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11. 发明授权

US06380390B1 Catalyst for the production of olefin polymers 失效
标题翻译：用于生产烯烃聚合物的催化剂
公开(公告)号：US06380390B1
公开(公告)日：2002-04-30
申请号：US09482795
申请日：2000-01-13
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： C07D21516
CPC分类号： C08F10/00 , C07F7/003 , C08F210/16 , Y10S526/901 , C08F4/64189 , C08F4/6028 , C08F4/64048 , C08F210/14
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.
摘要翻译：提供了一种用于烯烃聚合的催化剂组合物，其包含双（羟基芳族氮配体）过渡金属催化剂前体和活化助催化剂。

12. 发明授权

US6069109A Process for the production of half-sandwich transition metal based catalyst precursors 失效
标题翻译：制备半夹心过渡金属基催化剂前体的方法
公开(公告)号：US6069109A
公开(公告)日：2000-05-30
申请号：US108824
申请日：1998-07-01
申请人： Sun-Chueh Kao , Frederick John Karol
发明人： Sun-Chueh Kao , Frederick John Karol
IPC分类号： B01J31/22 , C07F17/00 , C08F4/64 , C08F4/6592 , C08F10/00 , B01J31/00 , C07F7/00 , C07F7/28
CPC分类号： B01J31/1805 , B01J31/2204 , B01J31/223 , B01J31/2295 , C07F17/00 , C08F10/00 , B01J2531/30 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , B01J2531/70 , B01J2531/80
摘要： A process for the production of a catalyst precursor comprising reacting (a) a metallocene dihalide; (b) a compound of the formula: ##STR1## wherein each Q is the same or different and is independently selected from the group consisting of O, NR, CR.sub.2, and S; E is either C or S; Z is selected from the group consisting of --OR, --NR.sub.2, --CR.sub.3, --SR, --SiR.sub.3, --PR.sub.2, --H, and a substituted or unsubstituted aryl group; and each R is independently a group containing carbon, silicon, nitrogen, oxygen, and/or phosphorus; and (c) a trialkylamine.
摘要翻译：一种制备催化剂前体的方法，包括使（a）金属茂二卤化物（b）下式的化合物：其中每个Q相同或不同并且独立地选自O，NR，CR 2和S; E是C或S; Z选自-OR，-NR2，-CR3，-SR，-SiR3，-PR2，-H和取代或未取代的芳基; 并且每个R独立地是含有碳，硅，氮，氧和/或磷的基团; 和（c）三烷基胺。

13. 发明授权

US5644023A Process for the manufacture of copolymers of ethylene and carbon monoxide 失效
标题翻译：制备乙烯和一氧化碳共聚物的方法
公开(公告)号：US5644023A
公开(公告)日：1997-07-01
申请号：US871652
申请日：1992-04-21
申请人： Nicholas Joseph Conti , Frederick John Karol , George Norris Foster
发明人： Nicholas Joseph Conti , Frederick John Karol , George Norris Foster
IPC分类号： B01J31/16 , B01J31/18 , B01J31/24 , C08G67/02
CPC分类号： B01J31/1616 , B01J31/18 , B01J31/2409 , C08G67/02 , B01J2531/822 , B01J2531/824 , B01J2531/847
摘要： A process comprising:(a) introducing a mixture comprising one or more alpha-olefins, carbon monoxide, and, optionally, one or more dienes into a reaction zone under polymerization conditions;(b) contacting the mixture with a catalyst prepared by a process comprising:(i) providing a transition metal in the zero valence state adsorbed on a support;(ii) reacting the supported metal with an oxidant to form a supported compound wherein the metal has a positive valence;(iii) ligating the supported compound with a ligand; and(c) introducing a reoxidant into the reaction zone to maintain the positive valence of the metal.
摘要翻译：一种方法，包括：（a）在聚合条件下将包含一种或多种α-烯烃，一氧化碳和任选的一种或多种二烯的混合物引入反应区; （b）使所述混合物与通过以下方法制备的催化剂接触：所述方法包括：（i）提供吸附在载体上的零价态的过渡金属; （ii）使负载的金属与氧化剂反应以形成其中金属具有正价的负载化合物; （iii）将负载的化合物与配体连接; 和（c）将再氧化物引入反应区以维持金属的正价。

