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161. 发明申请

US20120277484A1 Using A Dilute Acid Stream As An Extractive Agent 有权
标题翻译：使用稀酸酸流作为萃取剂
公开(公告)号：US20120277484A1
公开(公告)日：2012-11-01
申请号：US13456504
申请日：2012-04-26
申请人： R. Jay Warner , Victor J. Johnston , David Lee , Adam Orosco
发明人： R. Jay Warner , Victor J. Johnston , David Lee , Adam Orosco
IPC分类号： C07C29/149 , C07C29/80
CPC分类号： C07C29/149 , C07C29/80 , C07C31/08
摘要： Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using an extractive distillation column. A diluted acid stream, comprising less than 30 wt. % acetic acid, is used as the extractive agent and is fed at a point above the crude feed stream. The column yields a residue that comprises ethanol, acetic acid, and water. The diluted acid stream may be separated from the residue and returned to the extractive distillation column.
摘要翻译：从使用萃取蒸馏塔的乙酸氢化获得的粗乙醇产物中回收乙醇。稀释的酸流，包含小于30wt。％乙酸用作萃取剂，并在原油进料流上方进料。该柱产生包含乙醇，乙酸和水的残余物。稀释的酸流可以与残余物分离并返回到萃取蒸馏塔。

162. 发明授权

US08168824B2 Purification of acetic acid from wood acetylation process using extraction 失效
标题翻译：使用提取从木材乙酰化工艺中纯化乙酸
公开(公告)号：US08168824B2
公开(公告)日：2012-05-01
申请号：US12806349
申请日：2010-08-11
申请人： R. Jay Warner , Melchior A. Meilchen
发明人： R. Jay Warner , Melchior A. Meilchen
IPC分类号： C07C51/42
CPC分类号： C07C51/48 , C07C53/08
摘要： There is shown a method of purifying glacial acetic acid containing terpene and terpenoid impurities. Substantially dry acetic acid containing terpene and terpenoid impurities is combined with water and a suitable organic solvent, which is substantially immiscible with acetic acid and water, to form a separating composite extraction medium having a weight ratio of acetic acid:water of at least 1:1. The components are separated into an organic phase and an aqueous acid phase, with the terpene and terpenoid impurities concentrated in the organic phase, and with the aqueous acid phase purified of terpene and terpenoid impurities. The purified aqueous acid phase is recovered, and the purified acetic acid is dried.
摘要翻译：显示了一种纯化含有萜烯和萜类杂质的冰醋酸的方法。将含有萜烯和萜类杂质的基本干燥的乙酸与水和与乙酸和水基本上不混溶的合适的有机溶剂结合形成分离复合萃取介质，其重量比为乙酸：水至少为1： 1。将组分分离成有机相和酸性水相，萜烯和萜类杂质浓缩在有机相中，并且酸水相含有纯化的萜烯和萜类杂质。回收纯化的含水酸相，干燥纯化的乙酸。

