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11. 发明授权

US5525696A Crosslinkable compositions and their use for the production of non-stick coatings 失效
标题翻译：可交联组合物及其用于生产不粘涂料的用途
公开(公告)号：US5525696A
公开(公告)日：1996-06-11
申请号：US327739
申请日：1994-10-24
申请人： Christian Herzig , Bernward Deubzer , Inge Seeger-Feichtinger
发明人： Christian Herzig , Bernward Deubzer , Inge Seeger-Feichtinger
IPC分类号： C08L83/04 , C08L83/05 , C08L83/07 , C09D183/04 , C09J183/00 , C09J183/05 , C09J183/07 , C08G77/08
CPC分类号： C08L83/04 , C09D183/04 , C08G77/12 , C08G77/20
摘要： Compositions which comprise(A) a polymeric organosilicon compound having 1 to 6 Si-bonded hydrogen atoms per molecule,(B) a polymeric organosilicon compound having at least two alkenyl groups per molecule and a viscosity of not more than 100 mm.sup.2 /s,(C) a polymeric organosilicon compound having on average at least 10 Si-bonded hydrogen atoms per molecule,(D) a catalyst and, optionally(E) an inhibitor,with the proviso thatthe molar ratio of all the Si-bonded hydrogen atoms to all the SiC-bonded alkenyl groups in the composition is on average less than 1,the composition comprises (B) in an amount such that the composition comprises on average at least 1.1 alkenyl radicals of (B) per Si-bonded hydrogen atom of (A)and the content of Si-bonded hydrogen atoms of (C) is 5% to 50%, based on the number of all the Si-bonded hydrogen atoms present.
摘要翻译：包含（A）每分子具有1至6个Si键合的氢原子的聚合物有机硅化合物的组合物，（B）每分子具有至少两个烯基并且粘度不超过100mm 2 / s的聚合物有机硅化合物（ C）每分子平均具有至少10个Si键合氢原子的聚合物有机硅化合物，（D）催化剂和任选的（E）抑制剂，条件是所有Si键合的氢原子与组合物中所有SiC键合的烯基平均小于1，组合物包含（B），其量使得组合物平均包含（B）的至少1.1个烯基（每个Si键合的氢原子的（B））（ A），（C）的Si键合氢原子的含量相对于存在的所有Si键合氢原子的数量为5〜50％。

12. 发明授权

US4857608A Process for preparing weather-resistant coatings 失效
标题翻译：制备耐候性涂料的方法
公开(公告)号：US4857608A
公开(公告)日：1989-08-15
申请号：US166950
申请日：1988-03-11
申请人： Christian Herzig , Bernward Deubzer , Volker Frey , Esterbauer Josef
发明人： Christian Herzig , Bernward Deubzer , Volker Frey , Esterbauer Josef
IPC分类号： C08G59/40 , C09D163/00
CPC分类号： C08G59/4085 , C09D163/00 , Y10T428/31529
摘要： Substrates which are exposed to weathering are coated with paints containing an epoxy resin and a silicon compound containing basic nitrogen which is bonded to the silicon via a carbon and which has at least one hydrogen atom bonded directly to the nitrogen atom.
摘要翻译：暴露于风化的底物涂覆有含有环氧树脂的涂料和含有碱性氮的硅化合物，其通过碳键合到硅上，并且具有至少一个与氮原子直接键合的氢原子。

