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11. 发明授权

US4099537A Method for transportation of viscous hydrocarbons by pipeline 失效
标题翻译：通过管道运输粘性烃的方法
公开(公告)号：US4099537A
公开(公告)日：1978-07-11
申请号：US664711
申请日：1976-03-08
申请人： George Kalfoglou , Kenoth H. Flournoy
发明人： George Kalfoglou , Kenoth H. Flournoy
IPC分类号： B01F17/00 , F02M25/07 , F17D1/17
CPC分类号： B01F17/0057 , F17D1/17 , Y10S516/02 , Y10S516/03 , Y10S516/909 , Y10S516/91 , Y10T137/0391
摘要： A method of transporting viscous hydrocarbons which involves introducing into a pipeline or well-bore with the viscous hydrocarbons a solution containing an oxyalkylated anionic surfactant such as sodium nonyl phenol polyoxyethylene sulfonate or a mixture of such surfactants and, optionally, with an alkalinity agent thereby forming a low-viscosity, salt-tolerant oil-in-water emulsion.
摘要翻译：一种输送粘性烃的方法，其包括用粘性烃将含有烷氧基化阴离子表面活性剂如壬基酚聚氧乙烯磺酸钠的溶液或这种表面活性剂的混合物和任选地与碱性剂引入管道或井眼，从而形成低粘度，耐盐水包油乳液。

12. 发明授权

US4006779A Lignosulfonates as sacrificial agents in oil recovery processes 失效
标题翻译：木质素磺酸盐作为石油采收过程中的牺牲剂
公开(公告)号：US4006779A
公开(公告)日：1977-02-08
申请号：US591574
申请日：1975-06-30
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/88 , E21B43/20 , E21B43/22
CPC分类号： C09K8/885
摘要： A process for producing petroleum from subterranean formations is disclosed wherein production from the formation is obtained by driving a fluid from an injection well to a production well. The process involves injecting via the injection well into the formation an aqueous solution of lignosulfonate salt as a sacrificial agent to inhibit the deposition of surfactant contained in a micellar dispersion (microemulsion) on the reservoir matrix. Normally the process would be carried out by first injecting the lignosulfonates into the formation through the injection well and following them with a micellar dispersion which may contain lignosulfonates. The micellar dispersion would then be followed by a drive fluid such as water to push the dispersion to the production well.
摘要翻译：公开了一种从地层生产石油的方法，其中从地层中的生产是通过将流体从注入井驱动到生产井获得的。该方法包括通过注射井将木质素磺酸盐的水溶液作为牺牲剂注入，以抑制胶束分散体（微乳液）中所含的表面活性剂沉积在储层基质上。通常，该方法将通过首先通过注入井将木质素磺酸盐注入地层中，然后用可能含有木素磺酸盐的胶束分散体进行。然后，胶束分散体之后是驱动流体例如水，以将分散体推到生产井。

13. 发明授权

US5251698A Method of using lignosulfonate-acrylic acid graft copolymers as sacrificial agents for surfactant flooding 失效
标题翻译：使用木质素磺酸盐 - 丙烯酸接枝共聚物作为表面活性剂浸渍的牺牲剂的方法
公开(公告)号：US5251698A
公开(公告)日：1993-10-12
申请号：US903114
申请日：1992-06-23
申请人： George Kalfoglou , Grover S. Paulett
发明人： George Kalfoglou , Grover S. Paulett
IPC分类号： C09K8/88 , E21B43/22
CPC分类号： C09K8/88 , Y10S507/936
摘要： A sacrificial agent method employing lignosulfonate-acrylic acid graft copolymers to reduce chemical loss to the formation during hydrocarbon recovery by surfactant system injection and sweep through an underground formation.
摘要翻译：使用木质素磺酸盐 - 丙烯酸接枝共聚物的牺牲剂方法，通过表面活性剂体系注入和扫过地下地层来减少烃回收期间的形成的化学损失。

14. 发明授权

US5009268A Method of using a combination lignosulfonate/polyalkylene glycol system as a sacrificial agent for surfactant flooding 失效
标题翻译：使用木质素磺酸盐/聚亚烷基二醇体系组合作为表面活性剂浸渍的牺牲剂的方法
公开(公告)号：US5009268A
公开(公告)日：1991-04-23
申请号：US459611
申请日：1990-01-02
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/588 , C09K8/88
CPC分类号： C09K8/88 , C09K8/584 , C09K8/588 , Y10S507/936
摘要： A sacrificial agent solution which is compatible with high molecular weight mobility control polymers for enhanced oil recovery, said solution comprising about 0.1% to about 5% by weight of a lignosulfonate and about 0.01% to about 5% by weight of a polyalkylene glycol having a relatively low molecular weight.
摘要翻译：与用于提高采油量的高分子量迁移率控制聚合物相容的牺牲剂溶液，所述溶液包含约0.1％至约5％重量的木质素磺酸盐和约0.01％至约5％重量的聚亚烷基二醇，其具有相对较低的分子量。

