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131. 发明授权

US3972958A Conversion of coal to high octane gasoline 失效
标题翻译：煤转化为高辛烷值汽油
公开(公告)号：US3972958A
公开(公告)日：1976-08-03
申请号：US566153
申请日：1975-04-08
申请人： William E. Garwood , Solomon M. Jacob , James C. Kuo , John J. Wise
发明人： William E. Garwood , Solomon M. Jacob , James C. Kuo , John J. Wise
IPC分类号： C07C1/04 , C07C2/62 , C07C29/151 , C10L1/06 , C07C3/54 , C07C27/06
CPC分类号： C10G29/205 , C01B3/34 , C07C1/0485 , C07C2/62 , C07C29/1518 , C10G2/32 , C10J3/00 , C10K3/006 , C10L1/06 , C01B2203/0233 , C01B2203/062 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1659 , Y02P20/125 , Y02P20/52 , Y10S585/905 , Y10S585/943
摘要： An integrated process for converting coal to high octane gasoline by gasifying the coal in such manner as to form a gas comprising carbon oxides, hydrogen and methane; contacting this gas in one or a series of steps with one or a series of catalysts, respectively comprising a special high silica to alumina ratio zeolite; converting the carbon oxides and hydrogen by such contact to a product comprising water, high octane aromatic gasoline and light hydrocarbon gases; alkylating the C.sub.3 and C.sub.4 olefins with the isobutane in the light gases to produce alkylate gasoline; admixing the aromatic and alkylate gasoline; and subjecting the C.sub.2 .sup.- portion of the product to steam reforming whereby additional synthesis gas to be admixed with the gas produced by coal gasification is formed.
摘要翻译：通过气化煤以形成包含碳氧化物，氢气和甲烷的气体的方式将煤转化为高辛烷值汽油的综合方法; 将该气体与一种或一系列催化剂在一个或一系列步骤中接触，分别包含特殊的高二氧化硅与氧化铝比的沸石; 通过这样的接触将碳氧化物和氢气转化为包含水，高辛烷值芳烃汽油和轻烃气体的产品; 在轻质气体中用异丁烷烷基化C3和C4烯烃以产生烷基化汽油; 混合芳烃和烷基化汽油; 并使产物的C2 - 部分进行蒸汽重整，从而形成与煤气化产生的气体混合的其它合成气。

132. 发明授权

US3940432A Process for making ethylene glycol 失效
标题翻译：制备乙二醇的方法
公开(公告)号：US3940432A
公开(公告)日：1976-02-24
申请号：US470115
申请日：1974-05-15
申请人： Wellington E. Walker , Jean B. Cropley
发明人： Wellington E. Walker , Jean B. Cropley
IPC分类号： C07C27/06 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C29/15 , C07C29/151 , C07C29/152 , C07C29/158 , C07C31/04 , C07C31/20 , C07C67/00 , C07C29/16
CPC分类号： B01J31/0244 , B01J31/0241 , B01J31/1805 , B01J31/20 , C07C29/1512 , C07C29/1514 , C07C29/152 , C07C29/158 , B01J2231/648 , B01J2531/0211 , B01J2531/822 , B01J31/2234 , B01J31/4046 , Y02P20/52 , Y02P20/584
摘要： This invention is concerned with improving the ethylene glycol production capabilities of the metal carbonyl catalyzed reaction between carbon monoxide and hydrogen by conducting the reaction such that the ethylene glycol concentration in the reaction mixture is less than 5 gram moles per liter, preferably between about 0.4 to 5 gram moles per liter of reaction mixture and the molar formation ratio between ethylene glycol and methanol in the reaction mixture exceeds about 0.3. In a preferred embodiment, a continuous process is operated in such a manner that the concentration of ethylene glycol in the product mixture removed from the reactor is greater than the average concentration of ethylene glycol in the reactor.
摘要翻译：本发明涉及通过进行反应来改善一氧化碳和氢气之间的羰基羰基催化反应的乙二醇生产能力，使得反应混合物中的乙二醇浓度小于5克/升，优选在约0.4至每升反应混合物为5克摩尔，反应混合物中乙二醇与甲醇的摩尔形成比超过约0.3。在优选的实施方案中，连续方法以使得从反应器中除去的产物混合物中的乙二醇的浓度大于反应器中乙二醇的平均浓度的方式操作。

