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11. 发明申请

US20120065427A1 Process For Producing Catalyst For Methacrylic Acid Production And Process For Producing Methacrylic Acid 有权
标题翻译：用于生产甲基丙烯酸生产催化剂的方法和生产甲基丙烯酸的方法
公开(公告)号：US20120065427A1
公开(公告)日：2012-03-15
申请号：US13298645
申请日：2011-11-17
申请人： Atsushi Sudo , Kazuo Shiraishi , Hideki Sugi , Hiroyoshi Nowatari , Fumio Sakai , Tomoaki Kobayashi , Tatsuhiko Kurakami
发明人： Atsushi Sudo , Kazuo Shiraishi , Hideki Sugi , Hiroyoshi Nowatari , Fumio Sakai , Tomoaki Kobayashi , Tatsuhiko Kurakami
IPC分类号： C07C51/16 , B01J27/199
CPC分类号： B01J37/0219 , B01J23/002 , B01J27/199 , B01J37/0045 , B01J37/0221 , B01J2523/00 , C07C51/252 , B01J2523/17 , B01J2523/51 , B01J2523/52 , B01J2523/55 , B01J2523/68 , C07C57/04
摘要： An object of the present invention is to provide a process for stably producing a catalyst for methacrylic acid production exhibiting high activity and high performance. The process for producing a catalyst for methacrylic acid production of the invention is characterized in that the water content of the catalyst ingredient powder for use in molding, temperature and humidity of a molding step, humidity and temperature of a baking step are individually controlled in the case where molding is performed by a coating method using an Mo—V—P—Cu-based hetero polyacid as an active ingredient and water or an alcohol and/or an aqueous solution of an alcohol as a binder.
摘要翻译：本发明的目的是提供稳定地生产表现出高活性和高性能的甲基丙烯酸生产催化剂的方法。本发明的甲基丙烯酸制造用催化剂的制造方法的特征在于，在成型步骤中使用的成型用的催化剂成分粉末，成型步骤的温度和湿度，烘烤步骤的湿度和温度的含水量分别控制在通过使用Mo-V-P-Cu系杂多酸作为活性成分的涂布法和水或醇和/或醇的水溶液作为粘合剂进行成型的情况。

12. 发明申请

US20130310604A1 Process For Producing Unsaturated Aldehyde And/or Unsaturated Carboxylic Acid 有权
标题翻译：生产不饱和醛和/或不饱和羧酸的方法
公开(公告)号：US20130310604A1
公开(公告)日：2013-11-21
申请号：US13982808
申请日：2012-01-16
申请人： Tatsuhiko Kurakami , Susumu Matsumoto , Atsushi Sudo , Kazuo Shiraishi , Masashi Hashiba
发明人： Tatsuhiko Kurakami , Susumu Matsumoto , Atsushi Sudo , Kazuo Shiraishi , Masashi Hashiba
IPC分类号： C07C51/25 , C07C45/38 , C07C51/235 , C07C45/35
CPC分类号： C07C51/235 , C07C45/35 , C07C45/38 , C07C51/252 , C07C47/22 , C07C57/04
摘要： There is provided a process for producing aerolein, acrylic acid, methacrolein, methacrylic acid in a safe and steady manner and in high yields, which avoids a phenomenon of occurrence of an abnormal reaction attributable to the fact that the temperature at a raw material gas outlet side becomes considerably higher than the temperature at a raw material gas inlet side, with regard to the temperature of a catalyst packed in a reaction tube at vapor-phase catalytic oxidation of propylene, isobutylene, or the like.In the process of using a reaction tube on which a plurality of catalyst layers formed in a raw material gas flow direction, a catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5≦Cmax−Ccrs≦5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed.
摘要翻译：提供了以安全稳定的方式和高产率生产气溶胶，丙烯酸，甲基丙烯醛，甲基丙烯酸的方法，避免了由于原料气体出口处的温度导致的异常反应的发生现象相对于在丙烯，异丁烯等的气相催化氧化反应管中填充的催化剂的温度，原料气体入口侧的温度显着高于原料气体入口侧的温度。在使用在原料气体流动方向上形成有多个催化剂层的反应管的过程中，设计催化剂和催化剂填充进度，使得目的物的产率的原料转化率之间的关系产物变得最大，并且最接近反应气体入口侧的催化剂层的最高温度和最接近反应气体出口侧的催化剂层的最高温度之间的高低相关性的原料转化率反转满足0.5 @ Cmax-Ccrs @ 5的特定条件，其中Cmax：目标产物的产率变为最大的原料转化率; Ccrs：将催化剂层Zin的最高温度设为Tin时的原料转化率，将催化剂层Zout的最高温度设为Tout，将原料转化率变更为高，低相关 Tin和Tout之间是相反的。

