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    • 12. 发明授权
    • Oil-in-water emulsifiers
    • 水包油乳化剂
    • US07045580B2
    • 2006-05-16
    • US10689266
    • 2003-10-20
    • John J. MullayJeffrey M. CareyJames H. BushStuart L. Bartley
    • John J. MullayJeffrey M. CareyJames H. BushStuart L. Bartley
    • C08F8/00
    • B01F17/005B01F17/0057B01F17/0064
    • The invention provides an amphiphilic compound suitable for oil-in-water systems. The amphiphilic compound contains: (a) a lipophilic component that is hydrocarbon group containing about 20 or more carbon atoms; (b) a hydrophilic component selected from (i) a monomer or an oligomer of an oxyalkylene group containing 2 or more carbon atoms; (ii) a monomer or an oligomer of an oxyalkylene group containing 3 or more carbon atoms; (iii) an oligiomer containing: (1) an oxyalkylene group containing 3 or more carbon atoms; (2) an oxyalkylene group containing 2 or more carbon atoms, provided component (2) is different from component (1); (iv) a hydrocarbyl substituted hydroxyamino group; (v) a polyhydric alcohol group; and (vi) a polyamino group; and (c) a linker covalently bonding the hydrophilic component and the lipophilic component, wherein the hydrophilic component is present in an amount sufficient to at least partially disperse the amphiphilic compound in water. The invention further provides a method of preparing the amphiphilic compound.
    • 本发明提供了一种适用于水包油系统的两亲化合物。 两亲性化合物包含:(a)含有约20个或更多个碳原子的烃基的亲脂性组分; (b)选自(i)含有2个或更多个碳原子的氧化烯基团的单体或低聚物的亲水组分; (ii)含有3个以上碳原子的氧化烯基的单体或低聚物; (iii)含有:(1)含有3个或更多个碳原子的氧化烯基团的低聚物; (2)含有2个以上碳原子的氧化烯基,提供成分(2)与成分(1)不同。 (iv)烃基取代的羟基氨基; (v)多元醇基团; 和(vi)聚氨基; 和(c)共价键合亲水组分和亲油组分的接头,其中亲水组分以足以使两亲性化合物至少部分分散在水中的量存在。 本发明还提供了制备两亲性化合物的方法。
    • 13. 发明授权
    • Emulsion explosive compositions
    • 乳化炸药组合物
    • US06200398B1
    • 2001-03-13
    • US09222661
    • 1998-12-30
    • James H. Bush
    • James H. Bush
    • C06B4500
    • C06B47/145
    • Water in oil emulsion explosive compositions comprises a discontinuous aqueous phase comprising at least one oxygen-supplying component, a continuous organic phase, an emulsifying amount of an emulsifier composition comprising: the reaction product of an amine (C) characterized by the presence within its structure of at least one H—N group and an intermediate formed in the reaction of (A) at least one olefinic compound containing at least one group of the formula  and (B) at least one carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5  (III)  wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof and optionally, from about 0.5 to about 2 moles, per mole of (B), of (D) at least one aldehyde or ketone; and optionally a sensitizer.
    • 油包水乳化炸药组合物包含不连续的水相,其包含至少一种供氧组分,连续有机相,乳化剂量的乳化剂组合物,其包含:胺(C)的反应产物,其特征在于其结构内的存在 至少一个HN基团和在(A)至少一种含有至少一个式的基团的至少一种烯烃化合物与(B)的反应中形成的中间体形成的至少一种选自下式的化合物的羧酸反应物,其中 R 3和R 5各自独立地为H或烃基,R 4为二价亚烃基,n为0或1,并且其活性源和任选地约0.5至约2摩尔每摩尔(B) (D)至少一种醛或酮; 和任选的敏化剂。
    • 14. 发明授权
    • Controlled release emulsion fertilizer compositions
    • 控制释放乳化肥组合物
    • US06176893B1
    • 2001-01-23
    • US09222660
    • 1998-12-30
    • James H. Bush
    • James H. Bush
    • A01N2500
    • C05G3/007C05G3/06
    • Non-explosive water in oil emulsion fertilizer compositions comprise a discontinuous aqueous phase comprising at least one fertilizer component, a continuous organic phase, an emulsifying amount of an emulsifier composition comprising: the reaction product of an amine (C) characterized by the presence within its structure of at least one H—N group and an intermediate formed in the reaction of (A) at least one olefinic compound containing at least one group of the formula and (B) at least one carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5   (III) wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof and optionally, from about 0.5 to about 2 moles, per mole of (B), of (D) at least one aldehyde or ketone. The fertilizer compositions provide for controlled release of the fertilizer components.