133. 发明授权

US3847963A Methanation processes 失效
标题翻译：甲烷过程
公开(公告)号：US3847963A
公开(公告)日：1974-11-12
申请号：US32872373
申请日：1973-02-01
申请人： VENTRON CORP
发明人： LALANCETTE J
IPC分类号： B01J31/16 , C07C1/04 , C07C27/06
CPC分类号： B01J31/1616 , B01J2531/0277 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07C1/0435 , C07C2521/08 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2523/755 , C07C9/04
摘要： 1. A SINGLE STAGE PROCESS FOR PRODUCING METHANE SUBSTANTIALLY DEVOIDE OF ANY CARBON OXIDE FROM A GASEOUS MIXTURE OF HYDROGEN AND AT LEAST ONE CARBON OXIDE WHICH COMPRISES: (A) HEATING SAID GASEOUS MIXTURE TO A TEMPERATURE WITHIN THE RANGE OF 200 TO 450*C., AND (B) PASSING SAID GASEOUS MIXTURE AT A FLOW RATE OF FROM 10 TO 500 VG VC-1 HR.-1 AND UNDER A PRESSURE OF AS LOW AS ONE ATMOSPHERE IN CONTACT WITH A CATALYST COMPOSITION CONSISTING ESSENTIALLY OF A TRANSITION METAL CATALYST INTERCALATED WITHIN THE CRYSTALS OF A CRYSTALLIZED CARBON GRAPHITE, THE CARBON ATOMS HAVING A DEFINITE PLANAR ALIGNMENT AND WHEREIN THE TRANSITION METAL IS IN THE METALLIC STATE HAVING A ZERO VALENCE, AND IS SELECTED FROM THE GROUP CONSISTING OF NICKEL, PALLADIUM AND PLATINUM,

THEREBY TO PRODUCE METHANE GAS SUBSTANTIALLY DEVOID OF ANY CARBON OXIDE.

134. 发明申请

US20210269616A1 FRACTIONATION AND DEPOLYMERISATION OF LIGNOCELLULOSIC MATERIAL 有权
公开(公告)号：US20210269616A1
公开(公告)日：2021-09-02
申请号：US17255163
申请日：2019-06-25
申请人： KATHOLIEKE UNIVERSITEIT LEUVEN
发明人： Bert Sels , Tom Renders , Elias Cooreman , Sander Van Den Bosch
IPC分类号： C08J11/16 , C07C27/06 , B01J19/00
摘要： Lignocellulose constitutes an alluring renewable feedstock for the production of bio-based chemicals. This contribution demonstrates for the first time a chemocatalytic biorefinery concept that produces three separate product fractions of valuable product families at high yield and purity from lignocellulosic biomass; the product families, merely comprising of stable products, are (i) a lignin oil enriched with high contents of lignin-derived (mono)phenolics, (ii) essentially humin (furanic oligomers)-free hemicellulose-derived polyols, and (iii) a cellulose pulp. This is achieved by processing biomass in a close to equivolumetric mixture of an alcohol (such as n-butanol) and water at elevated temperature, in the presence of a metal catalyst and hydrogen. During this one-pot fractionation process, the hot liquor disentangles the polymeric biomass and depolymerises lignin and hemicellulose, while the catalyst and reductive environment are essential to accumulate and target stable products at high yield (such as phenolics and polyols, respectively). The process is particularly industrially relevant because its overcomes difficult and complex separation protocols, at place in classic biorefinery technology; the process foresees simple product recuperation in one process step into the three fractions; the solid carbohydrate pulp (mainly cellulose) is retrieved upon filtration, while phase separation of n-butanol and water occurs below 125° C., offering a facile and effective strategy to isolate lignin-derived phenolics, present in the alcohol (such as n-butanol phase) from polyols, present in the aqueous phase at the same time. The three resulting product streams provide a versatile platform for down-stream conversion towards added-value bio-based chemicals.

135. 发明授权

US09725385B2 Process for operating an integrated gas-to-liquids facility 有权
公开(公告)号：US09725385B2
公开(公告)日：2017-08-08
申请号：US15141685
申请日：2016-04-28
申请人： Velocys Technologies, Ltd.
发明人： Andre Steynberg , Roy Lipski
IPC分类号： C01B3/38 , C01B3/48 , C07C27/06 , C10G2/00 , C07C29/151 , C01B13/02
CPC分类号： C07C29/1518 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0233 , C01B2203/0238 , C01B2203/0244 , C01B2203/025 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/061 , C01B2203/062 , C01B2203/0822 , C01B2203/1241 , C07C2/84 , C07C27/06 , C10G2/00 , Y02P20/128 , C07C11/04
摘要： The present technology is directed to processes involving formation of hydrocarbons and oxygenated hydrocarbons through use of oxygen supplied by ion transport membranes. More particularly, the present technology relates in part to a process involving steam reforming and subsequent production of a synthetic product where carbon dioxide and/or hydrogen downstream of the process is reclaimed to generate the synthetic product. The present technology also relates in part to an ethylene formation process involving a viral-templated coupling catalyst in the presence of an ion transport membrane.

