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11. 发明授权

US08217198B2 Process for purifying removal of a chemical target compound from a suspension of crystals thereof in mother liquor 有权
标题翻译：从母液中的晶体悬浮液中净化化学靶化合物的方法
公开(公告)号：US08217198B2
公开(公告)日：2012-07-10
申请号：US12706367
申请日：2010-02-16
申请人： Joerg Heilek , Wolfgang Schneider , Wolfgang Gunkel , Volker Schliephake , Klaus Joachim Mueller-Engel
发明人： Joerg Heilek , Wolfgang Schneider , Wolfgang Gunkel , Volker Schliephake , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/42
CPC分类号： B01D9/005 , B01D9/004 , B01D9/0045 , F16C19/30 , F16C19/38 , F16C19/545 , F16C19/56 , F16C23/086
摘要： A process for purifying removal of a chemical target compound from a suspension of crystals thereof in mother liquor in a wash column with forced transport of the crystal bed from the top downward, in which crystals are removed from the lower end of the crystal bed with a rotating removal device and melted, and a portion of the crystal melt is conducted back toward the crystal bed as wash melt, the removal device being secured with a drive shaft conducted into the wash column from the bottom through an inlet having a seal, said drive shaft being driven about its longitudinal axis by a drive unit for rotation and being mounted so as to be rotatable about its longitudinal axis in more than one bearing, such that the mounting in one of the bearings absorbs the downward force acting on the drive shaft, the mounting in two or more bearings absorbs forces acting radially outward from the drive shaft, and the mounting in one bearing is additionally capable of absorbing an upward force acting on the drive shaft.
摘要翻译：一种用于从其晶体悬浮液中清除化学目标化合物从洗涤塔母液中排出的方法，其中从顶部向下将晶体床强制输送，其中晶体从晶体床的下端被除去，旋转去除装置并熔化，并且一部分晶体熔体作为洗涤熔体被导回到晶体床，所述去除装置通过具有密封件的入口从底部传导到洗涤塔中的驱动轴固定，所述驱动轴通过用于旋转的驱动单元围绕其纵向轴线被驱动并且被安装成可以在多于一个轴承中围绕其纵向轴线旋转，使得其中一个轴承中的安装吸收作用在驱动轴上的向下的力，安装在两个或更多个轴承中吸收从驱动轴径向向外作用的力，并且在一个轴承中的安装另外能够吸收作用的向上的力在驱动轴上。

12. 发明授权

US07795470B2 Method for the heterogeneously catalyzed partial direct oxidation of n-propane to acrylic acid 有权
标题翻译：将丙烷非均相催化部分直接氧化成丙烯酸的方法
公开(公告)号：US07795470B2
公开(公告)日：2010-09-14
申请号：US12142444
申请日：2008-06-19
申请人： Martin Dieterle , Joerg Heilek , Klaus Joachim Mueller-Engel
发明人： Martin Dieterle , Joerg Heilek , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/16
CPC分类号： C07C51/215 , C07C57/04
摘要： A method for the heterogeneously catalyzed partial direct oxidation of propane to acrylic acid in the gas phase, in which the reaction gas inlet mixture comprises cyclopropane as an impurity and the acrylic acid, after it has been converted from the product gas mixture into the liquid phase, is operated from the other constituents of the liquid phase with the aid of a separation by crystallization.
摘要翻译：在气相中异丙烯催化部分直接氧化丙烷到丙烯酸的方法，其中反应气体入口混合物包含作为杂质的环丙烷和丙烯酸，在其从产物气体混合物转化成液相之后，借助于通过结晶分离，从液相的其它组分操作。

