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    • 13. 发明授权
    • Surface charge enhanced atomic layer deposition of pure metallic films
    • 表面电荷增强纯金属薄膜的原子层沉积
    • US08425987B2
    • 2013-04-23
    • US12347940
    • 2008-12-31
    • Juan E. DominguezAdrien R. LavoieJohn J. PlombonHarsono S. Simka
    • Juan E. DominguezAdrien R. LavoieJohn J. PlombonHarsono S. Simka
    • C23C8/00C23C16/00
    • C23C16/45536C23C16/18C23C16/44C23C16/45525C23C16/4581C23C16/487
    • A method including applying an electric charge to a substrate in a chamber; introducing an organometallic substituent into the chamber, the organometallic substituent including a metal ligand and an organic ligand; and depositing a metal film by reducing the metal ligand of the organometallic substituent. A method including applying a removable electric charge to a substrate; in the presence of the applied electric charge, introducing an organometallic substituent into the chamber, the organometallic substituent including a metal ligand and an organic ligand; and depositing a metal film by reducing the metal ligand of the organometallic substituent. A method including introducing an organometallic substituent into the chamber, the organometallic substituent including a metal ligand and an organic ligand; and depositing a metal film by reducing the metal ligand of the organometallic substituent with an externally applied electric charge.
    • 一种方法,包括向腔室中的基板施加电荷; 将有机金属取代基引入室中,有机金属取代基包括金属配体和有机配体; 以及通过还原有机金属取代基的金属配体沉积金属膜。 一种方法,包括将可移除的电荷施加到基底上; 在所施加的电荷的存在下,将有机金属取代基引入室中,所述有机金属取代基包括金属配体和有机配体; 以及通过还原有机金属取代基的金属配体沉积金属膜。 一种包括将有机金属取代基引入到室中的方法,包括金属配体和有机配体的有机金属取代基; 以及通过用外部施加的电荷还原有机金属取代基的金属配体来沉积金属膜。
    • 19. 发明申请
    • ORGANOMETALLIC COMPOUNDS, PROCESSES FOR THE PREPARATION THEREOF AND METHODS OF USE THEREOF
    • 有机化合物,其制备方法及其使用方法
    • US20090209777A1
    • 2009-08-20
    • US12352256
    • 2009-01-12
    • David M. ThompsonJoan GearyAdrien R. LavoieJuan E. Dominguez
    • David M. ThompsonJoan GearyAdrien R. LavoieJuan E. Dominguez
    • C07F17/02
    • C07F15/0053C08K5/56C09D1/00C09D7/63C23C16/18
    • This invention relates to organometallic compounds having the formula (L1)M(L2)y wherein M is a metal or metalloid, L1 is a substituted or unsubstituted anionic 6 electron donor ligand, L2 is the same or different and is (i) a substituted or unsubstituted anionic 2 electron donor ligand, (ii) a substituted or unsubstituted anionic 4 electron donor ligand, (iii) a substituted or unsubstituted neutral 2 electron donor ligand, or (iv) a substituted or unsubstituted anionic 4 electron donor ligand with a pendant neutral 2 electron donor moiety; and y is an integer of from 1 to 3; and wherein the sum of the oxidation number of M and the electric charges of L1 and L2 is equal to 0; a process for producing the organometallic compounds, and a method for producing a film or coating from the organometallic compounds. The organometallic compounds are useful in semiconductor applications as chemical vapor or atomic layer deposition precursors for film depositions.
    • 本发明涉及具有式(L1)M(L2)y的有机金属化合物,其中M是金属或准金属,L1是取代或未取代的阴离子6电子供体配体,L2相同或不同,为(i)取代的 或未取代的阴离子2电子供体配体,(ii)取代或未取代的阴离子4电子供体配体,(iii)取代或未取代的中性2电子供体配体,或(iv)取代或未取代的具有侧基的阴离子4电子给体配体 中性2电子供体部分; y为1〜3的整数, 并且其中M的氧化数和L1和L2的电荷之和等于0; 一种生产有机金属化合物的方法,以及由有机金属化合物制备薄膜或涂层的方法。 有机金属化合物可用作半导体应用,作为用于膜沉积的化学蒸气或原子层沉积前体。