136. 发明授权

US09636665B2 Catalyst compositions for converting syngas to produce higher alcohols 有权
公开(公告)号：US09636665B2
公开(公告)日：2017-05-02
申请号：US13883686
申请日：2011-12-01
申请人： Christopher W. Jones , Pradeep K. Agrawal , Tien Thao Nguyen
发明人： Christopher W. Jones , Pradeep K. Agrawal , Tien Thao Nguyen
IPC分类号： C07C27/06 , B01J27/236 , B01J23/00 , B01J23/28 , C07C29/153
CPC分类号： B01J27/236 , B01J23/007 , B01J23/28 , C07C27/06 , C07C29/153 , C07C31/08 , C07C31/10
摘要： Catalyst compositions for production of higher alcohols comprise a hydrotalcite or hydrotalcite-like support impregnated with molybdenum and an alkali metal. When the compositions are used to convert syngas, selectivity to higher (C2+) alcohols is increased in comparison to conversions accomplished over many other catalyst systems.

137. 发明授权

US09029429B2 Fischer-tropsch process 有权
标题翻译：费 - 托过程
公开(公告)号：US09029429B2
公开(公告)日：2015-05-12
申请号：US14364367
申请日：2012-12-10
申请人： Shell Oil Company
发明人： Maarten Bracht , Martin Philipp Rohde
IPC分类号： C07C27/06 , C07C1/04 , C01B3/36 , C01B3/38 , C10G2/00
CPC分类号： C07C1/04 , C01B3/36 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/062 , C01B2203/08 , C01B2203/1241 , C01B2203/1247 , C01B2203/141 , C01B2203/142 , C01B2203/1671 , C01B2203/168 , C10G2/32 , C10K3/06 , Y02P20/52
摘要： The present invention is directed to a process for the production of hydrocarbon product from two different hydrocarbonaceous feedstocks comprising the steps of preparing a feed syngas having a hydrogen/carbon monoxide [H2/CO] molar feed ratio suitable for Fischer-Tropsch synthesis, wherein the feed syngas is prepared by combining a first syngas having a H2/CO molar ratio below the molar feed ratio and a second syngas having a H2/CO molar ratio above the molar feed ratio; the first syngas is prepared from a liquid hydrocarbon comprising feedstock as the sole source of carbon in a first syngas manufacturing process comprising a non-catalytic partial oxidation step; the second syngas is prepared from a methane comprising feedstock as the sole source of carbon in a second syngas manufacturing process comprising a heat exchange reforming step and an auto-thermal reforming step; and the first and second syngas manufacturing processes are operated in parallel.
摘要翻译：本发明涉及从两种不同的烃类原料生产烃产物的方法，包括以下步骤：制备具有适用于费 - 托合成的氢/一氧化碳[H 2 / CO]摩尔进料比的进料合成气，其中通过将具有低于摩尔进料比的H 2 / CO摩尔比的第一合成气和H 2 / CO摩尔比高于摩尔进料比的第二合成气组合来制备进料合成气; 在包括非催化部分氧化步骤的第一合成气制备方法中，第一合成气由包含原料的液体烃制备为唯一的碳源，在包括热交换重整步骤和自动热重整步骤的第二合成气制造方法中，第二合成气由包含原料的甲烷作为唯一的碳源制备，并且第一和第二合成气制造工艺并行操作。