13. 发明授权

US07589236B2 Process for separating acrylic acid and benzoic acid present in a product gas mixture of a partial heterogeneously catalyzed gas phase oxidation of a C3 precursor compound of acrylic acid 有权
标题翻译：在丙烯酸C3前体化合物的部分非均相催化气相氧化的产物气体混合物中存在的丙烯酸和苯甲酸分离方法
公开(公告)号：US07589236B2
公开(公告)日：2009-09-15
申请号：US11873883
申请日：2007-10-17
申请人： Joerg Heilek , Klaus Joachim Mueller-Engel , Martin Dieterle , Armin Diefenbacher
发明人： Joerg Heilek , Klaus Joachim Mueller-Engel , Martin Dieterle , Armin Diefenbacher
IPC分类号： C07C51/42
CPC分类号： C07C51/42 , C07C51/235 , C07C51/43 , C07C51/44 , C07C57/04 , C07C63/06
摘要： A process for separating acrylic acid and benzoic acid present in the product gas mixture of a partial oxidation to acrylic acid, in which the acrylic acid and the benzoic acid are first converted to a liquid phase, constituents having a lower boiling point than benzoic acid and acrylic acid are removed therefrom by thermal separating processes, and the acrylic acid is removed by crystallization from the remaining liquid phase.
摘要翻译：将部分氧化的产物气体混合物中存在的丙烯酸和苯甲酸分离为丙烯酸的方法，其中丙烯酸和苯甲酸首先转化为液相，沸点低于苯甲酸的组分和通过热分离方法除去丙烯酸，通过从剩余液相中结晶除去丙烯酸。

14. 发明授权

US08461383B2 Process for starting up a separating process for purifying removal of acrylic acid crystals from a suspension S of crystals thereof in mother liquor 有权
标题翻译：用于启动分离过程的方法，用于从母液中的晶体的悬浮液S中纯化除去丙烯酸晶体
公开(公告)号：US08461383B2
公开(公告)日：2013-06-11
申请号：US12897199
申请日：2010-10-04
申请人： Joerg Heilek , Dirk Litters , Klaus Joachim Mueller-Engel
发明人： Joerg Heilek , Dirk Litters , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/43
CPC分类号： C07C51/43 , C07C51/47 , C07C57/04
摘要： A process for starting up a separating process for purifying removal of acrylic acid crystals from a suspension S of crystals thereof in mother liquor with a hydraulic wash column which has a crystal melt circuit including crystal melt space, and a process space and a distributor space which are separated by an end with passages connecting the two spaces, in which the crystal bed is formed for the first time by first filling the crystal melt circuit and, at least partly, the process space with an acrylic acid-comprising startup liquid whose acrylic acid crystal formation temperature is less than or equal to the temperature of the suspension S increased by 15° C., and then continuing the filling of the wash column with the suspension S and optionally with control liquor until the difference between the pressure in the crystal melt space and the pressure in the distributor space falls suddenly, the arithmetic mean of the total waste liquor flow flowing through the filters of the filter tubes of the wash column until this time, based on the area of all filters, being not more than 80 m3/(m2·h).
摘要翻译：一种用于利用具有包括晶体熔融空间的晶体熔融回路的液压洗涤柱从母液中的晶体悬浮液S中纯化除去丙烯酸晶体的分离过程的工艺，以及工艺空间和分配器空间，通过连接两个空间的通道分开一端，其中通过首先填充晶体熔融回路并且至少部分地与包含丙烯酸的启动液体的工艺空间首次形成晶体床，其中丙烯酸晶体形成温度小于或等于悬浮液S的温度升高15℃，然后用悬浮液S和任选地与对照液体继续填充洗涤柱，直到晶体熔体中的压力差空间和分配器空间中的压力突然下降，流过滤器过滤器的总废液流的算术平均值根据所有过滤器的面积，直到此时为止，洗涤塔的管子不超过80立方米/（m2·h）。

