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    • 13. 发明申请
    • NMR analyzer
    • NMR分析仪
    • US20070279059A1
    • 2007-12-06
    • US11717138
    • 2007-03-13
    • Katsuzou AiharaMichiya OkadaShigeru KakugawaHiroshi MoritaTsuyoshi Wakuda
    • Katsuzou AiharaMichiya OkadaShigeru KakugawaHiroshi MoritaTsuyoshi Wakuda
    • G01R33/44
    • G01R33/34046G01R33/34053G01R33/3806G01R33/3815G01R33/44G01R33/4808
    • A first room-temperature space is formed penetrating through a cryostat along a center axis of a split-type multi-layer cylindrical superconducting coil system which has a ratio of the maximum empirical magnetic field to the central magnetic filed of not larger than 1.3 and is horizontally arranged such that the center axis of the coil is in the horizontal direction, a room-temperature shim coil system is arranged in said first room-temperature space to improve the homogeneity of the magnetic field, a second room-temperature space is formed penetrating through the cryostat and passing through the center of said split gap in the vertical direction, and a sample to be measured and an NMR probe having a solenoid-type probe coil are inserted in said second room-temperature space. Further, the NMR analyzer has a new function constituted by a system for irradiating and detecting the electromagnetic waves having wavelengths of shorter than 0.1 mm.
    • 第一室温空间形成为沿分离型多层圆柱形超导线圈系统的中心轴穿过低温恒温器,该分离型多层圆柱形超导线圈系统的最大经验磁场与中心磁场的比值不大于1.3, 水平排列为使得线圈的中心轴线处于水平方向,在所述第一室温空间内布置室温垫片线圈系统,以改善磁场的均匀性,形成第二室温空间 通过低温恒温器并沿着垂直方向穿过所述分割间隙的中心,并且将待测量样品和具有螺线管型探针线圈的NMR探针插入所述第二室温空间中。 此外,NMR分析仪具有由用于照射和检测波长小于0.1mm的电磁波的系统构成的新功能。
    • 16. 发明申请
    • NMR magnet device for solution analysis and NMR apparatus
    • 用于溶液分析的NMR磁体装置和NMR装置
    • US20050253586A1
    • 2005-11-17
    • US11078360
    • 2005-03-14
    • Shigeru KakugawaMichiya OkadaKatsuzou AiharaHiroshi MoritaTsuyoshi Wakuda
    • Shigeru KakugawaMichiya OkadaKatsuzou AiharaHiroshi MoritaTsuyoshi Wakuda
    • G01R33/38G01R33/3815G01V3/00
    • G01R33/381G01R33/3815
    • A split type magnet device for a high-sensitivity NMR apparatus to be used for solution analysis generates a remarkably uniform magnetic field at the center portion of the magnet device used for determining a sample. The magnet device for NMR apparatus has first multilayer coils and second multilayer coils, which face each other with a predetermined distance being provided therebetween, each of pairs of the first and the second coils being substantially coaxial with respect to a central axis, and each of layers of each of the first and the second multilayer coils having at least one coil. An energizing current of at least one of the coils constituting an innermost layer of each of the first and the second multilayer coils is in a minus direction, when an energizing current of the coil used for generating a main magnetic field for NMR detection in the vicinity of a center portion of the apparatus is in a plus direction.
    • 用于溶液分析的用于高灵敏度NMR装置的分体式磁体装置在用于确定样品的磁体装置的中心部分处产生显着均匀的磁场。 用于NMR装置的磁体装置具有第一多层线圈和第二多层线圈,它们之间以预定的距离彼此面对,每对第一和第二线圈相对于中心轴线基本上同轴, 第一和第二多层线圈中的每一个的层具有至少一个线圈。 构成第一和第二多层线圈中的每一个的最内层的至少一个线圈的通电电流为负方向,当用于在附近生成用于NMR检测的主磁场的线圈的通电电流时 的装置的中心部分处于正方向。
    • 18. 发明申请
    • NMR analyzer
    • NMR分析仪
    • US20050122112A1
    • 2005-06-09
    • US11025915
    • 2005-01-03
    • Katsuzou AiharaMichiya OkadaShigeru KakugawaHiroshi MoritaTsuyoshi Wakuda
    • Katsuzou AiharaMichiya OkadaShigeru KakugawaHiroshi MoritaTsuyoshi Wakuda
    • G01R33/32G01R33/345G01R33/3815G01R33/3875G01V3/00
    • G01R33/34046G01R33/34053G01R33/3806G01R33/3815G01R33/44G01R33/4808
    • A first room-temperature space is formed penetrating through a cryostat along a center axis of a split-type multi-layer cylindrical superconducting coil system which has a ratio of the maximum empirical magnetic field to the central magnetic filed of not larger than 1.3 and is horizontally arranged such that the center axis of the coil is in the horizontal direction, a room-temperature shim coil system is arranged in said first room-temperature space to improve the homogeneity of the magnetic field, a second room-temperature space is formed penetrating through the cryostat and passing through the center of said split gap in the vertical direction, and a sample to be measured and an NMR probe having a solenoid-type probe coil are inserted in said second room-temperature space. Further, the NMR analyzer has a new function constituted by a system for irradiating and detecting the electromagnetic waves having wavelengths of shorter than 0.1 mm.
