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11. 发明授权

US06726850B1 Catalytic partial oxidation using staged oxygen addition 失效
标题翻译：使用分期加氧的催化部分氧化
公开(公告)号：US06726850B1
公开(公告)日：2004-04-27
申请号：US09484378
申请日：2000-01-14
申请人： Sebastian C. Reyes , Jennifer S. Feeley , Frank Hershkowitz , Harry W. Deckman , Ioannis P. Androulakis
发明人： Sebastian C. Reyes , Jennifer S. Feeley , Frank Hershkowitz , Harry W. Deckman , Ioannis P. Androulakis
IPC分类号： C01B326
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/061 , C01B2203/062 , C01B2203/065 , C01B2203/1011 , C01B2203/1029 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276
摘要： A multistage catalytic partial oxidation (CPO) process for oxidizing a hydrocarbon feedstream comprising C1-C4 hydrocarbons, with an oxygen-containing feedstream to produce a product comprising CO and H2, also known as synthesis gas or syngas. The process employs a CPO catalyst, and controlled process features, including: (A) the total oxygen requirement for the process is introduced incrementally, in more than one reaction stage, using an oxygen-containing feedstream at more than one feed point in the process, each stage including a catalyst; (B) the oxygen-containing feedstream, hydrocarbon feedstream and, in reaction stages after the first of said multiple stages, the intermediate product produced in the prior stage, are mixed for a period of time, after they are brought into contact with one another, of less than about 1 millisecond to form a substantially uniform mixture, wherein the mixture is then contacted with the catalyst; (C) the oxygen-containing feedstream and the hydrocarbon feedstream are preheated prior to entry into the first stage, to a temperature of from about 450° C. to less than about 1,000° C.; and (D) the mixture temperature of the product in each stage following the first stage is from greater than about 600° C. to less than about 1,000° C. Preferably, the process comprises less than or equal to about five stages, the first stage preheat temperature recited in step (C) is greater than about 550° C. and the mixture temperature of the product in each stage following the first stage is at least 700° C.
摘要翻译：用于将包含C1-C4烃的烃进料流与含氧进料流氧化以产生包含CO和H 2的产物（也称为合成气或合成气）的多级催化部分氧化（CPO）方法。该方法采用CPO催化剂和受控工艺特征，包括：（A）在多于一个反应阶段中，使用含氧进料流在多于一个进料点的过程中逐步引入该方法的总氧需求量，每个阶段包括催化剂; （B）含氧进料流，烃类原料流，在上述多阶段第一阶段后的反应阶段中，将前一阶段生产的中间产物在彼此接触后混合一段时间，小于约1毫秒以形成基本均匀的混合物，其中混合物然后与催化剂接触; （C）在进入第一阶段之前将含氧进料流和烃进料流预热至约450℃至小于约1,000℃的温度; 和（D）在第一阶段之后的每个阶段中的产物的混合物温度为大于约600℃至小于约1000℃。优选地，该方法包括小于或等于约五个阶段，第一阶段步骤（C）中所述的阶段预热温度大于约550℃，并且在第一阶段之后的每个阶段中的产品的混合物温度为至少700℃

