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11. 发明授权

US5959058A Coatings based on fluoropolyethers 失效
标题翻译：基于含氟聚醚的涂料
公开(公告)号：US5959058A
公开(公告)日：1999-09-28
申请号：US613518
申请日：1996-03-11
申请人： Claudio Tonelli , Massimo Scicchitano , Stefano Turri
发明人： Claudio Tonelli , Massimo Scicchitano , Stefano Turri
IPC分类号： C08G18/50 , C08G18/71 , C08G18/80 , C08G59/30 , C08G65/00 , C09D171/00 , C09D171/02 , C07C43/12
CPC分类号： C08G65/007 , C08G18/5015 , C08G18/71 , C08G18/718 , C08G18/8025 , C08G59/30 , C09D171/02
摘要： Use of fluorinated polymers based on fluoropolyethers for the preparation of crosslinkable high dry formulations comprising a fluorinated part R.sub.F and optionally an hydrogenated part R.sub.H, not containing groups capable of linking by means of hydrogen bonds to basic acceptors, an hydrogenated part Rh.sub.1 and Rh.sub.2, wherein Rh.sub.1 is equal to or different from Rh.sub.2, and Rh.sub.1 and/or Rh.sub.2 being linking bonds containing at least a functional group capable of linking by means of hydrogen bonds with basic acceptors, the bonds joining the fluorinated part to the hydrogenated part being of ether C--O simple type, the terminals T'.sub.a and T" being such as to render the structure mono-, bi- or polyfunctional, and subsequent crosslinking of the fluorinated polymer, the monofunctional products being always in admixture with a resin having even a higher functionality than the described type; the preferred fluorinated products have the formula:T"--(Rh.sub.2).sub.y (R.sub.H).sub.x --R.sub.F --(R.sub.H).sub.x --(Rh.sub.1).sub.y' T'.sub.a
摘要翻译：使用基于氟聚醚的氟化聚合物制备可交联的高干制剂，其包含氟化部分RF和任选的氢化部分RH，不含能够通过氢键与碱性受体连接的基团，氢化部分Rh1和Rh2，其中 Rh1等于或不同于Rh2，并且Rh1和/或Rh2是至少含有能够通过氢键与碱性受体连接的官能团的连接键，将氟化部分连接到氢化部分上的键为醚CO 简单型，终端T'a和T“使得结构单，双或多官能并随后交联氟化聚合物，单官能产品总是与甚至具有更高官能度的树脂混合比所描述的类型; 优选的氟化产物具有下式：T“ - （Rh 2）y（RH）x-RF-（RH）x-（Rh1）y'T'a

12. 发明授权

US5910614A Process for preparing perfluoropolyethers 失效
标题翻译：制备全氟聚醚的方法
公开(公告)号：US5910614A
公开(公告)日：1999-06-08
申请号：US903060
申请日：1997-07-30
申请人： Stefano Turri , Claudio Tonelli , Carlo Pogliani
发明人： Stefano Turri , Claudio Tonelli , Carlo Pogliani
IPC分类号： C08G65/32 , C08G65/00 , C08G65/30 , C07C43/11 , B01D16/08
CPC分类号： C08G65/30 , C08G65/007
摘要： Separation process of bifunctional macromolecules having hydroxylic termination from non functional and/or monofunctional macromolecules having hydroxylic termination contained in admixture in perfluoropolyoxyalkylenes (I) comprising the following phases:addition of the macromer (I) to a suspension of stationary phase in polar solvent, said stationary phase being formed by a compound containing sites and/or active groups, capable of establishing bonds or interactions of polar type, or hydrogen bonds, with the hydroxylic terminals of the perfluoropolyoxyalkylenes contained in the mixture of formula (I), the macromer/stationary phase ratio ranging from 2/3 to 1/1 w/w; solvent/(stationary phase+macromer) ratio ranging from 0.8/1 to 1.5/1 v/w; evaporation of the solvent, until obtainment of an incoherent and dry powder;first extraction with low polarity fluorinated solvent and separation of the phases by filtering;second extraction of the stationary phase with polar hydrogenated solvent, and separation of the phases by filtering;the macromer fraction having high bifunctionality degree being obtained by concentration of the liquid phase after second extraction, i.e. after removal of the solvent.
摘要翻译：具有羟基终止的具有羟基终止的羟基终止的双官能大分子的分离过程包含在包含以下相的全氟聚氧化烯（I）中的混合物中：将大分子单体（I）加入极性溶剂中的固定相的悬浮液，所述固定相由含有位点和/或活性基团的化合物形成，其能够与式（I）的混合物中所含的全氟聚氧化烯的羟基末端，大分子单体/固定体形成极性型或氢键的键或相互作用相位比范围为2/3至1/1 w / w; 溶剂/（固定相+大分子单体）比率范围为0.8 / 1至1.5 / 1v / w; 蒸发溶剂，直到得到非相干和干粉; 首先用低极性氟化溶剂萃取并通过过滤分离相; 用极性氢化溶剂二次萃取固定相，通过过滤分离相; 通过第二次萃取后的液相浓缩，即除去溶剂后，获得具有高双官能度的大分子单体馏分。

