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131. 发明授权

US3943170A Process for the preparation of halo-methylphosphinic acid halides 失效
标题翻译：制备卤代甲基次膦酸卤化物的方法
公开(公告)号：US3943170A
公开(公告)日：1976-03-09
申请号：US420696
申请日：1973-11-30
申请人： Hans-Jerg Kleiner
发明人： Hans-Jerg Kleiner
IPC分类号： C07F9/30 , C07F9/34
CPC分类号： C07F9/34
摘要： A process for the preparation of halo-methylphosphinic acid halides of the formula I ##EQU1## where R.sub.1 is alkyl, aralkyl or aryl having from 1 to 18 carbon atoms, and X is halogen, which comprises reacting phosphinic acid derivatives of the formula II ##EQU2## where R.sub.1 is as defined above and R.sub.2 is alkyl having from 1 to 18 carbon atoms optionally being substituted by halogen, hydrogen or a monovalent cation, with acid halides of the formula III(co).sub.n X.sub.2 (III)where n is 1 or 2 and X is halogen.
摘要翻译：制备式I的卤代甲基次膦酸卤化物的方法R1 ANGLE PX（I）PARALLEL XCH2O其中R1是具有1至18个碳原子的烷基，芳烷基或芳基，X是卤素，其包括使次膦酸衍生物式II R1 ANGLE PO-R2（II）平行HOCH 2 O其中R 1如上所定义，R 2是具有1至18个碳原子的烷基，任选被卤素，氢或一价阳离子取代，与式III的酰卤反应（CO）n X 2（III）其中n为1或2，X为卤素。

132. 发明授权

US06365071B1 Synergistic flame protection agent combination for thermoplastic polymers 有权
标题翻译：用于热塑性聚合物的协同阻燃剂组合
公开(公告)号：US06365071B1
公开(公告)日：2002-04-02
申请号：US09171031
申请日：1999-01-29
申请人： Elke Jenewein , Hans-Jerg Kleiner , Wolfgang Wanzke , Winfried Budzinsky
发明人： Elke Jenewein , Hans-Jerg Kleiner , Wolfgang Wanzke , Winfried Budzinsky
IPC分类号： C09K2104
CPC分类号： C08K5/5313 , C08K5/3445 , C08K5/34924 , C08K5/34928 , C08L67/02 , C08L85/00
摘要： The present invention relates to a synergistic flame retardant combination for thermoplastic polymers, preferably engineering plastics, especially for polyesters, which as component A comprises a phosphinic salt of the formula (I) defined in the description and/or a diphosphinic salt of the formula (II) and/or polymers thereof, and as component B comprises a nitrogen compound of the formula (III) to (VIII) defined in the description, or a mixture of the compounds represented by the formulae.
摘要翻译：本发明涉及用于热塑性聚合物，优选工程塑料，特别是聚酯的协同阻燃剂组合物，其作为组分A包含在说明书中定义的式（I）的次膦酸盐和/或下式的二膦酸盐（ II）和/或其聚合物，并且组分B包含在说明书中定义的式（III）至（VIII）的氮化合物或由式表示的化合物的混合物。

133. 发明授权

US06303674B1 Aluminium salts of alkylhydroxymethylphosphinic acids 失效
标题翻译：烷基羟甲基次膦酸的铝盐
公开(公告)号：US06303674B1
公开(公告)日：2001-10-16
申请号：US09380669
申请日：1999-12-06
申请人： Hans-Jerg Kleiner
发明人： Hans-Jerg Kleiner
IPC分类号： C08J320
CPC分类号： C08K5/5313 , C07F9/301
摘要： Aluminum salts of alkylhydroxymethylphosphinic acids are prepared by reacting phosphonous acids with aluminum hydroxide or paraformaldehyde or trioxane or mixtures thereof in water at 110 to 250° C. under pressure. The resulting aluminumphosphinates are incorporated into polymers, in particular into polyesters, and have a flame retardant action therein.
摘要翻译：通过使磷酸与氢氧化铝或多聚甲醛或三恶烷或其混合物在110-250℃的压力下在水中反应制备烷基羟甲基次膦酸的铝盐。所得到的铝磷酸盐掺入聚合物中，特别是聚酯中，并在其中具有阻燃作用。

