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11. 发明授权

US07638672B2 Method for converting ethylene into propylene 失效
标题翻译：乙烯转化成丙烯的方法
公开(公告)号：US07638672B2
公开(公告)日：2009-12-29
申请号：US11571602
申请日：2005-06-27
申请人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
发明人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
IPC分类号： C07C6/04
CPC分类号： C07C6/04 , C07C2531/12 , Y02P20/584 , C07C11/06
摘要： The invention relates to a method for converting ethylene into propylene consisting in reacting said ethylene with a supported metal compound comprising an aluminium oxide based support to which a tungsten hydride is grafted. Said reaction is carried out at a temperature ranging from 20 to 600° C., preferably between 50 and 350° C., at an absolute pressure ranging from 0.01 to 8 MPa, preferably between 0.01 and 1 MPa. A catalyst is regeneratable by introducing hydrogen at a temperature of 50-300° C.
摘要翻译：本发明涉及一种将乙烯转化成丙烯的方法，该方法是使所述乙烯与负载型金属化合物反应，该金属化合物包含接枝有氢化钨的氧化铝基载体。所述反应在20〜600℃，优选50〜350℃的温度下进行，绝对压力为0.01〜8MPa，优选为0.01〜1MPa。催化剂可以通过在50-300℃的温度下引入氢气来再生

12. 发明授权

US07473814B2 Process for converting methane into ethane 失效
标题翻译：将甲烷转化为乙烷的方法
公开(公告)号：US07473814B2
公开(公告)日：2009-01-06
申请号：US10517212
申请日：2003-06-04
申请人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Martin Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Martin Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C2/00
CPC分类号： C07C2/76 , C07C2531/12 , Y10S585/943 , C07C9/06
摘要： The invention relates to a process for producing ethane comprising contacting methane with a metal catalyst selected from metal hydrides, metal organic compounds and mixtures thereof. It also relates to a process for the conversion of methane to carbon-containing products comprising contacting methane with a metal catalyst comprising at least one metal, Me, chosen from the lanthanides, the actinides and the metals from Groups 2 to 12 of the Periodic Table of the Elements, so as to produce ethane in a proportion of at least 65%, especially at least 98% or 99% by weight with respect to carbon-containing products formed in the process. The process can be a single-step process, preferably carried out under conditions involving a non-oxidative catalytic coupling of methane, in particular under operating conditions maintained substantially constant, preferably continuously, during the ethane production, e.g. at a temperature ranging from −30° C. to +80° C., preferably from 20° C. to 500° C., under a total absolute pressure ranging from 10−3 to 100 MPa, preferably from 0.1 to 50 MPa. The metal catalyst may be chosen from metal catalysts supported on and preferably grafted to a solid support. One of the main advantages of the present invention is to produce ethane with a very high selectivity.
摘要翻译：本发明涉及一种生产乙烷的方法，包括使甲烷与选自金属氢化物，金属有机化合物及其混合物的金属催化剂接触。它还涉及将甲烷转化为含碳产物的方法，包括使甲烷与包含至少一种金属的金属催化剂接触，所述金属催化剂选自镧系元素，锕系元素和元素周期表第2至12族中的金属的元素，以便相对于在该方法中形成的含碳产品，以至少65重量％，特别是至少98重量％或99重量％的比例制备乙烷。该方法可以是单步骤方法，优选在涉及甲烷的非氧化催化偶合的条件下进行，特别是在乙烷生产期间，优选连续保持基本上恒定的操作条件下，例如乙烷生产。在-30℃至+ 80℃，优选20℃至500℃的温度下，在绝对压力范围为10-3-100MPa，优选0.1-50MPa的温度下进行。金属催化剂可以选自负载在并优选接枝到固体载体上的金属催化剂。本发明的主要优点之一是以非常高的选择性生产乙烷。