    • 非爆炸性水包油乳化肥组合物包含不连续水相,其包含至少一种肥料组分,连续有机相,乳化剂量的乳化剂组合物,其包含:胺(C)的反应产物,其特征在于其内 至少一个HN基团和在(A)至少一种含有至少一个式(B)基团的至少一种烯烃化合物的反应中形成的至少一个HN基团和中间体的结构,至少一种选自下列化合物的羧酸反应物: 的R 3和R 5独立地为H或烃基,R 4为二价亚烃基,n为0或1,其反应性源和任选地约0.5至约2摩尔每摩尔(B)的(B) D)至少一种醛或酮。 肥料组合物提供肥料组分的控制释放。
    • 16. 发明授权
    • Flotation process using a mixture of collectors
    • 使用收集器混合物的浮选过程
    • US5094746A
    • 1992-03-10
    • US539104
    • 1990-06-15
    • James H. Bush
    • James H. Bush
    • B03D1/004B03D1/012B03D1/014
    • B03D1/012B03D1/014B03D2201/02B03D2203/02B03D2203/025
    • The present invention relates to improved process for beneficiating an ore-containing sulfide material. In particular, the process is useful for beneficiating ores and recovering metals such as gold, copper, lead, molybdenum, zinc, etc., from the ores. In one embodiment, the process comprises the steps of:(1) forming a slurry comprising at least one crushed mineral-containing ore, water and a collector which is a mixture of (A) at least one metal salt of a phosphorus acid represented by the Formula: ##STR1## wherein each R.sub.1 is independently a hydrocarbyl, hydrocarbyloxy or hydrocarbylthio group having from 1 to about 18 carbon atoms, each X is independently oxygen or sulfur, and the lowest oxidation state of the metal is plus two, and (B) at least one thio compound comprising (i) at least one dithiocarbamate represented by the formula: ##STR2## wherein each R.sub.2 is independently hydrogen, a hydrocarbyl group having from 1 to about 18 carbon atoms, or R.sub.2 taken together with R.sub.3 and the nitrogen atom form a five, six or seven member heterocyclic group; each R.sub.3 is independently a hydrocarbyl group having from 1 to about 18 carbon atoms, or R.sub.3 taken together with R.sub.2 and the nitrogen atom form a five, six or seven member heterocyclic group; and R.sub.4 is a hydrocarbylene group having from 1 to about 10 carbon atoms, (ii) at least one thionocarbamate represented by the Formula ##STR3## wherein R.sub.5 and R.sub.6 are hydrocarbyl groups having from 1 to about 18 carbon atoms or mixtures of (i) and (ii);(2) subjecting the slurry from step (1) to froth flotation to produce a froth; and(3) recovering a mineral from the froth.
