is particularly remarkable because the operating temperature windows of the circulating fluidized bed coincide with the optimal temperature window of use of the membranes.
摘要翻译：本发明的锅炉具有循环流化床，使用固体燃料和由高温氧气生产膜获得的氧气，其特征在于将膜放置在床中。这些膜例如是OTM（氧气输送膜）型。由于膜的工作温度超过700°C，所以它们在外层床上的定位是理想的选择，因为在外层床中循环的固体的温度为750-900℃。这是特别显着的，因为循环流化床与使用膜的最佳温度窗口重合。

13. 发明申请

US20070175411A1 Oxygen-producing oxycombustion boiler 有权
标题翻译：生产氧气的氧化锅炉
公开(公告)号：US20070175411A1
公开(公告)日：2007-08-02
申请号：US10590357
申请日：2005-02-22
申请人： Jean-Xavier Morin , Corinne Beal , Silvestre Suraniti
发明人： Jean-Xavier Morin , Corinne Beal , Silvestre Suraniti
IPC分类号： F23C10/00
CPC分类号： F23C10/04 , F23C10/18 , F23L7/007 , Y02E20/322 , Y02E20/344
摘要： The boiler of the invention has a circulating fluidized bed, uses solid fuels and the oxygen obtained by high temperature oxygen production membranes, and is characterized in that the membranes are placed in the bed. These membranes are, for example, of the OTM (Oxygen Transport Membranes) type. Since the membranes operate at over 700° C., their positioning in the outer bed is ideally selected because the temperature of the solids circulating in the outer bed is between 750 and 900° C. This is particularly remarkable because the operating temperature windows of the circulating fluidized bed coincide with the optimal temperature window of use of the membranes.
摘要翻译：本发明的锅炉具有循环流化床，使用固体燃料和由高温氧气生产膜获得的氧气，其特征在于将膜放置在床中。这些膜例如是OTM（氧气输送膜）型。由于膜的工作温度超过700°C，所以它们在外层床上的定位是理想的选择，因为在外层床中循环的固体的温度为750-900℃。这是特别显着的，因为循环流化床与使用膜的最佳温度窗口重合。

14. 发明授权

US06938780B2 Centrifugal separator in particular for fluidized bed reactor device 失效
标题翻译：离心分离器特别适用于流化床反应器装置
公开(公告)号：US06938780B2
公开(公告)日：2005-09-06
申请号：US10451769
申请日：2002-10-29
申请人： Daniel Baglione , Jean-Claude Semedard , Pierre Gauville , Jean-Xavier Morin , Emmanuel Flores
发明人： Daniel Baglione , Jean-Claude Semedard , Pierre Gauville , Jean-Xavier Morin , Emmanuel Flores
IPC分类号： B04C5/04 , B04C5/081 , F27B15/00
CPC分类号： B04C5/04 , B04C5/081
摘要： A centrifugal separator for separating particles from gas uses a separator chamber having an upper potion with at least three substantially vertical planar walls with perpendicular inner faces, and a lower portion, for defining in the chamber a vertical gas vortex. The gas vortex has an inlet formed in the vicinity of a first corner between the first and second walls for gas to be dedusted, an outlet for dedusted gas, and an outlet for separated particles. The separator uses an acceleration duct with a first transverse section at the first end of the duct that is distinctly greater than a second cross section at the second end. This second end is connected to the inlet for gas to be dedusted at the first corner.
摘要翻译：用于从气体分离颗粒的离心分离器使用具有上部部分的分离器室，其具有至少三个具有垂直内表面的基本垂直的平面壁和用于在室中限定垂直气体涡流的下部。气体涡流具有在第一和第二壁之间的第一角附近形成用于要除尘的气体的入口，用于除尘气体的出口和用于分离的颗粒的出口。分离器使用在管道的第一端处具有明显大于第二端处的第二横截面的第一横截面的加速管道。该第二端连接到第一角处的用于除尘的气体入口。