13. 发明申请

US20080255328A1 Method For Metathesis of Compounds Comprising an Olefinic Double Bond, in Particular Olefins 失效
标题翻译：包含烯烃双键，特别是烯烃的化合物的复分解方法
公开(公告)号：US20080255328A1
公开(公告)日：2008-10-16
申请号：US11571395
申请日：2005-07-01
申请人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
发明人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
IPC分类号： C08F2/00 , C08F4/52
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/06
摘要： The invention relates to a method for metathesis of one or several reagents comprising a linear or branched hydrocarbon chain containing a double olefinic bond Csp2═Csp2 consisting in reacting said reagent or reagents with a supported metal compound comprising an aluminium oxide-based support to which a tungsten hydride is grafted. Typically, each said reagent or reagents comprises from 2 to 30 carbon atoms. The reagent can be embodied in the form of olefin. The inventive method can be used, for example for producing propylene from ethylene and butane.
摘要翻译：本发明涉及一种或多种试剂的复分解方法，所述试剂包括含有双重烯键Csp 2 -Csp 2的直链或支链烃链，所述双链烯键用于将所述试剂或具有负载金属化合物的试剂，其包含接枝氢化钨的基于氧化铝的载体。通常，每个所述试剂或试剂包含2至30个碳原子。试剂可以以烯烃的形式实施。本发明的方法可用于例如从乙烯和丁烷生产丙烯。

14. 发明申请

US20050272966A1 Process for converting methane into ethane 失效
标题翻译：将甲烷转化为乙烷的方法
公开(公告)号：US20050272966A1
公开(公告)日：2005-12-08
申请号：US10517212
申请日：2003-06-04
申请人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C2/76 , C07C6/08 , C07C9/06
CPC分类号： C07C2/76 , C07C2531/12 , Y10S585/943 , C07C9/06
摘要： The invention relates to a process for producing ethane comprising contacting methane with a metal catalyst selected from metal hydrides, metal organic compounds and mixtures thereof. It also relates to a process for the conversion of methane to carbon-containing products comprising contacting methane with a metal catalyst comprising at least one metal, Me, chosen from the lanthanides, the actinides and the metals from Groups 2 to 12 of the Periodic Table of the Elements, so as to produce ethane in a proportion of at least 65%, especially at least 98% or 99% by weight with respect to carbon-containing products formed in the process. The process can be a single-step process, preferably carried out under conditions involving a non-oxidative catalytic coupling of methane, in particular under operating conditions maintained substantially constant, preferably continuously, during the ethane production, e.g. at a temperature ranging from −30° C. to +80° C., preferably from 20° C. to 500° C., under a total absolute pressure ranging from 10−3 to 100 MPa, preferably from 0.1 to 50 MPa. The metal catalyst may be chosen from metal catalysts supported on and preferably grafted to a solid support. One of the main advantages of the present invention is to produce ethane with a very high selectivity.
摘要翻译：本发明涉及一种生产乙烷的方法，包括使甲烷与选自金属氢化物，金属有机化合物及其混合物的金属催化剂接触。它还涉及将甲烷转化为含碳产物的方法，包括使甲烷与包含至少一种金属的金属催化剂接触，所述金属催化剂选自镧系元素，锕系元素和元素周期表第2至12族中的金属的元素，以便相对于在该方法中形成的含碳产品，以至少65重量％，特别是至少98重量％或99重量％的比例制备乙烷。该方法可以是单步骤方法，优选在涉及甲烷的非氧化催化偶合的条件下进行，特别是在乙烷生产期间，优选连续保持基本上恒定的操作条件下，例如乙烷生产。在-30℃至+ 80℃，优选20℃至500℃的温度范围内，在绝对压力范围为10 -3至100MPa，优选为0.1〜50MPa。金属催化剂可以选自负载在并优选接枝到固体载体上的金属催化剂。本发明的主要优点之一是以非常高的选择性生产乙烷。