163. 发明授权

US07199263B2 Acetic anhydride and acetate ester co-production 有权
标题翻译：乙酸酐和醋酸酯共同生产
公开(公告)号：US07199263B2
公开(公告)日：2007-04-03
申请号：US10920688
申请日：2004-08-18
申请人： R. Jay Warner
发明人： R. Jay Warner
IPC分类号： C07C67/08 , C07C51/54
CPC分类号： C07C51/56 , C07C45/89 , C07C67/08 , C07C49/88 , C07C53/12 , C07C69/14
摘要： A method of co-producing acetic anhydride and an acetate ester includes pyrolizing acetic acid at elevated temperature to produce a first ketene stream, the first ketene stream being a vapor phase stream comprising ketene, acetic acid and water; cooling the first ketene stream to condense acetic acid and water therefrom, thereby generating (i) a weak acid aqueous stream and (ii) a ketene feed stream; feeding the ketene feed stream to an acetic anhydride reactor where the ketene is reacted with acetic acid to produce acetic anhydride; concurrently with step (c), feeding the weak acid aqueous stream to an esterification reactor wherein acetic acid in the weak acid stream is reacted with an organic alcohol to produce an acetate ester. Preferably, the organic alcohol is selected from organic alcohols which (i) form acetate esters which esters and optionally alcohols provide azeotropic mixtures with water and (ii) wherein the azeotropic mixtures have a water content greater than the amount of water generated by reaction of the alcohol with acetic acid to facilitate azeotropically separating the acetate ester from the reaction mixture.
摘要翻译：共生产乙酸酐和乙酸酯的方法包括在升高的温度下热解乙酸以产生第一乙烯酮流，第一乙烯酮流是包含乙烯酮，乙酸和水的气相物流; 冷却第一个乙烯酮流以从其中冷凝乙酸和水，从而产生（i）弱酸水流和（ii）乙烯酮进料流; 将乙烯酮进料流进料到乙酸酐反应器中，其中乙烯酮与乙酸反应生成乙酸酐; 与步骤（c）同时，将弱酸性水流进料到酯化反应器中，其中弱酸流中的乙酸与有机醇反应以产生乙酸酯。优选地，有机醇选自（i）形成乙酸酯的有机醇，其酯和任选的醇与水提供共沸混合物，和（ii）其中共沸混合物的水含量大于通过反应产生的水的量乙醇与乙酸共沸以促进乙酸酯与反应混合物的共沸分离。

164. 发明授权

US06768021B2 Process improvement for continuous ethyl acetate production 失效
标题翻译：连续乙酸乙酯生产的工艺改进
公开(公告)号：US06768021B2
公开(公告)日：2004-07-27
申请号：US09470360
申请日：1999-12-22
申请人： Kimberly Ann Horan , Carl David Murphy , Russell Mark Stephens , R. Jay Warner , Kenneth Allen Windhorst
发明人： Kimberly Ann Horan , Carl David Murphy , Russell Mark Stephens , R. Jay Warner , Kenneth Allen Windhorst
IPC分类号： C07C6974
CPC分类号： C07C67/08 , C07C69/14
摘要： Disclosed herein is an improved process for producing ethyl acetate comprising contacting acetic acid and ethanol in a reaction zone in the presence of an acid catalyst, distilling formed vapors and condensing to form an organic phase rich in ethyl acetate and an aqueous phase rich in water, separating the phases and further distilling each phase to obtain a final purified ethyl acetate product and a water stream low in organic components, the improvement comprising directing the organic phase from the first distillation to the reaction zone. An alternate embodiment involves directing at least a portion of the organic phase from the first distillation to a membrane separation unit which removes water and/or alcohol from the organic phase rich in ethyl acetate.
摘要翻译：本文公开了一种生产乙酸乙酯的改进方法，包括在酸催化剂存在下，在反应区中使乙酸和乙醇接触，蒸馏形成的蒸气并冷凝以形成富含乙酸乙酯的有机相和富含水的水相，分离各相并进一步蒸馏每相以获得最终纯化的乙酸乙酯产物和低级有机组分的水流，其改进包括将有机相从第一次蒸馏引导至反应区。替代实施方案包括将至少一部分有机相从第一次蒸馏引导至膜分离单元，其从富含乙酸乙酯的有机相中除去水和/或醇。

