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11. 发明授权

US3959414A Method of preparing stable condensation products using a water-alkylene oxide treatment and products therefrom 失效
标题翻译：使用水环氧烷处理制备稳定的缩合产物及其产物的方法
公开(公告)号：US3959414A
公开(公告)日：1976-05-25
申请号：US473468
申请日：1974-05-28
申请人： Kyung S. Shim , Edward N. Walsh
发明人： Kyung S. Shim , Edward N. Walsh
IPC分类号： C08G18/00 , C07F9/02 , C07F9/09 , C08G79/04 , C08J9/00 , C08K5/52 , C07F9/08
CPC分类号： C08J9/0061 , C07F9/025 , C08G79/04 , C08J2375/04 , C08J2485/00
摘要： Products which are phosphorus containing oligomers having ##EQU1## linkages between phosphorus atoms and which are obtained by the self-condensation of .beta.-haloalkyl esters of pentavalent phosphorus acids or the condensation of these esters with alkyl esters of a pentavalent phosphorus acid are treated after residual acidity has been neutralized, e.g., with an alkylene oxide, with water and then with an alkylene oxide for a period of time which is sufficient to enable the water to open labile groups contained in the product and the alkylene oxide to neutralize any further acidity generated by the opening of such groups. The stabilized product formed by this process when incorporated to a polyurethane foam gives a foam having superior green strength to a polyurethane foam which is not treated in accordance with the invention.
摘要翻译：含磷低聚物的产物，其中磷原子之间具有|| -OCCO- |键，它们通过五价磷酸的β-卤代烷基酯的自缩合或这些酯与五价磷酸的烷基酯的缩合获得在残留酸度被中和后，例如用环氧烷与水，然后与烯化氧反应一段时间，以使水能够打开包含在产物中的不稳定基团和烯化氧以中和任何进一步的酸度由开放这样的组产生。当结合到聚氨酯泡沫中时，通过该方法形成的稳定化产品得到与根据本发明未处理的聚氨酯泡沫体相比具有优异生坯强度的泡沫。

12. 发明授权

US3931361A Color improvement of phosphate esters 失效
标题翻译：磷酸酯的颜色改善
公开(公告)号：US3931361A
公开(公告)日：1976-01-06
申请号：US535883
申请日：1974-12-23
申请人： Fred Jaffe , Silvio L. Giolito , Edward N. Walsh
发明人： Fred Jaffe , Silvio L. Giolito , Edward N. Walsh
IPC分类号： C07F9/02 , C07F9/12 , C08K5/523
CPC分类号： C08K5/523 , C07F9/025 , C07F9/12
摘要： A method for decolorizing and stabilizing alkylphenyl esters of phosphoric acid which comprises contacting the esters with an effective amount of a sodium salt selected from the group consisting of sodium dithionite and sodium formaldehyde sulfoxylate for a sufficient length of time to decolorize and stabilize the esters against subsequent color formation.
摘要翻译：一种使磷酸烷基苯基酯脱色和稳定的方法，其包括使酯与有效量的选自连二亚硫酸钠和甲醛次硫酸钠的钠盐接触足够长的时间以使酯脱色并稳定颜色形成。

13. 发明授权

US4886895A Phosphate-containing and phosphonate-containing phosphate esters 失效
标题翻译：含磷酸盐和膦酸酯的磷酸酯
公开(公告)号：US4886895A
公开(公告)日：1989-12-12
申请号：US306113
申请日：1989-02-06
申请人： Thomas A. Hardy , Edward N. Walsh
发明人： Thomas A. Hardy , Edward N. Walsh
IPC分类号： C07F9/09 , C07F9/40 , C08K5/521 , C08K5/5333 , D06M13/292
CPC分类号： D06M13/292 , C07F9/091 , C07F9/093 , C07F9/4006 , C08K5/521 , C08K5/5333 , C23F11/1673
摘要： There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.
摘要翻译：公开了包含含膦酸酯或磷酸酯的磷酸酯的含有多磷的化合物。化合物可以通过以下方法制备：（a）通过与环氧化物反应，使含膦酸酯或含磷酸酯的醇与五氧化二磷反应，（b）使含膦酸酯或含磷酸盐的醇与磷酰卤反应，将任何磷卤素键，然后使所得磷酸衍生物与环氧化物反应，（c）将含膦酸酯或含磷酸酯的醇与亚磷酸二烷基酯酯交换，氧化所得化合物以产生磷酸衍生物，并使磷酸衍生物与环氧化物。该化合物可用作聚氨酯和纺织品的阻燃添加剂。