15. 发明授权

US4344487A Modified lignosulfonates as additives in oil recovery processes involving chemical recovery agents 失效
标题翻译：改性木素磺酸盐作为包含化学回收剂的油回收过程中的添加剂
公开(公告)号：US4344487A
公开(公告)日：1982-08-17
申请号：US130911
申请日：1980-03-17
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/88 , E21B43/22
CPC分类号： C09K8/885 , Y10S507/936
摘要： A process for producing petroleum from subterranean formations is disclosed wherein production from the formation is obtained by driving a fluid from an injection well to a production well. The process involves injecting via the injection well into the formation an aqueous solution of modified lignosulfonate salt as a sacrificial agent to inhibit the deposition of surfactant and/or polymer on the reservoir matrix. The process may best be carried out by injecting the modified lignosulfonates into the formation through the injection well mixed with either a polymer, a surfactant solution and/or a micellar dispersion. This mixture would then be followed by a drive fluid such as water to push the chemicals to the production well. The lignosulfonates may be modified by any combination of any two or more of: reaction with chloroacetic acid, reaction with carbon dioxide, addition of the methylene sulfonate radical to the lignosulfonate molecule and oxidation with oxygen.
摘要翻译：公开了一种从地层生产石油的方法，其中从地层中的生产是通过将流体从注入井驱动到生产井获得的。该方法包括通过注入井注入改性木质素磺酸盐的水溶液作为牺牲剂，以抑制表面活性剂和/或聚合物沉积在储层基质上。该方法最好通过将改性的木质素磺酸盐通过与聚合物，表面活性剂溶液和/或胶束分散体混合的注入井注入到地层中来进行。然后该混合物之后是驱动流体例如水，以将化学品推向生产井。木素磺酸盐可以通过以下任何两种或多种的任何组合进行改性：与氯乙酸反应，与二氧化碳反应，向木质素磺酸盐分子中加入亚甲基磺酸根基团并用氧气氧化。

16. 发明授权

US4296812A Surfacant waterflooding oil recovery method 失效
标题翻译： Surfacant注水采油方法
公开(公告)号：US4296812A
公开(公告)日：1981-10-27
申请号：US106212
申请日：1979-12-21
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/584 , C09K8/60 , E21B43/22
CPC分类号： C09K8/60 , C09K8/584 , Y10S507/936
摘要： Disclosed is a novel surfactant fluid and an oil recovery method using the fluid for recovering oil from subterranean formations thereof by surfactant waterflooding process. The fluid comprises water and at least one surfactant, preferably including an alkylpolyalkoxyalkylene sulfonate or an alkylarylpolyalkoxyalkylene sulfonate and as an additive for reducing the rigidity of the interfacial film, a silica-polydialkylsiloxane such as a silica-polydimethylsiloxane. Reduction in rididity of the interfacial film occupied by surfactant molecules of which the hydrophobic portion is dissolved in the oil phase and the hydrophilic portion is dissolved in the aqueous phase, improves the effectiveness of the surfactant fluid for recovering oil from subterranean formations.
摘要翻译：公开了一种新型的表面活性剂流体和油回收方法，该方法使用流体通过表面活性剂注水方法从其地层中回收油。流体包含水和至少一种表面活性剂，优选包括烷基聚烷氧基亚烷基磺酸盐或烷基芳基聚烷氧基亚烷基磺酸盐，并且作为用于降低界面膜刚性的添加剂，二氧化硅 - 聚二烷基硅氧烷如二氧化硅 - 聚二甲基硅氧烷。将疏水部分溶解在油相中的表面活性剂分子和亲水部分所溶解的界面膜的吸附性降低到水相中，提高了用于从地层中回收油的表面活性剂流体的有效性。

17. 发明授权

US4147214A Tannin materials as additives in oil recovery processes involving chemical recovery agents 失效
标题翻译：单宁材料作为添加剂在采油过程中涉及化学回收剂
公开(公告)号：US4147214A
公开(公告)日：1979-04-03
申请号：US859423
申请日：1977-12-12
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/90 , E21B43/22
CPC分类号： C09K8/90
摘要： A process for producing petroleum from subterranean formations is disclosed wherein production from the formation is obtained by driving a fluid from an injection well to a production well. The process involves injecting via the injection well into the formation an aqueous solution of tannin as a sacrificial agent to inhibit the deposition of surfactant and/or polymer on the reservoir matrix. The process may best be carried out by injecting the tannin into the formation through the injection well ahead of or mixed with either a polymer, a surfactant solution and/or a micellar dispersion. This mixture would then be followed by a drive fluid such as water to push the chemicals to the production well.
摘要翻译：公开了一种从地层生产石油的方法，其中从地层中的生产是通过将流体从注入井驱动到生产井获得的。该方法包括通过注射井将形成单宁的水溶液作为牺牲剂注入，以抑制表面活性剂和/或聚合物沉积在储层基质上。该方法最好通过将注入井中的单宁注射到地层中，或者与聚合物，表面活性剂溶液和/或胶束分散体混合来进行。然后该混合物之后是驱动流体例如水，以将化学品推向生产井。