15. 发明授权

US06779492B2 Circulating fluidized bed reactor device 有权
标题翻译：循环流化床反应器装置
公开(公告)号：US06779492B2
公开(公告)日：2004-08-24
申请号：US10451830
申请日：2003-06-25
申请人： Daniel Baglione , Jean-Claude Semedard , Pierre Gauville , Jean-Xavier Morin , Emmanuel Flores , Alain Quaranta , Christian Bonnand
发明人： Daniel Baglione , Jean-Claude Semedard , Pierre Gauville , Jean-Xavier Morin , Emmanuel Flores , Alain Quaranta , Christian Bonnand
IPC分类号： B09B300
CPC分类号： F23C10/10
摘要： The circulating fluidized bed reactor device comprising a reactor chamber delimited horizontally by walls, a centrifugal separator and a back pass for heat recovery The reactor device allows for the introduction of a fluidizing gas into the reactor chamber and for maintaining a fluidized bed of particles in said chambers. The gas to be dedusted is transferred from the reactor chamber into the separator, and the separated particles are discharged from the separator and the dedusted gas is transferred from the separator into the back pass. The reactor chamber and the separator both have a common wall with the back pass.
摘要翻译：循环流化床反应器装置包括由壁水平界定的反应器室，离心分离器和用于热回收的反向通道。反应器装置允许将流化气体引入反应器室中，并将颗粒流化床保持在所述房间。要除尘的气体从反应器室转移到分离器中，并且分离的颗粒从分离器排出，并且除尘气体从分离器转移到后通道中。反应器室和分离器都具有带有后通道的公共壁。

16. 发明授权

US07658167B2 Fluidized-bed device with oxygen-enriched oxidizer 有权
标题翻译：具有富氧氧化剂的流化床装置
公开(公告)号：US07658167B2
公开(公告)日：2010-02-09
申请号：US11579097
申请日：2005-05-26
申请人： Jean-Xavier Morin , Silvestre Suraniti
发明人： Jean-Xavier Morin , Silvestre Suraniti
IPC分类号： F23C10/20
CPC分类号： F23C10/20 , B01J8/0055 , B01J8/1818 , B01J8/1863 , B01J8/26 , B01J8/44 , F23C10/10 , F23L7/005 , F23L7/007 , Y02E20/344
摘要： The invention relates to a fluidized-bed device (F1, F2) provided with a hearth (1, 23) equipped with gas mixture feeds called primary feeds, said gas mixture being enriched with oxygen, and said hearth (1, 23) being provided with a network of two types of primary feed nozzle, a first type of nozzle (B1, B′1) injecting a first gas mixture at a first level close to the hearth (1, 23) and a second type of nozzle (B2, B′2) injecting a second oxygen-enriched gas mixture at a second level above the first level.According to the invention, said second type of nozzle (B2, B′2) consists of a device for mixing oxygen with a second gas component and connected by its lower end to an oxygen feed (11A, 11A′) and to a feed of second gas component, and of a device for injecting this mixture into the combustion chamber.
摘要翻译：本发明涉及一种流化床装置（F1，F2），其设有装有称为初级进料的气体混合物进料的炉床（1,23），所述气体混合物富含氧气，所述炉床（1）和具有两种类型的主进料喷嘴的网络，第一类型的喷嘴（B1，B'1）将第一气体混合物注入靠近炉床（1,23）的第一级和第二类型的喷嘴（B2， B'2）在第一级以上的第二级注入第二富氧气体混合物。根据本发明，所述第二类型的喷嘴（B2，B'2）由用于将氧气与第二气体组分混合并通过其下端连接到氧气进料（11A，11A'）的装置组成，第二气体成分和用于将该混合物注入燃烧室的装置。