13. 发明授权

US5593787A Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use 失效
标题翻译：含有（甲基）丙烯酰氧基的有机硅化合物，其制备及其应用
公开(公告)号：US5593787A
公开(公告)日：1997-01-14
申请号：US548127
申请日：1995-10-25
申请人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
发明人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
IPC分类号： B01J31/22 , C07B61/00 , C07F7/08 , C07F7/18 , C08F30/08 , C08G77/14 , C08G77/20 , C08G77/22 , C08G77/38 , C08L83/07 , C09D137/00 , C09D143/04 , C09D183/06 , C09D183/07 , B32B9/04
CPC分类号： C08G77/38 , C08G77/20 , C09D183/06 , Y10T428/31663
摘要： The present invention relates to organosilicon compounds containing (meth)acryloxy groups which can be prepared in a simple manner with high selectivity using readily accessible starting substances. The organopolysiloxanes containing (meth)acryloxy groups rapidly crosslink in the presence of a photoinitiator and light. The compounds of the present invention may be employed in the production of coatings.
摘要翻译：本发明涉及含有（甲基）丙烯酰氧基的有机硅化合物，其可以使用容易获得的起始物质以高选择性以简单的方式制备。含有（甲基）丙烯酰氧基的有机聚硅氧烷在光引发剂和光的存在下迅速交联。本发明的化合物可用于制备涂料。

14. 发明授权

US5401821A Process for the preparation of an organopolysiloxane resin 失效
标题翻译：制备有机聚硅氧烷树脂的方法
公开(公告)号：US5401821A
公开(公告)日：1995-03-28
申请号：US165788
申请日：1993-12-13
申请人： Michael Geck , Christian Herzig , Bernward Deubzer , Helmut Oswaldbauer
发明人： Michael Geck , Christian Herzig , Bernward Deubzer , Helmut Oswaldbauer
IPC分类号： B01D19/04 , C08G77/06 , C08G77/32 , C08G77/36 , C09D7/12 , D21H19/32 , G03G9/087 , C08G77/08
CPC分类号： B01D19/0409 , C08G77/06 , C09D7/125 , D21H19/32 , G03G9/08773
摘要： Process for the preparation of an organopolysiloxane resin, which comprisesin a first stage reacting at least one silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)in which a has a value of 0, 1, 2 or 3, R and R.sup.1 are monovalent organic radicals which may be the same or different and/or a partial hydrolyzate thereof, with the proviso that at least one silane of formula (I), where a is 0 or 1 and/or a partial hydrolyzate thereof is employed, and optionally an organo(poly)siloxane with water in the presence of a poly-protic acid and optionally other substances, subsequently partly neutralizing the acid by addition of a base and then distilling off at least some of the compound R.sup.1 OH formed,in a second stage reacting the homogeneous reaction mass resulting from the first stage in the presence of a base and a water-insoluble organic solvent and distilling off the water and the compound R.sup.1 OH,in a third stage, bringing the homogeneous reaction mass resulting from the second stage to a pH of between 6 and 8 by buffering with a poly-protic acid and/or salts thereof, distilling off the water and any compound R.sup.1 OH still present and filtering off the salt which has precipitated, andoptionally, in a fourth stage separating the homogeneous reaction mass resulting from the third stage from the water-insoluble organic solvent.
摘要翻译：一种制备有机聚硅氧烷树脂的方法，该方法包括在第一阶段使至少一种式RaSi（OR1）4-a（I）的硅烷反应其中a值为0,1,2或3，R和 R 1是可以相同或不同的一价有机基团和/或其部分水解产物，条件是使用至少一种式（I）的硅烷，其中a为0或1，和/或其部分水解产物，和任选的有机（聚）硅氧烷与水在多质子酸和任选的其它物质的存在下，随后通过加入碱部分中和酸，然后在第二次蒸馏出至少一些所形成的化合物R 1 OH 在碱的存在和水不溶性有机溶剂的存在下使由第一阶段产生的均相反应物质反应，并在第三阶段中蒸馏除去水和化合物R1OH，使由第二阶段产生的均匀反应物质 pH在6 a之间通过用聚 - 质子酸和/或其盐缓冲，蒸出水和仍存在的任何化合物R1OH，并过滤沉淀的盐，并且任选地在第四阶段中分离由第三阶段来自水不溶性有机溶剂。

