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11. 发明授权

US08889786B2 Cyclopentene ring-opening polymer and method of production of same 有权
标题翻译：环戊烯开环聚合物及其制备方法
公开(公告)号：US08889786B2
公开(公告)日：2014-11-18
申请号：US13877124
申请日：2011-09-30
申请人： Yasuo Tsunogae , Shigetaka Hayano , Takeshi Sugimura
发明人： Yasuo Tsunogae , Shigetaka Hayano , Takeshi Sugimura
IPC分类号： C08L83/00 , B22F1/00 , C08L75/04 , B60C1/00 , C08G61/08 , C08G18/38
CPC分类号： C08G18/3893 , B60C1/00 , C08G61/08 , C08G2261/135 , C08G2261/3321 , C08G2261/418 , C08G2261/76 , C08K3/04 , C08K3/36 , C08K5/5419 , C08L9/00 , C08L9/06 , C08L65/00 , C08L75/04
摘要： A cyclopentene ring-opening polymer which has hydroxy groups at the polymer chain terminal ends is produced, then the hydroxy groups of the cyclopentene ring-opening polymer and isocyanate groups of a compound containing alkoxysilyl groups and isocyanate groups in its molecule are made to react to thereby produce a cyclopentene ring-opening polymer which contains structures at the polymer chain terminal ends where the polymer chains and groups including alkoxysilyl groups are bonded through urethane bond groups and which has a weight average molecular weight of 100,000 to 1,000,000.
摘要翻译：产生在聚合物链末端具有羟基的环戊烯开环聚合物，然后使环戊烯开环聚合物的羟基和其分子中含有烷氧基甲硅烷基和异氰酸酯基团的化合物的异氰酸酯基团与从而产生环戊烯开环聚合物，该聚合物在聚合物链末端含有结构，其中聚合物链和包括烷氧基甲硅烷基的基团通过氨基甲酸酯键基团键合并且其重均分子量为100,000至1,000,000。

12. 发明授权

US07868107B2 Process for producing cycloolefin addition polymer, catalyst for addition polymerization of cycloolefin, and transition metal compound 有权
标题翻译：环烯加成聚合物的制造方法，环烯烃的加成聚合用催化剂和过渡金属化合物
公开(公告)号：US07868107B2
公开(公告)日：2011-01-11
申请号：US12073704
申请日：2008-03-07
申请人： Kei Nishii , Sigetaka Hayano , Yasuo Tsunogae
发明人： Kei Nishii , Sigetaka Hayano , Yasuo Tsunogae
IPC分类号： C08F4/64 , C08F4/642 , C08F4/643 , C08F4/6592
CPC分类号： C07F7/28 , C08F4/65912 , C08F4/6592 , C08F210/02 , Y10S526/943 , C08F232/00
摘要： A process for producing a cycloolefin addition polymer comprising addition-polymerizing a cycloolefin in the presence of a catalyst comprising a combination of a specific transition metal compound of Group 4 of the Periodic Table, with an organoaluminum oxy compound, and/or a compound capable of reacting with the Group 4 transition metal compound to form an ion pair. The specific group 4 transition metal compound preferably has a structure such that the group 4 transition metal is bonded to a cyclopentadienyl ring in an η1 mode. The above-mentioned catalyst exhibits high activity for both of addition homopolymerization of a cycloolefin and addition copolymerization of a cycloolefin with an α-olefin.
摘要翻译：一种制备环烯加成聚合物的方法，包括在包含周期表第4族的特定过渡金属化合物与有机铝氧化合物的组合的催化剂存在下，将环烯加成聚合，和/或能够与第4族过渡金属化合物反应形成离子对。特别的第4族过渡金属化合物优选具有使第4族过渡金属以“1”模式结合到环戊二烯基环上的结构。上述催化剂对环烯烃的均相聚合和环烯烃与α-烯烃的加成共聚均显示出高活性。

