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11. 发明授权

US07179871B2 Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins 失效
标题翻译：用于乙烯低聚成直链α-烯烃的非对称配体及其催化剂体系
公开(公告)号：US07179871B2
公开(公告)日：2007-02-20
申请号：US10320213
申请日：2002-12-16
申请人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
IPC分类号： C08F4/44 , C08F4/52
CPC分类号： C07D213/53 , Y02P20/582
摘要： Non-symmetrical ligands of formula (I); bis-aryliminepyridine MXn complexes comprising a non-symmetrical ligand of formula (I), wherein M is a metal selected from Fe or Co, n is 2 or 3, and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; [bis-aryliminepyridine MYp.Ln+][NC−]q complexes, comprising a non-symmetrical ligand of formula (I), wherein Y is a ligand which may insert an olefin, M is Fe or Co, NC− is a non-coordinating anion and p+q is 2 or 3, matching the formal oxidation of the metal atom M, L is a neutral Lewis donor molecule and n=0, 1, or 2; and processes for the production of alpha-olefins from ethylene, using said complexes.
摘要翻译：式（I）的非对称配体; 包含式（I）的非对称配位体的双芳基亚氨基吡啶MX复合物，其中M为选自Fe或Co的金属，n为2或3，X为卤化物，任选取代的烃基，醇盐，酰胺或氢化物; [双 - 芳基亚氨基吡啶] n + 1 / n + >络合物，其包含式（I）的非对称配体，其中Y是可插入烯烃的配体，M是Fe或Co，NC是非配位阴离子，p + q是2或3，匹配金属原子M的形式氧化，L是中性Lewis供体分子，n = 0,1或2; 以及使用所述复合物从乙烯生产α-烯烃的方法。

12. 发明申请

US20060069220A1 Process for preparing an alkoxylated alcohol or phenol 审中-公开
标题翻译：制备烷氧基化醇或苯酚的方法
公开(公告)号：US20060069220A1
公开(公告)日：2006-03-30
申请号：US11232047
申请日：2005-09-21
申请人： Jan Hermen Meurs , Wilhelmina Verhoef-Van Wijk , Arie Van Zon
发明人： Jan Hermen Meurs , Wilhelmina Verhoef-Van Wijk , Arie Van Zon
IPC分类号： C08F4/44
CPC分类号： C08G65/2684 , C07C41/03 , C08G65/2654 , C08G65/269 , C07C43/11 , C07C43/13
摘要： Process for preparing an alkoxylated alcohol comprising reacting a starting monohydroxy alcohol selected from secondary alcohols, tertiary alcohols and mixtures thereof with an alkylene oxide in the presence of hydrogen fluoride and a boron-containing compound comprising at least one B—O bond. The alcohol may also be a primary monohydroxy alcohol when the boron containing compound is boric acid or boric acid anhydride or a mixture thereof, or may be a primary mono hydroxy alcohol, except a C14/C15 alcohol when reacted with ethylene oxide in the presence of HF and trimethyl borate. A phenol may be alkoxylated in the same way instead of the mono-hydroxyalcohol.
摘要翻译：包括制备烷氧基化醇的方法，包括在氟化氢和含有至少一个B-O键的含硼化合物的存在下使选自仲醇，叔醇及其混合物的起始单羟基醇与烯化氧反应。当含硼化合物是硼酸或硼酸酐或其混合物时，醇也可以是主要的单羟基醇，或者可以是主要单羟基醇，除了C 14 N 13 > 15当醇与环氧乙烷在HF和硼酸三甲酯存在下反应时。苯酚可以以相同的方式进行烷氧基化，而不是单羟基醇。

13. 发明申请

US20060014989A1 Process for preparring linear alpha olefins 失效
标题翻译：制备直链α-烯烃的方法
公开(公告)号：US20060014989A1
公开(公告)日：2006-01-19
申请号：US11179459
申请日：2005-07-12
申请人： Eric Johannes De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
发明人： Eric Johannes De Boer , Harry Van Der Heijden , Inge Oosterveld , Arie Van Zon
IPC分类号： C07C2/00
CPC分类号： C07C2/08 , C07C1/327 , C07C5/2575 , C07C2523/755 , C07C2527/128 , C07C2531/14 , C07C11/02
摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i) reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin; and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.
摘要翻译：制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下二聚具有n个碳原子的直链α-烯烃以产生线性内烯烃具有2n个碳原子; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化，从所述三烷基铝化合物置换烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是由所述直链内烯烃的异构化衍生的直链烷基; 和（b）（ii）任选地在置换催化剂存在下使所述烷基铝化合物与α-烯烃反应，以使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

