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11. 发明授权

US4902803A Aromatic heterocyclic peroxycarboxylic acids 失效
标题翻译：芳香杂环过氧羧酸
公开(公告)号：US4902803A
公开(公告)日：1990-02-20
申请号：US219141
申请日：1988-07-15
申请人： Carlo Venturello , Claudio Cavallotti
发明人： Carlo Venturello , Claudio Cavallotti
IPC分类号： C07D213/78 , C07D213/79 , C07D213/89 , C07D215/50 , C11D3/39 , C11D7/54 , D06L3/02
CPC分类号： C07D213/79 , C07D213/78 , C07D213/89 , C07D215/50 , C11D3/3945
摘要： Nitrogen-containing aromatic heterocyclic (poly)peroxycarbonxylic acids having the formula: ##STR1## wherein R represents a hydrogen atom or a straight or branched alkyl, (hetero)cycloalkyl, (hetero)aryl, alkylaryl or arylalkyl group, wherein said groups are optionally substituted, or a carboxylic group or any other substituents non-reactive in the presence of the active oxygen of the peroxycarboxylic group;n is a number selected from 0 and 1;m is a number selected from 1, 2 and 3, andX represents an acidic anion selected from HSO.sub.4.sup.- and CH.sub.3 SO.sub.3.sup.-, and wherein the pyridinic ring may in its turn be condensed with at least one further (hetero) aromatic or (hetero)cycloalkylic ring;to their preparation process and to their use as bleaching agents.

12. 发明授权

US5688434A Imide-aromatic peroxyacids as bleaching agents 失效
标题翻译：酰亚芳基过氧酸作为漂白剂
公开(公告)号：US5688434A
公开(公告)日：1997-11-18
申请号：US593655
申请日：1996-01-29
申请人： Carlo Venturello , Claudio Cavallotti , Fulvio Burzio
发明人： Carlo Venturello , Claudio Cavallotti , Fulvio Burzio
IPC分类号： C11D7/54 , C07C67/00 , C07C407/00 , C07C409/40 , C07D209/48 , C07D209/66 , C11D3/39 , C01B15/10 , C11D3/395 , D06L3/02
CPC分类号： C07D209/48 , C11D3/3945
摘要： A process of bleaching using at least one imide-aromatic (poly)peroxyacid, having a formula: ##STR1## wherein A represents the residue of a benzene or napthalene ring optionally substituted by a COOH or COOOH group, the symbol or symbols R, which may be the same or different from each other, represent a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, an OH group, a COOH group, a COOOH group, a COOR' group, wherein R' represents a C.sub.1 -C.sub.5 alkyl group, or a substituted C.sub.1 -C.sub.5 alkyl group wherein the substituent is nitro, an OH group or a C.sub.1 -C.sub.5 alkoxy group, and n is an integer from 1 to 5.
摘要翻译：使用至少一种具有下式的酰亚胺 - 芳族（聚）过氧酸的漂白方法：其中A表示任选被COOH或COOOH基团取代的苯或萘环的残基，符号或符号 R可以相同或不同，表示氢原子，C1-C5烷基，OH基，COOH基，COOOH基，COOR'基，其中R'表示C1-C5 烷基或取代的C1-C5烷基，其中取代基是硝基，OH基或C1-C5烷氧基，n是1至5的整数。

