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131. 发明申请

US20100305360A1 Purification of acetic acid from wood acetylation process using extraction 失效
公开(公告)号：US20100305360A1
公开(公告)日：2010-12-02
申请号：US12806349
申请日：2010-08-11
申请人： R. Jay Warner , Melchior A. Meilchen
发明人： R. Jay Warner , Melchior A. Meilchen
IPC分类号： C07C51/48
CPC分类号： C07C51/48 , C07C53/08
摘要： There is shown a method of purifying glacial acetic acid containing terpene and terpenoid impurities. Substantially dry acetic acid containing terpene and terpenoid impurities is combined with water and a suitable organic solvent, which is substantially immiscible with acetic acid and water, to form a separating composite extraction medium having a weight ratio of acetic acid:water of at least 1:1. The components are separated into an organic phase and an aqueous acid phase, with the terpene and terpenoid impurities concentrated in the organic phase, and with the aqueous acid phase purified of terpene and terpenoid impurities. The purified aqueous acid phase is recovered, and the purified acetic acid is dried.

132. 发明申请

US20090234157A1 Purification of acetic acid from wood acetylation process using extraction 失效
标题翻译：使用提取从木材乙酰化工艺中纯化乙酸
公开(公告)号：US20090234157A1
公开(公告)日：2009-09-17
申请号：US12075928
申请日：2008-03-14
申请人： R. Jay Warner , Melchior A. Meilchen
发明人： R. Jay Warner , Melchior A. Meilchen
IPC分类号： C07C53/08
CPC分类号： C07C51/48 , C07C53/08
摘要： There is shown a method of purifying glacial acetic acid containing terpene and terpenoid impurities. Substantially dry acetic acid containing terpene and terpenoid impurities is combined with water and a suitable organic solvent, which is substantially immiscible with acetic acid and water, to form a separating composite extraction medium having a weight ratio of acetic acid:water of at least 1:1. The components are separated into an organic phase and an aqueous acid phase, with the terpene and terpenoid impurities concentrated in the organic phase, and with the aqueous acid phase purified of terpene and terpenoid impurities. The purified aqueous acid phase is recovered, and the purified acetic acid is dried.
摘要翻译：显示了一种纯化含有萜烯和萜类杂质的冰醋酸的方法。将含有萜烯和萜类杂质的基本干燥的乙酸与水和与乙酸和水基本上不混溶的合适的有机溶剂结合形成分离复合萃取介质，其重量比为乙酸：水至少为1： 1。将组分分离成有机相和酸性水相，萜烯和萜类杂质浓缩在有机相中，并且酸水相含有纯化的萜烯和萜类杂质。回收纯化的含水酸相，干燥纯化的乙酸。

133. 发明授权

US6143930A Removal of permanganate reducing compounds and alkyl iodides from a carbonylation process stream 失效
公开(公告)号：US6143930A
公开(公告)日：2000-11-07
申请号：US951952
申请日：1997-10-17
申请人： Madan Singh , George A. Blay , Michael L. Karnilaw , Melchior A. Meilchen , Wayne David Picard , Valerie Santillan , Mark O. Scates , Robin Suzanne Tanke , G. Paull Torrence , Richard F. Vogel, Jr. , R. Jay Warner
发明人： Madan Singh , George A. Blay , Michael L. Karnilaw , Melchior A. Meilchen , Wayne David Picard , Valerie Santillan , Mark O. Scates , Robin Suzanne Tanke , G. Paull Torrence , Richard F. Vogel, Jr. , R. Jay Warner
IPC分类号： B01J27/32 , B01J38/00 , C07C51/00 , C07C51/12 , C07C51/44 , C07C51/48 , C07C53/08 , C08G2/12 , C08G2/28 , C07C51/42 , C07C67/36
CPC分类号： C07C51/44 , C07C51/12 , C07C51/48
摘要： Disclosed is a method to manufacture high purity acetic acid. Although described in relation to that produced by a low water carbonylation process the present invention is applicable to other mechanisms for production of acetic acid which results in formation of permanganate reducing compounds such as acetaldehyde, propionic acid, and alkyl iodide impurities in intermediate process streams. It has been found that permanganate reducing compounds and alkyl iodides may be conveniently removed from a light phase of an intermediate stream in the reaction process by employing a multiple distillation process coupled with an optional extraction of acetaldehyde. The distillation process involves first distilling a light phase to concentrate the permanganate reducing compounds, and in particular the acetaldehyde, and then separating the permanganate reducing compounds and alkyl iodides in a second distillation tower. The second distillation serves to remove the permanganate reducing compounds and alkyl iodides from methyl iodide, methyl acetate, and methanol mixture. As an optional third step, the twice distilled stream may be directed to an extractor to remove any remaining quantities of methyl iodide from the aqueous acetaldehyde stream to obtain acetic acid as a final product in greater than 99% purity.It has been found that this process removes at least 50% of the permanganate reducing compounds and alkyl iodides and at least 20% of the propionic acid impurity from the intermediate light phase stream, and results in lower alkyl iodide concentration in the carbonylation reaction process, and in particular in the carbonylation reactor.It has also been found that during shut down of the inventive process, polymers of acetaldehyde tend to form in the base of the second distillation tower. To avoid or minimize the formation of these polymers, a constant flow of solvent is passed through the base of the column.

