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11. 发明申请

US20130303362A1 CONVERSION OF ETHANOL TO A REACTION PRODUCT COMPRISING 1-BUTANOL USING HYDROXYAPATITE CATALYSTS 有权
标题翻译：乙醇转化为包含使用羟基脂肪酸催化剂的1-丁醇的反应产物
公开(公告)号：US20130303362A1
公开(公告)日：2013-11-14
申请号：US13942759
申请日：2013-07-16
申请人： E I Du Pont De Nemours and Company
发明人： Paul Joseph Fagan , Thomas G. Calvarese , Ronald James Davis , Ronnie Ozer
IPC分类号： B01J27/182 , B01J27/18 , C07C29/34
CPC分类号： B01J27/182 , B01J27/1806 , B01J27/1853 , B01J27/186 , B01J27/198 , B01J35/002 , B01J35/1014 , B01J37/031 , B01J37/06 , B01J37/08 , C07C29/34 , C07C31/12
摘要： Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM′xM″yM′″z)5(PO4)3(OH), wherein M is Mg; M′ is Ca; M″ is Sr; M′″ is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.
摘要翻译：提供了在合适的反应条件下通过使包含乙醇的反应物与催化剂组合物接触来生产包含1-丁醇的反应产物的催化方法。催化剂组合物可以包含式（MwM'xM'yM“z）5（PO4）3（OH）的羟基磷灰石，其中M是Mg; M'是Ca; M“是Sr; M“”是Ba; w是0和1之间的任何数字; x是从0到小于0.5的任何数字; y是0和1之间的任何数字; z是0和1之间的任何数字; 并且w + x + y + z = 1。可以使用碱处理的催化剂组合物。还提供了使包含羟基磷灰石的初始催化剂组合物与碱反应以制备碱处理的催化剂组合物的方法，以及如此获得的碱处理的催化剂组合物。

12. 发明授权

US10457657B2 Processes for preparing 2,5-furandicarboxylic acid and esters thereof 有权
公开(公告)号：US10457657B2
公开(公告)日：2019-10-29
申请号：US16159891
申请日：2018-10-15
申请人： E I DU PONT DE NEMOURS AND COMPANY , ARCHER DANIELS MIDLAND COMPANY
发明人： Pranit S. Metkar , Ronnie Ozer , Bhuma Rajagopalan
IPC分类号： C07D307/02 , C07D307/68
摘要： A process for producing furan dicarboxylic acid or an ester thereof from a feedstock comprising hydroxymethyl furfural (HMF) and humins is disclosed. Humins are a byproduct from reactions forming HMF from sugars and are typically removed from the HMF prior to any further processing. A humins-containing HMF feedstock is utilized to produce furan dicarboxylic acids and ester substantially free from humins.

13. 发明申请

US20190300494A1 PROCESSES FOR PREPARING 2,5-FURANDICARBOXYLIC ACID AND ESTERS THEREOF 审中-公开
公开(公告)号：US20190300494A1
公开(公告)日：2019-10-03
申请号：US16447153
申请日：2019-06-20
申请人： E I DU PONT DE NEMOURS AND COMPANY
发明人： PRANIT S METKAR , Ronnie Ozer , Bhuma Rajagopalan
IPC分类号： C07D307/68
摘要： A process for producing furan dicarboxylic acid or an ester thereof from a feedstock comprising hydroxymethyl furfural (HMF) and humins is disclosed. Humins are a byproduct from reactions forming HMF from sugars and are typically removed from the HMF prior to any further processing. A humins-containing HMF feedstock is utilized to produce furan dicarboxylic acids and ester substantially free from humins.

14. 发明申请

US20190047973A1 PROCESSES FOR PREPARING 2,5-FURANDICARBOXYLIC ACID AND ESTERS THEREOF 审中-公开
公开(公告)号：US20190047973A1
公开(公告)日：2019-02-14
申请号：US16159891
申请日：2018-10-15
申请人： E I DU PONT DE NEMOURS AND COMPANY , ARCHER DANIELS MIDLAND COMPANY
发明人： Pranit S. METKAR , Ronnie Ozer , Bhuma Rajagopalan
IPC分类号： C07D307/68
摘要： A process for producing furan dicarboxylic acid or an ester thereof from a feedstock comprising hydroxymethyl furfural (HMF) and humins is disclosed. Humins are a byproduct from reactions forming HMF from sugars and are typically removed from the HMF prior to any further processing. A humins-containing HMF feedstock is utilized to produce furan dicarboxylic acids and ester substantially free from humins.