13. 发明授权

US5520844A Imide-aromatic peroxyacids as bleaching agents 失效
标题翻译：酰亚芳基过氧酸作为漂白剂
公开(公告)号：US5520844A
公开(公告)日：1996-05-28
申请号：US637479
申请日：1991-01-04
申请人： Carlo Venturello , Claudio Cavallotti , Fulvio Burzio
发明人： Carlo Venturello , Claudio Cavallotti , Fulvio Burzio
IPC分类号： C11D7/54 , C07C67/00 , C07C407/00 , C07C409/40 , C07D209/48 , C07D209/66 , C11D3/39 , C01B15/10
CPC分类号： C07D209/48 , C11D3/3945
摘要： Bleaching agents constituted by at least one imidearomatic (poly)peroxyacid, having the formula (I): ##STR1## wherein A represents a residue of a substituted or unsubstituted benzene or naphthalene ring, R is a hydrogen atom, a lower alkyl group, an OH group, a COOH group, a COOOH group or a COOR' group wherein R' represents a C.sub.1 -C.sub.5 alkyl group, and n is an integer from 1 to 5.
摘要翻译：由至少一种具有式（I）的酰亚胺（poly）过氧酸构成的漂白剂：fa取代或未取代的苯或萘环，R是氢原子，低级烷基，OH基，COOH基，COOOH 基团或COOR'基团，其中R'表示C1-C5烷基，n为1至5的整数。

14. 发明授权

US5041546A Certain piperidine or azepine peroxy compounds and derivatives useful as bleaching agents 失效
标题翻译：某些哌啶或吖庚因过氧化合物和衍生物可用作漂白剂
公开(公告)号：US5041546A
公开(公告)日：1991-08-20
申请号：US366512
申请日：1989-06-14
申请人： Carlo Venturello , Claudio Cavallotti
发明人： Carlo Venturello , Claudio Cavallotti
IPC分类号： C07D223/06 , C07D207/16 , C07D211/60 , C07D211/62 , C07D233/06 , C11D3/39 , C11D3/395
CPC分类号： C07D211/60 , C07D211/62 , C11D3/3945
摘要： Heterocyclic (poly)peroxycarboxylic acids having a N-amidic heteroatom, which have the formula:R--(CH.sub.2).sub.m --R' (I)wherein:R and R', alike or different from each other, represent hydrogen atoms or a group: ##STR1## with the proviso that at least one of R and R' shall be different from H, and wherein the other symbols have the following meaning:R" represents a hydrogen atom or any other substituent non-reactive in the presence of the active oxygen of the peroxycarboxylic group and/or under the preparation conditions;m represents a number between 1 to 12;n represents a number selected from 0, 1 and 2;p represents a number between 1 and 3;their process of preparation and their use as bleaching agents.

15. 发明授权

US4994573A Pyridine-3-peroxycarboxylic acid monopersulfate 失效
标题翻译：吡啶-3-过氧羧酸单过硫酸盐
公开(公告)号：US4994573A
公开(公告)日：1991-02-19
申请号：US448894
申请日：1989-12-12
申请人： Carlo Venturello , Claudio Cavallotti
发明人： Carlo Venturello , Claudio Cavallotti
IPC分类号： C07D213/78 , C11D3/395 , D06L3/02
CPC分类号： C07D213/78
摘要： Pyridine-3-peroxycarboxylic acid monopersulfate is herein disclosed, which has the formula: ##STR1## The process for its preparation and its use as bleaching agent.

16. 发明授权

US5274140A Process for catalytically epoxidizing olefin with hydrogen peroxide 失效
标题翻译：用过氧化氢催化环氧化烯烃的方法
公开(公告)号：US5274140A
公开(公告)日：1993-12-28
申请号：US582814
申请日：1990-09-14
申请人： Carlo Venturello , Enzo Alneri , Giulio Lana
发明人： Carlo Venturello , Enzo Alneri , Giulio Lana
IPC分类号： B01J10/00 , C07D301/12 , C07D303/04
CPC分类号： C07D301/12 , B01J10/00 , C07D303/04
摘要： There is disclosed a new process for the epoxidization of olefins by reaction with hydrogen peroxide according to the double phase technique with "onium" salts, characterized in that the reaction is conducted in a liquid aqueous-organic biphasic system consisting of:(a) an organic phase substantially containing the olefin, and(b) an aqueous acid phase substantially containing hydrogen peroxide,in the presence of a catalytic system consisting of a first component which is at least one element selected from W. Mo, V or at least one derivative of said elements, and of a second component which is at least one derivative selected from the derivatives of P and As.
摘要翻译：公开了通过根据双相技术与“过氧化氢”盐与过氧化氢反应的烯烃的环氧化的新方法，其特征在于反应在液体含水 - 有机双相体系中进行，该系统由以下组成：（a）有机相基本上含有烯烃，和（b）基本上含有过氧化氢的酸性水相，在催化体系存在下，该催化体系由选自W.Mo，V或至少一种衍生物的至少一种元素组成的第一组分的所述元素，以及作为选自P和As的衍生物的至少一种衍生物的第二成分。