12. 发明授权

US5935489A Distributed injection process and apparatus for producing synthesis gas 失效
标题翻译：分布式注射工艺和生产合成气的设备
公开(公告)号：US5935489A
公开(公告)日：1999-08-10
申请号：US845707
申请日：1997-04-25
申请人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito
发明人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito
IPC分类号： B01F3/02 , B01F5/00 , B01F5/06 , B01J4/00 , B01J8/02 , B01J10/00 , B01J19/24 , C01B3/36 , C01B3/38 , C10G2/00 , F23D14/22 , F23D14/62 , C07C1/02 , C01B3/24 , C01B31/18 , C07C27/00
CPC分类号： F23D14/62 , B01F5/0604 , B01F5/0682 , B01J10/00 , B01J19/249 , B01J8/0278 , C01B3/36 , C01B3/363 , C01B3/382 , C10G2/30 , F23D14/22 , B01F3/02 , B01J2208/022 , B01J2219/2453 , B01J2219/2462 , B01J2219/247 , B01J2219/2477 , B01J2219/2481 , B01J2219/2485 , C01B2203/142 , C01B2203/82
摘要： A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources comprising a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas, preheated and pressurized, are injected through an injector means at high velocity into admixture with each other in the desired relative proportions, at a plurality of mixing nozzles which are open to the partial oxidation zone of a reactor and are uniformly-spaced over the face of the injector means, to form a reactant gaseous premix having a pressure at least 3% lower than the lowest upstream pressure of either of the streams of the individual gases. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into the partial oxidation zone of the reactor. The gas mixture reacts before or simultaneously with the autoignition time delay of the mixture, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to form a useful syngas which is cooled and recovered.
摘要翻译：一种新颖的注射器/反应器装置以及用于部分氧化轻质烃气体（例如甲烷）的有效方法，以将这种气体转化成有用的合成气以用于回收和/或随后的烃合成。源于包含轻质烃气体（例如甲烷）和预热和加压的氧气或含氧气体的源通过喷射器装置以高速度以相关比例以所需的相对比例在多个混合喷嘴其对于反应器的部分氧化区开放并且在喷射器装置的表面上均匀间隔开，以形成反应物气体预混物，该反应物气体预混物的压力比其中任一流的最低上游压力低至少3％个别气体。在低于其自燃时间（优选小于9毫秒）的时间段内，以约25至1000英尺/秒的速度将气体预混物注入反应器的部分氧化区。气体混合物在混合物的自燃时间延迟之前或同时反应，以减少CO 2，H 2 O的量和由部分氧化反应产生的热量，以形成冷却和回收的有用的合成气。

13. 发明授权

US08529663B2 Process for removing a target gas from a mixture of gases by swing adsorption 有权
标题翻译：通过摆动吸附从气体混合物中除去目标气体的方法
公开(公告)号：US08529663B2
公开(公告)日：2013-09-10
申请号：US12080782
申请日：2008-04-04
申请人： Sebastian C. Reyes , Harry W. Deckman , Ronald R. Chance , Gregory J. DeMartin , Frank Hershkowitz , Eugene R. Thomas , Paul S. Northrop , Bruce T. Kelley , Edward W. Corcoran, Jr.
发明人： Sebastian C. Reyes , Harry W. Deckman , Ronald R. Chance , Gregory J. DeMartin , Frank Hershkowitz , Eugene R. Thomas , Paul S. Northrop , Bruce T. Kelley , Edward W. Corcoran, Jr.
IPC分类号： B01D53/047
CPC分类号： B01D53/0423 , B01D2253/108 , B01D2253/1085 , B01D2257/102 , B01D2257/504 , C10L3/10 , Y02C10/08
摘要： The present invention relates the separation of a target gas from a mixture of gases through the use of engineered structured adsorbent contactors in pressure swing adsorption and thermal swing adsorption processes. Preferably, the contactors contain engineered and substantially parallel flow channels wherein 20 volume percent or less of the open pore volume of the contactor, excluding the flow channels, is in the mesopore and macropore range.
摘要翻译：本发明涉及通过使用工程化的结构化吸附剂接触器在变压吸附和热变形吸附方法中将目标气体与气体混合物分离。优选地，接触器包含工程化和基本上平行的流动通道，其中不包括流动通道的接触器的开孔体积的20体积％或更少在中孔和大孔范围内。

14. 发明授权

US07938886B2 Process for removing a target gas from a mixture of gases by thermal swing adsorption 有权
标题翻译：通过热变形吸附从气体混合物中除去目标气体的方法
公开(公告)号：US07938886B2
公开(公告)日：2011-05-10
申请号：US12152870
申请日：2008-05-16
申请人： Frank Hershkowitz , Harry W. Deckman , Paul S. Northrop , Bruce T. Kelley
发明人： Frank Hershkowitz , Harry W. Deckman , Paul S. Northrop , Bruce T. Kelley
IPC分类号： B01D53/04
CPC分类号： B01D53/0423 , B01D53/02 , B01D53/0462 , B01D2253/108 , B01D2253/308 , B01D2253/311 , B01D2253/342 , B01D2256/10 , B01D2257/102 , B01D2257/304 , B01D2257/504 , C10L3/10 , C10L3/102 , Y02C10/08
摘要： The separation of a target gas from a mixture of gases using a thermal swing adsorption process wherein a thermal wave is used, primarily in the desorption step. The process of this invention enables one to separately remove multiple contaminants from a treated gaseous stream.
摘要翻译：使用其中使用热波的热变形吸附方法将主要气体与气体混合物分离，主要在解吸步骤中。本发明的方法使得能够从经处理的气流中分离除去多种污染物。