134. 发明授权

US08927788B2 Process to recover alcohol with reduced water from overhead of acid column 有权
标题翻译：从酸塔塔顶馏出水中还原水回收酒精的方法
公开(公告)号：US08927788B2
公开(公告)日：2015-01-06
申请号：US13457280
申请日：2012-04-26
申请人： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
发明人： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
IPC分类号： C07C29/149 , C07C29/80 , C07C27/04 , C07C51/12 , C07C67/08 , C07C67/54
CPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C29/84 , C07C51/12 , C07C67/08 , C07C67/54 , C10L1/02 , C10L2200/04 , C10L2290/543 , C10L2290/548 , C07C31/08 , C07C53/08 , C07C69/14
摘要： A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
摘要翻译：一种从乙酸氢化中回收乙醇的方法。将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。从残余物流中回收乙醇产物。

135. 发明授权

US08907141B2 Process to recover alcohol with secondary reactors for esterification of acid 有权
标题翻译：用二级反应器回收酒精的方法用于酯化酸
公开(公告)号：US08907141B2
公开(公告)日：2014-12-09
申请号：US13456594
申请日：2012-04-26
申请人： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
发明人： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
IPC分类号： C07C29/12 , C07C51/12 , C07C67/08 , C07C29/149 , C07C29/80
CPC分类号： C07C29/80 , C07C29/149 , C07C51/12 , C07C67/08 , C07C31/08 , C07C53/08 , C07C69/14
摘要： A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. Unreacted acetic acid can be reduced or removed through configurations of esterification secondary reactors. The ethanol product is recovered from the residue stream.
摘要翻译：一种从乙酸氢化中回收乙醇的方法。将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。未反应的乙酸可以通过酯化二级反应器的构型被还原或除去。从残余物流中回收乙醇产物。

136. 发明授权

US08884081B2 Integrated process for producing acetic acid and alcohol 有权
标题翻译：生产乙酸和酒精的综合方法
公开(公告)号：US08884081B2
公开(公告)日：2014-11-11
申请号：US13094661
申请日：2011-04-26
申请人： R. Jay Warner , Victor J. Johnston , David Lee , Manuel Salado , Mark O. Scates
发明人： R. Jay Warner , Victor J. Johnston , David Lee , Manuel Salado , Mark O. Scates
IPC分类号： C07C31/08 , C07C67/08 , C07C29/90 , C07C29/149 , C07C29/80
CPC分类号： C07C29/90 , C07C29/149 , C07C29/80 , C07C67/08 , Y02P20/125 , Y02P20/127 , C07C31/08 , C07C69/14
摘要： The present invention relates generally to processes for producing ethanol and acetic acid and, in particular, to a process for integrating an ethanol production process with an acetic acid production process.
摘要翻译：本发明一般涉及生产乙醇和乙酸的方法，尤其涉及将乙醇生产过程与乙酸生产过程相结合的方法。

137. 发明授权

US08829251B2 Liquid esterification method to produce ester feed for hydrogenolysis 有权
标题翻译：液体酯化法生产酯原料用于氢解
公开(公告)号：US08829251B2
公开(公告)日：2014-09-09
申请号：US13299798
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana H. Sonnenberg
IPC分类号： C07C29/149 , C07C67/08 , C07C29/80
CPC分类号： C07C29/149 , C07C29/80 , C07C67/08 , C07C31/08 , C07C69/14
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying, in the liquid phase, acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.
摘要翻译：本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。该方法包括在液相中酯化乙酸和醇如乙醇以产生酯化产物。在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。