18. 发明授权

US4143716A Tertiary oil recovery process utilizing a preflush 失效
标题翻译：采用预冲洗的三次采油工艺
公开(公告)号：US4143716A
公开(公告)日：1979-03-13
申请号：US718993
申请日：1976-08-30
申请人： George Kalfoglou , Kenoth H. Flournoy
发明人： George Kalfoglou , Kenoth H. Flournoy
IPC分类号： C09K8/588 , C09K8/60 , E21B43/22
CPC分类号： C09K8/584 , C09K8/588 , C09K8/607 , Y10S507/936 , Y10S516/922
摘要： An adjusted salinity and hardness, aqueous preflush containing a thickening material which can be, for example, a hydrophilic material such as polyacrylamide, polysaccharide, polyvinyl aromatic sulfonate, polyethylene oxide, methyl cellulose, etc. or colloidal silica, etc. in a concentration sufficient to increase the viscosity of the adjusted salinity aqueous preflush fluid is injected into a subterranean, petroleum-containing formation. Optionally, the preflush fluid may contain a sacrificial agent, such as sodium tripolyphosphate, etc. The high salinity formation water is efficiently displaced by viscous low salinity aqueous preflush fluid to increase the effectiveness of a subsequently injected high salinity sensitive single surfactant solution. The surfactant may be displaced by a mobility buffer solution, which then may be displaced by water.
摘要翻译：调节的盐度和硬度，含有增稠材料的水性预冲洗，其可以是例如浓度足够的例如聚丙烯酰胺，多糖，聚乙烯基芳族磺酸盐，聚环氧乙烷，甲基纤维素等或胶态二氧化硅等亲水性材料为了增加调节后的盐度水性预喷流体的粘度被注入地下含石油的地层中。任选地，预冲洗流体可以含有牺牲剂，例如三聚磷酸钠等。高盐度形成水通过粘性低盐度水性预冲洗液有效地移位，以增加随后注射的高盐度敏感性单一表面活性剂溶液的有效性。表面活性剂可以被移动性缓冲溶液置换，然后移动性缓冲溶液可能被水置换。

19. 发明授权

US4133385A Oxidized lignosulfonates as additives in oil recovery processes involving chemical recovery agents 失效
标题翻译：氧化木质素磺酸盐作为涉及化学回收剂的采油过程中的添加剂
公开(公告)号：US4133385A
公开(公告)日：1979-01-09
申请号：US807948
申请日：1977-06-20
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/88 , E21B43/22
CPC分类号： C09K8/885 , Y10S507/936
摘要： A process for producing petroleum from subterranean formations is disclosed wherein production from the formation is obtained by driving a fluid from an injection well to a production well. The process involves injecting via the injection well into the formation an aqueous solution of oxidized lignosulfonate salt as a sacrificial agent to inhibit the deposition of surfactant and/or polymer on the reservoir matrix. The process may best be carried out by injecting the oxidized lignosulfonates into the formation through the injection well mixed with either a polymer, a surfactant solution and/or a micellar dispersion. This mixture would then be followed by a drive fluid such as water to push the chemicals to the production well.
摘要翻译：公开了一种从地层生产石油的方法，其中从地层中的生产是通过将流体从注入井驱动到生产井获得的。该方法包括通过注入井注入氧化木质素磺酸盐的水溶液作为牺牲剂，以抑制表面活性剂和/或聚合物沉积在储层基质上。该方法最好通过将氧化的木质素磺酸盐通过与聚合物，表面活性剂溶液和/或胶束分散体混合的注射剂注入到地层中来进行。然后该混合物之后是驱动流体例如水，以将化学品推向生产井。

20. 发明授权

US4129183A Use of organic acid chrome complexes to treat clay containing formations 失效
标题翻译：使用有机酸铬配合物处理含粘土的地层
公开(公告)号：US4129183A
公开(公告)日：1978-12-12
申请号：US811804
申请日：1977-06-30
申请人： George Kalfoglou
发明人： George Kalfoglou
IPC分类号： C09K8/592 , C09K8/60 , E21B43/24 , E21B43/22
CPC分类号： E21B43/24 , C09K8/592 , C09K8/607
摘要： The instant invention is concerned with the use of organic acid chrome complexes for stabilizing a formation against clay swelling and particle migration and, in one embodiment, to improve oil recovery by rendering watered out channels within a produced formation water repellent and oil wettable.
摘要翻译：本发明涉及使用有机酸铬配合物来稳定地层以抵抗粘土溶胀和颗粒迁移，并且在一个实施方案中，通过在产生的地层防水剂和油可润湿的水中使浇水渠改善油回收。

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