15. 发明申请

US20080282886A1 Process for removing a target gas from a mixture of gases by swing adsorption 有权
标题翻译：通过摆动吸附从气体混合物中除去目标气体的方法
公开(公告)号：US20080282886A1
公开(公告)日：2008-11-20
申请号：US12080782
申请日：2008-04-04
申请人： Sebastian C. Reyes , Harry W. Deckman , Ronald R. Chance , Gregory J. DeMartin , Frank Hershkowitz , Eugene R. Thomas , Paul S. Northrop , Bruce T. Kelley , Edward W. Corcoran, JR.
发明人： Sebastian C. Reyes , Harry W. Deckman , Ronald R. Chance , Gregory J. DeMartin , Frank Hershkowitz , Eugene R. Thomas , Paul S. Northrop , Bruce T. Kelley , Edward W. Corcoran, JR.
IPC分类号： B01D53/047
CPC分类号： B01D53/0423 , B01D2253/108 , B01D2253/1085 , B01D2257/102 , B01D2257/504 , C10L3/10 , Y02C10/08
摘要： The present invention relates the separation of a target gas from a mixture of gases through the use of engineered structured adsorbent contactors in pressure swing adsorption and thermal swing adsorption processes. Preferably, the contactors contain engineered and substantially parallel flow channels wherein 20 volume percent or less of the open pore volume of the contactor, excluding the flow channels, is in the mesopore and macropore range.
摘要翻译：本发明涉及通过使用工程化的结构化吸附剂接触器在变压吸附和热变形吸附方法中将目标气体与气体混合物分离。优选地，接触器包含工程化和基本上平行的流动通道，其中不包括流动通道的接触器的开孔体积的20体积％或更少在中孔和大孔范围内。

16. 发明授权

US07217304B2 Electric power generation with heat exchanged membrane reactor 有权
标题翻译：用热交换膜反应器发电
公开(公告)号：US07217304B2
公开(公告)日：2007-05-15
申请号：US10978163
申请日：2004-10-29
申请人： Harry W. Deckman , John W. Fulton , Jeffrey M. Grenda , Frank Hershkowitz
发明人： Harry W. Deckman , John W. Fulton , Jeffrey M. Grenda , Frank Hershkowitz
IPC分类号： C01B3/24
CPC分类号： C01B3/501 , B01J8/009 , B01J12/007 , B01J19/2425 , B01J19/2475 , B01J35/065 , B01J2208/00256 , B01J2208/00309 , B01J2208/0053 , B01J2208/00539 , B01J2219/0002 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0288 , C01B2203/041 , C01B2203/0495 , C01B2203/06 , C01B2203/0805 , C01B2203/0811 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/1011 , C01B2203/1035 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1205 , C01B2203/1241 , C01B2203/1288 , C01B2203/148 , C01B2203/82 , C01B2203/84 , C01B2203/86 , Y02C10/14 , Y02P20/52 , Y02P30/30
摘要： This invention is directed to a heat exchanged membrane reactor for electric power generation. More specifically, the invention comprises a membrane reactor system that employs catalytic or thermal steam reforming and a water gas shift reaction on one side of the membrane, and hydrogen combustion on the other side of the membrane. Heat of combustion is exchanged through the membrane to heat the hydrocarbon fuel and provide heat for the reforming reaction. In one embodiment, the hydrogen is combusted with compressed air to power a turbine to produce electricity. A carbon dioxide product stream is produced in inherently separated form and at pressure to facilitate injection of the CO2 into a well for the purpose of sequestering carbon from the earth's atmosphere.
摘要翻译：本发明涉及用于发电的热交换膜反应器。更具体地，本发明包括在膜的一侧采用催化或热蒸汽重整和水煤气变换反应的膜反应器系统，并且在膜的另一侧上进行氢燃烧。燃烧热通过膜交换以加热烃燃料并为重整反应提供热量。在一个实施例中，氢气与压缩空气一起燃烧，为涡轮机供电以产生电力。二氧化碳产物流以固有分离的形式和压力产生，以便于将CO 2注入到井中，以便从地球大气中隔离碳。