138. 发明授权

US08802901B2 Continuous ethyl acetate production and hydrogenolysis thereof 有权
标题翻译：连续的乙酸乙酯生产和氢解
公开(公告)号：US08802901B2
公开(公告)日：2014-08-12
申请号：US13299878
申请日：2011-11-18
申请人： R. Jay Warner , Wei Qi , Tatiana Sonnenberg
发明人： R. Jay Warner , Wei Qi , Tatiana Sonnenberg
IPC分类号： C07C27/06 , C07C27/08 , C07C27/30 , C07C31/08
CPC分类号： C07C29/80 , C07C27/06 , C07C27/08 , C07C27/30 , C07C29/86 , C07C29/92 , C07C31/08
摘要： Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture. Ethyl acetate from the crude reaction mixture may be recovered as returned to assist in recovering the esterification product.
摘要翻译：本文公开了通过还原酯化产物如乙酸乙酯生产醇的方法。该方法包括酯化乙酸和醇如乙醇以产生酯化产物。在催化剂存在下，用氢还原酯化产物，得到包含可与粗反应混合物分离的醇，特别是乙醇的粗反应混合物。可以从粗反应混合物中回收乙酸乙酯以帮助回收酯化产物。

139. 发明授权

US08759576B2 Processes for purifying acetic anhydride 有权
标题翻译：乙酸酐纯化方法
公开(公告)号：US08759576B2
公开(公告)日：2014-06-24
申请号：US13605278
申请日：2012-09-06
申请人： R. Jay Warner , Melchoir Meilchen , Nathan Kirk Powell
发明人： R. Jay Warner , Melchoir Meilchen , Nathan Kirk Powell
IPC分类号： C07C51/573 , C07C53/12
CPC分类号： C07C53/12 , C07C51/56 , C07C51/573
摘要： In one embodiment, the invention is to a process for purifying acetic anhydride. The process includes the steps of feeding a liquid crude acetic anhydride stream directly to a distillation column and separating the liquid crude acetic anhydride stream to produce a light ends stream, a sidedraw and a residue stream. The sidedraw comprises substantially pure acetic anhydride product. The distillation column is operated at a pressure less than 101 kPa. The substantially pure acetic anhydride product comprises greater than 98 wt. % acetic anhydride, has a permanganate time of greater than 10 minutes, and has an APHA color of less than 10.
摘要翻译：在一个实施方案中，本发明涉及纯化乙酸酐的方法。该方法包括以下步骤：将液体粗乙酸酐流直接供给到蒸馏塔中，并分离液体粗乙酸酐流以产生轻馏分物流，侧刮和残留物流。侧面包括基本上纯的乙酸酐产物。蒸馏塔在低于101kPa的压力下运行。基本上纯的乙酸酐产物包含大于98wt。％乙酸酐，高锰酸盐时间大于10分钟，APHA颜色小于10。

140. 发明授权

US08653303B2 Processes for preparing acetic anhydride 有权
标题翻译：制备乙酸酐的方法
公开(公告)号：US08653303B2
公开(公告)日：2014-02-18
申请号：US13359060
申请日：2012-01-26
申请人： R. Jay Warner , Melchoir Meilchen
发明人： R. Jay Warner , Melchoir Meilchen
IPC分类号： C07C51/54
CPC分类号： C07C51/56 , C07C51/12 , C07C51/573 , C07C53/08 , C07C53/12
摘要： In one embodiment, the invention is to a process for producing acetic anhydride. The process includes at least a step of carbonylating methanol and/or a methanol derivative with carbon monoxide to form acetic acid, and contacting ketene with the acetic acid to form a crude acetic anhydride product stream and a vent stream having unreacted ketene. The process further comprises a step of directing at least a portion of the vent stream to a liquid ring vacuum compressor having a ring seal fluid comprising acetic acid The unreacted ketene in the portion of the vent stream contacts the ring seal fluid to form supplemental acetic anhydride.
摘要翻译：在一个实施方案中，本发明涉及一种生产乙酸酐的方法。该方法至少包括使甲醇和/或甲醇衍生物与一氧化碳羰化以形成乙酸的步骤，并使乙烯酮与乙酸接触以形成粗乙酸酐产物流和具有未反应的乙烯酮的排放流。该方法还包括将排气流的至少一部分引导到具有包含乙酸的环密封流体的液环真空压缩机的步骤。排气流的部分中的未反应的烯酮与环密封流体接触以形成补充的乙酸酐。

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