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11. 发明申请

US20150034243A1 RESIN COMPOSITION 审中-公开
标题翻译：树脂组合物
公开(公告)号：US20150034243A1
公开(公告)日：2015-02-05
申请号：US14123372
申请日：2012-05-31
申请人： Daniel Haveman , Daniel Raimann , Johan Franz Gradus Antonius Jansen
发明人： Daniel Haveman , Daniel Raimann , Johan Franz Gradus Antonius Jansen
IPC分类号： C08F283/00 , C08G18/76 , B32B38/00 , C08G18/34 , B32B37/12 , C09J155/00 , C08G18/38
CPC分类号： C08F283/008 , B32B37/12 , B32B38/164 , B32B2037/1253 , B32B2038/0076 , B32B2367/00 , B32B2379/00 , C08G18/329 , C08G18/348 , C08G18/3819 , C08G18/672 , C08G18/7664 , C08G18/8116 , C08G2170/00 , C08J3/24 , C08J2375/00 , C08K5/0025 , C08K5/14 , C09J155/005
摘要： The present invention relates to a resin composition comprising (a) an unsaturated polyester resin and/or a methacrylate functional resin, wherein the resin composition further comprises an aromatic amine (b) according to formula (1) in which P1 is an organic residue, R1=H or a C1-C6 alkyl, R2=H or CH3.
摘要翻译：本发明涉及一种树脂组合物，其包含（a）不饱和聚酯树脂和/或甲基丙烯酸酯官能树脂，其中所述树脂组合物还包含其中P1为有机残基的根据式（1）的芳族胺（b） R1 = H或C1-C6烷基，R2 = H或CH3。

12. 发明授权

US08790762B2 Unsaturated polyester resin 有权
标题翻译：不饱和聚酯树脂
公开(公告)号：US08790762B2
公开(公告)日：2014-07-29
申请号：US13255609
申请日：2010-03-24
申请人： Marian Henryk Szkudlarek , Johan Franz Gradus Antonius Jansen , Silvana Rensina Antonnietta Di Silvestre , Stefanus Jacobus Duyvestijn
发明人： Marian Henryk Szkudlarek , Johan Franz Gradus Antonius Jansen , Silvana Rensina Antonnietta Di Silvestre , Stefanus Jacobus Duyvestijn
IPC分类号： B32B1/02 , B32B1/08 , C08G63/47 , C08G63/54
CPC分类号： C08G63/52 , C08F283/01 , C09D5/03 , C09D167/06 , Y10T428/1352 , Y10T428/139 , Y10T428/1393
摘要： The present invention relates to an unsaturated polyester resin comprising itaconate esters as reactive unsaturations, wherein the acid value of the resin is in the range of from 25 to 125 and the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 0.33 to 3. In one embodiment, the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 0.33 to 0.9. In another embodiment, the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 1.1 to 3.
摘要翻译：本发明涉及包含衣康酸酯作为活性不饱和度的不饱和聚酯树脂，其中树脂的酸值在25至125的范围内，羟基端基和羧酸端基的摩尔比在在一个实施方案中，羟基端基和羧酸端基的摩尔比在0.33至0.9的范围内。在另一个实施方案中，羟基端基和羧酸端基的摩尔比在1.1至3的范围内。

13. 发明申请

US20140066581A1 PROCESS FOR RADICALLY CURING A COMPOSITION 审中-公开
标题翻译：用于放射性固化组合物的方法
公开(公告)号：US20140066581A1
公开(公告)日：2014-03-06
申请号：US14007650
申请日：2012-03-29
申请人： Iris Hilker , Johan Franz Gradus Antonius Jansen , Nanning Joerg Arfsten
发明人： Iris Hilker , Johan Franz Gradus Antonius Jansen , Nanning Joerg Arfsten
IPC分类号： C08F224/00
CPC分类号： C08F224/00 , C08F220/00 , C08F283/01
摘要： The present invention relates to a process for radically curing a composition comprising a methacrylate containing compound (a1) and a monomer copolymerizable with said methacrylate containing compound in the presence of a 5 transition metal compound (c) and a peroxide, wherein the composition comprises a compound (b) according to formula (1) as monomer copolymerizable with said methacrylate containing compound whereby n=0-3; R1 and R2 each individually represent H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl or C7-C20 arylalkyl; X=O, S or NR3 whereby R3=H, C1C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, C7-C20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the composition comprises at least one transition metal compound (c) selected from the group consisting of Co, Cu, Mn and Fe compounds, and the curing is effected in the presence of a peroxide selected from the group consisting of hydroperoxides, perketals, peresters, percarbonates and mixtures thereof.
摘要翻译：本发明涉及一种在5过渡金属化合物（c）和过氧化物的存在下自由基固化包含含甲基丙烯酸酯化合物（a1）和可与所述含甲基丙烯酸酯化合物共聚的单体的组合物的方法，其中组合物包含作为可与所述含甲基丙烯酸酯化合物共聚的单体的根据式（1）的化合物（b），其中n = 0-3; R1和R2各自独立地表示H，C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基或C7-C20芳基烷基; X = O，S或NR 3，由此R3 = H，C1C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基，C7-C20芳基烷基，或连接到聚合物链的聚合物链的一部分，包含至少一种选自Co，Cu，Mn和Fe化合物的过渡金属化合物（c），并且在选自以下的过氧化物的存在下进行固化：选自氢过氧化物，庚酮，过酸酯，过碳酸盐和其混合物。