165. 发明授权

US06444842B1 Continuous process for the production of carboxylic acid esters of alkylene glycol monoalkyl ethers 失效
标题翻译：用于生产亚烷基二醇单烷基醚的羧酸酯的连续方法
公开(公告)号：US06444842B1
公开(公告)日：2002-09-03
申请号：US09529899
申请日：2000-04-19
申请人： H. Robert Gerberich , R. Jay Warner
发明人： H. Robert Gerberich , R. Jay Warner
IPC分类号： C07C6702
CPC分类号： C07C67/54 , C07C67/58 , C07C69/003 , C07C69/14
摘要： The present invention provides an improved method for the preparation of carboxylic acid esters of alkylene glycol monoalkyl ethers by the acid catalyzed esterification of the monoalkyl ether with a carboxylic acid. In a preferred embodiment of the invention, the carboxylic acid and alcohol are reacted in a reactor/column and the resulting ester product is distilled into an overhead decanter/extractor as a single phase. A small amount of solvent, preferably a hydrocarbon is added to the mixture causing the resulting distillate to separate into two phases, one phase containing the desired product, the other containing primarily water. The process described is applicable to both batch and continuous operation and is not constrained by the difficulty of separating closely boiling azeotropes and results in substantially higher production rates than achieved by current processes.
摘要翻译：本发明提供了通过单烷基醚与羧酸的酸催化酯化来制备亚烷基二醇单烷基醚的羧酸酯的改进方法。在本发明的优选实施方案中，羧酸和醇在反应器/塔中反应，所得酯产物作为单相蒸馏成塔顶馏分/萃取器。向混合物中加入少量溶剂，优选烃，使所得馏出物分离成两相，一相含有所需产物，另一相主要含水。所描述的方法适用于批次和连续操作，并且不受分离紧密沸腾的共沸物的困难的限制，并且导致比通过当前方法实现的生产率显着更高的生产率。

166. 发明授权

US06303813B1 Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile 有权
标题翻译：铑/无机碘化物催化剂体系用于甲醇羰基化工艺，杂质分布改进
公开(公告)号：US06303813B1
公开(公告)日：2001-10-16
申请号：US09386708
申请日：1999-08-31
申请人： Mark O. Scates , Valerie Santillan , Pramod Agrawal , G. Paull Torrence , R. Jay Warner
发明人： Mark O. Scates , Valerie Santillan , Pramod Agrawal , G. Paull Torrence , R. Jay Warner
IPC分类号： C07C5112
CPC分类号： C07C51/12 , C07C53/08
摘要： The method of the present invention provides an improvement upon prior art methanol carbonylation methods which substantially reduces the production of carbonyl impurities. The production of carbonyl impurities, particularly acetaldehyde, crotonaldehyde, and 2-ethyl crotonaldehyde, in methanol carbonylation reactions has been found to decrease by maintaining a partial pressure of hydrogen between about 0.1 and 4 psia at reaction total pressure of from about 15 to about 40 atmospheres total reaction pressure.
摘要翻译：本发明的方法提供了现有技术的甲醇羰基化方法的改进，其大大降低了羰基杂质的产生。已经发现在甲醇羰基化反应中羰基杂质，特别是乙醛，巴豆醛和2-乙基巴豆醛的生产降低通过在反应总压力为约15至约40大气压的总反应压力下保持约0.1和4psia之间的氢分压。

167. 发明授权

US5300685A Removal of halide impurities from organic liquids 失效
标题翻译：从有机液体中除去卤素杂质
公开(公告)号：US5300685A
公开(公告)日：1994-04-05
申请号：US799455
申请日：1991-11-25
申请人： Mark O. Scates , R. Jay Warner , G. Paull Torrence
发明人： Mark O. Scates , R. Jay Warner , G. Paull Torrence
IPC分类号： C07C51/487 , B01D15/04 , B01D15/08 , C07C51/47 , C07C51/567 , C07C51/573 , C07C53/08 , C07C53/12 , C07C51/42
CPC分类号： C07C51/47 , C07C51/573
摘要： A method is provided for removing iodide compounds, particularly alkyl iodide compounds, from iodine-containing liquids, particularly carboxylic acids and anhydrides manufactured by the carbonylation of alcohols, ethers, esters, and the like in the presence of a rhodium catalyst and an alkali metal or alkaline earth metal salt, particularly a lithium salt, wherein the carboxylic acid or anhydride is contacted with a silver or mercury salt coordinated to a polymeric resin containing functional groups having the capability to quaternize with or form ionic salts with the alkyl halides.
摘要翻译：提供了一种从含碘液体中除去碘化物，特别是烷基碘化合物的方法，特别是在铑催化剂和碱金属存在下通过醇，醚，酯等的羰基化制备的羧酸和酸酐或碱土金属盐，特别是锂盐，其中羧酸或酸酐与与含有与烷基卤化物季铵化或与其形成离子盐的能力的官能团的聚合树脂配位的银或汞盐接触。

