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    • 11. 发明授权
    • Ferrocene derivative for supplying plants with iron
    • 用于供应铁矿石的FERROCENE DERIVATIVE
    • US4053296A
    • 1977-10-11
    • US721736
    • 1976-09-09
    • Volker MuesJohannes Niggemann
    • Volker MuesJohannes Niggemann
    • C05D9/02C07F9/6518C07F15/02C07F17/02C05F11/10
    • C07F17/02C05D9/02Y10S71/02
    • Ferrocene derivatives of the formula ##STR1## IN WHICH R represents the group COOR.sup.1,in whichR.sup.1 represents hydrogen, alkyl, one equivalent of an alkali metal, alkaline earth metal or heavy metal cation, or an ammonium cation in which one or moreHydrogen atoms can be replaced by alkyl,Or R represents the group COR.sup.2in whichR.sup.2 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted cycloalkenyl or optionally substituted phenyl,OrR represents the group ##STR2## in which R.sup.3 represents hydrogen or alkyl andR.sup.4 represents a ureido or thioureido radical, a radical of the formula --CH.sub.2 --CH.sub.2 --N.dbd.CH--ferrocene, a 5-membered or 6-membered heterocyclic radical or a group of the formula --OR.sup.5 or --NH-R.sup.6,in whichR.sup.5 represents hydrogen, alkyl, one equivalent of an alkali metal or alkaline earth metal cation, or an ammonium cation in which one or more hydrogen atoms canbe replaced by alkyl, andR.sup.6 represents aryl or a 5-membered or 6-membered heterocyclic radical,OrR represents the sulfonamide group or the radical --SO.sub.3 R.sup.7,in whichR.sup.7 represents hydrogen, alkyl, one equivalent of an alkali metal or alkaline earth metal cation, or an ammonium cation in which one or more hydrogen atoms can be replaced by alkyl,Or p1 R represents an alkyl, aralkyl or aryl radical which can be substituted by hydroxyl, cyano, COOR.sup.1 or ##STR3## in which R.sup.1 has the above-mentioned meansing,R', r" and R'", independently of one another, each represent hydrogen or alkyl andA.sup.- represents halide or methosulfate, are outstandingly effective for supplying plants with the micro-nutrient iron.
    • 12. 发明授权
    • 2-Substituted benzazole pesticide synergists
    • 2-取代的苯唑农药增效剂
    • US4328219A
    • 1982-05-04
    • US129853
    • 1980-03-12
    • Volker MuesWolfgang Behrenz
    • Volker MuesWolfgang Behrenz
    • A01N43/78A01N43/74A01N43/76C07D263/58C07D277/68
    • A01N43/74
    • 2-Substituted benzazoles of the formula ##STR1## in which R represents optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted aryl or optionally substituted aralkyl,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, halogen, optionally halogen-substituted alkyl, optionally halogen-substituted alkoxy, nitro, cyano, alkylcarbonyl or alkoxycarbonyl, or two radicals in combination form a benzo radical,X and Y independently of one another represent oxygen or sulphur andn represents zero or 1,synergize conventional pesticides. Those benzazoles in whichR is --CH.sub.2 --C.dbd..tbd.CH,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent independently of one another hydrogen or halogen (preferably chlorine),Y represents oxygen andn represents 1,are new and exhibit particularly high synergistic activity.