15. 发明授权

US4972029A Process for preparing thermally stable crosslinked epoxy resins 失效
标题翻译：制备热稳定交联环氧树脂的方法
公开(公告)号：US4972029A
公开(公告)日：1990-11-20
申请号：US325429
申请日：1989-03-20
申请人： Christian Herzig , Bernward Deubzer , Josef Esterbauer
发明人： Christian Herzig , Bernward Deubzer , Josef Esterbauer
IPC分类号： C08G59/40 , C08G59/50 , C08G77/38 , C08L83/08
CPC分类号： C08G59/504 , C08G59/4085 , C08L83/08
摘要： Thermally stable, crosslinked epoxy resins are obtained by crosslinking an epoxy resin with a silicon compound containing a basic nitrogen which is bonded to silicon via carbon and to which at least 1 hydrogen atom is bonded directly to the nitrogen atom, and thereafter conditioning the crosslinked epoxy resin.
摘要翻译：热稳定交联的环氧树脂通过环氧树脂与含有碱性氮的硅化合物交联而获得，所述硅化合物通过碳与硅键合，至少1个氢原子直接与氮原子键合，然后调节交联的环氧树脂树脂。

16. 发明授权

US5760145A Crosslinkable compositions comprising organopolysiloxanes containing aliphatically unsaturated hydrocarbon radicals 失效
标题翻译：包含含有脂肪族不饱和烃基的有机聚硅氧烷的可交联组合物
公开(公告)号：US5760145A
公开(公告)日：1998-06-02
申请号：US882841
申请日：1997-06-26
申请人： Christian Herzig , David Huettner , Kathy Beekel
发明人： Christian Herzig , David Huettner , Kathy Beekel
IPC分类号： C08G77/50 , C08L83/14 , C09D183/14 , C08G77/08
CPC分类号： C08L83/14 , C08G77/50 , C09D183/14 , Y10T428/31663
摘要： Novel crosslinkable compositions are described, comprising (A) organopolysiloxanes containing aliphatically unsaturated hydrocarbon radicals, comprising; (a) at least one unit, per molecule, of the formula ##STR1## in which A is a radical of the formula --(OSiR.sup.1 R.sup.2).sub.z --(OSiR.sub.2).sub.x --Y--SiR.sub.2 O.sub.1/2,R is identical or different and is a monovalent, aliphatically saturated or aromatic hydrocarbon radical having 1 to 12 carbon atoms per radical, R.sup.1 is a radical of the formula --OSiR.sub.2 --Y--SiR.sub.2 O.sub.1/2, R.sup.2 has the meaning of R, R.sup.1 or R', where R' is a monovalent, aliphatically saturated or aromatic hydrocarbon radical having 1 to 12 carbon atoms per radical, which contains one or more heteroatoms chosen from the group consisting of O, S, N, Si and Ti, Y is a divalent hydrocarbon radical of the formula --CH.sub.2 CHR.sup.5 (--R.sup.4).sub.v --, in which R.sup.4 is a divalent hydrocarbon radical having 1 to 10 carbon atoms per radical or a chemical bond, if v has the value 0, R.sup.5 is a hydrogen atom or has the meaning of R, v is 0 or 1, x and z is identical or different and is 0 or 1, and B has the meaning of A or R or R', with the proviso that B is R or R' if x is 0, (b) at least one unit, per molecule, of the formula O.sub.1/2 SiR.sub.2 R.sup.3 (II), in which R has the meaning given above for this radical and R.sup.3 is an aliphatically unsaturated hydrocarbon radical of the formula H.sub.2 C.dbd.CR.sup.5 (--R.sup.4).sub.v --, in which R.sup.4 and R.sup.5 have the meaning given above for these radicals.
摘要翻译：描述了新的可交联组合物，其包含（A）含有脂族不饱和烃基的有机聚硅氧烷，其包含：（a）每分子至少一个式（I）的化合物，其中A是式 - （OSiR 1 R 2）z - （OSiR 2）x Y-SiR 2 O + E，f 1/2 + EE R是相同或不同的，并且是每个基团具有1至12个碳原子的单价，脂族饱和或芳族烃基，R1是下式-OSiR2-Y-SiR2O + E的基团，1/2 + EE，R2 具有R，R 1或R'的含义，其中R'是每个基团具有1至12个碳原子的单价脂族饱和或芳族烃基，其含有一个或多个选自O，S，N ，Si和Ti，Y是式-CH 2 CHR 5（-R 4）v - 的二价烃基，其中R 4是每个基团或化学键具有1至10个碳原子的二价烃基，如果v具有值0 R 5为氢原子或具有R的含义，v为0或1，x和z相同或不同，为0或1，B具有A或R或R'的含义，条件是B 如果x为0，则为R或R'，（b）a 每分子至少一个单位，式O + E，1/2 + EESiR 2 R 3（II），其中R具有上述对该基团的含义，并且R 3是式IIC的脂族不饱和烃基： CR5（-R4）v-，其中R4和R5具有上述对这些基团的含义。