17. 发明授权

US4701550A Process for preparing alkyl esters of methyltartronic acid 失效
标题翻译：制备甲基三苯甲酸的烷基酯的方法
公开(公告)号：US4701550A
公开(公告)日：1987-10-20
申请号：US745238
申请日：1985-06-17
申请人： Carlo Venturello , Enzo Alneri , Alfredo Coassolo , Rino D'Aloisio
发明人： Carlo Venturello , Enzo Alneri , Alfredo Coassolo , Rino D'Aloisio
IPC分类号： C07C59/10 , B01J23/00 , B01J23/30 , B01J23/40 , C07B61/00 , C07C51/00 , C07C51/16 , C07C51/235 , C07C51/27 , C07C51/285 , C07C51/367 , C07C59/245 , C07C67/00 , C07C67/03 , C07C69/675 , C07C67/40
CPC分类号： C07C51/27 , C07C51/235 , C07C51/285
摘要： There is described a process for preparing alkyl esters of methyltartronic acid by hydroxylation of methacrylic acid to alpha-methylglyceric acid with H.sub.2 O.sub.2, in an aqueous medium, in the presence of H.sub.2 WO.sub.4 and optionally of H.sub.3 PO.sub.4 or H.sub.3 AsO.sub.4 or alkaline salts thereof as catalysts, at pH
摘要翻译：描述了一种通过在H 2 WO 4和任选的H 3 PO 4或H 3 AsO 4或其碱式盐作为催化剂的情况下，在水性介质中，在H 2 O 2中将甲基丙烯酸羟基化为α-甲基甘油酸的α-甲基甘油酸的烷基酯作为催化剂， <2，在50〜100℃的温度下，通过在含有碱性介质中的Pd或Pt的存在下，将α-甲基甘氨酸随后氧化为过量或与O 2的甲酸塔特酸反应，碳或其氧化物作为催化剂，在60℃-100℃的温度下进行，甲基泰特康酸与醇C1-C4的最终酯化反应。

18. 发明授权

US4562299A Process for the preparation of vicinal diols soluble in water 失效
标题翻译：制备可溶于水的连位二醇的方法
公开(公告)号：US4562299A
公开(公告)日：1985-12-31
申请号：US680833
申请日：1984-12-12
申请人： Carlo Venturello , Mario Gambaro
发明人： Carlo Venturello , Mario Gambaro
IPC分类号： B01J31/00 , B01J31/02 , C07B31/00 , C07B41/02 , C07B61/00 , C07C27/00 , C07C29/03 , C07C31/20 , C07C31/27 , C07C31/42 , C07C33/26 , C07C35/14 , C07C67/00
CPC分类号： C07C29/03 , C07B2200/09 , C07C2101/08 , C07C2101/14 , C07C2101/18
摘要： A process for the preparation of water-soluble vicinal diols by means of a direct catalytic hydroxylation of the corresponding olefines with H.sub.2 O.sub.2. An olefine possibly carrying functional groups inert under the reaction conditions, and whose corresponding vicinal diol is soluble in water, is made to react, under vigorous stirring, with H.sub.2 O.sub.2 at a temperature between 0.degree. and 120.degree. C. and at a pressure between 1 and 100 atmospheres, in a two-phase aqueous liquid/organic liquid system consisting or consisting essentially of an acid aqueous phase containing H.sub.2 O.sub.2 and of an organic phase containing (1) said olefine; (2) possibly a solvent immiscible with the aqueous phase; and (3) a catalyst of the formula:Q.sub.3 XW.sub.4 O.sub.24-2nwherein Q represents an onium (RR.sub.1 R.sub.2 R.sub.3 M).sup.+ cation, wherein M is chosen from among N, P, As and Sb, and R, R.sub.1, R.sub.2 and R.sub.3, equal to or different from each other, represent hydrogen atoms or hydrocarbon groups having a total of from 20 to 70 carbon atoms; X is an atom of P or As; and n is an integer chosen from among 0, 1 and 2.
摘要翻译：通过相应的烯烃与H 2 O 2的直接催化羟基化制备水溶性连二醇的方法。在剧烈搅拌下，在0〜120℃的温度和0〜120℃之间的压力下，将可能携带在反应条件下为惰性的官能团的烯烃及其相应的邻位二醇溶于水，使其反应在包含H 2 O 2的酸性水相和含有（1）所述烯烃的有机相中或基本上组成的两相含水液体/有机液体体系中，（2）可能是与水相不混溶的溶剂; 和（3）下式的催化剂：Q3XW4O24-2n其中Q表示鎓（RR1R2R3M）+阳离子，其中M选自N，P，As和Sb，R，R1，R2和R3等于或彼此不同，表示总共具有20至70个碳原子的氢原子或烃基; X是P或As的原子; 并且n是从0，1和2中选择的整数。