13. 发明授权

US08969618B2 Process for producing unsaturated aldehyde and/or unsaturated carboxylic acid 有权
标题翻译：不饱和醛和/或不饱和羧酸的制备方法
公开(公告)号：US08969618B2
公开(公告)日：2015-03-03
申请号：US13982808
申请日：2012-01-16
申请人： Tatsuhiko Kurakami , Susumu Matsumoto , Atsushi Sudo , Kazuo Shiraishi , Masashi Hashiba
发明人： Tatsuhiko Kurakami , Susumu Matsumoto , Atsushi Sudo , Kazuo Shiraishi , Masashi Hashiba
IPC分类号： C07C51/25 , C07C45/35 , C07C51/235 , C07C45/38
CPC分类号： C07C51/235 , C07C45/35 , C07C45/38 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5≦Cmax−Ccrs≦5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed.
摘要翻译：设计催化剂和催化剂填充进度，使得目标产物的产率变得最大的原料转化率与存在催化剂层的最高温度之间的高低相关性的原料转化率之间的关系最接近反应气体入口侧的Zin和最接近反应气体出口侧的催化剂层的最高温度Zout反过来满足特定条件为0.5＆amp; NlE; Cmax-Ccrs＆nlE; 5，其中Cmax：原料转化率目标产品的产量变得最大; Ccrs：将催化剂层Zin的最高温度设为Tin时的原料转化率，将催化剂层Zout的最高温度设为Tout，将原料转化率变更为高，低相关 Tin和Tout之间是相反的。

14. 发明授权

US08877964B2 Catalyst and method for producing acrylic acid 有权
标题翻译：催化剂及制备丙烯酸的方法
公开(公告)号：US08877964B2
公开(公告)日：2014-11-04
申请号：US13882265
申请日：2011-10-27
申请人： Yuta Nakazawa , Susumu Matsumoto , Tomoaki Kobayashi , Tatsuhiko Kurakami
发明人： Yuta Nakazawa , Susumu Matsumoto , Tomoaki Kobayashi , Tatsuhiko Kurakami
IPC分类号： C07C51/235 , B01J37/02 , C07C51/16 , B01J27/199 , B01J37/00 , B01J23/887 , B01J23/00 , B01J35/00 , B01J35/04
CPC分类号： C07C51/16 , B01J23/002 , B01J23/8877 , B01J27/199 , B01J35/0006 , B01J35/04 , B01J37/0036 , B01J37/0045 , B01J37/0244 , B01J2523/00 , C07C51/235 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68
摘要： The present invention relates to a method for producing acrylic acid through vapor-phase contact oxidation of acrolein, wherein a reactor tube is divided into at least two catalyst layers, and catalysts having a higher activity are charged in the reactor tube sequentially toward an outlet port side from a material source gas inlet port side for a reaction therein to give acrylic acid, and wherein a catalyst activity-controlling method is a method comprising: a step of mixing a molybdenum-containing compound, a vanadium-containing compound, a copper-containing compound and an antimony-containing compound with water, then drying and calcining a resulting mixture, in which a catalytically-active element composition is kept constant but material source compounds are made to vary in type to give composite metal oxides having a different activity.
摘要翻译：本发明涉及一种通过丙烯醛的气相接触氧化制备丙烯酸的方法，其中将反应器管分成至少两个催化剂层，并且具有较高活性的催化剂依次连接到反应器管的出口一边从材料源气体入口侧进行反应，得到丙烯酸，其中催化剂活性控制方法是一种方法，包括：将含钼化合物，含钒化合物，铜 - 然后干燥和煅烧所得混合物，其中催化活性元素组合物保持恒定，但是使材料源化合物的类型变化，得到具有不同活性的复合金属氧化物。