14. 发明申请

US20130203938A1 LOW TEMPERATURE CURE HEAT-CURABLE POWDER COATING COMPOSITION COMPRISING A CRYSTALLINE POLYESTER RESIN, AN AMORPHOUS POLYESTER RESIN, A CROSSLINKING AGENT AND A THERMAL RADICAL INITIATOR 有权
标题翻译：低温固化热稳定性粉末涂料组合物，包括结晶聚酯树脂，非晶聚酯树脂，交联剂和热辐射体
公开(公告)号：US20130203938A1
公开(公告)日：2013-08-08
申请号：US13696449
申请日：2011-05-06
申请人： Tosko Alexandar Misev , Leendert Jan Molhoek , Johan Franz Gradus Antonius Jansen , Nicole Van Der Werf , Sven Johan Wilbert Reijmer , Jan Pieter Drijfhout , Peter Wellenberg
发明人： Tosko Alexandar Misev , Leendert Jan Molhoek , Johan Franz Gradus Antonius Jansen , Nicole Van Der Werf , Sven Johan Wilbert Reijmer , Jan Pieter Drijfhout , Peter Wellenberg
IPC分类号： C09D167/02
CPC分类号： C09D167/02 , C08K3/011 , C08K5/0025 , C08K5/06 , C08K5/10 , C08K5/101 , C08K5/14 , C08L67/00 , C08L67/06 , C09D167/00 , C09D167/06 , C08L2666/18
摘要： The invention relates to a heat-curable powder coating composition comprising i) at least one crystalline polyester resin present in an amount of at most 90 wt %; and ii) at least one amorphous polyester resin; and iii) at least one crosslinking agent; and iv) at least one thermal radical initiator, wherein, the at least one crystalline polyester resin and/or the at least one amorphous polyester resin has di-acid ethylenic unsaturations; wherein the at least one crosslinking agent is either crystalline or amorphous; wherein the at least one crosslinking agent has reactive unsaturations that are reactable with the ethylenic unsaturations of the di-acid ethylenic unsaturations of the at least one crystalline polyester resin and/or the at least one amorphous polyester resin to be crosslinked, said unsaturations of the crosslinking agent are different from the unsaturations of the at least one crystalline polyester resin and the unsaturations of the at least amorphous polyester resin; wherein the wt % is based on the total amount of i)+ii)+iii). The compositions of the invention may be cured to an acceptable degree at low temperature of for example at most 130° C. for at most 20 minutes, said compositions may be ground, sieved and extrudable and said compositions can upon heat cure form powder coatings that may also exhibit a good balance of properties between good flexibility, good smoothness and good adhesion. In addition, the compositions of the invention can suitably be used on heat- and/or non heat-sensitive, even if the composition is highly pigmented.
摘要翻译：本发明涉及一种可热固化粉末涂料组合物，其包含i）至少一种以至多90重量％存在的结晶聚酯树脂; 和ii）至少一种无定形聚酯树脂; 和iii）至少一种交联剂; 和iv）至少一种热自由基引发剂，其中所述至少一种结晶聚酯树脂和/或所述至少一种无定形聚酯树脂具有二酸烯属不饱和度; 其中所述至少一种交联剂是结晶或无定形的; 其中所述至少一种交联剂具有可与所述至少一种结晶性聚酯树脂和/或所述至少一种待交联的至少一种无定形聚酯树脂的二酸烯属不饱和度的烯属不饱和度反应的反应性不饱和度，所述不饱和度交联剂不同于至少一种结晶聚酯树脂的不饱和度和至少非晶形聚酯树脂的不饱和度; 其中wt％基于i）+ ii）+ iii）的总量。本发明的组合物可以在低温例如最多130℃下固化至可接受的程度，最多20分钟，所述组合物可以研磨，筛分和挤出，并且所述组合物可以在热固化时形成粉末涂料，也可以在良好的柔韧性，良好的光滑度和良好的粘合性之间表现出良好的性能平衡。此外，即使组合物高度着色，本发明的组合物也可适用于热和/或非热敏感。

