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    • 12. 发明授权
    • Oxazolidines containing silane groups
    • 含有硅烷基的恶唑烷
    • US5047546A
    • 1991-09-10
    • US612737
    • 1990-11-09
    • Giovanni ParrinelloRolf MulhauptHubert Simon
    • Giovanni ParrinelloRolf MulhauptHubert Simon
    • C07F7/18C08G18/10C08G18/83C08K5/544C08L75/00C08L75/04C09J175/00C09J175/04
    • C08G18/10C07F7/1836C08K5/5442Y10T442/2803
    • Compounds of the general formula I ##STR1## wherein R.sub.1 is a hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or benzy.,R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, orR.sub.1 and R.sub.2, together with the linking carbon atom, form a 5- or 6-membered ring, andR.sub.3, R.sub.4, R.sub.5 and R.sub.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted by 1 to 3 members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, halogen or C.sub.1 -C.sub.4 alkoxy or are a group of formula --CH.sub.2 OR.sub.11, where R.sub.11 is C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted by 1 to 3 members selected from the group consisting of C.sub.1 -C.sub.4 alkyl, halogen or C.sub.1 -C.sub.4 alkoxy, or are --C(O)-R.sub.12, and R.sub.12 is C.sub.1 -C.sub.12 alkyl,R.sub.7 is C.sub.1 -C.sub.4 alkylene, R.sub.8 is C.sub.1 -C.sub.8 alkylene, R.sub.9 is C.sub.1 -C.sub.4 alkyl, or two radicals R.sub.9 together are C.sub.1 -C.sub.4 alkylene, and R.sub.10 is C.sub.1 -C.sub.4 alkyl or phenyl,q is a value from 0 to 2,X is --S-- or --NH--,Y is O or S, andZ is an organic radical which is derived from a polyisocyanate or a polyisothiocyanate containing at least three three NCO or NCS groups respectively,n is a value.gtoreq.1 and m is a value.gtoreq.1, with the proviso that n+m.gtoreq.3, are suitable for use as couplers, especially for moisture-curable polyurethane resins.
    • 其中R 1是氢,C 1 -C 12烷基,C 5 -C 7环烷基,苯基或苄基,R 2是氢或C 1 -C 4烷基,或者R 1和R 2与 连接碳原子形成5-或6-元环,并且R 3,R 4,R 5和R 6相同或不同,为氢,C 1 -C 12烷基,苯基或被1至3个选自C 1 C 1-4烷基,卤素或C 1 -C 4烷氧基,或者是式-CH 2 OR 11的基团,其中R 11是C 1 -C 12烷基,苯基或被1至3个选自C 1 -C 4烷基,卤素或C 1 -C 4烷氧基的成员取代的苯基,或 是-C(O)-R 12,R 12是C 1 -C 12烷基,R 7是C 1 -C 4亚烷基,R 8是C 1 -C 8亚烷基,R 9是C 1 -C 4烷基或两个基团R 9一起是C 1 -C 4亚烷基,R 10是C 1 -C 4烷基 或苯基,q为0至2的数值,X为-S-或-NH-,Y为O或S,Z为衍生自多异氰酸酯或多异硫氰酸酯的有机基团,该多异氰酸酯或多异硫氰酸酯含有至少三种三NCO或 NCS格 分别为n =值> / = 1,m为值> / = 1,条件是n + m> / = 3适合用作成色剂,尤其适用于湿固化型聚氨酯树脂。
    • 14. 发明授权
    • Epoxy resin compositions containing polyester flexibilizer and
metallocene complex initiator
    • 含有聚酯增韧剂和茂金属络合物引发剂的环氧树脂组合物
    • US4920182A
    • 1990-04-24
    • US279884
    • 1988-12-05
    • Aloysius H. ManserDieter StrasillaRolf Mulhaupt
    • Aloysius H. ManserDieter StrasillaRolf Mulhaupt
    • C08K5/56C08G59/00C08G59/40C08G59/68C08L63/00C09D163/00C09J163/00C09J175/00
    • C08G59/687C08G59/68C08L63/00
    • Compositions are described containing(A) an epoxy resin having on average at least two 1,2-epoxy groups per molecule or a mixture of these epoxy resins,(B) a compound of the formula I or a mixture of these compounds ##STR1## in which a and b independently of one another are 1 or 2, R.sup.1 is a .pi.-arene, R.sup.2 is a .pi.-arene, an indenyl anion or a cyclopentadienyl anion, X.sup..crclbar. is an [LQ.sub.m ].sup..crclbar. or an anion of a partially fluorinated or perfluorinated aliphatic or aromatic sulfonic acid, L is B, P, As or Sb, Q is fluorine or some of the radicals Q can also be hydroxyl groups and m corresponds to the valence of L increased by one, and(C) a flexible polyester which is terminated by, on average, at least two carboxyl groups and which is derived from an aliphatic or cycloaliphatic polyol or a mixture of such polyols and from an aliphatic, cycloaliphatic or aromatic polycarboxylic acid or a mixture of such polycarboxylic acids.The compositions can be employed as coating agents or as adhesives.