15. 发明授权

US08106240B2 Process for operating a continuous removal of a target product X in the form of fine crystals of the target product X 有权
标题翻译：用于以目标产物X的细晶体的形式连续移除靶产物X的方法
公开(公告)号：US08106240B2
公开(公告)日：2012-01-31
申请号：US12208559
申请日：2008-09-11
申请人： Joerg Heilek , Ulrich Hammon , Klaus Joachim Mueller-Engel
发明人： Joerg Heilek , Ulrich Hammon , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/42
CPC分类号： B01D9/0009 , B01D9/0013 , B01D9/005 , B01D9/0063 , C07C51/43 , C07C57/04
摘要： A process for operating a continuous removal of a target product X in the form of fine crystals of a liquid phase P comprising the target product X and constituents other than the target product X by cooling suspension crystallization in the secondary chamber of an indirect heat exchanger to which liquid phase P flows continuously with simultaneous continuous flow through the primary chamber of the indirect heat exchanger with a coolant, and continuous withdrawal of a crystal suspension S having a degree of crystallization Y from the secondary chamber in two operating states I and II, wherein the coolant temperature is lower, the mass flow of liquid phase P is greater and the molar proportion of the constituents other than the target product X in the liquid phase P in operating state II is greater than in operating state I.
摘要翻译：通过在间接热交换器的二次室中冷却悬浮液结晶来操作以含有目标产物X和除了目标产物X的成分的液相P的细晶体的形式连续除去目标产物X的方法，该液相P以连续的流动方式连续流过间接热交换器的主室，并具有冷却剂，并且在两个操作状态I和II中连续取出具有结晶Y的程度的结晶悬浮液，冷却剂温度较低，液相P的质量流量较大，并且在运行状态II下的液相P中除目标产物X以外的成分的摩尔比例大于运行状态I.

16. 发明授权

US08232425B2 Process for heterogeneously catalyzed partial gas phase oxidation of propylene to acrylic acid 有权
标题翻译：将丙烯非均相催化的部分气相氧化成丙烯酸的方法
公开(公告)号：US08232425B2
公开(公告)日：2012-07-31
申请号：US11564530
申请日：2006-11-29
申请人： Martin Dieterle , Joerg Heilek , Klaus Joachim Mueller-Engel
发明人： Martin Dieterle , Joerg Heilek , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/42
CPC分类号： C07C51/252 , B01J23/002 , B01J2523/00 , C07C45/35 , C07C51/43 , C07C47/22 , C07C57/04 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/17 , B01J2523/55 , B01J2523/69 , B01J2523/13 , B01J2523/41 , B01J2523/845
摘要： A process for heterogeneously catalyzed partial gas phase oxidation of propylene to acrylic acid, in which the starting reaction gas mixture comprises cyclopropane as an impurity and the acrylic acid, after conversion from the product gas mixture into the condensed phase, is removed with the aid of a crystallative removal.
摘要翻译：丙烯到丙烯酸的非均相催化的部分气相氧化丙烯酸的方法，其中起始反应气体混合物包含环丙烷作为杂质，丙烯酸在从产物气体混合物转化为冷凝相之后，借助于结晶除去。

17. 发明授权

US07637965B2 Process for controlling a hydraulic wash column 有权
标题翻译：用于控制液压清洗柱的方法
公开(公告)号：US07637965B2
公开(公告)日：2009-12-29
申请号：US11400406
申请日：2006-04-10
申请人： Joerg Heilek , Klaus Joachim Mueller-Engel , Ulrich Hammon , Thomas Walter
发明人： Joerg Heilek , Klaus Joachim Mueller-Engel , Ulrich Hammon , Thomas Walter
IPC分类号： C30B17/00
CPC分类号： C07C51/43 , B01D9/0013 , B01D9/0036 , B01D9/004 , B01D9/0045 , B01D9/005 , B01D9/0063 , C07C51/47 , C07C51/48 , C07C57/04
摘要： A process for operating a hydraulic wash column, in which the position of the buildup front in the wash column is positioned by means of the flow rates of control liquor conducted into the wash column and/or by means of the flow rate of the suspension conducted into the wash column, and the flow rate determination is with the aid of the pressure difference which exists in the column between points in the suspension zone disposed upstream of the buildup front and points in the zone projecting from the buildup front up to the end of the crystal bed.
摘要翻译：一种用于操作液压清洗柱的方法，其中通过进入洗涤塔的对照液的流速和/或借助于悬浮液的流速来定位洗涤塔中积聚前沿的位置进入洗涤塔，并且流量确定借助于设置在积聚前沿的上游的悬浮区域中的点之间的柱中存在的压力差和从积聚前端直到末端的区域中的点水晶床。