13. 发明授权

US07358306B2 Curable polyurethanes 失效
标题翻译：可固化聚氨酯
公开(公告)号：US07358306B2
公开(公告)日：2008-04-15
申请号：US10177859
申请日：2002-06-20
申请人： Stefano Turri , Sergio Novelli , Anna Staccione
发明人： Stefano Turri , Sergio Novelli , Anna Staccione
IPC分类号： C08L75/14 , C08L75/08 , C08G71/04
CPC分类号： C08G18/675 , C08G18/10 , C08G18/5015 , C08G18/3203
摘要： Curable (per)fluoropolyether polyurethanes obtained by reaction in a first step of a) (per)fluoropolyether diols having a number average molecular weight from 2,000 to 5,000; with b) diisocyanates of formula OCN—R—NCO (VIA) wherein R is a hydrogenated and/or fluorinated radical; in a second step with the compound c) saturated or unsaturated aliphatic hydrogenated diols, (alkyl)cycloaliphatic, aromatic; oligomers or polymers of butadiene with a number average molecular weight from 500 to 4,000 having end hydroxyl groups; provided that: when the diisocyanate b) is used and the radical R in formula (VIA) is: —Ph—CH2—Ph—, the hydrogenated diols c) are optional; when the radical R has a meaning different from that above mentioned, at least one of the used hydrogenated diols c) is selected from those belonging to the c2)-c6) groups; the sum of the equivalents of the compounds a) and c) being equal to the equivalents of the compound b).
摘要翻译：在第一步中通过在数均分子量为2,000至5,000的a）（全）氟代聚醚二醇中反应获得的可固化（全）氟聚醚聚氨酯; 其中b）式的线性公式描述=“在线公式”end =“lead”→OCN-R-NCO（VIA）<βin-line-formula description =“In-line Formulas “end =”tail“？>其中R是氢化和/或氟化基团; 在第二步中，化合物c）饱和或不饱和脂族氢化二醇，（烷基）脂环族，芳族; 数均分子量为500〜4000的具有末端羟基的丁二烯低聚物或聚合物; 条件是：当使用二异氰酸酯b）时，式（VIA）中的基团R为：-Ph-CH 2 -Ph-，氢化二醇c）为任选的; 当基团R具有与上述不同的含义时，使用的氢化二醇c）中的至少一种选自属于C 2〜C 6的那些，）组化合物a）和c）的当量的总和等于化合物b）的当量。

14. 发明授权

US06992132B2 Compositions of crosslinkable polyurethanes 失效
公开(公告)号：US06992132B2
公开(公告)日：2006-01-31
申请号：US10453575
申请日：2003-06-04
申请人： Tania Trombetta , Fiorenza D'Aprile , Stefano Turri
发明人： Tania Trombetta , Fiorenza D'Aprile , Stefano Turri
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , B05D3/02 , B32B27/00
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/348 , C08G18/5015 , C08G18/792 , C09D175/04 , Y10T428/31551 , C08G18/3228 , C08L2666/20
摘要： Compositions comprising anionic ionomeric polyurethanes crosslinkable in a wide temperature range, said composition comprising the following components: I) an aqueous dispersion of a linear crosslinkable ionomeric polyurethane, containing carboxylic groups and having a perfluoropolyether structure; II) a crosslinking agent, the ratio between the equivalents of the functional groups of the crosslinking agent and of the carboxylic groups of component I) being at least 0.7 up to 1.5, preferably 0.9–1.2, said crosslinking agent being dispersible or soluble in the dispersion component I).