168. 发明授权

US09487466B2 Process for producing acrylic acids and acrylates 有权
标题翻译：制备丙烯酸和丙烯酸酯的方法
公开(公告)号：US09487466B2
公开(公告)日：2016-11-08
申请号：US13327888
申请日：2011-12-16
申请人： Craig J. Peterson , R. Jay Warner , Josefina T. Chapman
发明人： Craig J. Peterson , R. Jay Warner , Josefina T. Chapman
IPC分类号： C07C67/48 , C07C51/42
CPC分类号： C07C51/42
摘要： In one embodiment, the invention is to process for producing acrylics. The process includes the steps of contacting a crude product stream with an extraction agent mixture at a temperature less than 50° C.
摘要翻译：在一个实施方案中，本发明是用于生产丙烯酸树脂的方法。该方法包括在低于50℃的温度下使粗产物流与提取剂混合物接触的步骤

169. 发明授权

US08829249B2 Integrated esterification and hydrogenolysis process for producing ethanol 有权
标题翻译：用于生产乙醇的综合酯化和氢解方法
公开(公告)号：US08829249B2
公开(公告)日：2014-09-09
申请号：US13299841
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana Sonnenberg
IPC分类号： C07C27/06 , C07C27/08 , C07C27/30 , C07C31/08
CPC分类号： C07C27/06 , C07C27/08 , C07C27/30 , C07C29/149 , C07C29/80 , C07C31/08 , C07C67/08 , C07C69/14
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture. The crude reaction mixture may be further purified to recover ethanol.
摘要翻译：本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。该方法包括酯化乙酸和醇如乙醇以产生酯化产物。在催化剂存在下，用氢还原酯化产物，得到包含醇，特别是乙醇的粗反应混合物，其可与粗反应混合物分离。粗反应混合物可以进一步纯化以回收乙醇。

170. 发明授权

US08658824B2 Processes for producing acrylic acids and acrylates 失效
标题翻译：制备丙烯酸和丙烯酸酯的方法
公开(公告)号：US08658824B2
公开(公告)日：2014-02-25
申请号：US13420787
申请日：2012-03-15
申请人： Craig Peterson , Josefina Chapman , R. Jay Warner , Mark Scates
发明人： Craig Peterson , Josefina Chapman , R. Jay Warner , Mark Scates
IPC分类号： C07C51/44
CPC分类号： C07C51/48 , Y02P20/582 , C07C57/04
摘要： In one embodiment, the invention is to a process for producing an acrylate product. The process comprises the step of providing a crude product stream comprising the acrylate product, an alkylenating agent, and water. The process further comprises the step of contacting at least a portion of the crude product stream or a derivative thereof with an extraction agent mixture to form an extract stream and a raffinate stream. The extract stream comprises acrylate product and extraction agent. The raffinate stream comprises alkylenating agent and water. Preferably, the extraction agent mixture comprises at least two extraction agents.
摘要翻译：在一个实施方案中，本发明涉及一种生产丙烯酸酯产物的方法。该方法包括提供包含丙烯酸酯产物，亚烷基化剂和水的粗产物流的步骤。该方法还包括将至少一部分粗产物流或其衍生物与提取剂混合物接触以形成萃取物流和萃余液流的步骤。提取物流包含丙烯酸酯产物和提取剂。萃余液流包括亚烷基化剂和水。优选地，提取剂混合物包含至少两种提取剂。

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