17. 发明申请

US20080000403A1 Fluidized-Bed Device With Oxygen-Enriched Oxidizer 有权
标题翻译：带氧氧化剂的流化床装置
公开(公告)号：US20080000403A1
公开(公告)日：2008-01-03
申请号：US11579097
申请日：2005-05-26
申请人： Jean-Xavier Morin , Silvestre Suraniti
发明人： Jean-Xavier Morin , Silvestre Suraniti
IPC分类号： F23C10/10
CPC分类号： F23C10/20 , B01J8/0055 , B01J8/1818 , B01J8/1863 , B01J8/26 , B01J8/44 , F23C10/10 , F23L7/005 , F23L7/007 , Y02E20/344
摘要： The invention relates to a fluidized-bed device (F1, F2) provided with a hearth (1, 23) equipped with gas mixture feeds called primary feeds, said gas mixture being enriched with oxygen, and said hearth (1, 23) being provided with a network of two types of primary feed nozzle, a first type of nozzle (B1, B′1) injecting a first gas mixture at a first level close to the hearth (1, 23) and a second type of nozzle (B2, B′2) injecting a second oxygen-enriched gas mixture at a second level above the first level. According to the invention, said second type of nozzle (B2, B′2) consists of a device for mixing oxygen with a second gas component and connected by its lower end to an oxygen feed (11A, 11A′) and to a feed of second gas component, and of a device for injecting this mixture into the combustion chamber.
摘要翻译：本发明涉及一种流化床装置（F 1，F 2），该流化床装置（F 1，F 2）设置有装有称为初级进料的气体混合物进料的炉床（1,23），所述气体混合物富含氧气，所述炉床（1）设置有两种类型的主进料喷嘴的网络，第一类型的喷嘴（B 1，B'1），其在靠近炉床（1）的第一级注入第一气体混合物，第二类型的喷嘴（B 2，B'2）以高于第一水平的第二水平注入第二富氧气体混合物。根据本发明，所述第二类型的喷嘴（B 2，B'2）由用于将氧气与第二气体组分混合并通过其下端连接到氧气进料（11A，11A'）的装置组成，并且第二气体组分的进料和用于将该混合物喷射到燃烧室中的装置。

18. 发明授权

US5700431A Method and a device for monitoring the internal circulation in a fluidized bed reactor, and a reactor provided with such a device 失效
标题翻译：用于监测流化床反应器内部循环的方法和装置，以及设置有这种装置的反应器
公开(公告)号：US5700431A
公开(公告)日：1997-12-23
申请号：US731005
申请日：1996-10-09
申请人： Silvestre Suraniti , Jean-Xavier Morin
发明人： Silvestre Suraniti , Jean-Xavier Morin
IPC分类号： B01J8/18 , B01J8/24 , F23C10/28
CPC分类号： B01J8/1809 , F23C10/28 , F28D13/00 , F28F27/00 , B01J2208/00044 , B01J2208/00548 , B01J2208/00654 , B01J2219/187
摘要： A monitoring device for continuously monitoring the internal circulation flow-rate of solid particles in a circulating fluidized bed reactor including a bottom zone into which the fluidization gas is injected and a top zone surrounded by walls. The device includes a sampling tank for sampling internal circulation of solids, which tank is fixed against one of the walls of the reactor and is provided with a fluidization device. A removal pipe is provided for removing the solids from the tank and conveying them to a measuring device for measuring the flow-rate of the solids. A return pipe is provided for returning the solids from the measuring device to the inside of the reactor.
摘要翻译：一种监测装置，用于连续监测循环流化床反应器中固体颗粒的内部循环流动速率，该循环流化床反应器包括注入流化气体的底部区域和由壁围成的顶部区域。该装置包括用于对固体的内部循环进行采样的采样罐，该罐被固定在反应堆的一个壁上并且设置有流化装置。提供了一种去除管，用于从罐中取出固体并将其输送到用于测量固体流速的测量装置。提供了一个返回管，用于将固体从测量装置返回到反应器的内部。

