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    • 138. 发明授权
    • Process for making low density foams, polyol composition and reaction system useful therefor
    • 制备低密度泡沫的方法,多元醇组合物和对其有用的反应体系
    • US06590008B1
    • 2003-07-08
    • US09979849
    • 2002-03-01
    • Alain ParfondryJianming Yu
    • Alain ParfondryJianming Yu
    • C08G1810
    • C08G18/4072C08G18/4816C08G2101/0008C08G2101/005C08G2101/0083
    • The invention relates to a polyol composition comprising by weight 60-97% of b1) a polyoxyethylene-polyoxypropylene polyol, having a functionality of 2-6, with 10-25% tipped EO, 3-40% of b2) a polyoxyethylene-polyoxypropylene polyol, having a functionality of 2-6, with 20-50% total EO and 10-20% tipped EO; and 0-25% of b3) a polyol, having a functionality of 2-6, with at least 50% random EO. The invention also relates to a process for preparing a flexible polyurethane foam by reacting a) a polyisocyanate composition; b) a polyol composition of the invention; c) water; and d) additives and auxiliaries known per se. The invention finally relates to a reaction system comprising A) a polyisocyanate and B) an isocyanate-reactive component comprising the polyol of the invention.
    • 本发明涉及一种多元醇组合物,该组合物包含重量百分比为60-97%的b1)聚氧乙烯 - 聚氧丙烯多元醇,其官能度为2-6,具有10-25%的EO,3-40%的b2)聚氧乙烯 - 聚氧丙烯 多官能度为2-6,总EO为20-50%,末端EO为10-20%的多元醇; 和0-25%的b3)官能度为2-6的多元醇,具有至少50%的随机EO。 本发明还涉及通过使a)多异氰酸酯组合物与多异氰酸酯组合物反应来制备软质聚氨酯泡沫的方法; b)本发明的多元醇组合物; c)水; 和d)本身已知的添加剂和助剂。 本发明最终涉及包含A)多异氰酸酯和B)包含本发明多元醇的异氰酸酯反应性组分的反应体系。
    • 139. 发明授权
    • Method and compositions for spray molding polyurethane three dimensional objects
    • 喷涂聚氨酯三维物体的方法和组成
    • US06362302B1
    • 2002-03-26
    • US09449871
    • 1999-11-29
    • Carl E. Boddie
    • Carl E. Boddie
    • C08G1832
    • C08G18/6685C08G18/0885C08G18/222C08G18/3256C08G18/4816C08G18/7671
    • A method of producing three dimensional polyurethane shapes by spray molding a quasi-gel like polymer precursor composition that is first mixed and then sprayed by a spray gun. The spray coating of quasi-gel polymer precursor composition subsequently cures to form a molded polyurethane polymer shape. Such artificial three dimensional shapes may include rocks, rock walls or faces, tree stumps or limbs, animals, architectural features or settings in which a certain visual appearance is desired. The method includes: creating a mold and supporting cradle having a mold cavity conforming to the exterior of shape desired, the mold having a substantial degree of flexibility; spraying a quasi-gel polymer precursor composition into the mold cavity, the quasi-gel polymer precursor composition comprising a mixture of an isocyanate portion and a curative portion and being mixed prior to introduction into a spray gun, carrying out the spraying to build up the molded three dimensional shape to a desired thickness and stripping the cradle and mold from the molded polyurethane three dimensional shape after the curing of the quasi-gel polymer precursor.
    • 通过喷射模制准凝胶状聚合物前体组合物来生产三维聚氨酯形状的方法,其首先混合然后通过喷枪喷雾。 随后固化准凝胶聚合物前体组合物的喷涂以形成模塑的聚氨酯聚合物形状。 这种人造三维形状可以包括需要某种视觉外观的岩石,岩石墙壁或面部,树桩或四肢,动物,建筑特征或设置。 该方法包括:产生具有与所需形状相符的模腔的模具和支撑支架,模具具有相当大的灵活性; 将准凝胶聚合物前体组合物喷射到模腔中,准凝胶聚合物前体组合物包含异氰酸酯部分和固化部分的混合物,并在引入喷枪之前混合,进行喷雾以建立 模制的三维形状达到所需厚度,并且在准凝胶聚合物前体固化之后从模制的聚氨酯三维形状中剥离托架和模具。