    • 第一室温空间形成为沿分离型多层圆柱形超导线圈系统的中心轴穿过低温恒温器,该分离型多层圆柱形超导线圈系统的最大经验磁场与中心磁场的比值不大于1.3, 水平排列为使得线圈的中心轴线处于水平方向,在所述第一室温空间内布置室温垫片线圈系统,以改善磁场的均匀性,形成第二室温空间 通过低温恒温器并沿着垂直方向穿过所述分割间隙的中心,并且将待测量样品和具有螺线管型探针线圈的NMR探针插入所述第二室温空间中。 此外,NMR分析仪具有由用于照射和检测波长小于0.1mm的电磁波的系统构成的新功能。
    • 19. 发明授权
    • NMR analyzer
    • NMR分析仪
    • US06859036B2
    • 2005-02-22
    • US10315215
    • 2002-12-10
    • Katsuzou AiharaMichiya OkadaShigeru KakugawaHiroshi MoritaTsuyoshi Wakuda
    • Katsuzou AiharaMichiya OkadaShigeru KakugawaHiroshi MoritaTsuyoshi Wakuda
    • G01R33/32G01R33/345G01R33/3815G01R33/3875G01V3/00
    • G01R33/34046G01R33/34053G01R33/3806G01R33/3815G01R33/44G01R33/4808
    • A first room-temperature space is formed penetrating through a cryostat along a center axis of a split-type multi-layer cylindrical superconducting coil system which has a ratio of the maximum empirical magnetic field to the central magnetic field of not larger than 1.3 and is horizontally arranged such that the center axis of the coil is in the horizontal direction, a room-temperature shim coil system is arranged in said first room-temperature space to improve the homogeneity of the magnetic field, a second room-temperature space is formed penetrating through the cryostat and passing through the center of said split gap in the vertical direction, and a sample to be measured and an NMR probe having a solenoid-type probe coil are inserted in said second room-temperature space. Further, the NMR analyzer has a new function constituted by a system for irradiating and detecting the electromagnetic waves having wavelengths of shorter than 0.1 mm.
    • 第一室温空间形成为沿着分离式多层圆柱形超导线圈系统的中心轴穿过低温恒温器,其具有最大经验磁场与中心磁场的比例不大于1.3,并且是 水平排列为使得线圈的中心轴线处于水平方向,在所述第一室温空间内布置室温垫片线圈系统,以改善磁场的均匀性,形成第二室温空间 通过低温恒温器并沿着垂直方向穿过所述分割间隙的中心,并且将待测量样品和具有螺线管型探针线圈的NMR探针插入所述第二室温空间中。 此外,NMR分析仪具有由用于照射和检测波长小于0.1mm的电磁波的系统构成的新功能。
    • 20. 发明授权
    • Probe for NMR apparatus using magnesium diboride
    • 使用二硼化镁的NMR仪器的探头
    • US06967482B2
    • 2005-11-22
    • US10383655
    • 2003-03-10
    • Hiroshi MoritaMichiya OkadaKatsuzou Aihara
    • Hiroshi MoritaMichiya OkadaKatsuzou Aihara
    • H01F6/00G01R33/34G01V3/00H01F6/06
    • G01R33/34053G01R33/34023G01R33/34069G01R33/34092H01F6/06
    • To provide a probe coil for an NMR apparatus which can transmit and receive high frequency radio waves with improved Q-factor and S/N ratio. As a measure, the probe coil for an NMR apparatus is provided as of a solenoid type formed of magnesium diboride superconductor. As another measure, the probe coil for an NMR apparatus has a plurality of coils using magnesium diboride superconductors connected in series. As further another measure, there is used a magnesium diboride superconductor mixed with metal. As still further another measure, the probe coil for an NMR apparatus is formed by using a single metal selected from gold, silver, copper, aluminum, iron, platinum, palladium, nickel, stainless steel, chromium, magnesium, tantalum, niobium, titanium, zinc, beryllium, tungsten, or cobalt, or an alloy including a plurality thereof.
    • 提供一种能够以改善的Q因子和S / N比发送和接收高频无线电波的NMR装置的探针线圈。 作为测量,用于NMR装置的探针线圈以由二硼化镁超导体形成的螺线管形式提供。 作为另一个措施,用于NMR装置的探针线圈具有使用串联连接的二硼化硼超导体的多个线圈。 作为另一个措施,使用与金属混合的二硼化镁超导体。 作为另一种措施,NMR装置的探针线圈通过使用选自金,银,铜,铝,铁,铂,钯,镍,不锈钢,铬,镁,钽,铌,钛的单一金属形成 ,锌,铍,钨或钴,或包含多个的合​​金。