15. 发明申请

US20100197482A1 SOLID METAL COMPOUND, PREPARATIONS AND USES THEREOF 审中-公开
标题翻译：固体金属化合物，其制备及其用途
公开(公告)号：US20100197482A1
公开(公告)日：2010-08-05
申请号：US12733809
申请日：2008-09-25
申请人： Jean-Marie Basset , Nicolas Merle , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Nicolas Merle , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： B01J31/12 , B01J21/04
CPC分类号： B01J31/121 , B01J21/04 , B01J31/128 , B01J37/0209 , B01J37/18 , C07C2/34 , C07C2/76 , C07C4/10 , C07C6/02 , C07C6/04 , C07C6/10 , C07C2521/04 , C07C2531/22 , C10G49/02 , C10G50/00 , Y02P20/52 , C07C9/06 , C07C11/107 , C07C11/06
摘要： The invention relates to a solid metal compound comprising (i) a solid support comprising aluminium oxide, (ii) at least one first metal compound (C1) selected from metal hydrides, organometallic compounds and organometallic hydrides, and comprising a metal (M1) selected from the lanthanides, the actinides and the metals of Groups 4 to 7 of the Periodic Table of the Elements, and (iii) at least one second metal compound (C2) comprising a metal (M2) selected from the metals of Groups 8 to 10 of said Table. The compounds (C1) and (C2) are preferably supported on, particularly grafted onto the solid support. The invention also relates to processes for preparing the solid metal compound, preferably comprising stage (1) comprising dispersing and preferably grafting (i) an organometallic precursor (Pr1) comprising the metal (M1) and (ii) a precursor (Pr2) comprising the metal (M2) onto the support, so as to produce the solid metal compound, and preferably stage (2) comprising contacting the solid metal compound thus obtained with hydrogen and/or a reducing agent. The invention also relates to the use of the solid metal compound in processes comprising hydrocarbon reactions optionally in the presence of hydrogen, and preferably involving the splitting and recombining of carbon-carbon and/or carbon-hydrogen and/or carbon-metal bonds, so as to produce final hydrocarbons different from the starting ones. The solid metal compound can be used in processes comprising alkane and/or alkene metathesis, non-oxidative methane coupling, alkene oligomerisation, methane-olysis of hydrocarbons, cross-metathesis and hydrogenolysis of hydrocarbons, e.g. saturated hydrocarbons, hydrocarbon polymers/oligomers or waxes, in the presence of hydrogen.
摘要翻译：本发明涉及一种固体金属化合物，其包含（i）包含氧化铝的固体载体，（ii）至少一种选自金属氢化物，有机金属化合物和有机金属氢化物的第一金属化合物（C1），并且包含选择的金属（M1）镧系元素，元素周期表第4至7族中的锕系元素和金属，和（iii）至少一种第二金属化合物（C2），其包含选自第8〜10族金属的金属（M2）的表。化合物（C1）和（C2）优选负载在，特别是接枝到固体载体上。本发明还涉及制备固体金属化合物的方法，优选包含阶段（1），其包括分散并优选接枝（i）包含金属（M1）的有机金属前体（Pr1）和（ii）包含金属（M2），以制备固体金属化合物，并且优选包括将由此获得的固体金属化合物与氢气和/或还原剂接触的阶段（2）。本发明还涉及固体金属化合物在任选地在氢气存在下包括烃反应的方法中的用途，并且优选涉及碳 - 碳和/或碳 - 氢和/或碳 - 金属键的分解和重组，因此以生产与起始烃不同的最终烃。固体金属化合物可用于包括烷烃和/或烯烃复分解，非氧化甲烷偶合，烯烃低聚，烃的甲烷溶解，烃的氢解，交叉复分解等过程。饱和烃，烃聚合物/低聚物或蜡，在氢的存在下。

16. 发明申请

US20100048926A1 CATALYST SYSTEM AND PROCESS FOR THE PRODUCTION OF EPOXIDES 审中-公开
标题翻译：催化剂体系和生产环氧化物的方法
公开(公告)号：US20100048926A1
公开(公告)日：2010-02-25
申请号：US12522840
申请日：2008-01-10
申请人： Jean-Marie Basset , Jean-Richard Llinas , Mathias Mauvezin , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Jean-Richard Llinas , Mathias Mauvezin , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07D301/10 , C07D301/22 , B01J23/50
CPC分类号： C07D301/10 , B01J21/04 , B01J23/50 , B01J23/8474 , B01J23/898 , B01J35/0006 , B01J37/04
摘要： The present invention relates to a catalyst system which is a mixture of at least two catalytic species, the first catalytic species being a dehydrogenation catalyst and the second catalytic species being an epoxidation catalyst and comprising silver. The present invention also relates to a process for the production of epoxides, in particular a process for the production of an epoxide from an alkane or a mixture comprising an alkane and an alkene, which process comprises contacting said alkane or mixture comprising said alkane and said alkene and a source of oxygen with such a catalyst system comprising a mixture of at least two catalytic species, the first catalytic species providing dehydrogenation activity and the second catalytic species providing epoxidation activity and comprising silver.
摘要翻译：本发明涉及一种催化剂体系，其是至少两种催化物质的混合物，第一催化物质是脱氢催化剂，第二催化物质是环氧化催化剂并包含银。本发明还涉及生产环氧化物的方法，特别是一种由烷烃或包含烷烃和烯烃的混合物生产环氧化物的方法，该方法包括将所述烷烃或包含所述烷烃和所述烯烃和氧源，其中包含至少两种催化物质的混合物的催化剂体系，所述第一催化物质提供脱氢活性和第二催化物质提供环氧化活性并包含银。