19. 发明授权

US5179205A Heterocyclic peroxides having N-amidic heteroatoms 失效
标题翻译：具有N-酰胺杂原子的杂环过氧化物
公开(公告)号：US5179205A
公开(公告)日：1993-01-12
申请号：US687147
申请日：1991-04-18
申请人： Carlo Venturello , Claudio Cavalotti
发明人： Carlo Venturello , Claudio Cavalotti
IPC分类号： C07D211/60 , C07D211/62 , C11D3/39
CPC分类号： C07D211/60 , C07D211/62 , C11D3/3945
摘要： Heterocyclic (poly)peroxycarboxylic acids having a N-amidic heteroatom, which have the formula:R--(CH.sub.2) .sub.m --R' (I)wherein: R and R', alike or different from each other, represent hydrogen atoms or a group: ##STR1## with the proviso that at least one of R and R' shall be different from H, and wherein the other symbols have the following meaning:R" represents a hydrogen atom or any other substituent non-reactive in the presence of the active oxygen of the peroxycarboxylic group and/or under the preparation conditions;m represents a number between 1 to 12;n represents a number selected from 0, 1 and 2;p represents a number between 1 and 3;their process of preparation and their use as bleaching agents.
摘要翻译：具有N-酰胺基杂原子的杂环（多）过氧羧酸，其具有下式：R-（CH 2）m -R'（I）其中：R和R'彼此相同或不同，表示氢原子或基团：，条件是R和R'中的至少一个不同于H，并且其中其他符号具有以下含义：R“表示氢原子或任何其它在无过氧羧基的活性氧和/或在制备条件下; m表示1〜12的数; n表示选自0,1和2的数; p表示1和3之间的数字; 其制备方法及其作为漂白剂的用途。

20. 发明授权

US5026911A Process for oxidizing saturated primary amines to oximes 失效
标题翻译：将饱和伯胺氧化成肟的方法
公开(公告)号：US5026911A
公开(公告)日：1991-06-25
申请号：US514218
申请日：1990-04-25
申请人： Carlo Venturello , Rino D'Aloisio
发明人： Carlo Venturello , Rino D'Aloisio
IPC分类号： B01J27/04 , B01J27/053 , B01J27/135 , B01J31/12 , C07B61/00 , C07C249/04 , C07C251/38 , C07C251/44
CPC分类号： C07C249/04 , C07C2101/14
摘要： The invention relates to a process for preparing oximes starting from saturated primary (cyclo)aliphatic amines optionally substituted by groups which are inert under the reaction conditions, by reacting the saturated primary amine with oxygen, the reaction being conducted in the liquid phase in the presence of at least a catalyst based on compounds belonging to Group IV B of the Periodic System, thereby obtaining the corresponding aliphatic and cycloaliphatic oximes.

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