15. 发明授权

US06683128B2 Additives for hydrogenated resins 失效
标题翻译：氢化树脂添加剂
公开(公告)号：US06683128B2
公开(公告)日：2004-01-27
申请号：US10094807
申请日：2002-03-12
申请人： Stefano Turri , Aldo Sanguineti , Massimo Scicchitano
发明人： Stefano Turri , Aldo Sanguineti , Massimo Scicchitano
IPC分类号： C08K300
CPC分类号： C08K3/00 , C08G65/007 , C08G69/40 , C08G81/025 , C08L71/02 , C08L77/06 , C08L2666/04 , C08L51/00
摘要： Additives for hydrogenated resins obtainable by using the following components: a) bifunctional perfluoropolyethers having a —COOR end group, optionally in admixture with monofunctional perfluoropolyethers having a —COOR end group, b) mono, bi or polyfunctional hydrogenated monomers having functional groups able to react with the —COOR end groups of compound a); c) polyolefins having functional groups able to react with the block oligomer/polymer obtained by reaction of a) with b), preferably said functional groups being obtained by grafting with maleic anhydride; reacting in a first step a) with b), until disappearance of the —COOR group of component a), and in a second step the product obtained from the reaction of a) with b) with the functionalized polyolefins c).
摘要翻译：通过使用以下组分可获得的氢化树脂添加剂：a）具有-COOR端基的双功能全氟聚醚，任选地与具有-COOR端基的单官能全氟聚醚混合，b）具有能够反应的官能团的单，双或多官能氢化单体与化合物a）的-COOR端基; c）具有能够与a）与b）反应获得的嵌段低聚物/聚合物反应的官能团的聚烯烃，优选所述官能团通过与马来酸酐接枝而获得; 第一步a）与b）直到组分a）的-COOR基团消失，并且在第二步中，从a）与b）的反应获得的产物与官能化的聚烯烃c）。

16. 发明授权

US07323084B2 Methods for paper sizing with fluorinated polymers 有权
标题翻译：用氟化聚合物进行纸张施胶的方法
公开(公告)号：US07323084B2
公开(公告)日：2008-01-29
申请号：US10183350
申请日：2002-06-28
申请人： Stefano Turri , Tania Trombetta , Paolo Iengo
发明人： Stefano Turri , Tania Trombetta , Paolo Iengo
IPC分类号： D21H21/16 , D21H17/57 , D21H17/08
CPC分类号： D21H17/57 , C08G18/0823 , C08G18/5015 , D21H21/16
摘要： Use for the paper sizing of aqueous polyurethane dispersions from (per)fluoropolyethers obtainable by reaction among the following compounds: a) (per)fluoropolyether diols having a number average molecular weight from 400 to 5,000; b) diisocyanates having formula: OCN—R—NCO (VIa) wherein R is an aliphatic, cycloaliphatic bifunctional radical; or an aromatic bifunctional radical; c) diols containing one carboxylic function and optionally one or both the following components: d) hydrazine and/or aliphatic diamines; e) monofunctional hydroxylic (per)fluoropolyethers having a number average molecular weight in the range 300-1,000.
摘要翻译：用于通过以下化合物之间的反应可得到的（全）氟聚醚的水性聚氨酯分散体的纸张尺寸：a）数均分子量为400至5,000的（全）氟聚醚二醇; b）具有式的二异氰酸酯：<？in-line-formula description =“In-line formula”end =“lead”？> OCN-R-NCO（VIa）<？in-line-formula description =“In-line Formulas “end =”tail“？>其中R是脂族，脂环族双功能基团; 或芳族双功能基团; c）含有一个羧基官能团的二醇和任选的一种或两种以下组分：d）肼和/或脂族二胺; e）数均分子量在300-1,000范围内的单官能羟基（全）氟聚醚。