15. 发明申请

US20190031633A1 LOW PRESSURE, HIGH TEMPERATURE PROCESS FOR FORMING 2,5-FURANDICARBOXYLIC ACID DIALKYL ESTER 审中-公开
公开(公告)号：US20190031633A1
公开(公告)日：2019-01-31
申请号：US15742946
申请日：2016-07-21
申请人： E I DU PONT DE NEMOURS AND COMPANY
发明人： Judy H. Cipot-Wechsler , Pranit S. Metkar , Ronnie Ozer
IPC分类号： C07D307/68
摘要： Processes for preparing a dialkyl ester of 2,5-furan dicarboxylic acid are disclosed. The processes comprise contacting 2,5-furan dicarboxylic acid with excess alcohol and, optionally, a catalyst at a pressure in the range of between 1 bar and 21 bar and a temperature in the range of from 65° C. to 325° C. to form a vapor reaction product comprising an ester of 2,5-furan dicarboxylic acid, the alcohol and water; and distilling the vapor reaction product at a pressure in the range of from 0 bar to 3.5 bar at a temperature in the range of from 38° C. to 204° C. to separate the water and alcohol from the ester of 2,5-furan dicarboxylic acid.

16. 发明申请

US20130172584A1 PROCESS FOR THE PRODUCTION OF FURFURAL 有权
标题翻译：生产过程的过程
公开(公告)号：US20130172584A1
公开(公告)日：2013-07-04
申请号：US13729480
申请日：2012-12-28
申请人： E I DU PONT DE NEMOURS AND COMPANY
发明人： David Richard Corbin , Paul Joseph Fagan , Ronnie Ozer , Bhuma Rajagopalan , Eric J. Till
IPC分类号： C07D307/50
CPC分类号： C07D307/50
摘要： Furfural is produced by mixing an aqueous feedstock solution containing C5 sugar and/or C6 sugar with a heated high boiling, water-miscible solvent, such as sulfolane, and a solid acid catalyst. Furfural product and water can be distilled off, leaving non-volatile solvent behind. Furfural yields of over 70% at as high as 99% conversion have been obtained with this process with sulfolane as the reaction solvent and zeolite beta as the solid acid catalyst. Also, certain by-products (e.g., humins) solubilized in the reaction solvent can be precipitated by addition of water or aqueous feedstock solution and then removed by filtration, thereby providing a convenient and effective way of removing these undesirable byproducts from the reaction mixture.
摘要翻译：通过将含有C5糖和/或C6糖的水性原料溶液与加热的高沸点，水混溶性溶剂如环丁砜和固体酸催化剂混合来制备糠醛。糠醛产品和水可以蒸馏出来，留下非挥发性溶剂。用环丁砜作为反应溶剂和沸石β作为固体酸催化剂，该方法已经获得高达99％转化率的糠醛产率超过70％。此外，溶解在反应溶剂中的某些副产物（例如，胡氏体）可以通过加入水或原料溶液沉淀，然后通过过滤除去，从而提供从反应混合物中除去这些不期望的副产物的方便有效的方法。

17. 发明申请

US20180179173A1 MULTI-STAGE ESTERIFICATION PROCESS 审中-公开
公开(公告)号：US20180179173A1
公开(公告)日：2018-06-28
申请号：US15580395
申请日：2016-07-21
申请人： E I DU PONT DE NEMOURS AND COMPANY
发明人： Judy H. Cipot-Wechsler , Stuart B. Fergusson , Larin Godfroy , Ronnie Ozer
IPC分类号： C07D307/68
CPC分类号： C07D307/68
摘要： A process for efficiently esterifying furan dicarboxylic acid, especially 2,5-furan dicarboxylic acid in the presence of an alcohol and, optionally, a catalyst is disclosed. The process provides high yields of the diesters of furan dicarboxylic acid and comprises a multi-stage esterification process wherein a portion of a gas phase is removed at each stage of the multi-stage process.