15. 发明申请

US20100069575A1 UNSATURATED POLYESTER RESIN OR VINYL ESTER RESIN COMPOSITIONS 有权
标题翻译：不饱和聚酯树脂或乙烯基酯树脂组合物
公开(公告)号：US20100069575A1
公开(公告)日：2010-03-18
申请号：US12307486
申请日：2007-07-05
申请人： Johan Franz Gradus Antonius JANSEN
发明人： Johan Franz Gradus Antonius JANSEN
IPC分类号： C08F120/10
CPC分类号： C08L67/06 , C08F290/061 , C08K3/08 , C08K5/0025 , C08K5/0091 , C08K5/098 , C08K5/16 , C08K5/20 , C08K2003/0818 , C08K2003/085 , C08L33/04
摘要： The present invention relates to an unsaturated polyester resin or vinyl ester resin composition, wherein the unsaturated polyester resin or vinyl ester resin composition comprises an unsaturated polyester resin or vinyl ester resin and a copper compound and an acetoacetamide compound having the following formula: whereby R1, R2, R3, R4 and R5 each individually may represent hydrogen (H), or a C1-C20 alkyl, C6-C20 aryl, alkylaryl or arylalkyl group, that each optionally may contain one or more hetero-atoms (e.g. oxygen, phosphor, nitrogen or sulphur atoms) and/or substituents; a ring may be present between R1 and R2, R2 and R3, R3 and R5, and/or between R4 and R5; R4 and/or R5 may be part of a polymer chain or may be attached to a polymer chain; and the resin being curable with a peroxide and the resin composition contains less than 0.01 mmol cobalt per kg primary resin system and less than 0.01 mmol titanium per kg primary resin system.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物，其中不饱和聚酯树脂或乙烯基酯树脂组合物包含不饱和聚酯树脂或乙烯基酯树脂和铜化合物和具有下式的乙酰乙酰胺化合物：其中R1， R 2，R 3，R 4和R 5各自独立地表示氢（H）或C 1 -C 20烷基，C 6 -C 20芳基，烷基芳基或芳基烷基，其各自任选地可以含有一个或多个杂原子（例如氧，氮或硫原子）和/或取代基; R1和R2，R2和R3，R3和R5之间，和/或R4和R5之间可能存在一个环; R 4和/或R 5可以是聚合物链的一部分或可以连接到聚合物链上; 并且树脂可用过氧化物固化，并且树脂组合物每kg初级树脂体系含有少于0.01mmol的钴，并且每kg初级树脂体系含有小于0.01mmol的钛。

16. 发明申请

US20100069549A1 UNSATURATED POLYESTER RESIN COMPOSITIONS 有权
标题翻译：不饱和聚酯树脂组合物
公开(公告)号：US20100069549A1
公开(公告)日：2010-03-18
申请号：US12307395
申请日：2007-07-05
申请人： Johan Franz Gradus Antonius Jansen , Ronald Ivo Kraeger
发明人： Johan Franz Gradus Antonius Jansen , Ronald Ivo Kraeger
IPC分类号： C08K5/07 , C08K5/10
CPC分类号： C08F299/04 , C08F283/01 , C08K5/0091 , C08K5/07 , C08K5/16 , Y10T428/1362 , Y10T428/2395 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin composition comprising an unsaturated polyester resin, a manganese compound, a 1,3-dioxo compound and a base; the molar ratio between the dioxo compound and the basic functionality of the base is from 170:1 to 1:30 and the resin composition being curable with a peroxide. The present invention further relates to a process for radically curing such a resin composition wherein a peroxide is added to the resin composition and the curing is effected in the absence of cobalt.
摘要翻译：本发明涉及不饱和聚酯树脂组合物，其包含不饱和聚酯树脂，锰化合物，1,3-二氧化合物和碱; 二氧化合物与碱的官能度之间的摩尔比为170:1至1:30，树脂组合物可用过氧化物固化。本发明还涉及一种使这种树脂组合物自由基固化的方法，其中在树脂组合物中加入过氧化物，并且在没有钴的情况下进行固化。

