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    • 20. 发明授权
    • Liquid crystalline polymer compositions, process, and products
    • 液晶聚合物组合物,方法和产品
    • US4772678A
    • 1988-09-20
    • US762750
    • 1985-08-05
    • Joanne R. SybertJames F. WolfePaul D. SybertBlake Wilson
    • Joanne R. SybertJames F. WolfePaul D. SybertBlake Wilson
    • C08G73/06C08G73/22C08G75/00C08J5/18C08L79/04D01F6/74D01F6/78
    • C08G73/22C08G75/00
    • Novel liquid crystalline extended chain polymer compositions comprising a high concentration of one or more extended chain homopolymer(s), copolymer(s), or block polymer(s) and certain strong acids are prepared by admixing a high concentration of one or more selected homo- or hetero-bifunctional monomer(s) with or without oxidation protecting atoms or groups and one or more of a substantially non-oxidizing strong acid(s) having a high or low P.sub.2 O.sub.5 content. Such compositions are capable of exhibiting excellent cohesive strength, and are especially suited to the production of high molecular weight ordered polymer fibers by dry-jet wet spinning. These liquid crystalline compositions are capable of being drawn through long air gap distances and spun at exceptionally high spin draw ratios. Fibers, films and other articles formed from these liquid crystalline compositions exhibit exceptionally high physical and heat resistant properties.
    • 包含高浓度一种或多种延伸链均聚物,共聚物或嵌段聚合物和某些强酸的新型液晶延伸链聚合物组合物通过将高浓度的一种或多种选择的同型物 - 或具有或不具有氧化保护原子或基团的一个或多个具有高或低P 2 O 5含量的一种或多种基本上非氧化的强酸的异双官能单体。 这种组合物能够表现出优异的内聚强度,特别适用于通过干喷湿法纺丝生产高分子量有序聚合物纤维。 这些液晶组合物能够通过长的气隙距离被拉伸并以非常高的旋转拉伸比旋转。 由这些液晶组合物形成的纤维,薄膜和其它制品表现出极高的物理和耐热性能。