19. 发明授权

US5628967A Method and a device for monitoring the internal circulation in a fluidized bed reactor, and a reactor provided with such a device 失效
标题翻译：用于监测流化床反应器内部循环的方法和装置，以及设置有这种装置的反应器
公开(公告)号：US5628967A
公开(公告)日：1997-05-13
申请号：US499912
申请日：1995-07-11
申请人： Silvestre Suraniti , Jean-Xavier Morin
发明人： Silvestre Suraniti , Jean-Xavier Morin
IPC分类号： B01J8/18 , B01J8/24 , F23C10/28
CPC分类号： B01J8/1809 , F23C10/28 , F28D13/00 , F28F27/00 , B01J2208/00044 , B01J2208/00548 , B01J2208/00654 , B01J2219/187
摘要： A monitoring device for continuously monitoring the internal circulation flow-rate of solid particles in a circulating fluidized bed reactor including a bottom zone into which the fluidization gas is injected, and a top zone surrounded by walls. The device includes a sampling tank for sampling internal circulation solids, which tank is fixed against one of the walls of the reactor and is provided with a fluidization device. A removal pipe is provided for removing the solids from the tank and conveying them to a measuring device for measuring the flow-rate of the solids. A return pipe is provided for returning the solids from the measuring device to the inside of the reactor.
摘要翻译：一种用于连续监测循环流化床反应器中的固体颗粒的内部循环流量的监测装置，其包括注入流化气体的底部区域和被壁围成的顶部区域。该装置包括用于对内部循环固体进行采样的采样罐，该采样罐固定在反应堆的一个壁上并设置有流化装置。提供了一种去除管，用于从罐中取出固体并将其输送到用于测量固体流速的测量装置。提供了一个返回管，用于将固体从测量装置返回到反应器的内部。

20. 发明授权

US06737031B2 Method of simultaneously reducing CO2 and SO2 emissions in a combustion installation 有权
标题翻译：同时减少燃烧装置中二氧化碳和二氧化硫排放的方法
公开(公告)号：US06737031B2
公开(公告)日：2004-05-18
申请号：US09951389
申请日：2001-09-14
申请人： Corinne Beal , Jean-Xavier Morin , Michel Vandycke
发明人： Corinne Beal , Jean-Xavier Morin , Michel Vandycke
IPC分类号： C01B1716
CPC分类号： B01D53/501 , B01D53/62 , B01D2251/404 , B01D2257/504 , F23C2206/10 , F23J7/00 , F23J15/003 , F23J15/006 , F23J2215/20 , F23J2215/50 , F23J2900/01007 , Y02A50/2342 , Y02C10/04 , Y02E20/324 , Y02E20/326
摘要： The method of simultaneously reducing carbon dioxide (CO2) emissions and sulfur dioxide (SO2) emissions produced by the combustion of carbon-containing matter in a hearth consists in injecting into the hearth a calcium-based agent, a fraction of which absorbs SO2 after decarbonization, and then, after the flue gases have been subjected to intermediate cooling, in causing them to transit via a first reactor and in putting them in contact therein with the other fraction of the absorbant that has not reacted with SO2 so as to capture CO2 from the flue gases by carbonization, then, in a separator, in extracting the solids contained in the flue gases output from the first reactor so as to subject them to heat treatment in a second reactor in order to extract CO2 therefrom by decarbonization and in order to recycle the resulting regenerated CO2 absorbant to the first reactor.
摘要翻译：同时减少二氧化碳（CO2）排放和炉内含碳物质燃烧产生的二氧化硫（SO2）排放的方法是在炉内注入钙基剂，其中一部分在脱碳后吸收SO2 然后，在烟道气已经进行中间冷却之后，使得它们经由第一反应器运输并使其与未与SO 2反应的吸收剂的其它部分接触以从其中吸收CO 2 烟道气通过碳化，然后在分离器中提取从第一反应器输出的烟道气中所含的固体，以使其在第二反应器中进行热处理，以便通过脱碳从其中提取二氧化碳，并且为了将得到的再生的CO 2吸收剂再循环到第一反应器。

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