14. 发明申请

US20050014983A1 Process for producing linear alpha olefins 审中-公开
标题翻译：生产线性α-烯烃的方法
公开(公告)号：US20050014983A1
公开(公告)日：2005-01-20
申请号：US10883600
申请日：2004-07-01
申请人： Eric De Boer , Harry Van Der Heijden , Eric Kragtwijk , Quoc On , Johan Smit , Arie Van Zon
发明人： Eric De Boer , Harry Van Der Heijden , Eric Kragtwijk , Quoc On , Johan Smit , Arie Van Zon
IPC分类号： B01J31/12 , B01J31/14 , B01J31/18 , C07C2/32 , C08F4/70 , C08F10/00 , C07C2/26 , B01J31/00
CPC分类号： C07C2/32 , B01J31/143 , B01J31/1815 , B01J2231/20 , B01J2531/842 , B01J2531/845 , C07C2531/14 , C08F10/00 , C08F4/7042
摘要： A process for the production of alpha-olefins comprising reacting ethylene under oligomerization conditions in the presence of a mixture comprising: (a) a metal salt based on Fe(II), Fe(III), Co(II) or Co(III); (b) a pyridine bis-imine ligand; and (c) a co-catalyst which is the reaction product of water with one or more organometallic aluminium compounds, wherein the one or more organometallic aluminium compounds is selected from: (i) βδ-branched compounds of formula (I): Al(CH2—CR1R2—CH2—CR4R5R6)xR3yHz; (ii) βγ-branched compounds of formula (II) Al(CH2—CR1R2—CR4R5R6)xR3yHz and mixtures thereof; wherein when the metal salt and the bis-arylimine pyridine ligand are mixed together they are soluble in aliphatic or aromatic hydrocarbon solvent.
摘要翻译：一种制备α-烯烃的方法，包括在低聚条件下，在混合物存在下使乙烯反应，所述混合物包含：（a）基于Fe（II），Fe（III），Co（II）或Co（III）的金属盐， ; （b）吡啶双亚胺配体; 和（c）作为水与一种或多种有机金属铝化合物的反应产物的助催化剂，其中所述一种或多种有机金属铝化合物选自：（i）式（I）的betadelta支化化合物：Al CH2-CR 1 R 2 -CH2-CR 4 R 5 R 6）xR 3Hz; （ⅱ）式（Ⅱ）bet ma ma ma branched branched branched）Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz;;;;;;;;;;;;;; 其中当将金属盐和双芳基亚胺吡啶配体混合在一起时，它们可溶于脂族或芳族烃溶剂。

15. 发明授权

US4288333A Dissolving barium sulfate scale with aqueous solutions of salts of phosphomethyl and amino-substituted macrocyclic polyethers 失效
标题翻译：用磷酸甲基和氨基取代的大环聚醚的盐溶液溶解硫酸钡垢
公开(公告)号：US4288333A
公开(公告)日：1981-09-08
申请号：US91009
申请日：1979-11-05
申请人： Arie van Zon , Feike de Jong , Gerridina J. Torny-Schutte
发明人： Arie van Zon , Feike de Jong , Gerridina J. Torny-Schutte
IPC分类号： C07F9/6527 , C09K8/528 , C02F5/14 , E21B43/25
CPC分类号： C07F9/6527 , C09K8/528 , Y10S507/927
摘要： Barium sulfate scale can be removed from remote locations such as those in or around the borehole of a well extending into a subterranean earth formation by contacting the scale with an aqueous solution consisting essentially of water, a monovalent cation salt of a macrocyclic polyether containing at least two nitrogen-linked phosphomethyl groups and enough monovalent basic compound to provide a solution pH of about 8.
摘要翻译：硫酸钡垢可以从远距离的位置移除，例如通过使水垢与基本上由水组成的水溶液接触，在延伸到地下地层中的孔的钻孔内或周围的硫酸钡垢，大环聚醚的一价阳离子盐至少包含两个氮连接的磷酸甲基和足够的单价碱性化合物，以提供约8的溶液pH。