15. 发明申请

US20130217915A1 Catalyst and Method for Producing Acrylic Acid 有权
标题翻译：催化剂和生产丙烯酸的方法
公开(公告)号：US20130217915A1
公开(公告)日：2013-08-22
申请号：US13882265
申请日：2011-10-27
申请人： Yuta Nakazawa , Susumu Matsumoto , Tomoaki Kobayashi , Tatsuhiko Kurakami
发明人： Yuta Nakazawa , Susumu Matsumoto , Tomoaki Kobayashi , Tatsuhiko Kurakami
IPC分类号： C07C51/16
CPC分类号： C07C51/16 , B01J23/002 , B01J23/8877 , B01J27/199 , B01J35/0006 , B01J35/04 , B01J37/0036 , B01J37/0045 , B01J37/0244 , B01J2523/00 , C07C51/235 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68
摘要： The present invention relates to a method for producing acrylic acid through vapor-phase contact oxidation of acrolein, wherein a reactor tube is divided into at least two catalyst layers, and catalysts having a higher activity are charged in the reactor tube sequentially toward an outlet port side from a material source gas inlet port side for a reaction therein to give acrylic acid, and wherein a catalyst activity-controlling method is a method comprising: a step of mixing a molybdenum-containing compound, a vanadium-containing compound, a copper-containing compound and an antimony-containing compound with water, then drying and calcining a resulting mixture, in which a catalytically-active element composition is kept constant but material source compounds are made to vary in type to give composite metal oxides having a different activity.
摘要翻译：本发明涉及一种通过丙烯醛的气相接触氧化制备丙烯酸的方法，其中将反应器管分成至少两个催化剂层，并且具有较高活性的催化剂依次连接到反应器管的出口一边从材料源气体入口侧进行反应，得到丙烯酸，其中催化剂活性控制方法是一种方法，包括：将含钼化合物，含钒化合物，铜 - 然后干燥和煅烧所得混合物，其中催化活性元素组合物保持恒定，但是使材料源化合物的类型变化，得到具有不同活性的复合金属氧化物。

16. 发明申请

US20110137078A1 Catalyst And Method For Producing Unsaturated Aldehyde And Unsaturated Carboxylic Acid 审中-公开
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂和方法
公开(公告)号：US20110137078A1
公开(公告)日：2011-06-09
申请号：US12994206
申请日：2009-05-25
申请人： Masaki Nakahara , Hideki Sugi , Yoshimasa Seo , Tatsuhiko Kurakami , Hiroyuki Onoue
发明人： Masaki Nakahara , Hideki Sugi , Yoshimasa Seo , Tatsuhiko Kurakami , Hiroyuki Onoue
IPC分类号： C07C51/16 , B01J35/02 , B01J37/02
CPC分类号： C07C51/235 , B01J23/002 , B01J35/026 , B01J37/0215 , B01J37/0217 , B01J2523/00 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/17 , B01J2523/36 , B01J2523/44 , B01J2523/52 , B01J2523/55
摘要： Provided is a catalyst which can prevent a lowering in selectivity for a target product in a gas phase catalytic reaction and has an excellent frictional resistance. A catalyst which is a supported catalyst comprising an inert support that is coated with a catalyst powder, characterized in that the inert support is ring-shaped and has an outer periphery that is curved in the lengthwise direction of the support, and the catalyst is produced by granulation in a moisten environment. The above described catalyst is useful in the gas phase oxidation of propylene, isobutylene, tertiary-butyl alcohol or methyl tertiary-butyl ether to thereby produce an unsaturated aldehyde corresponding thereto, or in the gas phase oxidation of such an unsaturated aldehyde as described above to thereby produce an unsaturated carboxylic acid.
摘要翻译：本发明提供能够防止气相催化反应中的对象物的选择性降低且具有优异的摩擦阻力的催化剂。一种催化剂，其是包含涂覆有催化剂粉末的惰性载体的载体催化剂，其特征在于惰性载体是环状的，并且具有在载体的长度方向上弯曲的外周，并且产生催化剂通过在湿润的环境中制粒。上述催化剂可用于丙烯，异丁烯，叔丁醇或甲基叔丁基醚的气相氧化，从而产生与其对应的不饱和醛，或在如上所述的这种不饱和醛的气相氧化中从而产生不饱和羧酸。

