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    • 11. 发明授权
    • Rubber powders
    • 橡胶粉
    • US4421901A
    • 1983-12-20
    • US337010
    • 1982-01-04
    • Christian LindnerKarl-Heinz Ott
    • Christian LindnerKarl-Heinz Ott
    • C08F2/18C08F285/00C08F265/04
    • C08F285/00Y10S525/902
    • Pourable rubber powders comprising particles having an average diameter of from 0.01 to 10 mm which contain, polymerized thereon, a shell of the polymer or copolymer of one or more vinyl monomers in a quantity of from 2 to 20% by weight, based on the rubber, and the core rubber is a latex polymer, the latex particles of which are composed of a core polymer and a sheath polymer, the core and sheath differing in their chemical composition and at least the sheath polymer being a diene or acrylate rubber having glass transition temperatures of below 0.degree. C., and a process for the preparation of such rubber powders, wherein a latex of an approximate rubber is completely broken with the formation of an aqueous suspension of the rubber; from 2 to 20% by weight, based on the rubber, of one or more vinyl monomers which form polymers having glass transition temperatures of above 25.degree. C. are then introduced into the suspension; and the monomer(s) is/are polymerized, optionally after adding a radical-forming catalyst.
    • 包含平均直径为0.01至10mm的颗粒的可浇注橡胶粉末,其含有基于橡胶的2-20重量%的聚合物或一种或多种乙烯基单体的共聚物的聚合物的壳 ,核心橡胶是胶乳聚合物,其胶乳颗粒由芯聚合物和鞘聚合物组成,芯和鞘的化学组成不同,并且至少鞘聚合物是具有玻璃化转变的二烯或丙烯酸酯橡胶 温度低于0℃,以及制备这种橡胶粉末的方法,其中近似橡胶的胶乳完全破碎,形成橡胶的水性悬浮液; 然后将2至20重量%的基于橡胶的一种或多种形成玻璃化转变温度高于25℃的聚合物的乙烯基单体引入悬浮液中; 并且任选地在添加自由基形成催化剂之后使单体聚合。