17. 发明申请

US20100048764A1 COMPOSITION WITH POLYMER AND AN OXIDATION-CATALYST 失效
标题翻译：与聚合物和氧化催化剂的组合物
公开(公告)号：US20100048764A1
公开(公告)日：2010-02-25
申请号：US12373148
申请日：2007-07-04
申请人： Pieter Gijsman , Johan Franz Gradus Antonius Jansen
发明人： Pieter Gijsman , Johan Franz Gradus Antonius Jansen
IPC分类号： C08K5/07
CPC分类号： C08K5/07 , C08K5/0033 , C08K5/098 , C08L101/00 , C08L2666/34
摘要： The invention relates to a process for increasing the rate of oxo-biodegradation of a carbon-containing polymer which process at least comprises the step of adding a component containing at least one 1,2-oxo-hydroxy-moiety as an oxidation catalyst to the carbon-containing polymer. The invention further relates to a composition with an increased rate of oxo-biodegradability that is obtained by the process of the invention and to the product with increased rate of oxo-biodegradability made from the composition.
摘要翻译：本发明涉及一种提高含碳聚合物的氧代 - 生物降解速率的方法，该方法至少包括将含有至少一个1,2-氧代 - 羟基部分的组分作为氧化催化剂加入到含碳聚合物。本发明还涉及通过本发明的方法获得的具有增加的氧代 - 生物降解性的速率的组合物，以及由组合物制成的具有增加的氧代 - 生物降解率的产物。

18. 发明授权

US09296917B2 Low temperature cure heat-curable powder coating composition comprising a crystalline polyester resin, an amorphous polyester resin, a crosslinking agent and a thermal radical initiator 有权
标题翻译：包含结晶聚酯树脂，无定形聚酯树脂，交联剂和热自由基引发剂的低温固化热固化粉末涂料组合物
公开(公告)号：US09296917B2
公开(公告)日：2016-03-29
申请号：US13696449
申请日：2011-05-06
申请人： Tosko Alexandar Misev , Leendert Jan Molhoek , Johan Franz Gradus Antonius Jansen , Nicole Van Der Werf , Sven Johan Wilbert Reijmer , Jan Pieter Drijfhout , Peter Wellenberg
发明人： Tosko Alexandar Misev , Leendert Jan Molhoek , Johan Franz Gradus Antonius Jansen , Nicole Van Der Werf , Sven Johan Wilbert Reijmer , Jan Pieter Drijfhout , Peter Wellenberg
IPC分类号： C08L67/00 , C08K5/00 , C09D167/02 , C09D167/00 , C09D167/06 , C08K3/00 , C08K5/06 , C08K5/10 , C08K5/101 , C08K5/14 , C08L67/06
CPC分类号： C09D167/02 , C08K3/011 , C08K5/0025 , C08K5/06 , C08K5/10 , C08K5/101 , C08K5/14 , C08L67/00 , C08L67/06 , C09D167/00 , C09D167/06 , C08L2666/18
摘要： The invention relates to a heat-curable powder coating composition comprising i) at least one crystalline polyester resin present in an amount of at most 90 wt %; and ii) at least one amorphous polyester resin; and iii) at least one crosslinking agent; and iv) at least one thermal radical initiator, wherein, the at least one crystalline polyester resin and/or the at least one amorphous polyester resin has di-acid ethylenic unsaturations; wherein the at least one crosslinking agent is either crystalline or amorphous; wherein the at least one crosslinking agent has reactive unsaturations that are reactable with the ethylenic unsaturations of the di-acid ethylenic unsaturations of the at least one crystalline polyester resin and/or the at least one amorphous polyester resin to be crosslinked, said unsaturations of the crosslinking agent are different from the unsaturations of the at least one crystalline polyester resin and the unsaturations of the at least amorphous polyester resin; wherein the wt % is based on the total amount of i)+ii)+iii). The compositions of the invention may be cured to an acceptable degree at low temperature of for example at most 130° C. for at most 20 minutes, said compositions may be ground, sieved and extrudable and said compositions can upon heat cure form powder coatings that may also exhibit a good balance of properties between good flexibility, good smoothness and good adhesion. In addition, the compositions of the invention can suitably be used on heat- and/or non heat-sensitive, even if the composition is highly pigmented.
摘要翻译：本发明涉及一种可热固化粉末涂料组合物，其包含i）至少一种以至多90重量％存在的结晶聚酯树脂; 和ii）至少一种无定形聚酯树脂; 和iii）至少一种交联剂; 和iv）至少一种热自由基引发剂，其中所述至少一种结晶聚酯树脂和/或所述至少一种无定形聚酯树脂具有二酸烯属不饱和度; 其中所述至少一种交联剂是结晶或无定形的; 其中所述至少一种交联剂具有可与所述至少一种结晶性聚酯树脂和/或所述至少一种待交联的至少一种无定形聚酯树脂的二酸烯属不饱和度的烯属不饱和度反应的反应性不饱和度，所述不饱和度交联剂不同于至少一种结晶聚酯树脂的不饱和度和至少非晶形聚酯树脂的不饱和度; 其中wt％基于i）+ ii）+ iii）的总量。本发明的组合物可以在低温例如最多130℃下固化至可接受的程度，最多20分钟，所述组合物可以研磨，筛分和挤出，并且所述组合物可以在热固化时形成粉末涂料，也可以在良好的柔韧性，良好的光滑度和良好的粘合性之间表现出良好的性能平衡。此外，即使组合物高度着色，本发明的组合物也可适用于热和/或非热敏感。