13. 发明申请

US20090143523A1 Cycloolefin additon polymer, composite material and molded article thereof, and optical material 审中-公开
标题翻译：环烯烃添加剂聚合物，复合材料及其模制品，以及光学材料
公开(公告)号：US20090143523A1
公开(公告)日：2009-06-04
申请号：US11990700
申请日：2006-08-11
申请人： Atsushi Ishiguro , Shintaro Ikeda , Yasuo Tsunogae
发明人： Atsushi Ishiguro , Shintaro Ikeda , Yasuo Tsunogae
IPC分类号： C08K3/36 , C08F112/08 , C08L25/06 , C08K3/22
CPC分类号： C08F232/08 , C08F32/08
摘要： [Problems] To provide a cycloolefin addition polymer that is capable of satisfying high heat resistance and high refractive index simultaneously, a composite material of the cycloolefin addition polymer with an inorganic material, and a molded article thereof.[Means for Solution] A cycloolefin addition polymer consisting essentially of a cycloolefin monomer unit and containing as an essential component a norbornene monomer unit having an aromatic ring. The cycloolefin addition polymer is preferably a cycloolefin addition polymer that consists essentially of a norbornene monomer unit having an aromatic ring. The cycloolefin addition polymers are excellent in heat resistance and have a high refractive index. The composite material is comprised of the cycloolefin addition polymer and an inorganic material. The molded article is obtained by molding the cycloolefin addition polymer or the composite material.
摘要翻译： [问题]为了提供能够同时满足高耐热性和高折射率的环烯加成聚合物，可以使环烯烃加成聚合物与无机材料的复合材料及其成型体。 [解决方案]一种环烯烃加成聚合物，主要由环烯烃单体单元组成，并含有具有芳香环的降冰片烯单体单元作为必需组分。环烯加成聚合物优选是基本上由具有芳环的降冰片烯单体单元组成的环烯加成聚合物。环烯加成聚合物的耐热性优异，折射率高。复合材料由环烯加成聚合物和无机材料组成。模塑制品通过模制环烯加成聚合物或复合材料而获得。

14. 发明申请

US20090018296A1 Norbornene Addition Copolymer and Moldings 审中-公开
标题翻译：降冰片烯加成共聚物和木线条
公开(公告)号：US20090018296A1
公开(公告)日：2009-01-15
申请号：US11886672
申请日：2006-03-24
申请人： Shintaro Ikeda , Kei Nishii , Yasuo Tsunogae
发明人： Shintaro Ikeda , Kei Nishii , Yasuo Tsunogae
IPC分类号： C08F132/08
CPC分类号： C08F210/02 , C08F212/08 , C08F232/08 , C08F212/00 , C08F232/00 , C08F2500/25 , C08F2500/03
摘要： A norbornene addition copolymer obtained by subjecting a norbornene monomer (A), an aromatic vinyl compound (B), and an α-olefin having 2 to 20 cabon atoms (C) to addition copolymerization, the sum of the content of repeating units derived from the norbornene monomer (A) and the content of repeating units derived from the aromatic vinyl compound (B) being 25 to 90 mol % based on the total repeating units, and the content of repeating units derived from the aromatic vinyl compound (B) being 0.55 to 10 (mol) times the content of repeating units derived from the norbornene monomer (A); and a molded article obtained by molding the norbornene addition copolymer. According to the present invention, a norbornene addition copolymer exhibiting excellent transparency, a high refractive index, and a small intrinsic birefringence value, and a molded article obtained by molding the norbornene addition copolymer are provided.
摘要翻译：通过将降冰片烯单体（A），芳族乙烯基化合物（B）和具有2-20个碳原子（C）的α-烯烃进行加成共聚而得到的降冰片烯加成共聚物，来自降冰片烯单体（A）的含量和衍生自芳香族乙烯基化合物（B）的重复单元的含量相对于全部重复单元为25〜90摩尔％，芳香族乙烯基化合物（B）的重复单元的含量为从降冰片烯单体（A）衍生的重复单元的含量为0.55〜10（摩尔）倍; 以及通过将降冰片烯类加成共聚物成型得到的成型品。根据本发明，提供了显示出优异的透明性，高折射率和小的固有双折射值的降冰片烯加成共聚物和通过模塑降冰片烯加成共聚物而获得的模制品。

15. 发明授权

US06730736B1 Alicyclyc structure-containing resin composition 有权
标题翻译：含有脂环结构的树脂组合物
公开(公告)号：US06730736B1
公开(公告)日：2004-05-04
申请号：US09647573
申请日：2000-10-02
申请人： Shojiro Kaita , Takashi Iga , Yasuhiro Wakizaka , Yasuo Tsunogae
发明人： Shojiro Kaita , Takashi Iga , Yasuhiro Wakizaka , Yasuo Tsunogae
IPC分类号： C08F25500
CPC分类号： C08F8/00 , C08L45/00 , C08F32/00 , C08L2666/02
摘要： An alicyclic structure-containing resin composition comprising an alicyclic structure-containing resin (A) having a polar group in a proportion of 3 to 50 mol % based on the whole repeating unit in the resin, and a soft polymer (B), a varnish containing the resin composition, a sheet formed of the resin composition, and an insulating film formed of the resin composition.
摘要翻译：含有脂环式结构的树脂组合物，其含有相对于树脂中的全部重复单元为3〜50摩尔％的极性基团的脂环式结构的树脂（A）和软质聚合物（B），清漆含有树脂组合物，由树脂组合物形成的片材和由树脂组合物形成的绝缘膜。

