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    • 135. 发明授权
    • Positive metal image-forming element and process
    • 积极的金属成像元素和过程
    • US3649272A
    • 1972-03-14
    • US3649272D
    • 1969-06-18
    • EASTMAN KODAK CO
    • GILMAN PAUL B JR
    • G03C1/705G03C1/72G03C1/73G03C5/00
    • G03C1/705G03C1/72G03C1/73
    • This invention relates to photographic processes for the formation of positive, metal, nonsilver halide photographic images and to photographic elements for carrying out these processes. A photographic element having a metal, e.g., silver, surface or a surface having thereon nonsilver halide nuclei, e.g., silver particles, and a photoreactive composition comprising a spectral sensitizing dye, a mercaptan and an Alpha , Beta unsaturated monomer, adsorbed to said surface or nuclei which inhibits the removal of said metal or nuclei by chemical solvents or bleaching agents is featured in the present process. Upon imagewise exposure of said element to light, the inhibiting effect of the photoreactive composition is destroyed; and subsequent treatment with a bleaching agent removes the exposed metal surface or nonsilver halide nuclei, resulting in the formation of a direct positive metal photographic image or an active site capable of physical development to a negative metal photographic image.
    • 本发明涉及用于形成正,金,非卤化物摄影图像和用于进行这些方法的照相元件的照相方法。 具有金属的照相元件,例如银,表面或其上具有非卤化物卤素核的表面,例如银颗粒,以及包含吸附在所述表面上的光谱增感染料,硫醇和α,β不饱和单体的光反应性组合物 或者通过化学溶剂或漂白剂抑制所述金属或细胞核的去除的核,其特征在于本发明。 当所述元件成像曝光时,光反应性组合物的抑制作用被破坏; 并且随后用漂白剂处理除去暴露的金属表面或非卤化物卤素核,导致形成直接正金属照相图像或能够对负金属照相图像进行物理显影的活性位点。