17. 发明授权

US07635794B2 Method for metathesis of compounds comprising an olefinic double bond, in particular olefins 失效
标题翻译：包含烯属双键，特别是烯烃的化合物的复分解方法
公开(公告)号：US07635794B2
公开(公告)日：2009-12-22
申请号：US11571395
申请日：2005-07-01
申请人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
发明人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
IPC分类号： C07C6/04
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/06
摘要： The invention relates to a method for metathesis of one or several reagents comprising a linear or branched hydrocarbon chain containing a double olefinic bond Csp2═Csp2 consisting in reacting said reagent or reagents with a supported metal compound comprising an aluminum oxide-based support to which a tungsten hydride is grafted. Typically, each said reagent or reagents comprises from 2 to 30 carbon atoms. The reagent can be embodied in the form of olefin. The inventive method can be used, for example for producing propylene from ethylene and butane.
摘要翻译：本发明涉及一种一种或多种试剂的复分解方法，其包含含有双重烯键Csp2-Csp2的直链或支链烃链，所述双链烯烃键Csp2-Csp2使所述试剂或试剂与包含氧化铝基载体的负载金属化合物反应，接枝氢化钨。通常，每个所述试剂或试剂包含2至30个碳原子。试剂可以以烯烃的形式实施。本发明的方法可用于例如从乙烯和丁烷生产丙烯。

18. 发明申请

US20090306441A1 Method for treatment of oil and/or gas field waste and by product materials 审中-公开
标题翻译：用于处理油和/或气田废物和产品材料的方法
公开(公告)号：US20090306441A1
公开(公告)日：2009-12-10
申请号：US12308747
申请日：2007-06-12
申请人： Jean Marie Basset , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean Marie Basset , Francois Stoffelbach , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C10L1/16 , C07C6/00
CPC分类号： B01J31/121 , B01J21/04 , B01J31/2265 , B01J37/0203 , B01J37/0207 , B01J37/0209 , B01J2531/66 , C07C6/10 , C07C2521/04 , C07C2531/12 , C10L1/06 , C07C9/16
摘要： The present invention relates to a process for preparing 2,3-dimethylbutane which comprises contacting in a reaction zone isobutane with a supported catalyst comprising a tungsten hydride and a support comprising an aluminium oxide, so as to form a reaction mixture comprising 2,3-dimethylbutane. The contacting essentially leads to performing a metathesis reaction of the isobutane, with a very high specificity in the formation of 2,3-dimethylbutane. The catalyst is preferably a tungsten hydride grafted onto a support based on aluminium oxide. The support can be chosen from aluminium oxides, mixed aluminium oxides and modified aluminium oxides. The reaction mixture can be isolated and preferably subjected to one or more fractionating operations in order to recover 2,3-dimethylbutane and optionally one or more other components of the reaction mixture, such as C5+ alkanes. The process can comprise isolating from the reaction mixture the C5+ alkanes including 2,3-dimethylbutane as a single component, which can be blended with gasoline to enhance the gasoline octane number, or be used as a gasoline blendstock. At least one separated fraction containing 2,3-dimethylbutane can be isolated from the single component, which can be blended with gasoline to enhance the gasoline octane number, or be used as a gasoline blendstock.
摘要翻译：本发明涉及一种制备2,3-二甲基丁烷的方法，该方法包括使反应区异丁烷与包含氢化钨的载体催化剂和包含氧化铝的载体接触，以形成包含2,3-二甲基丁烷的反应混合物，二甲基丁烷。该接触基本上导致进行异丁烷的复分解反应，在2,3-二甲基丁烷的形成中具有非常高的特异性。催化剂优选为基于氧化铝接枝到载体上的氢化钨。载体可以选自氧化铝，混合氧化铝和改性氧化铝。可以分离反应混合物，并优选进行一次或多次分馏操作，以回收2,3-二甲基丁烷和任选的一种或多种其它反应混合物的组分，例如C5 +烷烃。该方法可以包括从反应混合物中分离出包含2,3-二甲基丁烷作为单一组分的C5 +烷烃，其可以与汽油混合以增强汽油辛烷值，或者用作汽油混合料。可以从单一成分中分离出含有2,3-二甲基丁烷的至少一个分离馏分，其可以与汽油混合以提高汽油辛烷值，或者用作汽油混合料。