17. 发明授权

US5980782A Face-mixing fluid bed process and apparatus for producing synthesis gas 失效
标题翻译：面混合流化床工艺和生产合成气的设备
公开(公告)号：US5980782A
公开(公告)日：1999-11-09
申请号：US845708
申请日：1997-04-25
申请人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito , Russell J. Koveal , Lavanga R. Veluswamy , James H. Taylor , Alfredo M. Lopez
发明人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito , Russell J. Koveal , Lavanga R. Veluswamy , James H. Taylor , Alfredo M. Lopez
IPC分类号： B01F5/06 , B01J8/24 , B01J8/44 , C01B3/44 , C07C1/02 , C01B3/24 , C01B31/18 , C07C27/00
CPC分类号： B01F5/0604 , B01J8/44 , C01B3/44 , B01J2219/00259 , C01B2203/0233 , C01B2203/0261 , C01B2203/062 , C01B2203/065 , C01B2203/0811 , C01B2203/1082 , C01B2203/1241 , C01B2203/1276
摘要： A novel fluidized bed syngas (FBSG) injector/reactor apparatus and an efficient process for the partial oxidation and steam reforming of light hydrocarbon gases such as methane, to convert such gases to useful synthesis gas containing CO and H.sub.2 for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through gas orifices of an injector at high velocity and comparable momentums into admixture with each other in the desired proportions, at a plurality of mixing chambers or recessed cups which are open to the fluidized bed reaction zone of a reaction chamber and are spaced over the face of the injector, to form a reactant gas premix having a pressure drop of at least 1% through the injector. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a partial oxidation reaction zone comprising a fluid bed catalyst so that the gas mixture reacts in the catalyst bed, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to favor the desired stoichiometry. The formed syngas is cooled and recovered, such as use in further synthesis processing.
摘要翻译：一种新型流化床合成气（FBSG）注射器/反应器装置以及用于轻质烃气体如甲烷的部分氧化和蒸汽重整的有效方法，以将这些气体转化为含CO和H 2的有用合成气以用于回收和/或随后的烃合成。来自诸如甲烷和氧气或含氧气体的轻质烃气体被预热和加压，并通过注射器的气体孔以高速度和可比较的动量将其以所需的比例彼此混合，以多个的混合室或凹形杯，其对反应室的流化床反应区开放并且在喷射器的表面上间隔开，以形成通过喷射器具有至少1％的压降的反应物气体预混物。将气体预混物在小于其自燃时间（优选小于9毫秒）的时间内以约25至1000英尺/秒的速度注入到包含流化床催化剂的部分氧化反应区中，使得气体混合物在催化剂床中反应，以减少CO 2，H 2 O的量和由部分氧化反应产生的热量，以有利于所需的化学计量。形成的合成气被冷却和回收，例如用于进一步合成处理。

18. 发明申请

US20130319662A1 Systems and Methods For Hydrotreating A Shale Oil Stream Using Hydrogen Gas That Is Concentrated From The Shale Oil Stream 审中-公开
标题翻译：使用从页岩油流中浓缩的氢气加氢处理页岩油流的系统和方法
公开(公告)号：US20130319662A1
公开(公告)日：2013-12-05
申请号：US13888704
申请日：2013-05-07
申请人： Emilio Alvarez , Harry W. Deckman , Frank Hershkowitz , William P. Meurer , Thomas R. Palmer
发明人： Emilio Alvarez , Harry W. Deckman , Frank Hershkowitz , William P. Meurer , Thomas R. Palmer
IPC分类号： E21B36/00 , C10G1/00
CPC分类号： E21B36/008 , C10G1/002 , C10G1/02 , C10G49/22 , C10G70/046 , C10G2300/4037 , E21B43/24
摘要： Systems and methods for hydrotreating a liquid fraction of a shale oil stream using hydrogen gas that is concentrated from a gaseous fraction of the shale oil stream. The systems and methods include providing a portion of the gaseous fraction to a sorptive separation assembly and separating a concentrated hydrogen stream from the portion of the gaseous fraction within the sorptive separation assembly. The system and methods further include providing the concentrated hydrogen stream and the liquid fraction to a hydrotreater and reacting the concentrated hydrogen stream with the liquid fraction within the hydrotreater to produce the hydrotreated liquid stream. The systems and methods may include generating the shale oil stream within a subterranean formation using an in situ process, such as an in situ shale oil conversion process and/or providing a supplemental hydrogen stream to the hydrotreater.
摘要翻译：使用从页岩油流的气体部分浓缩的氢气加氢处理页岩油流的液体馏分的系统和方法。该系统和方法包括将一部分气态馏分提供给吸附分离组件，并将浓缩的氢气流与吸附分离组件内气态馏分的部分分离。该系统和方法还包括将浓缩的氢气流和液体馏分提供给加氢处理器，并使浓缩的氢流与加氢处理器内的液体馏分反应以产生加氢处理的液体流。系统和方法可以包括使用原位过程（例如原位页岩油转化方法）和/或向加氢处理器提供补充氢气流，在地层内产生页岩油流。