14. 发明授权

US4101445A Preparation of modified and activated chromocene catalysts for ethylene polymerization 失效
标题翻译：乙烯聚合改性和活化的色烯催化剂的制备
公开(公告)号：US4101445A
公开(公告)日：1978-07-18
申请号：US725542
申请日：1976-09-22
申请人： Isaac Jacob Levine , Frederick John Karol
发明人： Isaac Jacob Levine , Frederick John Karol
IPC分类号： C08F4/00 , C08F4/06 , C08F4/24 , C08F4/60 , C08F4/76 , C08F10/02 , C08F4/78
CPC分类号： C08F10/02
摘要： Ethylene polymerization catalysts are prepared by depositing a chromocene compound on a support with a titanium compound and activating the final blend at 300.degree. C. to about 1000.degree. C. A fluoriding agent can be optionally added where a narrower molecular weight distribution of the polyethylene to be obtained is desired. Catalysts with good reproducibility, when prepared by this method, show particular utility in production of polyethylene by a fluid bed process.
摘要翻译：乙烯聚合催化剂是通过在支撑体上用钛化合物沉积色烯化合物并在300℃至约1000℃下活化最终共混物来制备的。可以任选加入氟化剂，其中聚乙烯的较窄分子量分布为需要获得。当通过该方法制备时，具有良好重复性的催化剂在通过流化床方法生产聚乙烯时显示出特别的用途。

15. 发明授权

US4100337A Olefin polymerization process and catalyst therefor 失效
公开(公告)号：US4100337A
公开(公告)日：1978-07-11
申请号：US823749
申请日：1977-08-11
申请人： Allen Noshay , Frederick John Karol
发明人： Allen Noshay , Frederick John Karol
IPC分类号： C08F4/00 , C08F4/06 , C08F4/42 , C08F4/60 , C08F4/78 , C08F10/02 , C08F10/00
CPC分类号： C08F10/02
摘要： Catalysts for the polymerization of ethylene and the copolymerization of ethylene with other olefins have been prepared by depositing an organo-chromium compound on a silica support which has been fluorided at low temperatures.

16. 发明授权

US06177527B1 Process for the preparation of polyethylene or polypropylene 失效
标题翻译：制备聚乙烯或聚丙烯的方法
公开(公告)号：US06177527B1
公开(公告)日：2001-01-23
申请号：US09149579
申请日：1998-09-08
申请人： Purna Chand Sishta , Xinmin Yang , Frederick John Karol
发明人： Purna Chand Sishta , Xinmin Yang , Frederick John Karol
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F110/06 , C08F4/65927 , C08F2500/03 , C08F2500/15
摘要： A process for the preparation of (i) polyethylene or (ii) polypropylene, which is essentially isotactic or a mixture of atactic and isotactic polypropylenes comprising contacting ethylene or propylene per se, or in admixture with one or more alpha-olefins, under polymerization conditions, with a catalyst system comprising: (a) a precatalyst comprising a mixture of racemic and meso stereoisomers of a metallocene catalyst containing two cycloalkadienyl ligands joined by a bridging linkage, said ligands complexed to a metal atom; and (b) (1) to obtain polyethylene catalyzed by the rac epimer only, a cocatalyst selected from the group consisting of tris(perfluorophenyl)borane and isobutyl alumoxane; (2) to obtain polyethylene catalyzed by both the rac and the meso epimers, a cocatalyst selected from the group consisting of dimethylanilinium tetrakis(perfluorophenyl)borate and triphenylmethyl tetrakis(perfluorophenyl)borate; (3) to obtain polypropylene, which is essentially isotactic, a cocatalyst selected from the group consisting of tris(perfluorophenyl)borane and isobutyl alumoxane; (4) to obtain polypropylene, which is a mixture of atactic and isotactic polypropylenes in a weight ratio of atactic to isotactic polypropylenes of about 0.01:1 to about 1:1, a cocatalyst selected from the group consisting of dimethylanilinium tetrakis(perfluorophenyl)borate and triphenylmethyl tetrakis(perfluorophenyl)borate.
摘要翻译：一种制备（i）聚乙烯或（ii）聚丙烯的方法，其基本上是全同立构的，或无规立构和全同立构聚丙烯的混合物，包括在聚合条件下使乙烯或丙烯本身接触或与一种或多种α-烯烃混合催化剂体系包括：（a）预催化剂，其包含茂金属催化剂的外消旋和内立体异构体的混合物，所述茂金属催化剂含有通过桥连键连接的两个环二烯基配体，所述配体与金属原子络合; 和（b）（1）获得由外消旋差向异构体催化的聚乙烯，选自三（全氟苯基）硼烷和异丁基铝氧烷的助催化剂; （2）获得由外消旋和中等差向异构体催化的聚乙烯，选自四（全氟苯基）硼酸二甲基苯铵和四（全氟苯基）硼酸三苯基甲酯的助催化剂; （3）得到选自三（全氟苯基）硼烷和异丁基铝氧烷的助催化剂基本上是全同立构的聚丙烯; （4）得到无规立构聚丙烯与全同立构聚丙烯的重量比为约0.01:1至约1:1的无规立构聚丙烯的混合物的聚丙烯，选自四（全氟苯基）硼酸二甲基苯铵和四（全氟苯基）硼酸三苯基甲酯。