14. 发明授权

US4622276A Fuel cell electrolyte 失效
标题翻译：燃料电池电解液
公开(公告)号：US4622276A
公开(公告)日：1986-11-11
申请号：US751119
申请日：1985-07-02
申请人： Edward N. Walsh
发明人： Edward N. Walsh
IPC分类号： H01M8/08 , H01M8/00
CPC分类号： H01M8/08
摘要： This invention relates to a novel intermediate temperature fuel cell electrolyte, fuel cells containing this electrolyte and a process for operating these fuel cells.The fuel cell electrolyte composition comprises one or more phosphonic acids. Typical phosphonic acids are compounds of the formula ##STR1## wherein R is a moiety derived from hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl, halomethylphenyl, vinyl, amine, ammonia and ##STR2## and m represents an integer from 1 to 3 and n represents 0 (zero) or the integer 1. This electrolyte composition can further comprise phosphoric acid.The fuel cell electrolyte composition can include a gelling agent and can be effectively used in fuel cells wherein the fuel is hydrogen, the oxidizer is oxygen and the operating temperature is between about 100.degree. C. and 250.degree. C.
摘要翻译：本发明涉及一种新型的中温燃料电池电解质，含有该电解质的燃料电池和这些燃料电池的操作方法。燃料电池电解质组合物包含一种或多种膦酸。典型的膦酸是下式的化合物，其中R是衍生自羟基烷基，烷基，苯基，烷基苯基，乙烯基，卤代烷基，卤代苯基，卤代甲基苯基，乙烯基，胺，氨的部分，m表示1的整数至3，n表示0（零）或整数1.该电解质组合物可进一步包含磷酸。燃料电池电解质组合物可以包括胶凝剂，并且可以有效地用于燃料为氢的燃料电池中，氧化剂为氧，工作温度为约100℃至250℃。

15. 发明授权

US4292036A Process for imparting flame retardance to textile materials 失效
标题翻译：赋予纺织材料阻燃性的方法
公开(公告)号：US4292036A
公开(公告)日：1981-09-29
申请号：US146582
申请日：1980-05-05
申请人： Edward N. Walsh , Thomas A. Hardy
发明人： Edward N. Walsh , Thomas A. Hardy
IPC分类号： C07F9/09 , D06M13/292 , C07F9/11 , C07F9/40 , D06M1/00 , D06M13/34
CPC分类号： D06M13/292 , C07F9/091
摘要： Flame retardance is imparted to textile materials by impregnating them with a flame retardant composition comprising(a) at least one compound represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of aryl, arylalkyl, alkylaryl, alkenyl and alkyl having from 1 to about 6 carbon atoms and ##STR2## R.sup.3 represents an alkylene group having from 1 to about 5 carbon atoms, and R.sup.4 and R.sup.5 are each independently selected from the group consisting of hydrogen, ##STR3## wherein R.sup.6 represents an alkyl group having from 1 to about 4 carbon atoms; provided that not all of said R.sup.4 's and R.sup.5 's are --CH.sub.3 at the same time:(b) an aminoplast; and(c) an acid catalyst; and heating the impregnated textile material sufficiently to cure said flame retardant composition.
摘要翻译：通过用阻燃组合物浸渍它们来赋予纺织材料阻燃性，所述阻燃组合物包含（a）至少一种由下式表示的化合物：其中R 1和R 2各自独立地选自芳基，芳基烷基，烷基芳基，烯基和具有1至约6个碳原子的烷基，并且R 3代表具有1至约5个碳原子的亚烷基，且R 4和R 5各自独立地选自氢，其中R 6表示具有1至约4个碳原子的烷基; 条件是并不是所有的R 4和R 5都是同时的-CH 3：（b）氨基塑料; 和（c）酸催化剂; 并充分加热浸渍的纺织材料以固化所述阻燃组合物。