16. 发明授权

US5248746A Method of producing polymers 失效
标题翻译：生产聚合物的方法
公开(公告)号：US5248746A
公开(公告)日：1993-09-28
申请号：US679193
申请日：1991-04-02
申请人： Yoshiharu Shimokawa , Yasuo Tsunogae , Shin-ichiro Tahara , Masami Kitaoka , Yoshitsugu Hirokawa
发明人： Yoshiharu Shimokawa , Yasuo Tsunogae , Shin-ichiro Tahara , Masami Kitaoka , Yoshitsugu Hirokawa
IPC分类号： C08F2/00 , C08F2/38 , C08F4/00 , C08F4/06 , C08F4/16 , C08F4/60 , C08F4/62 , C08F8/00 , C08F10/00 , C08F10/10 , C08F12/00 , C08F12/08 , C08F295/00 , C08F297/00
CPC分类号： C08F297/00 , C08F10/10 , C08F4/00
摘要： A method of producing a polymer of a cationically polymerizable vinyl monomer by polymerizing at least one cationically polymerizable vinyl monomer using a polymerization initiator system composed of an organic compound having a functional group represented by formula (I) below ##STR1## where R.sup.1 represents a hydrogen atom, an alkyl group, or an aryl group; R.sup.2 represents an alkyl group, or an aryl group; X represents a halogen atom, an alkoxy group, or an acyloxy group, and a Lewis acid, wherein polymerization is carried out in the presence of a phosphorus-containing compound selected from the group consisting of a phosphine, a phosphine oxide, a phosphite, and a phosphate.

17. 发明申请

US20140012012A1 POLYETHER COMPOUND AND ELECTROLYTE COMPOSITION 有权
标题翻译：聚合物和电解质组合物
公开(公告)号：US20140012012A1
公开(公告)日：2014-01-09
申请号：US14008283
申请日：2012-03-30
申请人： Shigetaka Hayano , Yasuo Tsunogae
发明人： Shigetaka Hayano , Yasuo Tsunogae
IPC分类号： C07D233/64
CPC分类号： C07D233/64 , C08G65/105 , C08G65/24 , C08G65/2654 , C08G65/33317 , C08L71/03 , H01B1/122
摘要： A polyether compound containing oxirane monomer units in an average number per molecule of 10 to 100, wherein the polyether compound contains repeating units which are represented by the general formula (2) as at least part of the oxirane monomer units is provided. According to the present invention, it is possible to provide a polymer material which has suitable fluidity and is excellent in ion conductivity. (R1 to R4 respectively independently indicate a hydrogen atom or C1 to C3 alkyl group, and R2 and R3 may be bonded with each other. Further, X− is an anion which is comprised of 2 to 25 atoms.)
摘要翻译：含有平均数分子数为10〜100的环氧乙烷单体单元的聚醚化合物，其中聚醚化合物含有作为至少一部分环氧乙烷单体单元的由通式（2）表示的重复单元。根据本发明，可以提供具有合适的流动性并且离子传导性优异的聚合物材料。（R 1〜R 4分别独立地表示氢原子或C1〜C3烷基，R2和R3可以相互键合，此外，X是由2〜25个原子构成的阴离子）

18. 发明申请

US20130281615A1 CYCLOPENTENE RING-OPENING POLYMER AND METHOD OF PRODUCTION OF SAME 有权
标题翻译：环烯烃环开环聚合物及其生产方法
公开(公告)号：US20130281615A1
公开(公告)日：2013-10-24
申请号：US13877124
申请日：2011-09-30
申请人： Yasuo Tsunogae , Shigetaka Hayano , Takeshi Sugimura
发明人： Yasuo Tsunogae , Shigetaka Hayano , Takeshi Sugimura
IPC分类号： C08G18/38 , C08L75/04
CPC分类号： C08G18/3893 , B60C1/00 , C08G61/08 , C08G2261/135 , C08G2261/3321 , C08G2261/418 , C08G2261/76 , C08K3/04 , C08K3/36 , C08K5/5419 , C08L9/00 , C08L9/06 , C08L65/00 , C08L75/04
摘要： A cyclopentene ring-opening polymer which has hydroxy groups at the polymer chain terminal ends is produced, then the hydroxy groups of the cyclopentene ring-opening polymer and isocyanate groups of a compound containing alkoxysilyl groups and isocyanate groups in its molecule are made to react to thereby produce a cyclopentene ring-opening polymer which contains structures at the polymer chain terminal ends where the polymer chains and groups including alkoxysilyl groups are bonded through urethane bond groups and which has a weight average molecular weight of 100,000 to 1,000,000.
摘要翻译：产生在聚合物链末端具有羟基的环戊烯开环聚合物，然后使环戊烯开环聚合物的羟基和其分子中含有烷氧基甲硅烷基和异氰酸酯基团的化合物的异氰酸酯基团与从而产生环戊烯开环聚合物，该聚合物在聚合物链末端含有结构，其中聚合物链和包括烷氧基甲硅烷基的基团通过氨基甲酸酯键基团键合并且其重均分子量为100,000至1,000,000。