16. 发明授权

US08680220B2 Catalyst systems for the catalytic oligomerization of olefinic monomers 失效
标题翻译：用于催化低聚烯烃单体的催化剂体系
公开(公告)号：US08680220B2
公开(公告)日：2014-03-25
申请号：US13204020
申请日：2011-08-05
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/78 , B01J31/00 , C07F9/6574
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (VI): (R9)(R10)P—N(R3)—P(R4) (VI) wherein: the R9 and R10 groups are independently selected from optionally substituted alkyl or heteroalkyl groups; the R3 group is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R4 group is an optionally substituted alkylenedioxy or alkylenedimercapto structure which is bound to the phosphorus atom through the two oxygen or sulphur atoms of the alkylenedioxy or alkylenedimercapto structure or an optionally substituted arylenedioxy or arylenedimercapto structure which is bound to the phosphorus atom through the two oxygen or sulphur atoms of the arylenedioxy or arylenedimercapto structure.
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的用途，具有通式（VI）的配体：（R9）（R10）P-N（R3）-P（R4）（VI）其中：R 9和R 10基团独立地选自任选取代的烷基或杂烷基; R3基团选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R4基团是任选取代的亚烷基二氧基或亚烷基二巯基结构，其通过亚烷基二氧基或亚烷基二巯基结构的两个氧原子或硫原子与磷原子结合，或者通过两个氧与磷原子结合的任选取代的亚芳基二氧基或亚芳基二巯基结构或亚芳基二氧基或亚芳基二巯基结构的硫原子。

17. 发明授权

US08476181B2 Catalyst systems for the oligomerization of olefin monomers 失效
标题翻译：用于烯烃单体低聚的催化剂体系
公开(公告)号：US08476181B2
公开(公告)日：2013-07-02
申请号：US13426372
申请日：2012-03-21
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： B01J31/00
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using those ligands.
摘要翻译：本发明涉及催化剂体系和使用这些配体同时使烯属单体三聚化和四聚的方法。

18. 发明授权

US08252874B2 Ligands and catalyst systems for the oligomerization of olefinic monomers 失效
标题翻译：用于烯烃单体低聚的配体和催化剂体系
公开(公告)号：US08252874B2
公开(公告)日：2012-08-28
申请号：US11961719
申请日：2007-12-20
申请人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Harry Van Der Heijden , Quoc An On , Johan Paul Smit , Arie Van Zon
IPC分类号： C08F4/06
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to ligands and catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands, the ligands having the general formula (I): (R1)2P—P(R1)m(R2)n═N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; with the proviso that m is 0 or 1, n is 1 or 2 and the total of m+n is 2.
摘要翻译：本发明涉及配体和催化剂体系以及使用所述配体同时使烯属单体三聚和四聚的方法，具有通式（I）的配体：（R1）2P-P（R1）m（R2）n = N（R3）（I）其中R3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基; 条件是m为0或1，n为1或2，m + n的总数为2。

19. 发明申请

US20120178889A1 CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFIN MONOMERS 失效
标题翻译：催化剂系统对烯烃单体的低级化
公开(公告)号：US20120178889A1
公开(公告)日：2012-07-12
申请号：US13426372
申请日：2012-03-21
申请人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
发明人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
IPC分类号： C08F4/22 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using those ligands.
摘要翻译：本发明涉及使用这些配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

20. 发明申请

US20110319577A1 Catalyst Systems for the Catalytic Oligomerization of Olefinic Monomers 失效
标题翻译：用于烯烃单体催化低聚的催化剂体系
公开(公告)号：US20110319577A1
公开(公告)日：2011-12-29
申请号：US13198997
申请日：2011-08-05
申请人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
发明人： Eric Johannes Maria DE BOER , Harry VAN DER HEIJDEN , Quoc An ON , Johan Paul SMIT , Arie VAN ZON
IPC分类号： C08F4/78 , B01J31/02
CPC分类号： C07C2/34 , B01J31/0265 , B01J31/189 , B01J2231/14 , B01J2231/20 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F9/5355 , C07F9/6571 , C07F9/657154 , C07F11/005 , C08F110/02
摘要： The present invention relates to a ligand and its use in a catalyst for the oligomerization of olefinic monomers, the ligand having the general formula (IV); (R8)(R1)P—N(R3)—P(R4) (IV).
摘要翻译：本发明涉及一种配体及其在烯烃单体低聚催化剂中的应用，具有通式（Ⅳ）的配体; （R8）（R1）P-N（R3）-P（R4）（IV）。

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