16. 发明授权

US4162279A Phosphonoxycarboxamides 失效
标题翻译：膦氧基酰胺
公开(公告)号：US4162279A
公开(公告)日：1979-07-24
申请号：US837072
申请日：1977-09-28
申请人： Edward N. Walsh , Ralph B. Fearing
发明人： Edward N. Walsh , Ralph B. Fearing
IPC分类号： C07F9/40 , D06M13/447 , C07F9/11
CPC分类号： D06M13/447 , C07F9/4075
摘要： Novel phosphonoxycarboxamides of the formula: ##STR1## WHEREIN R.sup.1 and R.sup.2 are selected from the group consisting of aryl and alkyl having from 1-6 carbon atoms and may be the same or different; R.sup.3 represents hydrogen or --CH.sub.2 OH; R.sup.4 represents hydrogen, --CH.sub.3, --CH.sub.2 OH, or --C.sub.2 H.sub.4 OH, R.sup.5 represents an alkyl group having from 1-5 carbon atoms; and n represents 1 or 2 are useful as flame retardant agents for textile materials.
摘要翻译：下式的新型膦酰氧甲酰胺：其中R 1和R 2选自芳基和具有1-6个碳原子的烷基，可以相同或不同; R3代表氢或-CH2OH; R 4表示氢，-CH 3，-CH 2 OH或-C 2 H 4 OH，R 5表示具有1-5个碳原子的烷基; n表示1或2可用作纺织材料的阻燃剂。

17. 发明授权

US4092357A Production of perchloromethyl mercaptan 失效
标题翻译：全氯甲基硫醇的生产
公开(公告)号：US4092357A
公开(公告)日：1978-05-30
申请号：US753133
申请日：1976-12-22
申请人： Carl C. Greco , Edward N. Walsh
发明人： Carl C. Greco , Edward N. Walsh
IPC分类号： C07C319/02 , C07C321/04 , C07C145/00
CPC分类号： C07C313/08
摘要： A method for improving the yield of perchloromethyl mercaptan by including in the reaction mixture amounts of difunctional carbonyl compounds effective to suppress the formation of undesirable byproducts, such as carbon tetrachloride and sulfur monochloride.
摘要翻译：通过在反应混合物中包含有效抑制不希望的副产物（如四氯化碳和一氯化硫）形成的双官能羰基化合物的量来提高全氯甲基硫醇的产率的方法。

18. 发明授权

US4604330A Fuel cell electrolyte 失效
公开(公告)号：US4604330A
公开(公告)日：1986-08-05
申请号：US562319
申请日：1983-12-16
申请人： Edward N. Walsh
发明人： Edward N. Walsh
IPC分类号： H01M8/08
CPC分类号： H01M8/08
摘要： This invention relates to a novel intermediate temperature fuel cell electrolyte, fuel cells containing this electrolyte and a process for operating these fuel cells.The fuel cell electrolyte composition comprises one or more phosphonic acids. Typical phosphonic acids are compounds of the formula ##STR1## wherein R is a moiety derived from hydroxyalkyl, alkyl, phenyl, alkylphenyl, vinyl, haloalkyl, halophenyl, halomethylphenyl, vinyl, amine, ammonia and ##STR2## and m represents an integer from 1 to 3 and n represents 0 (zero) or the integer 1. This electrolyte composition can further comprise phosphoric acid.The fuel cell electrolyte composition can include a gelling agent and can be effectively used in fuel cells wherein the fuel is hydrogen, the oxidizer is oxygen and the operating temperature is between about 100.degree. C. and 250.degree. C.