19. 发明授权

US07731782B2 Temperature swing adsorption of CO2 from flue gas utilizing heat from compression 有权
标题翻译：利用来自压缩的热量从烟道中的二氧化碳的温度变化吸附
公开(公告)号：US07731782B2
公开(公告)日：2010-06-08
申请号：US12152877
申请日：2008-05-16
申请人： Bruce T. Kelley , Harry W. Deckman , Frank Hershkowitz , Paul S. Northrop , Peter I. Ravikovitch
发明人： Bruce T. Kelley , Harry W. Deckman , Frank Hershkowitz , Paul S. Northrop , Peter I. Ravikovitch
IPC分类号： B01D53/04 , B01D53/28
CPC分类号： B01D53/0423 , B01D53/02 , B01D53/0462 , B01D2253/108 , B01D2253/311 , B01D2253/342 , B01D2257/504 , B01D2259/4143 , Y02C10/04 , Y02C10/08
摘要： Adsorption of CO2 from flue gas streams using temperature swing adsorption. The resulting CO2 rich stream is compressed for sequestration into a subterranean formation and at least a portion of the heat of compression is used in the desorption step of the temperature swing adsorption process.
摘要翻译：使用变温吸附从烟气流吸附二氧化碳。所得到的富CO 2流被压缩成地下地层，并且在变温吸附过程的解吸步骤中使用至少一部分压缩热。

20. 发明授权

US07491250B2 Pressure swing reforming 有权
标题翻译：压力摆动重整
公开(公告)号：US07491250B2
公开(公告)日：2009-02-17
申请号：US10458399
申请日：2003-06-10
申请人： Frank Hershkowitz , Harry W. Deckman
发明人： Frank Hershkowitz , Harry W. Deckman
IPC分类号： C01B3/32 , C01B3/36 , C10J3/46 , C10J3/54 , F28D21/00
CPC分类号： C01B3/46 , B01J19/2485 , B01J2219/00117 , C01B3/38 , C01B2203/0233 , C01B2203/0238 , C01B2203/0805 , C01B2203/0811 , C01B2203/0822 , C01B2203/1619 , C01B2203/169 , Y02P20/128 , Y02P20/142
摘要： Synthesis gas is produced though a cyclic method where the first step of the cycle includes reforming a hydrocarbon feed over a catalyst to synthesis gas in a first zone of a bed and the second step reheats this first zone. A hydrocarbon feed is introduced to a bed along with CO2 and optionally steam where it is reformed into synthesis gas. The synthesis gas is collected at a second zone of the bed and an oxygen-containing gas is then introduced to this second zone of the bed and combusted with a fuel, thereby reheating the first zone to sufficient reforming temperatures. Additionally, a non-combusting gas can also be introduced to the second zone to move heat from the second zone to the first zone.
摘要翻译：通过循环方法制备合成气体，其中循环的第一步骤包括将催化剂上的烃进料在床的第一区中重整为合成气，第二步重新加热该第一区。将碳氢化合物进料与CO 2和任选的蒸汽一起引入床中，其中它被重整成合成气。在床的第二区域收集合成气体，然后将含氧气体引入床的该第二区域并与燃料一起燃烧，从而将第一区域再加热至足够的重整温度。此外，也可以将不燃烧的气体引入到第二区域，以将热量从第二区域移动到第一区域。

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