17. 发明授权

US06936654B2 Additives for hydrogenated resins 失效
标题翻译：氢化树脂添加剂
公开(公告)号：US06936654B2
公开(公告)日：2005-08-30
申请号：US10713204
申请日：2003-11-17
申请人： Stefano Turri , Aldo Sanguineti , Massimo Scicchitano
发明人： Stefano Turri , Aldo Sanguineti , Massimo Scicchitano
IPC分类号： C08J3/22 , C08F8/00 , C08G65/00 , C08G69/40 , C08G81/02 , C08L71/02 , C08L77/06 , C08L101/00 , C08K3/00
CPC分类号： C08K3/00 , C08G65/007 , C08G69/40 , C08G81/025 , C08L71/02 , C08L77/06 , C08L2666/04 , C08L51/00
摘要： Additives for hydrogenated resins obtainable by using the following components: a) bifunctional perfluoropolyethers having a —COOR end group, optionally in admixture with monofunctional perfluoropolyethers having a —COOR end group, b) mono, bi or polyfunctional hydrogenated monomers having functional groups able to react with the —COOR end groups of compound a); c) polyolefins having functional groups able to react with the block oligomer/polymer obtained by reaction of a) with b), preferably said functional groups being obtained by grafting with maleic anhydride; reacting in a first step a) with b), until disappearance of the —COOR group of component a), and in a second step the product obtained from the reaction of a) with b) with the functionalized polyolefins c).
摘要翻译：通过使用以下组分可获得的氢化树脂添加剂：a）具有-COOR端基的双功能全氟聚醚，任选地与具有-COOR端基的单官能全氟聚醚混合，b）具有能够反应的官能团的单，双或多官能氢化单体与化合物a）的-COOR端基; c）具有能够通过a）与b）反应获得的嵌段低聚物/聚合物反应的官能团的聚烯烃，优选通过与马来酸酐接枝而获得的所述官能团; 在第一步a）中与b）反应，直到组分a）的-COOR基团消失，并且在第二步中，从a）与b）的反应获得的产物与官能化的聚烯烃c）反应。

18. 发明授权

US06899955B2 Antifouling coating composition comprising a fluorinated resin 有权
标题翻译：包含氟化树脂的防污涂料组合物
公开(公告)号：US06899955B2
公开(公告)日：2005-05-31
申请号：US10297536
申请日：2001-06-01
申请人： Robert Lines , David Neil Williams , Stefano Turri
发明人： Robert Lines , David Neil Williams , Stefano Turri
IPC分类号： C09D171/00 , C08G65/00 , C08G65/32 , C08G65/336 , C09D5/16 , C09D171/02 , C09D183/08 , B32B9/04
CPC分类号： C09D5/1637 , C08G65/007 , C08G65/336 , C09D171/02 , Y10T428/31663
摘要： A process for inhibiting the fouling of a substrate in a marine fouling environment, which comprises forming on the substrate, before exposure to the said environment, a coating comprising a curable fluorinated resin of the general formula: W-L-YFC—O—Rf—CFY-L-W wherein: W is a group of the general formula —Si(R1)α(OR2)3-α, wherein α=0, 1, or 2, preferably α=0, R1 and R2 independently have the meaning of linear of branched C1-C6 alkyl groups, optionally containing one or more ether groups, or C7-C12 aryl or alkyl groups, and preferably R1 and R2 are C1-C4 alkyl groups; L is an organic linking group; Y is F or CF3; and Rf is a group having an average molecular weight by number between 350 and 8000, preferably between 500 and 3000, and comprising repeating units having at least one of the following structures randomly distributed along the chain: —CFXO—, CF2CF2O—, CF2CF2CF2O—, CF2CF2CF2CF2O—, CR4R5CF2CF2O—, —(CF(CF3)CF2O)—, —CF2CF(CF3)O—, wherein X is F or CF3, R4 and R5 independently have the meaning of H, Cl, or C1-C4 perfluoroalkyl.
摘要翻译：一种抑制海洋污染环境中的基材结垢的方法，其包括在暴露于所述环境之前在所述基材上形成包含以下通式的可固化氟化树脂的涂层：WL-YFC-OR -CFY-LW其中：W是通式-Si（R 1）2的基团（OR 2） 3-α，其中α= 0,1或2，优选α= 0，R 1和R 2独立地具有支链C 1 -C 6烷基的直链，任选地含有一个或多个醚基或C 7 -C 12烷基，芳基或烷基，优选R 1和R 2是C 1 -C 4烷基; L是有机连接基团; Y是F或CF 3 N; 且R f是平均分子量在350和8000之间，优选在500和3000之间的基团，并且包含具有沿链无规分布的至少一个以下结构的重复单元： CFXO-，CF 2 CO 2 O，CF 2 CF 2 CO 2，/ SUB > O-，CF 2，CF 2，CF 2，C 2 O，CR 4， O 2 - ， - （CF（CF 3））CF 3，其中R 1，R 2， 2 O） - ， - CF 2 CF（CF 3）O-，其中X是F或CF 3，R 4和R 5独立地具有H，Cl或C 1 -C 4全氟烷基的含义。

