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    • 153. 发明授权
    • Reactive polyester-amide polymers as co-reactants or curing agents for
polyepoxides and polyisocyanates
    • 活性聚酯 - 酰胺聚合物作为共反应物或聚环氧化物和多异氰酸酯的固化剂
    • US4042546A
    • 1977-08-16
    • US682474
    • 1976-05-03
    • Eli Simon
    • Eli Simon
    • C08G18/60C08G59/42C08G69/44C09D3/70C09D3/72
    • C08G69/44C08G18/606C08G59/4269
    • The reactive polyester-amide polymers of this invention are comprised of trihydric alcohols, aminoalcohols, and aliphatic dicarboxylic acids, containing an excess of functional groups reactive with carboxylic acid, and condensation heat-polymerized to an acid number of approximately 50.The polymerization is carried short of gelation so that the polymer remains soluble in solvents. Cure is subsequently effected by using the reactive polyester-amide, either from solution or as 100% solids, as a co-reactant with polyepoxides and polyisocyantates at relatively low temperatures.The preferred ratio of the components of the polyester-amide polymers of this invention is approximately 1-mol of a trihydric alcohol: 1-mol of a monoamino-monohydric alcohol: 2-moles of an aliphatic dibasic acid. The cured reaction products of reactive polyester-amide with polyepoxides and polyisocyanates can be controlled from rigid-brittle to rigid-flexible to soft-flexible depending on the selection and the mol ratios of the resin components. Reaction with polyepoxides and polyisocyanates may be conducted at room temperature or accelerated by elevating the temperature, concomitantly increasing the toughness of the cured products, having useable temperature ranges from about -40.degree. C. to 200.degree. C.
    • 本发明的反应性聚酯 - 酰胺聚合物包含三元醇,氨基醇和脂族二羧酸,其含有过量的与羧酸反应的官能团,并且缩合热聚合至约50的酸值。