19. 发明授权

US08716368B2 Unsaturated polyester resin or vinyl ester resin composition 有权
标题翻译：不饱和聚酯树脂或乙烯基酯树脂组合物
公开(公告)号：US08716368B2
公开(公告)日：2014-05-06
申请号：US11921646
申请日：2006-06-06
申请人： Johan Franz Gradus Antonius Jansen , Ivo Ronald Kraeger
发明人： Johan Franz Gradus Antonius Jansen , Ivo Ronald Kraeger
IPC分类号： C08L67/00 , C08K5/07 , C08L33/04 , C08L67/06 , C08K5/00 , C08K5/16 , C08K3/08
CPC分类号： C08L63/10 , C08K5/07 , C08L33/08 , C08L33/10 , C08L67/06 , C08L67/07 , C08L67/08 , C08L2666/04
摘要： This invention relates to unsaturated polyester resin or vinyl ester resin compositions comprising a polymer containing reactive unsaturations as a resin; a 1,3-dioxo-component, and optionally a reactive diluent and/or an inhibitor and/or a stabilizer; the resin compositions being curable with a peroxide component, and wherein the resin in the resin composition has an acid value=10; and the resin composition contains—while being cured—a base, which is either selected from the group of organic or inorganic oxides, hydroxides, alkoxides or carboxylates for each of which the cation has a redox potential of the metal of at most −1V, or of ammonium ions; or is selected from the group of nitrogen-containing organic compounds. The present invention also relates to objects and structural parts prepared from such resin composition by curing with a peroxide. Finally the invention also relates to methods of peroxide curing of unsaturated polyester or vinyl ester curing and its use in chemical anchoring, roof coatings etc.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物，其包含含有作为树脂的反应性不饱和度的聚合物; 1,3-二氧代组分和任选的反应性稀释剂和/或抑制剂和/或稳定剂; 所述树脂组合物可用过氧化物组分固化，并且其中树脂组合物中的树脂的酸值= 10; 并且所述树脂组合物含有固化的碱，所述碱选自有机或无机氧化物，氢氧化物，醇盐或羧酸盐，其中阳离子的金属氧化还原电位至多为-1V，或铵离子; 或选自含氮有机化合物的组。本发明还涉及通过用过氧化物固化由这种树脂组合物制备的物体和结构部件。本发明还涉及不饱和聚酯或乙烯基酯固化的过氧化物固化方法及其在化学锚固，屋顶涂料等中的应用。

20. 发明授权

US08513343B2 Unsaturated polyester resin compositions 有权
标题翻译：不饱和聚酯树脂组合物
公开(公告)号：US08513343B2
公开(公告)日：2013-08-20
申请号：US12307395
申请日：2007-07-05
申请人： Johan Franz Gradus Antonius Jansen , Ronald Ivo Kraeger
发明人： Johan Franz Gradus Antonius Jansen , Ronald Ivo Kraeger
IPC分类号： C08K5/04 , C08G18/42 , C08L33/04
CPC分类号： C08F299/04 , C08F283/01 , C08K5/0091 , C08K5/07 , C08K5/16 , Y10T428/1362 , Y10T428/2395 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin composition comprising an unsaturated polyester resin, a manganese compound, a 1,3-dioxo compound and a base; the molar ratio between the dioxo compound and the basic functionality of the base is from 170:1 to 1:30 and the resin composition being curable with a peroxide. The present invention further relates to a process for radically curing such a resin composition wherein a peroxide is added to the resin composition and the curing is effected in the absence of cobalt.
摘要翻译：本发明涉及不饱和聚酯树脂组合物，其包含不饱和聚酯树脂，锰化合物，1,3-二氧化合物和碱; 二氧化合物与碱的官能度之间的摩尔比为170:1至1:30，树脂组合物可用过氧化物固化。本发明还涉及一种使这种树脂组合物自由基固化的方法，其中在树脂组合物中加入过氧化物，并且在没有钴的情况下进行固化。

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