18. 发明授权

US07601866B2 Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component 有权
标题翻译：从含有丙烯酸为主要成分和目标产物的液相中除去甲基丙烯醛的方法，以及甲基丙烯醛作为次要成分
公开(公告)号：US07601866B2
公开(公告)日：2009-10-13
申请号：US11357975
申请日：2006-02-22
申请人： Joerg Heilek , Klaus Joachim Mueller-Engel , Christoph Adami , Martin Dieterle
发明人： Joerg Heilek , Klaus Joachim Mueller-Engel , Christoph Adami , Martin Dieterle
IPC分类号： C07C51/42
CPC分类号： C07C51/43 , C07C57/04
摘要： A process for removing methacrolein from liquid phase P comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component in which the removal is effected by crystallization, the acrylic acid accumulating in the crystals formed and the methacrolein in the remaining mother liquor.
摘要翻译：从包含丙烯酸作为主要成分和目标产物的液相P中除去甲基丙烯醛的方法，以及甲基丙烯醛作为其中通过结晶进行除去的次要组分，积聚在形成的晶体中的丙烯酸和剩余母体中的异丁烯醛酒。

19. 发明授权

US07393436B2 Thermal separating process for removing at least one stream containing enriched (meth) acrylic monomers 有权
标题翻译：用于除去至少一种含有富含（甲基）丙烯酸单体的物流的热分离方法
公开(公告)号：US07393436B2
公开(公告)日：2008-07-01
申请号：US10888933
申请日：2004-07-12
申请人： Bernd Eck , Ulrich Hammon , Klaus Joachim Mueller-Engel , Juergen Schroeder , Joachim Thiel , Hans Martan
发明人： Bernd Eck , Ulrich Hammon , Klaus Joachim Mueller-Engel , Juergen Schroeder , Joachim Thiel , Hans Martan
IPC分类号： B01D3/14 , B01D3/42 , C07C51/43
CPC分类号： C07C51/43 , B01D3/14 , B01D3/225 , B01D3/322 , C07C51/215 , C07C51/252 , C07C51/44 , Y10S203/22 , C07C57/04
摘要： A thermal separating process for removing a stream containing enriched (meth)acrylic monomers from a mixture containing (meth)acrylic monomers, in which the liquid phases retained in the separating space at high temperature and high (meth)acrylic monomer content are minimized.
摘要翻译：一种用于从含有（甲基）丙烯酸单体的混合物中除去含有富含（甲基）丙烯酸单体的物流的热分离方法，其中在高温和高（甲基）丙烯酸单体含量保留在分离空间中的液相被最小化。

20. 发明授权

US09149799B2 Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body 有权
标题翻译：蛋壳催化剂由中空圆柱形支撑体和催化活性氧化物材料组成，其应用于支撑体的外表面
公开(公告)号：US09149799B2
公开(公告)日：2015-10-06
申请号：US13093333
申请日：2011-04-25
申请人： Andrey Karpov , Catharina Horstmann , Cornelia Katharina Dobner , Josef Macht , Frank Rosowski , Klaus Joachim Mueller-Engel
发明人： Andrey Karpov , Catharina Horstmann , Cornelia Katharina Dobner , Josef Macht , Frank Rosowski , Klaus Joachim Mueller-Engel
IPC分类号： B01J37/02 , C07C51/235 , B01J23/00 , B01J23/888 , B01J35/00 , B01J35/02 , B01J37/00 , B01J37/08
CPC分类号： B01J37/0219 , B01J23/002 , B01J23/8885 , B01J35/008 , B01J35/023 , B01J35/026 , B01J37/0045 , B01J37/0221 , B01J37/08 , B01J2523/00 , C07C51/235 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On (I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.
摘要翻译：一种蛋壳催化剂，其由长度为2-10mm，外径为4-10mm，壁厚为1-4mm的中空圆柱形支撑体和应用于支撑体外表面的蛋壳组成，催化活性氧化物材料通式I，Mo12V2至4W0至3Cu0.8至1.5X10至4X20至400N（I），其中变量各自定义如下：X1 =碱金属和碱土金属的一种或多种元素; X2 = Si，Al，Ti和Zr组中的一种或多种元素; 并且n =元素氧的化学计量系数，其由除氧以外的元素的化学计量系数及其在I中的电荷确定。

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