19. 发明授权

US3970729A Process of synthesizing di-polyoxylalkylene hydroxymethylphosphonate 失效
标题翻译：合成二羟基亚烷基羟甲基膦酸酯的方法
公开(公告)号：US3970729A
公开(公告)日：1976-07-20
申请号：US494685
申请日：1974-08-05
申请人： Edward N. Walsh , Kyung Sup Shim
发明人： Edward N. Walsh , Kyung Sup Shim
IPC分类号： C07F9/38 , C07F9/40 , C08G65/00 , C08G65/26 , C08F2/44
CPC分类号： C07F9/4006 , C07F9/4075 , C10M2223/065 , C10N2240/08
摘要： Di-polyoxyalkylene hydroxymethylphosphonate is prepared by contacting phosphorous acid and formaldehyde, or a formaldehyde polymer such as trioxane or paraformaldehyde, preferably in an aqueous medium, to yield a hydroxymethylphosphonic acid intermediate. The intermediate is then contacted wiyth an alkylene oxide selected from ethylene oxide, propylene oxide or butylene oxide to yield di-polyoxyalkylene hydroxymethylphosphonate having the structureal formula: ##EQU1## wherein R is CH.sub.2, ##EQU2## n + m = 2-10. Di-polyoxyalkylene hydroxymethylphosphonate is utilized as a flame retardant, a stabilizer for polyester film and as a plasticizer for cellulose acetate and polyvinyl acetate, among others.
摘要翻译：通过使亚磷酸和甲醛或甲醛聚合物如三恶烷或多聚甲醛，优选在水性介质中接触，制备羟基甲基膦酸二聚氧化烯，得到羟甲基膦酸中间体。然后将中间体与选自环氧乙烷，环氧丙烷或环氧丁烷的环氧烷接触，得到具有以下结构式的二聚氧化亚烷基羟甲基膦酸酯：O＆amp; L-H-CH 2RO-P-ORCH 2 -OH | CH 2 OH; 其中R是CH 2，-CH-或-CH- | CH 3 CH 2 | CH 3 n + m = 2-10。二聚氧化烯羟甲基膦酸酯用作阻燃剂，聚酯膜的稳定剂和醋酸纤维素和聚乙酸乙烯酯的增塑剂等。

20. 发明授权

US4883892A Phosphate and phosphonate compounds 失效
标题翻译：磷酸盐和膦酸盐化合物
公开(公告)号：US4883892A
公开(公告)日：1989-11-28
申请号：US260342
申请日：1988-10-20
申请人： Thomas A. Hardy , Edward N. Walsh
发明人： Thomas A. Hardy , Edward N. Walsh
IPC分类号： C07F9/40 , C08K5/5333
CPC分类号： C08K5/5333 , C07F9/4006 , C07F9/4075
摘要： There are disclosed novel phosphorous-containing compounds including and derived from hydrogen phosphonates. The compounds of the present invention can be prepared by reacting a hydrogen phosphonate with: (a) an ethylene derivative in a Michael reaction, (b) an amine or amide and formaldehyde in a Mannich reaction, (c) an aldehyde or ketone, (d) a halogen, (e) carbon tetrachloride and an alkylamine, and (f) carbon tetrachloride and a hydroxyphosphonate. Halophosphonates produced according to procedure (d) can also be used in reactions with (a) alkylamines and (b) hydroxyphosphonates or epoxides to produce the compounds of the present invention.
摘要翻译：公开了包括并衍生自氢膦酸盐的新颖的含磷化合物。本发明的化合物可以通过使膦酸氢钾与（a）迈克尔反应中的乙烯衍生物，（b）曼尼希反应中的胺或酰胺和甲醛反应制得，（c）醛或酮（ d）卤素，（e）四氯化碳和烷基胺，和（f）四氯化碳和羟基膦酸盐。根据方法（d）制备的卤代膦酸盐也可用于与（a）烷基胺和（b）羟基膦酸酯或环氧化物的反应中，以产生本发明的化合物。

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