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    • 13. 发明授权
    • Method for forming amorphous ferroelectric materials
    • 形成非晶铁电材料的方法
    • US5342648A
    • 1994-08-30
    • US949744
    • 1992-09-23
    • John D. MacKenzieRen XuYuhuan Xu
    • John D. MacKenzieRen XuYuhuan Xu
    • C04B35/624H01L37/02H01L41/22B05D5/12C04B35/46
    • C04B35/624H01L37/025H01L41/081H01L41/318
    • Amorphous ferroelectric materials are formed by a sol-gel type process and the ferroelectric properties stabilized by complete hydrolysis and polycondensation, and extraction of residual organic materials, preferably by heating at temperatures below the temperature at which crystallization may occur. Stable solutions of metal alkoxides are prepared by reacting or dissolving a metal alkoxide in alcohol such as absolute ethanol. The solution may be spincast on essentially any substrate, conductor or nonconductor, crystalline or amorphous, transparent or opaque, and even including plastics. Hydrolysis and polycondensation occur in situ to deposit an amorphous ferroelectric film. Residual alcohol is extracted by heating below the temperature at which crystallization occurs. Such films show P-E hysteresis loops and pyroelectric current. Such ferroelectric thin films are useable in electronic, opto-electronic and optical devices.
    • 无定形铁电材料通过溶胶 - 凝胶型工艺形成,铁电性能通过完全水解和缩聚稳定,并提取残留的有机材料,优选通过在低于可能发生结晶的温度的温度下加热。 金属醇盐的稳定溶液通过使金属醇盐在无水乙醇等醇中反应或溶解来制备。 溶液可以在基本上任何基材,导体或非导体,晶体或无定形,透明或不透明的,甚至包括塑料上旋转。 原位发生水解和缩聚以沉积非晶铁电薄膜。 通过在低于发生结晶温度的加热下提取残余醇。 这种膜显示P-E磁滞回线和热电流。 这种铁电薄膜可用于电子,光电和光学器件。