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    • 15. 发明授权
    • Method for forming high contrast photographic image
    • 用于形成高对比度摄影图像的方法
    • US4377634A
    • 1983-03-22
    • US129458
    • 1980-03-11
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraYoshiharu Fuseya
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraYoshiharu Fuseya
    • G03C5/29C07D231/56C07D249/12C07D257/04C07D285/12C07D285/125G03C1/06G03C1/10G03C5/305G03C5/30
    • G03C1/061C07D231/56C07D249/12C07D257/04C07D285/125
    • A method for forming a high contrast negative photographic image, which comprises imagewise exposing a photographic material comprising a support having thereon at least one photographic silver halide emulsion layer with the photographic silver halide emulsion layer or at least one hydrophilic colloid layer of the photographic material containing a compound of the general formula (I)R.sup.1 --NHNHCO--R.sup.2 (I)wherein R.sup.1 represents an aryl group, and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group containing 1 to 3 carbon atoms, and then developing the imagewise exposed material in the presence of a hydroquinone compound of the general formula (II) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, a sulfo group, an alkyl group, an aryl group, an aralkyl group, a heterocyclic group, or a group of the formula --O--R.sup.7 or --S--R.sup.7 where R.sup.7 represents an alkyl group, an aryl group, an aralkyl group, or a heterocyclic group with at least one of R.sup.3, R.sup.4, R.sup.5 and R.sup.6 representing a group other than a hydrogen atom or a sulfo group.
    • 一种用于形成高对比度负摄影图像的方法,其包括将包含其上的至少一个照相卤化银乳剂层的支持体的照相材料成像曝光于所述照相卤化银乳剂层或所述照相材料的至少一个亲水胶体层, 通式(I)R1-NHNHCO-R2(I)的化合物,其中R1表示芳基,R2表示氢原子,苯基或含有1至3个碳原子的未取代的烷基,然后显影 在通式(II)的对苯二酚化合物(II)存在下的成像曝光材料,其中可以相同或不同的R 3,R 4,R 5和R 6各自表示氢原子,磺基 ,烷基,芳基,芳烷基,杂环基或式-O-R7或-S-R7的基团,其中R7表示烷基,芳基,芳烷基或杂环 与R3,R4,R5和R6中至少一个表示除氢原子或磺基以外的基团。
    • 16. 发明授权
    • Lithographic silver halide photographic light-sensitive material
    • 平版印刷卤化银照相感光材料
    • US4328302A
    • 1982-05-04
    • US232483
    • 1981-02-09
    • Tatsuo NishimuraHiroyuki MifuneYoshiharu FuseyaYukihide UrataTadao ShishidoYasuo Kasama
    • Tatsuo NishimuraHiroyuki MifuneYoshiharu FuseyaYukihide UrataTadao ShishidoYasuo Kasama
    • G03C1/06C07D257/04G03C1/35
    • C07D257/04G03C1/355Y10S430/15
    • A lithographic silver halide photographic light-sensitive material is described which scarcely exhibits colored fringe and black pepper, forms halftone dots of good quality whether a fresh or an exhausted developer is used for processing thereof, and which scarcely shows a drop in sensitivity even when a developer contaminated by a fixing solution is used; said material comprises a support and at least one lithographic silver halide emulsion layer, and containing in said emulsion layer or in another hydrophilic colliodal layer which does not contain silver halide emulsion at least one compound represented by formula (I) ##STR1## wherein M represents hydrogen, an alkali metal ion or --NH.sub.4.sup..sym. ; X represents --SO.sub.2 NHR', --COOM', --SO.sub.3 M', --OH or --CONH.sub.2, wherein M' represents hydrogen, an alkali metal ion or --NH.sub.4.sup..sym. ; and R' represents hydrogen or an alkyl group having from 1 to 3 carbon atoms; R represents hydrogen or an alkyl group having from 1 to 3 carbon atoms; and n represents 1 or 2.
    • 描述了几乎不显示有色边缘和黑胡椒的平版卤化银照相感光材料,即使使用新鲜或耗尽的显影剂进行处理,也形成质量好的半色调点,并且即使当 使用受固定液污染的显影剂; 所述材料包括载体和至少一个平版卤化银乳剂层,并且在所述乳剂层中或在不含有卤化银乳剂的另一亲水性乳液层中包含至少一种由式(I)表示的化合物(I) 其中M表示氢,碱金属离子或-NH4(+); X表示-SO 2 NHR',-COOM',-SO 3 M',-OH或-CONH 2,其中M'表示氢,碱金属离子或-NH 4(+)。 并且R'表示氢或具有1至3个碳原子的烷基; R表示氢或具有1至3个碳原子的烷基; n表示1或2。