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    • 13. 发明授权
    • Polymer production at supersolution conditions
    • 聚合物在超溶解条件下的生产
    • US08008412B2
    • 2011-08-30
    • US11954273
    • 2007-12-12
    • Patrick BrantKiss GaborChris B. FriedersdorfJames R. LattnerGary L. Casty
    • Patrick BrantKiss GaborChris B. FriedersdorfJames R. LattnerGary L. Casty
    • C08F10/06C08F2/06C08F4/60C08F4/64
    • C08F10/06C08F10/00C08F110/06C08F210/06C08F2/14C08F2/00C08F2/06C08F2500/15C08F2500/20C08F2500/09C08F2500/12C08F2500/01C08F2500/03C08F2500/17C08F2500/23C08F210/14C08F4/64144
    • This invention relates to a process to polymerize olefins comprising contacting propylene, at a temperature of 65° C. to 150° C. and a pressure of 1.72 to 34.5 MPa, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers selected from ethylene and C4 to C12 olefins, 3) diluent or solvent, and 4) optionally scavenger, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 30 wt % or more, b) the propylene is present in the feed at 80 wt % or more, c) the polymerization occurs at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure greater than 1 MPa below the cloud point pressure of the polymerization system, and d) the polymerization occurs: (1) at a temperature below the critical temperature of the polymerization system, or (preferably and) (2) at a pressure below the critical pressure of the polymerization system.
    • 本发明涉及聚合烯烃的方法,包括使丙烯在65℃至150℃的温度和1.72至34.5MPa的压力下接触,其中:1)包含一种或多种活化剂和一种或多种活化剂的催化剂体系 更多的非金属茂金属中心的杂芳基配位体催化剂化合物,其中金属选自第4,5,6族,镧系元素或元素周期表的锕系列,2)任选的一种或多种共聚单体,其选自 乙烯和C 4至C 12烯烃,3)稀释剂或溶剂,和4)任选的清除剂,其中:a)烯烃单体和任何共聚单体在聚合体系中以30重量%或更多存在,b)丙烯存在于 进料为80重量%以上,c)在高于聚合体系的固体 - 流体相转变温度的温度和低于聚合体系浊点压力1MPa的压力下进行聚合,和d)聚合反应 n发生:(1)在低于聚合体系临界温度的温度下,或(优选和)(2)在低于聚合体系临界压力的压力下。
    • 19. 发明授权
    • Methanol manufacture using pressure swing reforming
    • 使用压力挥发重整的甲醇制造
    • US07148261B2
    • 2006-12-12
    • US11011984
    • 2004-12-14
    • Frank HershkowitzJames R. Lattner
    • Frank HershkowitzJames R. Lattner
    • C07C27/00C07C1/00
    • C07C29/1518Y02P30/42C07C31/04C07C31/08C07C31/10C07C31/02
    • A process for producing methanol is described in which a hydrocarbon is steam reformed in a reforming zone, and during the reforming stage, of a cyclic steam reformer having a reforming stage and a regeneration stage, the steam reforming being conducted under conditions effective to produce a first effluent stream containing synthesis gas. Fuel and an oxygen-containing gas are combusted in the regeneration stage of the reformer so as to reheat the reforming zone to a temperature sufficient for the reforming stage and generate a flue gas. At least part of the first effluent stream is contacted with a methanol synthesis catalyst under conditions effective to convert synthesis gas to methanol and form a methanol-containing stream and a tail gas stream comprising unreacted carbon monoxide and hydrogen. At least part of the tail gas stream is recycled as fuel for the regeneration stage of the cyclic steam reformer.
    • 描述了一种生产甲醇的方法,其中烃在重整区中进行蒸汽重整,并且在重整阶段期间,在具有重整阶段和再生阶段的循环蒸汽重整器中,蒸汽重整在有效产生 含有合成气的第一流出物流。 燃料和含氧气体在重整器的再生阶段中燃烧,以便将重整区再加热到足以进行重整阶段的温度并产生烟道气。 在有效地将合成气转化成甲醇并形成含甲醇流和包含未反应的一氧化碳和氢气的尾气流的条件下,将至少部分第一流出物流与甲醇合成催化剂接触。 至少部分尾气流作为循环蒸汽重整器的再生阶段的燃料再循环。