    • 描述的组合物包含(A)每分子平均具有至少两个1,2-环氧基团的环氧树脂或这些环氧树脂的混合物,(B)式I化合物或这些化合物的混合物[R1( a)(+)ab ab x [X]( - )(I)其中a和b彼此独立地为1或2,R 1为仲芳基,R 2为仲芳基,茚基阴离子 或环戊二烯基阴离子,X( - )是[LQm]( - )或部分氟化或全氟化的脂族或芳族磺酸的阴离子,L是B,P,As或Sb,Q是氟或一些基团 Q也可以是羟基,m对应于L的化合价增加1,和(C)柔性聚酯,其平均由至少两个羧基终止并且衍生自脂族或脂环族多元醇或 这种多元醇和脂族,脂环族或芳族多元羧酸或这些多元羧酸的混合物的混合物。 组合物可以用作包衣剂或粘合剂。
    • 15. 发明授权
    • Liquid crystalline (meth)acrylate compounds, composition and method
    • US06339114B1
    • 2002-01-15
    • US09391539
    • 1999-09-08
    • Joachim E. KleeHolger FreyDirk HolterRolf Mulhaupt
    • Joachim E. KleeHolger FreyDirk HolterRolf Mulhaupt
    • A61K6083
    • A61K6/0017A61K6/0023A61K6/0038A61K6/083A61K6/09C07C69/712C07C255/54C08F290/06C08F290/061C08F290/064C08G18/835C08G59/10C08G59/12C08G59/1466C08G59/1494C08G59/4292C08G63/52C08G2270/00C08L67/07C09K19/2028C09K19/3068C09K2019/0448C08L33/00C08L75/16C08L43/02
    • Liquid crystalline (meth)acrylates of the invention include at least three rigid rod-like moieties. One of these moieties is comprised between the (meth)acrylate rests and further two moieties are bonded as side chains. The liquid crystalline (meth)acrylates polymerizable using redox initiators and/or photo initiators. The (meth)acrylates of the invention polymerize quantitative and with very low volume shrinkage of less than 2.5 percent. The invention provides a polymerizable compound within the scope of the general formula: wherein R1 is a group of the general formula —A—, —A—Y1—B—, —A—Y1—B—Y2—C—, or a steroidal moiety, preferably selected of the group of cholesteryl compounds, wherein each A, B and C independently is a substituted or unsubstituted aromatic moiety having 6 to 24 carbon atoms, a substituted or unsubstituted heteroaromatic moiety having 2 to 24 carbon atoms or a substituted or unsubstituted cycloalkylene moiety having 5 to 30 carbon atoms, a substituted or unsubstituted alkylene moiety having 2 to 20 carbon atoms, each Y1 and Y2 independently is a covalent bond, OCO, N═N, CH═N, C═C, CO, O, S, SO2, O(CO)O, OCS, CH2—O, CH2—S, each L1 and L2 independently is a hydrogen, a alkylene having 1 to 20 carbon atoms or CN, R3 is a covalent bond or a substituted or unsubstituted alkylene having 1 to 20 carbon atoms, oxyalkylene having 1 to 20 carbon atoms, thioalkylene having 1 to 20 carbon atoms or a carboxyalkylene having 1 to 20 carbon atoms, R4 is hydrogen, a substituted or an unsubstituted alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, or aryl rest having 6 to 20 carbon atoms, M is a mesogenic group of the general formula —A—Z, —A—Y1—B—Z, —A—Y1—B—Y2—C—Z, or a steroidal moiety, preferably selected of the group of cholesteryl compounds, wherein each A, B and C independently is a substituted or unsubstituted aromatic moiety having 6 to 24 carbon atoms, a substituted or unsubstituted heteroaromatic moiety having 2 to 24 carbon atoms or a substituted or unsubstituted cycloalkylene moiety having 