18. 发明授权

US09211529B2 Conversion of ethanol to a reaction product comprising 1-butanol using hydroxyapatite catalysts 有权
公开(公告)号：US09211529B2
公开(公告)日：2015-12-15
申请号：US13942759
申请日：2013-07-16
申请人： E I DU PONT DE NEMOURS AND COMPANY
发明人： Paul Joseph Fagan , Thomas G Calvarese , Ronald James Davis , Ronnie Ozer
IPC分类号： C07C31/02 , C07C31/12 , C07C29/34 , B01J27/182 , B01J27/138 , B01J27/18 , B01J27/185 , B01J37/06 , B01J37/08 , B01J27/186 , B01J27/198 , B01J35/00 , B01J35/10 , B01J37/03
CPC分类号： B01J27/182 , B01J27/1806 , B01J27/1853 , B01J27/186 , B01J27/198 , B01J35/002 , B01J35/1014 , B01J37/031 , B01J37/06 , B01J37/08 , C07C29/34 , C07C31/12
摘要： Catalytic processes to produce a reaction product comprising 1-butanol by contacting a reactant comprising ethanol with a catalyst composition under suitable reaction conditions are provided. The catalyst composition may comprise a hydroxyapatite of the Formula (MwM′xM″yM′″z)5(PO4)3(OH), wherein M is Mg; M′ is Ca; M″ is Sr; M′″ is Ba; w is any number between 0 and 1 inclusive; x is any number from 0 to less than 0.5; y is any number between 0 and 1 inclusive; z is any number between 0 and 1 inclusive; and w+x+y+z=1. Base-treated catalyst compositions may be used. Also provided are processes for contacting an initial catalyst composition comprising the hydroxyapatite with a base to produce a base-treated catalyst composition, and the base-treated catalyst compositions so obtained.

19. 发明授权

US09012664B2 Process for the production of furfural 有权
标题翻译：糠醛生产工艺
公开(公告)号：US09012664B2
公开(公告)日：2015-04-21
申请号：US13729445
申请日：2012-12-28
申请人： E I du Pont de Nemours and Company
发明人： David Richard Corbin , Paul Joseph Fagan , Stuart B Fergusson , Keith W Hutchenson , Pranit S Metkar , Ronnie Ozer , Carmo Joseph Pereira , Bhuma Rajagopalan , Sourav Kumar Sengupta , Eric J. Till
IPC分类号： C07D307/48 , C07D307/50
CPC分类号： C07D307/50 , C07D307/48 , Y02P20/127
摘要： Furfural is produced by contacting a feedstock solution containing C5 sugar and/or C6 sugar with a solid acid catalyst using reactive distillation. Both high yield and high conversion are obtained, without production of insoluble char in the reaction vessel. Degradation of furfural is minimized by its low residence time in contact with the solid acid catalyst. Higher catalyst lifetime can be achieved because the catalyst is continually washed with the refluxing aqueous solution and not sitting in high-boiling byproducts like humins, which are known to be deleterious to catalyst lifetime.
摘要翻译：通过使用反应蒸馏将含有C5糖和/或C6糖的原料溶液与固体酸催化剂接触来制备糠醛。获得高产率和高转化率，而在反应容器中不产生不溶性焦炭。通过其与固体酸催化剂接触的低停留时间使糠醛的降解最小化。可以实现更高的催化剂寿命，因为催化剂连续地用回流水溶液洗涤，而不是位于已知对催化剂寿命有害的高沸点副产物如胡氏。

20. 发明申请

US20130172581A1 PROCESS FOR THE PRODUCTION OF FURFURAL 有权
标题翻译：生产过程的过程
公开(公告)号：US20130172581A1
公开(公告)日：2013-07-04
申请号：US13729375
申请日：2012-12-28
申请人： E I DU PONT DE NEMOURS AND COMPANY
发明人： Paul Joseph Fagan , Ronnie Ozer , Eric J. Till
IPC分类号： C07D307/50
CPC分类号： C07D307/50
摘要： Furfural is produced by mixing an aqueous feedstock solution containing C5 sugar and/or C6 sugar with a heated, high boiling, water-miscible solvent, such as sulfolane, and a soluble acid catalyst. Furfural product and water are distilled off through a multistage distillation column, leaving non-volatile solvent behind. Typical furfural yields with sulfolane as the reaction solvent are about 80% at as high as 99% conversion. Also, certain by-products (e.g., humins) solubilized in the reaction solvent can be precipitated by addition of water or aqueous feedstock solution and then removed by filtration, thereby providing a convenient and effective way of removing these undesirable byproducts from the reaction mixture.
摘要翻译：糠醛通过将含有C5糖和/或C6糖的原料水溶液与加热的，沸点高的水混溶性溶剂如环丁砜和可溶性酸催化剂混合而制备。通过多级蒸馏塔蒸馏出糠醛产物和水，留下非挥发性溶剂。以环丁砜作为反应溶剂的典型糠醛产率为高达99％转化率的约80％。此外，溶解在反应溶剂中的某些副产物（例如，胡氏体）可以通过加入水或原料溶液沉淀，然后通过过滤除去，从而提供从反应混合物中除去这些不期望的副产物的方便有效的方法。

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