138. 发明授权

US08557729B2 Shaped heterogeneous catalysts 有权
标题翻译：异型非均相催化剂
公开(公告)号：US08557729B2
公开(公告)日：2013-10-15
申请号：US13063633
申请日：2009-08-24
申请人： Daniel Lee Cairns , Mileta Babovic , Terence James Fitzpatrick , Elizabeth Margaret Holt , Colin William Park , William Maurice Sengelow , Edmund Hugh Stitt
发明人： Daniel Lee Cairns , Mileta Babovic , Terence James Fitzpatrick , Elizabeth Margaret Holt , Colin William Park , William Maurice Sengelow , Edmund Hugh Stitt
IPC分类号： B01J21/18 , B01J27/236 , B01J23/00 , B01J23/10 , B01J23/40 , B01J23/42 , B01J23/56 , B01J23/58 , B01J23/02 , B01J23/08 , B01J21/04 , C10G35/00 , C10G45/00 , C10G17/00 , C01B21/00 , C01C1/00 , C07C27/00 , C07C27/06
CPC分类号： B01J37/0009 , B01J23/40 , B01J23/70 , B01J23/755 , B01J23/80 , B01J35/002 , B01J35/023 , B01J35/026
摘要： A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has two or more flutes running along its length, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst may be used particularly in reactions where hydrogen is a reactant such as hydroprocessing, hydrogenation, water-gas shift reactions, methanation, hydrocarbon synthesis by the Fischer-Tropsch reaction, methanol synthesis and ammonia synthesis.
摘要翻译：催化剂单元以具有长度C和直径D的圆柱体的形式描述，其具有沿其长度延伸的两个或更多个凹槽，其中所述圆筒具有长度为A和B的圆顶端，使得（A + B + C ）/ D在0.50〜2.00的范围内，（A + B）/ C在0.40〜5.00的范围内。催化剂可以特别用于其中氢是反应物的反应，例如加氢处理，氢化，水煤气变换反应，甲烷化，通过费 - 托反应的烃合成，甲醇合成和氨合成。

139. 发明授权

US08522573B2 Method for production of carbon dioxide and apparatus therefor 失效
标题翻译：生产二氧化碳的方法及其设备
公开(公告)号：US08522573B2
公开(公告)日：2013-09-03
申请号：US13372189
申请日：2012-02-13
申请人： P. Mark Golben
发明人： P. Mark Golben
IPC分类号： F25D25/00 , B01J19/00 , B01J8/00 , B01J8/04 , C07C27/00 , C07C27/06 , B01D53/14 , C01B6/24 , C01B3/02 , C01B3/26
CPC分类号： C10L1/04 , C01B3/0005 , C10G2/32 , C10L3/08 , C10L2290/42 , C25B1/04 , Y02E60/324 , Y02E60/366 , Y02E70/10 , Y02P20/134
摘要： A system for conversion of waste and solar heat energy into a carbon sequestration device, including as a collector for collecting carbon dioxide gas from a carbon dioxide gas source, such as ambient air. The Joule Thompson effect is used to cool and thereby refrigerate/liquefy ambient air and then extracting carbon dioxide therefrom, comprising steps of and means for providing a hydride heat engine, operating the hydride heat engine utilizing hydride thermal compression technology to compress hydrogen gas and thereby to cool ambient air to a temperature rendering air into a refrigerated/liquefied state by use of a Joule-Thompson type process, and extracting carbon dioxide from the refrigerated/liquefied ambient air and collecting the carbon dioxide.
摘要翻译：将废弃物和太阳能热能转换成碳封存装置的系统，包括作为用于从二氧化碳气体源（例如环境空气）收集二氧化碳气体的收集器。焦耳汤普森效应用于冷却，从而冷却/液化环境空气，然后从其中提取二氧化碳，包括提供氢化物热机的步骤和方法，利用氢化物热压技术来操作氢化物热机，以压缩氢气，从而通过使用焦耳汤普森型方法将环境空气冷却至使空气进入冷藏/液化状态的温度，并从冷藏/液化的环境空气中提取二氧化碳并收集二氧化碳。

140. 发明授权

US08507566B2 Process for the preparation of synthesis gas 有权
标题翻译：合成气的制备方法
公开(公告)号：US08507566B2
公开(公告)日：2013-08-13
申请号：US12310488
申请日：2007-09-07
申请人： Siebolt Doorn
发明人： Siebolt Doorn
IPC分类号： C01B3/22 , C01B3/24 , C01B3/26 , C07C27/06
CPC分类号： C01B3/32 , C01B3/323 , C01B2203/0216 , C01B2203/0233 , C01B2203/061 , C01B2203/1058 , C01B2203/1217 , C01B2203/1288
摘要： Process for the production of synthesis gas which involves the steps of: a) preparing a vapor phase mixture comprising steam and at least one hydrocarbon or oxygenated hydrocarbon with an atmospheric boiling point in the range of −50 to 370° C., said vapor phase mixture having a H2O/C molar ratio at least 2, and b) catalytically or non-catalytically converting the vapor phase mixture into synthesis gas, which process is characterized in that the oxygen is only added in bonded form.
摘要翻译：制备合成气的方法，其包括以下步骤：a）制备包含蒸汽和至少一种烃 - 或氧化烃的气相混合物，其常压沸点在-50至370℃的范围内，所述气相 H 2 O / C摩尔比至少为2的混合物，以及b）将气相混合物催化或非催化转化成合成气，该方法的特征在于仅以键合形式加入氧气。

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