5 to 30 carbon atoms, each Y1 and Y2 independently is a covalent bond, OCO, N═N, CH═N, C═C, CO, O, S, SO2, O(CO)O, OCS, CH2—O, CH2—S, each L1 and L2 independently is a hydrogen, a alkylene having 1 to 20 carbon atoms or CN, Z is a hydrogen, halogen, CN, —OR, COOR, NO2, a halogen substituted or unsubstituted alkylene or alkenyl having 1 to 20 carbon atoms, a halogen substituted or unsubstituted oxyalkylene or oxyalkenyl having 1 to 20 carbon atoms, a halogen substituted or unsubstituted thioalkylene or thioalkenyl having 1 to 20 carbon atoms, a halogen substituted or unsubstituted carboxyalkylene or alkanoylenoxy having 1 to 20 carbon atoms, X is a covalent bond, CO, NHCO, OCO and n is an integer from 1 to 10. These compounds are used in dental compositions and methods of use thereof.
    • 17. 发明授权
    • Oxazoline compounds as stabilizers
    • 恶唑啉化合物作为稳定剂
    • US5962683A
    • 1999-10-05
    • US877449
    • 1997-06-17
    • Alfred SteinmannRolf Mulhaupt
    • Alfred SteinmannRolf Mulhaupt
    • C07D263/14C07D263/16C07D263/28C07D413/10C07D471/10C08K5/353C08K5/36C08L101/00C07D413/14
    • C07D413/10C07D263/14C08K5/353
    • A description is given of compounds of the formula I ##STR1## where r is 0 or 1 and y is a number from the range 1-3; X is a direct bond or --NR.sub.8 --, --CO--, --CONH-- or --COO-- or a divalent aliphatic or mixed aromatic-aliphatic C.sub.1 -C.sub.18 hydrocarbon radical;Z is an aromatic, aliphatic or mixed aromatic-aliphatic C.sub.3 -C.sub.18 hydrocarbon radical which is interrupted in the aliphatic moiety by one or more divalent functional groups, in each case in a carbon-carbon single bond, and/or in the aromatic or aliphatic moiety by one or more divalent functional groups, in each case in a carbon-hydrogen bond, possible functional groups being --O--, --NR.sub.8 --, --S--, --SO--, --SO.sub.2 --, --CONH--, --CO-- or --COO--;R is a mono-, di- or trivalent radical of a sterically hindered amine or of a UV absorber from the class of the 2-hydroxyphenylbenzotriazoles, 2-hydroxyphenylbenzophenones, oxalanilides or 2-hydroxyphenyl-4,6-diaryltriazines or a di- or trivalent radical of a sterically hindered phenol;R.sub.1 and R.sub.2, independently of one another, are H or C.sub.1 -C.sub.12 alkyl;R.sub.3 and R.sub.4, independently of one another, are H, C.sub.1 -C.sub.18 alkyl or --X--(Z).sub.r --R.sub.5 ;R.sub.5 is a monovalent radical of a sterically hindered amine or of a UV absorber from the class of the 2-hydroxyphenylbenzotriazoles, 2-hydroxyphenylbenzophenones, oxalanilides or 2-hydroxyphenyl-4,6-diaryltriazines or a radical of a sterically hindered phenol; andR.sub.8 is H, C.sub.1 -C.sub.18 alkyl, C.sub.7 -C.sub.11 phenylalkyl, C.sub.2 -C.sub.6 alkoxyalkyl or C.sub.5 -C.sub.12 cycloalkyl. Compounds of the formula I can be employed with advantage for stabilizing organic material against the damaging effect of light, oxygen and/or heat.