    • 本发明涉及用于选矿含硫硫化物材料的改进方法。 特别地,该方法可用于从矿石中选矿和回收金属如金,铜,铅,钼,锌等。 在一个实施方案中,该方法包括以下步骤:(1)形成包含至少一种破碎的含矿物矿石,水和收集器的浆料,其是(A)至少一种磷酸金属盐 式(I)其中每个R 1独立地为具有1至约18个碳原子的烃基,烃氧基或烃硫基,每个X独立地为氧或硫,并且金属的最低氧化态为加2, 和(B)至少一种硫代化合物,其包含(i)由下式表示的至少一种二硫代氨基甲酸盐:其中每个R 2独立地是氢,具有1至约18个碳原子的烃基,或者取R2 与R3和氮原子一起形成五,六或七元杂环基; 每个R 3独立地是具有1至约18个碳原子的烃基,或R 3与R 2一起并且氮原子形成5,6或7元杂环基; 并且R 4是具有1至约10个碳原子的亚烃基,(ii)至少一种由式(III)表示的硫代氨基甲酸酯,其中R 5和R 6是具有1至约18个碳原子的烃基或 (i)和(ii); (2)对来自步骤(1)的浆料进行泡沫浮选以产生泡沫; 和(3)从泡沫中回收矿物质。
    • 17. 发明授权
    • Compositions containing esters of carboxy-containing interpolymers and
methods of using the same
    • 含有含羧基的共聚体的酯的组合物及其使用方法
    • US5283235A
    • 1994-02-01
    • US853064
    • 1992-03-17
    • James H. BushRichard W. JahnkeLawrence J. Kocurek
    • James H. BushRichard W. JahnkeLawrence J. Kocurek
    • C09K8/28C09K8/36C09K7/02
    • C09K8/36C09K8/28
    • This invention relates to a composition comprising a mixture of a brine and a liquid hydrocarbon, and (A) a viscosity increasing amount of at least one ester of a carboxy-containing interpolymer or salt thereof wherein the interpolymer is prepared by polymerizing an olefin selected from the group consisting of alpha-olefins and vinyl aromatic monomers with at least one alpha, beta-unsaturated carboxylic acylating agent, and provided that when the olefin is vinyl toluene, then the alpha, beta-unsaturated carboxylic acylating agent is an alpha, beta-unsaturated dicarboxylic acylating agent. The compositions of the present invention are useful as drilling fluids as well as completion fluids. The esters of the carboxy-containing interpolymer or salts thereof provide beneficial viscosity, formation stabilization, emulsification and rheology properties to the fluids.
    • 本发明涉及包含盐水和液体烃的混合物的组合物,和(A)粘度增加量的至少一种含羧基的互聚物或其盐的酯,其中互聚物是通过将选自 由具有至少一种α,β-不饱和羧酸酰化剂的α-烯烃和乙烯基芳族单体组成的组,并且当烯烃为乙烯基甲苯时,α,β-不饱和羧酸酰化剂为α,β-不饱和羧酸酰化剂, 不饱和二羧酸酰化剂。 本发明的组合物可用作钻井液和完井液。 含羧基的互聚物或其盐的酯为流体提供有益的粘度,形成稳定性,乳化和流变性质。
    • 18. 发明授权
    • Ore flotation process using carbamate compounds
    • 矿石浮选工艺使用氨基甲酸酯化合物
    • US5015368A
    • 1991-05-14
    • US538864
    • 1990-06-15
    • Stephen A. Di BiaseJames H. Bush
    • Stephen A. Di BiaseJames H. Bush
    • B03D1/012
    • B03D1/012B03D1/002B03D1/018B03D2201/007B03D2201/02B03D2203/02B03D2203/025
    • The present invention relates to an improved process for beneficiating an ore. In particular, the process is useful for beneficiating ores and recovering metal values such as gold, copper, lead, molybdenum, zinc, etc., from the ores. In one embodiment, the process comprises(A) forming a slurry comprising at least one crushed mineral-containing ore, water and a collector which is at least one carbamate represented by the formula: ##STR1## wherein each R.sub.1 is independently hydrogen, a hydrocarbyl group having from 1 to about 18 carbon atoms, or R.sub.1 taken together with R.sub.2 and the nitrogen atom form a five, six or seven member heterocyclic group; each R.sub.2 is independently a hydrocarbyl group having from 1 to about 18 carbon atoms, or R.sub.2 taken together with R.sub.1 and the nitrogen atom form a five, six or seven member heterocyclic group; and R.sub.3 is a hydrocarbylene group having from 1 to about 10 carbon atoms;(B) subjecting the slurry from step (A) to froth flotation to produce a froth; and(C) recovering a mineral from the froth.