19. 发明授权

US06579835B2 Polyurethanes having a low friction coefficient 失效
标题翻译：具有低摩擦系数的聚氨酯
公开(公告)号：US06579835B2
公开(公告)日：2003-06-17
申请号：US09875980
申请日：2001-06-08
申请人： Massimo Scicchitano , Tania Trombetta , Stefano Turri
发明人： Massimo Scicchitano , Tania Trombetta , Stefano Turri
IPC分类号： C10M14912
CPC分类号： C09D175/04 , C08G18/0814 , C08G18/2875 , C08G18/5015 , C08L27/12 , C08L71/00
摘要： Use of fluorinated polyurethanes thermally crosslinkable for obtaining coatings having an improved friction coefficient for the dry lubrication of rubbers, plastics, metals, glass, said polyurethanes obtainable from aqueous dispersions of cationic oligourethanes having a molecular weight≦9,000, formed by: a) polyisocyanates, having NCO functionality higher than 2, b) bifunctional hydrogenated monomers, c) bifunctional hydroxylated (per)fluoropolyethers, e) monofunctional hydroxyl or carboxylic (per)fluoropolyethers or monofunctional hydroxyl (per)fluoroalkanes optionally: d) hydrogenated monomers by which it is possible to insert a crosslinkable chemical function in the oligourethane; dI) hydrogen-active compounds, able to form with the NCO functions thermolabile bonds.
摘要翻译：使用可热交联的氟化聚氨酯，用于获得具有改进的摩擦系数的涂层，用于橡胶，塑料，金属，玻璃的干燥润滑，所述聚氨酯可从具有分子量为= 9,000的阳离子低聚氨酯的水性分散体获得，所述聚氨酯由以下形成：a）多异氰酸酯具有高于2的NCO官能团，b）双功能氢化单体，c）双功能羟基化（全）氟聚醚，e）单官能羟基或羧基（全）氟聚醚或单官能羟基（全）氟烷烃，任选地：d）氢化单体，可能在低聚氨酯中插入可交联的化学功能; dI）能够与NCO形成的氢活性化合物具有热不稳定性键。

20. 发明授权

US07015278B2 Hydro-oil-repellent compositions 有权
公开(公告)号：US07015278B2
公开(公告)日：2006-03-21
申请号：US10330058
申请日：2002-12-30
申请人： Tania Trombetta , Stefano Turri
发明人： Tania Trombetta , Stefano Turri
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , B32B5/16 , B32B27/20
CPC分类号： D06M15/576 , C08G18/0814 , C08G18/10 , C08G18/5015 , C08G18/7642 , D06M2200/11 , D06M2200/12 , Y10T428/31551 , Y10T442/2123 , Y10T442/2164 , Y10T442/2172 , Y10T442/2197 , Y10T442/227 , Y10T442/2287 , C08G18/285 , C08G18/3275
摘要： Formulations formed by aqueous dispersions of cationic ionomer fluorinated polyurethanes based on (per)fluoropolyethers, having end groups constituted by —NCO groups reacted with hydrogenactive compounds to give covalent bonds stable to water but thermolabile, usable for the surface hydro- and oil-repellent treatment of textiles.

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