    • 给出式I化合物的描述,其中r为0或1,y为1-3范围内的数字; X是直接键或-NR8-,-CO-,-CONH-或-COO-或二价脂族或混合芳族 - 脂族C 1 -C 18烃基; Z是芳族,脂族或混合的芳族 - 脂族C 3 -C 18烃基,其在脂族部分中被一个或多个二价官能团中断,在每种情况下都在碳 - 碳单键中,和/或在芳族或脂族 部分由一个或多个二价官能团,在每种情况下都是碳 - 氢键,可能的官能团是-O - , - NR8 - , - S - , - SO - , - SO2-,-CONH-,-CO- 或-COO-; R是空间位阻胺或UV吸收剂的一价,二价或三价基团,来自2-羟基苯基苯并三唑类,2-羟基苯基二苯甲酮类,氧杂酰苯胺类或2-羟基苯基-4,6-二芳基三嗪类,或二 - 空间位阻酚的三价基团; R 1和R 2彼此独立地是H或C 1 -C 12烷基; R 3和R 4彼此独立地是H,C 1 -C 18烷基或-X-(Z)r -R 5; R5是2-羟基苯基苯并三唑类,2-羟基苯基二苯甲酮类,恶嗪酰胺类或2-羟基苯基-4,6-二芳基三嗪类或空间位阻酚基团的空间位阻胺或紫外线吸收剂的单价基团; R8是H,C1-C18烷基,C7-C11苯基烷基,C2-C6烷氧基烷基或C5-C12环烷基。 可以有利地使用式I化合物来稳定有机材料以抵抗光,氧和/或热的破坏作用。
    • 20. 发明授权
    • Tough epoxy casting resins based on polybutadiene-polyoxyalkleneglycol
copolymers
    • 基于聚丁二烯 - 聚羟基胆甾醇共聚物的韧性环氧树脂
    • US5140069A
    • 1992-08-18
    • US481424
    • 1990-02-16
    • Rolf MulhauptWerner Rufenacht
    • Rolf MulhauptWerner Rufenacht
    • C08G59/00C08G59/42C08L63/00
    • C08L63/00
    • Curable compositions containingA) an epoxy resin having on average more than one epoxy group per molecule,B) a carboxylic anhydride curing agent for component A) andC) about 5 to 40% by weight, relative to the amount of the components A), B) and C), of a liquid mixture of C1) a polyalkylene glycol based on polypropylene glycol or polybutylene glycol having two to about six hydroxyl, carboxyl, carboxylic anhydride or glycidyl end groups and of C2) an elastomeric copolymer based on butadiene, a polar, ethylenically unsaturated comonomer and, if appropriate, further ethylenically unsaturated comonomers having carboxylic acid, hydroxyl, mercapto or glycidyl ether end groups are described. Components C1) and C2) can also occur together in a segmented copolymer.
    • 含有A)每分子平均具有多于一个环氧基的环氧树脂,B)组分A)的羧酸酐固化剂和C)相对于组分A)的量为约5至40重量% ,B)和C),C1)基于具有2至约6个羟基,羧基,羧酸酐或缩水甘油基端基的聚丙二醇或聚丁二醇的聚亚烷基二醇和C2)基于丁二烯的弹性体共聚物, 描述了具有羧酸,羟基,巯基或缩水甘油醚端基的极性烯属不饱和共聚单体和(如果合适的话)其它烯属不饱和共聚单体。 组分C1)和C2)也可以一起发生在分段共聚物中。