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    • 13. 发明申请
    • Method for the Manufacture of a Polyhydroxy-Carboxylic Acid
    • 多羟基羧酸的制造方法
    • US20130324697A1
    • 2013-12-05
    • US13985770
    • 2011-11-15
    • Manfred StepanskiFrancois LoviatAndrzej Kuszlik
    • Manfred StepanskiFrancois LoviatAndrzej Kuszlik
    • C08G63/78
    • C08G63/08B01D3/10B01D9/0013B01D9/0045B01D19/0036C07D319/12C08F124/00C08G63/78C08G63/785C08G63/90C08L67/04
    • Disclosed is a method to prepare a polylactic acid comprising the steps of performing a ring opening polymerization using a catalyst and either a catalyst killer compound or an endcapping additive to obtain a raw polylactic acid of MW greater than 10,000 g/mol, purifying the raw polylactic acid by removing and separating low boiling compounds comprising lactide and impurities from the raw polylactic acid by devolatization of the low boiling compounds as a gas phase stream, and purifying the lactide from the devolatization and removing the impurities from the gas phase stream of evaporated low boiling compounds by means of crystallization by desublimation from the gas phase, wherein the lactide is purified and the removed impurities include a catalyst residue and a compound containing at least one hydroxyl group such that the purified lactide is then polymerized by feeding it back into the ring opening polymerization. The invention further relates to an apparatus for carrying out the method comprising a polymerization reactor for performing a ring opening polymerization to obtain a raw polylactic acid, a devolatization apparatus for separating low boiling compounds comprising lactide and impurities from a raw polylactic acid, and a crystallization apparatus for purifying a lactide and removing impurities by means of a desublimation and a crystallization in the same crystallization apparatus.
    • 公开了一种制备聚乳酸的方法,其包括以下步骤:使用催化剂和催化剂杀菌化合物或封端添加剂进行开环聚合,得到MW大于10,000g / mol的原始聚乳酸,纯化原料聚乳酸 通过将作为气相物流的低沸点化合物脱挥发分,从原料聚乳酸中除去和分离包含丙交酯和杂质的低沸点化合物,并从脱挥发分纯化丙交酯并从蒸发的低沸点气相物流中除去杂质 化合物通过从气相中进行结晶化而得到,其中丙交酯被纯化,并且除去的杂质包括催化剂残余物和含有至少一个羟基的化合物,使得纯化的丙交酯通过将其送回到开环中而聚合 聚合。 本发明还涉及一种用于进行包括聚合反应器进行开环聚合以获得原始聚乳酸的方法的设备,用于从原始聚乳酸中分离包含丙交酯和杂质的低沸点化合物的脱挥发分装置和结晶 用于纯化丙交酯并通过在相同的结晶装置中进行凝胶化和结晶去除杂质的装置。
    • 17. 发明授权
    • Static mixer for a curing mixed product
    • 用于固化混合产品的静态混合器
    • US07322740B2
    • 2008-01-29
    • US11113522
    • 2005-04-25
    • Rolf HeusserSandro Martino
    • Rolf HeusserSandro Martino
    • B01F5/06
    • B01F5/0641B01F3/10
    • The static mixer is used for a curing mixed product of flowable components that react to form a solidifying mass on mixing. The mixer has mixing chambers that are arranged behind one another and next to one another along a tube axis. Each mixing chamber is delineated by longitudinal walls oriented in the direction of the tube axis and by transverse walls standing transversely to the tube axis. Openings in the longitudinal walls and in the floor of each mixing chamber establish inlets and outlets for the mixed product. The corner of at least some of the mixing chambers upstream of an outlet in the longitudinal walls is filled in to form a concave surface for directing the flowable components towards the outlet. The transverse wall at an inlet to at least some of the mixing chambers is also formed with a concave surface for directing the flowable components through the inlet into the mixing chamber.
    • 静态混合器用于在混合时反应形成固化物质的可流动组分的固化混合产物。 混合器具有彼此相互排列并沿着管轴彼此相邻的混合室。 每个混合室由沿管轴方向定向的纵向壁和横向于管轴的横向壁划定。 在每个混合室的纵向壁和地板中的开口建立用于混合产品的入口和出口。 在纵向壁中的出口上游的至少一些混合室的角部被填充以形成用于将可流动部件引向出口的凹面。 在至少一些混合室的入口处的横向壁也形成有凹面,用于将可流动部件引导通过入口进入混合室。
    • 18. 发明申请
    • Static mixer
    • 静态混合器
    • US20070263486A1
    • 2007-11-15
    • US11801551
    • 2007-05-10
    • Marcel Suhner
    • Marcel Suhner
    • B01F5/06
    • B01F5/0643
    • A mixing element is constructed for installation in a fluid-conducting conduit having an inlet opening of a first cross-section and an outlet opening of a larger second cross-section which is arranged in a plane disposed substantially normal to the main direction of flow. The mixing element has a cross-sectional design which increases substantially continuously from the first cross-section to the second cross-section. Flow-dividing layers are arranged in the mixing element such that a precise fitting of the mixing element into the substantially continuously expanding fluid-conducting means is made possible.
    • 混合元件构造成用于安装在具有第一横截面的入口开口和较大第二横截面的出口开口的流体导管中,该第二横截面布置在基本上垂直于主流动方向设置的平面中。 混合元件具有从第一横截面到第二横截面基本连续地增加的横截面设计。 分流层布置在混合元件中,使得可以将混合元件精确地配合到基本上连续膨胀的流体传导装置中。
    • 20. 发明申请
    • Tray column
    • 托盘栏
    • US20030102581A1
    • 2003-06-05
    • US10304255
    • 2002-11-25
    • Sulzer Chemtech AG
    • Markus Fischer
    • B01F003/04
    • B01D3/22B01D3/20
    • The tray column (1) has downcomers (3) for a transport of the liquid between adjacent trays (2). The liquid transport takes place in each downcomer through a plurality of discharge apertures (32) onto a loaded tray. Liquid flowing out of the discharge apertures in the form of jets (60) blending into a regionally divergent flow field (6) on striking the loaded tray, said flow field having transverse components of the flow speed with respect to a longitudinal main flow direction (61). Guide elements (4) are arranged beneath the discharge apertures and at a spacing from the loaded tray which each guide the impulse of liquid corresponding to the divergent flow field. The guide elements contribute to forming the transverse speed components such that the longitudinal component of the flow speed has a largely constant profile in each plane perpendicular to the main flow direction. The discharge apertures are preferably made in different sizes in a graduated fashion to be smaller in a central region than in adjacent flank regions.
    • 托盘塔(1)具有用于在相邻托盘(2)之间输送液体的降液管(3)。 在每个降液管中通过多个排放孔(32)在装载的托盘上进行液体输送。 以喷射形式(60)从出口孔流出的液体在撞击装载的托盘时混合到区域性发散流场(6)中,所述流场具有相对于纵向主流动方向的流动速度的横向分量( 61)。 引导元件(4)布置在排放孔下方并且与装载的托盘间隔开,每个引导元件引导对应于发散流场的液体脉冲。 引导元件有助于形成横向速度分量,使得流速的纵向分量在垂直于主流动方向的每个平面中具有大致恒定的轮廓。 放电孔优选以分级方式制成不同尺寸,在中央区域比在相邻侧翼区域中更小。