17. 发明授权

US6159617A Ethylene polymers having superior clarity enhanced toughness, low extractables, and processing ease 失效
标题翻译：具有优异透明度的乙烯聚合物增强韧性，低可提取物和加工容易性
公开(公告)号：US6159617A
公开(公告)日：2000-12-12
申请号：US053630
申请日：1998-04-02
申请人： George Norris Foster , Tong Chen , Robert Harold Vogel , Scott Hanley Wasserman , Day-Chyuan Lee , Walter Thomas Reichle , Frederick John Karol , Gregory Todd Whiteker
发明人： George Norris Foster , Tong Chen , Robert Harold Vogel , Scott Hanley Wasserman , Day-Chyuan Lee , Walter Thomas Reichle , Frederick John Karol , Gregory Todd Whiteker
IPC分类号： C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08J5/18 , C08L23/06 , H01B3/22 , B32B27/32
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F10/00 , C08F210/16 , C08J2323/08 , Y10S428/91 , Y10S526/943 , Y10T428/1328 , Y10T428/1331 , Y10T428/139 , Y10T428/294 , Y10T428/31938 , C08F210/08 , C08F2500/12 , C08F2500/03 , C08F210/14
摘要： Ethylene polymers having a) a Polydispersity Index of about 2 to about 4; b) a melt index, MI, and Relaxation Spectrum Index, RSI, such that (RSI)(MI.sup.0.6) is about 2.5 to about 6.5; c) a Crystallizable Chain Length Distribution Index, L.sub.w /L.sub.n, of about 1.0 to about 9; and d) a density, .rho., and a percent haze when fabricated into films such that the percent haze is less than 370.rho.-330, are provided. These ethylene polymers advantageously combine superior clarity and toughness with low extractables and enhanced processing ease.
摘要翻译：具有a）多分散指数为约2至约4的乙烯聚合物; b）熔体指数MI和松弛光谱指数RSI，使得（RSI）（MI0.6）为约2.5至约6.5; c）可结晶链长分布指数Lw / Ln为约1.0至约9; 以及d）制造成膜时的密度，rho和雾度百分比，使得雾度百分比小于370rho -330。这些乙烯聚合物有利地将优异的透明度和韧性与低可萃取物相结合并且增强了加工容易性。

18. 发明授权

US6136747A Mixed catalyst composition for the production of olefin polymers 失效
标题翻译：用于生产烯烃聚合物的混合催化剂组合物
公开(公告)号：US6136747A
公开(公告)日：2000-10-24
申请号：US100811
申请日：1998-06-19
申请人： Sun-Chueh Kao , Frederick John Karol , Paul Theodore Daniell , Gregory Mark Goode
发明人： Sun-Chueh Kao , Frederick John Karol , Paul Theodore Daniell , Gregory Mark Goode
IPC分类号： C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S526/943
摘要： A mixed catalyst composition comprising a) a solid Ziegler-Natta catalyst; b) a liquid single site catalyst; and c) at least one activating cocatalyst is provided. Polymers having a broad or bimodal molecular weight distribution may be made with this catalyst composition.
摘要翻译：一种混合催化剂组合物，其包含a）固体齐格勒 - 纳塔催化剂; b）液体单中心催化剂; 和c）提供至少一种活化助催化剂。可以用该催化剂组合物制备具有宽或双峰分子量分布的聚合物。

19. 发明授权

US6093824A Catalyst for the production of olefin polymers 失效
公开(公告)号：US6093824A
公开(公告)日：2000-07-25
申请号：US30365
申请日：1998-02-25
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： C07F7/00 , C07F7/28 , C08F4/60 , C08F4/602 , C08F4/64 , C08F10/00 , C07F5/00 , C07F19/00
CPC分类号： C08F10/00 , C07F7/006 , C08F210/16 , Y10S526/901
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.

20. 发明授权

US4100105A Titanium-modified silyl chromate catalysts for ethylene polymerization 失效
标题翻译：用于乙烯聚合的钛改性甲硅烷基铬酸盐催化剂
公开(公告)号：US4100105A
公开(公告)日：1978-07-11
申请号：US761213
申请日：1977-01-21
申请人： Isaac Jacob Levine , Frederick John Karol
发明人： Isaac Jacob Levine , Frederick John Karol
IPC分类号： C08F4/00 , B01J21/04 , B01J23/26 , B01J37/02 , C08F4/22 , C08F4/42 , C08F4/60 , C08F4/72 , C08F4/78 , C08F10/02 , B01J31/12 , B01J27/06 , C08F2/34
CPC分类号： C08F10/02
摘要： A catalyst for the preparation of ethylene polymers having higher melt indexes comprises a silyl chromate deposited on a silica support containing both aluminum and titanium.
摘要翻译：用于制备具有较高熔体指数的乙烯聚合物的催化剂包括沉积在含有铝和钛的二氧化硅载体上的甲硅烷基铬酸盐。

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