17. 发明授权

US08598108B2 Fabric care compositions comprising organosiloxane polymers 有权
公开(公告)号：US08598108B2
公开(公告)日：2013-12-03
申请号：US13569373
申请日：2012-08-08
申请人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
发明人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C11D3/2072 , C11D3/373 , C11D3/3738 , C11D3/50 , C11D11/0017
摘要： The present composition relates to fabric care compositions comprising an organosiloxane polymer. Methods of using such compositions including contacting a fabric with the composition and rinsing the fabric are also disclosed.

18. 发明授权

US08263543B2 Fabric care compositions comprising organosiloxane polymers 有权
标题翻译：包含有机硅氧烷聚合物的织物护理组合物
公开(公告)号：US08263543B2
公开(公告)日：2012-09-11
申请号：US12752860
申请日：2010-04-01
申请人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
发明人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C11D3/2072 , C11D3/373 , C11D3/3738 , C11D3/50 , C11D11/0017
摘要： The present composition relates to fabric care compositions comprising an organosiloxane polymer. Methods of using such compositions including contacting a fabric with the composition and rinsing the fabric are also disclosed.
摘要翻译：本发明组合物涉及包含有机硅氧烷聚合物的织物护理组合物。还公开了使用这种组合物的方法，包括使织物与组合物接触并漂洗织物。

19. 发明授权

US08084552B2 Method for producing silicone polyethers 有权
标题翻译：硅氧烷聚醚的制备方法
公开(公告)号：US08084552B2
公开(公告)日：2011-12-27
申请号：US12921044
申请日：2009-03-03
申请人： Christian Herzig
发明人： Christian Herzig
IPC分类号： C08F283/06 , C08F283/12 , C08G77/46
CPC分类号： C08G77/46 , C08G77/12
摘要： Silicone polyethers are prepared in a two stage process by reacting an unsaturated polyether with a first Si—H functional organopolysiloxane and then with a second organopolysiloxane, in which the weight ratio of silicon bonded hydrogen in the first and second organopolysiloxanes is at least 0.9. The reaction is more rapid than a single step process and produces a product with less unreacted Si—H content.
摘要翻译：通过使不饱和聚醚与第一Si-H官能的有机聚硅氧烷，然后与第二有机聚硅氧烷反应制备硅氧烷聚醚，其中第一和第二有机聚硅氧烷中硅键合氢的重量比至少为0.9。反应比单步法更快，并产生具有较少未反应的Si-H含量的产物。

20. 发明授权

US07645360B2 Defoamer formulations 有权
标题翻译：消泡剂配方
公开(公告)号：US07645360B2
公开(公告)日：2010-01-12
申请号：US11915941
申请日：2006-05-24
申请人： Willibald Burger , Christian Herzig , Josef Wimmer
发明人： Willibald Burger , Christian Herzig , Josef Wimmer
IPC分类号： D21H21/00
CPC分类号： C08G18/61 , B01D19/0409 , C08G77/458
摘要： Defoamer compositions of high effectiveness containing at least one siloxane-based antifoam and polysiloxane copolymers obtained by coupling a polysiloxane bearing active-hydrogen-containing hydrophilic polymer moieties by means of a di- or polyisocyanate.
摘要翻译：通过用二异氰酸酯或多异氰酸酯偶联含有含活性氢的亲水性聚合物部分的聚硅氧烷获得的含有至少一种基于硅氧烷的消泡剂和聚硅氧烷共聚物的高效消泡剂组合物。

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