19. 发明授权

US08013090B2 Film comprising norbornene compound addition polymer 有权
标题翻译：包含降冰片烯化合物加成聚合物的薄膜
公开(公告)号：US08013090B2
公开(公告)日：2011-09-06
申请号：US12223324
申请日：2007-01-26
申请人： Atsushi Ishiguro , Yoshihisa Takeyama , Yasuo Tsunogae
发明人： Atsushi Ishiguro , Yoshihisa Takeyama , Yasuo Tsunogae
IPC分类号： C08F232/08 , C08F232/04 , C09K19/32
CPC分类号： C08J5/18 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/306 , B32B27/32 , B32B27/325 , B32B27/34 , B32B2255/10 , B32B2255/20 , B32B2307/202 , B32B2307/308 , B32B2307/40 , B32B2307/412 , B32B2307/714 , B32B2307/7242 , B32B2307/7265 , B32B2307/734 , B32B2457/202 , C08F232/08 , C08J2345/00 , Y10T428/10 , Y10T428/31938
摘要： A film comprising a norbornene (NB) compound addition polymer that is excellent in chemical resistance, optical properties and the like, has a high Tg, a low water absorption ratio and a low linear expansion coefficient, and is soluble in an ordinary solvent.The film comprising a NB compound addition polymer essentially consisting of repeating units derived from NB compound monomers, wherein the addition polymer has a specific Mw and has a sum of the units (A1) and (A2) of 70% by mol or more based on the total units, wherein the molar number of each unit satisfies the following equations: 70/30≦[{(A1)+(A2)}/(B)]≦100 and 10/90≦(A1)/(A2)≦98/2, or the addition polymer has a specific Mw and Mn and essentially consists of the units (A1) and (B), wherein the molar number of each unit satisfies the following equation: 70/30≦[(A1)/(B)] ≦98/2.
摘要翻译：包含耐化学性，光学特性等优异的降冰片烯（NB）化合物加成聚合物的膜具有高Tg，低吸水率和低线膨胀系数，并且可溶于普通溶剂。该膜包含基本上由衍生自NB化合物单体的重复单元组成的NB化合物加成聚合物，其中加成聚合物具有特定的Mw，并且单位（A1）和（A2）之和为70摩尔％以上，基于其中每个单位的摩尔数满足以下等式：70/30＆nlE; [{（A1）+（A2）} /（B）]＆nlE; 100和10/90＆nlE;（A1）/（A2）（A1）和（B），其中每个单元的摩尔数满足以下等式：70/30＆nlE; [（A1） /（B）]＆nlE; 98/2。

20. 发明授权

US07238405B2 Insulating material containing cycloolefin polymer 失效
标题翻译：含环烯烃聚合物的绝缘材料
公开(公告)号：US07238405B2
公开(公告)日：2007-07-03
申请号：US10772181
申请日：2004-02-04
申请人： Yasuo Tsunogae , Yasuhiro Wakizaka , Junji Kodemura , Tohru Hosaka
发明人： Yasuo Tsunogae , Yasuhiro Wakizaka , Junji Kodemura , Tohru Hosaka
IPC分类号： B32B27/00 , C08F8/00
CPC分类号： B32B15/085 , B32B27/32 , B32B27/325 , B32B2307/204 , B32B2307/206 , B32B2307/306 , B32B2307/7265 , B32B2457/08 , H01B3/44 , H05K1/032 , Y10T428/24273 , Y10T428/24322 , Y10T428/3175
摘要： An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 μm in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.
摘要翻译：一种包含环烯烃聚合物的绝缘材料，特别是用于高密度组装板的层间绝缘材料，其具有直径最大为200μm的夹层连接通孔，其包含含有至少50mol％重复单元的环烯烃聚合物环烯烃单体; 由通过凝胶渗透色谱法测定的数均分子量在1,000〜1,000,000范围内的聚合物的固化性树脂组合物形成的干膜和硬化剂; 以及通过在金属箔的一面上形成环烯烃聚合物膜而获得的树脂附着金属箔。使用这些材料的层压板，多层层压板和堆积多层层压板及其制造方法。

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