    • 本发明涉及一种用于选矿的改进方法。 特别地,该方法可用于从矿石中选矿和回收金属,例如金,铜,铅,钼,锌等。 在一个实施方案中,该方法包括(A)形成包含至少一种破碎的含矿物矿石,水和收集器的浆料,该矿物质是至少一种由下式表示的氨基甲酸酯:其中每个R 1独立地是氢 ,具有1至约18个碳原子的烃基,或者R 1与R 2和氮原子一起形成五,六或七元杂环基; 每个R 2独立地为具有1至约18个碳原子的烃基,或R 2与R 1一起并且氮原子形成五,六或七元杂环基; 并且R 3是具有1至约10个碳原子的亚烃基; (B)对来自步骤(A)的浆料进行泡沫浮选以产生泡沫; 和(C)从泡沫中回收矿物质。
    • 19. 发明授权
    • Fifth wheel assembly
    • 第五轮总成
    • US4443025A
    • 1984-04-17
    • US354240
    • 1982-03-03
    • Samuel A. MartinFredrick J. BakkerGerald W. HungerinkJack L. GisingerJames H. Bush
    • Samuel A. MartinFredrick J. BakkerGerald W. HungerinkJack L. GisingerJames H. Bush
    • B62D53/08
    • B62D53/0807
    • A fifth wheel assembly for coupling tractor and trailer units includes an improved trunnion bracket, comprising a pair of forged bearing caps having an inverted, U-shaped configuration, with bearing sleeves fixedly mounted therein. In sliding fifth wheel embodiments of the present invention, the bearing caps are mounted on rectangular channels fabricated from two L-shaped channel members with a flat plate attached to the upper edges of the L-shaped channels. An improved plunger is provided for adjustably connecting the trunnioned fifth wheel assembly with a base plate on which slotted racks have been mounted, and comprises a forged, two-prong construction with internal guides which minimizes structural disruption in the channels to provide greater strength. Adjustable stops are mounted on the exterior ends of the plungers, and abut the exterior sides of the racks to accurately maintain the plungers in a locked position. A manual lock release comprises an over-centered lever arm arrangement, which securely retains the plungers in the unlocked position for adjustment.
    • 用于联接牵引车​​和拖车单元的第五轮组件包括改进的耳轴支架,包括一对具有倒置的U形构造的锻造轴承盖,其中固定地安装有轴承套筒。 在本发明的滑动第五轮实施例中,轴承盖安装在由两个L形通道构件制成的矩形通道上,平板连接到L形通道的上边缘。 提供了一种改进的柱塞,用于可调节地连接带齿的第五轮组件与已经安装有开槽的机架的底板,并且包括具有内部引导件的锻造的双管结构,其最小化通道中的结构中断以提供更大的强度。 可调节止动件安装在柱塞的外端上,并且邻接机架的外侧,以将柱塞准确地保持在锁定位置。 手动锁定释放装置包括过中心的杠杆臂布置,其将柱塞牢固地保持在解锁位置以进行调节。
    • 20. 发明授权
    • Fifth wheel suspension
    • 第五轮悬挂
    • US4199168A
    • 1980-04-22
    • US909615
    • 1978-05-26
    • James H. BushSamuel A. Martin
    • James H. BushSamuel A. Martin
    • B62D53/08
    • B62D53/0835
    • A support for a tilt stabilizing fifth wheel hitch that connects a truck tractor to a trailer, the fifth wheel plate being on a movable frame having a pair of convex shoes connected by a tie rod and resting on concave bearing plates on a fixed frame, the movable frame being movable on the fixed frame toward either of two opposite extreme positions from an intermediate neutral position. The movable frame is biased away from these extreme positions toward the intermediate position by variable force biasing means, preferably coil compression springs on said tie rod, which apply increasing biasing force with increased movement of the movable frame toward one of said extreme positions, thereby enabling the truck driver to "sense" or "feel" the tilted condition of his trailer relative to his tractor during operation.
    • 一种用于将卡车拖拉机连接到拖车上的倾斜稳定的第五轮牵引的支撑件,所述第五轮板位于具有通过拉杆连接并搁置在固定框架上的凹形支承板上的一对凸起的鞋的可动框架上, 可移动框架可在固定框架上朝向从中间中立位置的两个相对极限位置中的任一个移动。 可移动框架通过可变力偏置装置偏压从这些极限位置朝向中间位置,优选地是所述拉杆上的线圈压缩弹簧,其随着可移动框架朝向所述极限位置之一的增加的运动而施加增加的偏压力,从而使能 卡车司机在操作期间“感觉”或“感觉到”他的拖车相对于拖拉机的倾斜状态。