    • 其中R表示任选取代的烷基,烯基,炔基,环烷基,任选取代的芳基或任选取代的芳烷基,R 1,R 2,R 3和R 4彼此独立的2-取代的苯并唑代表氢,卤素,任选的卤素 取代的烷基,任选的卤素取代的烷氧基,硝基,氰基,烷基羰基或烷氧基羰基,或两个组合形成苯并基,X和Y彼此独立地表示氧或硫,n表示0或1,协同常规农药。 其中R为-CH 2 -C = 3BOND CH,R 1,R 2,R 3和R 4的那些苯并唑相互独立地表示氢或卤素(优选氯),Y表示氧且n表示1,表现出特别高的协同作用 。
    • 15. 发明授权
    • Combating arthropods with ferrocene-containing synergistic compositions
    • 将节肢动物与含有二茂铁的协同组合物相结合
    • US4206227A
    • 1980-06-03
    • US882824
    • 1978-03-02
    • Volker MuesWolfgang Behrenz
    • Volker MuesWolfgang Behrenz
    • A01N31/04A01N35/06A01N35/08A01N37/34A01N55/02A01N57/00A01N9/02
    • A01N55/02
    • An arthropodicidal composition containing, as active ingredients, an arthropodicidally effective amount of (1) at least one ferrocene derivative of the formula ##STR1## in which R and R.sup.1 each independently is hydrogen, an alkyl or alkenyl radical optionally substituted by alkoxycarbonyl, aralkyl, cyanoalkyl, nitrile, or ##STR2## R.sup.2 is hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted phenyl or alkoxy,R.sup.3 is hydrogen, alkyl, alkanoyl or a polyalkylene polyether group,R.sup.4 and R.sup.5 each independently is alkyl or together are an alkylene radical,X is oxygen, hydroxyimino or alkoxyimino and,Y is oxygen or sulphur,and (2) at least one compound selected from (A) carbamates, (B) carboxylic acid esters, including the natural and synthetic pyrethroids, (C) phosphoric acid esters, (D) cycloalkanes, (E) halogenoalkanes and (F) tin compounds.
    • 一种节肢动物杀伤组合物,其含有作为活性成分的节肢动物节肢动物有效量的(1)至少一种下式的二茂铁衍生物,其中R和R 1各自独立地为氢,任选被烷氧基羰基,芳烷基取代的烷基或烯基, 氰基烷基,腈或R 2是氢,任选取代的烷基,任选取代的环烷基,任选取代的苯基或烷氧基,R 3是氢,烷基,烷酰基或聚亚烷基聚醚基团,R 4和R 5各自独立地是烷基或一起是 亚烷基,X是氧,羟亚氨基或烷氧基亚氨基,Y是氧或硫,和(2)至少一种选自(A)氨基甲酸酯,(B)羧酸酯,包括天然和合成拟除虫菊酯的化合物,(C) 磷酸酯,(D)环烷烃,(E)卤代烷烃和(F)锡化合物。
    • 18. 发明授权
    • Combating arthropods with ferrocene-containing synergistic compositions
    • 将节肢动物与含有二茂铁的协同组合物相结合
    • US4288451A
    • 1981-09-08
    • US053563
    • 1979-06-29
    • Volker MuesWolfgang Behrenz
    • Volker MuesWolfgang Behrenz
    • A01N31/04A01N35/06A01N35/08A01N37/34A01N55/02A01N57/00A01N37/00A01N43/02A01N43/08A01N43/36A01N65/00
    • A01N55/02
    • An arthropodicidal composition containing, as active ingredients, an arthropodicidally effective amount of (1) at least one ferrocene derivative of the formula ##STR1## in which R and R.sup.1 each independently is hydrogen, an alkyl or alkenyl radical optionally substituted by alkoxycarbonyl, aralkyl, cyanoalkyl, nitrile, or ##STR2## R.sup.2 is hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted phenyl or alkoxy,R.sup.3 is hydrogen, alkyl, alkanoyl or a polyalkylene polyether group,R.sup.4 and R.sup.5 each independently is alkyl or together are an alkylene radical,X is oxygen, hydroxyimino or alkoxyimino and,Y is oxygen or sulphur,and (2) at least one compound selected from (A) carbamates, (B) carboxylic acid esters, including the natural and synthetic pyrethroids, (C) phosphoric acid esters, (D) cycloalkanes, (E) halogenoalkanes and (F) tin compounds.
    • 一种节肢动物杀伤组合物,其含有作为活性成分的节肢动物节肢动物有效量的(1)至少一种下式的二茂铁衍生物,其中R和R 1各自独立地为氢,任选被烷氧基羰基,芳烷基取代的烷基或烯基, 氰基烷基,腈或R 2是氢,任选取代的烷基,任选取代的环烷基,任选取代的苯基或烷氧基,R 3是氢,烷基,烷酰基或聚亚烷基聚醚基团,R 4和R 5各自独立地是烷基或一起是 亚烷基,X是氧,羟亚氨基或烷氧基亚氨基,Y是氧或硫,和(2)至少一种选自(A)氨基甲酸酯,(B)羧酸酯,包括天然和合成拟除虫菊酯的化合物,(C) 磷酸酯,(D)环烷烃,(E)卤代烷烃和(F)锡化合物。