17. 发明申请

US20070010394A1 Process for producing catalyst for methacrylic acid production 审中-公开
标题翻译：生产甲基丙烯酸催化剂的方法
公开(公告)号：US20070010394A1
公开(公告)日：2007-01-11
申请号：US10558501
申请日：2004-05-27
申请人： Sudo Atsushi , Yoshimasa Seo , Tatsuhiko Kurakami
发明人： Sudo Atsushi , Yoshimasa Seo , Tatsuhiko Kurakami
IPC分类号： B01J27/24
CPC分类号： C07C51/235 , B01J23/002 , B01J27/199 , B01J37/0219 , B01J37/0236 , B01J2523/00 , C07C51/252 , C07C51/377 , C07C57/04 , B01J2523/15 , B01J2523/50 , B01J2523/51 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/17
摘要： The object of the present invention is to provide a method for preparing a catalyst for producing methacrylic acid by subjecting methacrolein, isobutyl aldehyde or isobutyric acid to gas phase catalytic oxidation with high yield and high selectivity. A method for preparing a catalyst for producing methacrylic acid by subjecting methacrolein, isobutyl aldehyde or isobutyric acid to gas phase catalytic oxidation, the method comprising: (a) a step of blending compounds each containing any one of Mo, V, P, Cu, Cs or NH4 with water to prepare an aqueous solution or dispersion of the compounds (hereinafter referred to, both included, as a slurry); (b) a step of drying the slurry obtained in the step (a) to obtain a dried slurry; (c) a step of calcining the dried slurry obtained in..the step (b) to obtain a calcined body; (d) a step of filtering a mixture obtained by blending the calcined body obtained in the step (c) with water to separate an aqueous solution and water-insoluble matter; and (e) a step of drying the water-insoluble matter obtained in the step (d) to obtain a dried water-insoluble body.
摘要翻译：本发明的目的是提供一种通过以高产率和高选择性将甲基丙烯醛，异丁醛或异丁酸进行气相催化氧化来制备用于生产甲基丙烯酸的催化剂的方法。一种通过使甲基丙烯醛，异丁醛或异丁酸进行气相催化氧化来制备甲基丙烯酸的催化剂的方法，所述方法包括：（a）将各自含有Mo，V，P，Cu， Cs或NH 4与水反应以制备化合物的水溶液或分散体（以下称为两者，均为浆料）; （b）干燥步骤（a）中获得的浆料以获得干燥的浆料的步骤; （c）煅烧步骤（b）中获得的干燥浆料以获得煅烧体的步骤; （d）将通过将步骤（c）中获得的煅烧体与水混合而获得的混合物与水分离以分离水溶液和水不溶性物质的步骤; 和（e）干燥步骤（d）中获得的水不溶性物质以获得干燥的水不溶性体的步骤。

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