19. 发明授权

US06727397B2 Process for manufacturing alkanes with methane 失效
标题翻译：用甲烷制造烷烃的方法
公开(公告)号：US06727397B2
公开(公告)日：2004-04-27
申请号：US10040495
申请日：2002-01-09
申请人： Jean-Marie Basset , Christophe Coperet , Laurent Lefort , Barry Martin Maunders , Olivier Maury , Guillaume Saggio , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Laurent Lefort , Barry Martin Maunders , Olivier Maury , Guillaume Saggio , Jean Thivolle-Cazat
IPC分类号： C07C608
CPC分类号： B01J37/0203 , C07C6/10 , C07C2531/12
摘要： The present invention relates to a process for manufacturing alkanes, comprising, as main stage, a reaction resulting from bringing methane into contact with at least one other starting alkane (A) in the presence of a catalyst based on a metal M capable of catalyzing a metathesis of alkanes. The reaction results in the formation of at least one or two final alkanes (B) having a number of carbon atoms less than or equal to that of the starting alkane (A) and at least equal to 2. Preferably the catalyst comprises a hydride of a metal M grafted to and dispersed over a solid support. The metal M may be chosen from transition metals, lanthanides and actinides. The present invention also relates to the use of a catalyst capable of catalyzing a metathesis of alkanes in 3 reaction resulting from bringing methane into contact with at least one other starting alkane (A).
摘要翻译：本发明涉及一种制备烷烃的方法，该方法主要包括在催化剂存在下使甲烷与至少一种其它起始烷烃（A）接触而产生的反应，所述催化剂基于能够催化一种烷烃的复分解。反应导致至少一种或两种具有小于或等于起始烷烃（A）的碳原子的最终烷烃（B）的形成，并且至少等于2.优选地，催化剂包含金属M接枝并分散在固体支持物上。金属M可以选自过渡金属，镧系元素和锕系元素。本发明还涉及能够在使甲烷与至少一种其它起始烷烃（A）接触的情况下，在3反应中催化烷烃的复分解的催化剂的用途。

20. 发明授权

US06229060B1 Method of metathesis of alkanes and catalyst 有权
标题翻译：烷烃和催化剂复分解方法
公开(公告)号：US06229060B1
公开(公告)日：2001-05-08
申请号：US09147507
申请日：1999-03-12
申请人： Véronique Vidal , Albert Theolier , Jean Thivolle-Cazat , Jean-Marie Basset
发明人： Véronique Vidal , Albert Theolier , Jean Thivolle-Cazat , Jean-Marie Basset
IPC分类号： C07C608
CPC分类号： B01J37/0203 , B01J31/121 , C07C6/10 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/20 , C07C2529/06 , C07C2531/12 , C07C2531/36
摘要： A process for the metathesis of linear or branched starting alkanes involves, first, grafting metal atoms in the form of hydrides to a solid oxide, such that the grafted metal atoms are dispersed over the solid oxide, which effects a solid catalyst, and second, reacting the starting alkanes over the solid catalyst.
摘要翻译：线性或支化起始烷烃的复分解方法包括首先将氢化物形式的金属原子接枝到固体氧化物上，使得接枝的金属原子分散在固体氧化物上，其影响固体催化剂，其次，使起始烷烃在固体催化剂上反应。

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