134. 发明授权

US06194605B1 Process for preparing aluminum salts of dialkylphosphinic acids and diphosphinic acids 有权
标题翻译：制备二烷基次膦酸和二次膦酸的铝盐的方法
公开(公告)号：US06194605B1
公开(公告)日：2001-02-27
申请号：US09319712
申请日：1999-06-10
申请人： Hans-Jerg Kleiner
发明人： Hans-Jerg Kleiner
IPC分类号： C07F930
CPC分类号： C07F9/305 , C07F9/30 , C08K5/5313
摘要： A process for preparing aluminum salts (I) of dialkylphosphinic acids or (formula (II)) of alkylated diphosphinic acids where R1 and R2 are a linear or branched C1-C8-alkyl radical and R3 is a linear or branched C1-C10-alkylene radical or an arylene radical or an alkylarylene radical or an arylalkylene radical, which comprises reacting a dialkylphosphinic acid ester of the formula (III) or a diphosphinic acid ester of the formula (IV) where R1, R2 and R3 are as defined above and R4 is a linear or branched C1-C8-alkyl radical, in the presence of a saturated aliphatic monocarboxylic acid having a total of from 1 to 7 carbon atoms, with aluminum hydroxide at a temperature of from 150 to 350° C.
摘要翻译：制备烷基化二膦酸的二烷基次膦酸或（式（II））的铝盐（I）的方法，其中R 1和R 2是直链或支链C 1 -C 8 - 烷基，R 3是直链或支链C 1 -C 10亚烷基或亚芳基或烷基亚芳基或芳基亚烷基，其包括使式（III）的二烷基次膦酸酯或式（IV）的二膦酸酯与其中R 1，R 2和R 3如上所定义的二次膦酸酯反应，并且R 4是直链或支链在具有总共1至7个碳原子的饱和脂肪族单羧酸的存在下，在氢氧化铝的温度为150-350℃下加入C 1 -C 8烷基。

135. 发明授权

US06013707A Flameproofed polyester molding compositions 失效
标题翻译：防火聚酯成型组合物
公开(公告)号：US06013707A
公开(公告)日：2000-01-11
申请号：US94278
申请日：1998-06-09
申请人： Hans-Jerg Kleiner , Winfried Budzinsky , Gunther Kirsch
发明人： Hans-Jerg Kleiner , Winfried Budzinsky , Gunther Kirsch
IPC分类号： C07F9/30 , C08K5/00 , C08K5/5313 , C08L67/00 , C08L67/02 , C08L85/02
CPC分类号： C08K5/0091 , C07F9/30 , C08K5/5313
摘要： Polyesters such as polyethylene terephthalate or polybutylene terephthalate are provided with a flame-retardant finish by addition of calcium salts or aluminum salts of phosphinic or diphosphinic acids.
摘要翻译：诸如聚对苯二甲酸乙二醇酯或聚对苯二甲酸丁二醇酯的聚酯通过加入次膦酸或二次膦酸的钙盐或铝盐来提供阻燃整理剂。

136. 发明授权

US5880247A Phosphorus-containing dicarboxylic acid (anhydride)-modified epoxy resin 失效
标题翻译：含磷二羧酸（酸酐）改性环氧树脂
公开(公告)号：US5880247A
公开(公告)日：1999-03-09
申请号：US827436
申请日：1997-03-27
申请人： Sebastian Horold , Hans-Jerg Kleiner
发明人： Sebastian Horold , Hans-Jerg Kleiner
IPC分类号： B05D7/24 , B32B27/38 , C08G59/12 , C08G59/14 , C08G59/30 , C08G59/40 , C08G59/42 , C09D5/18 , C09K21/12 , H05K1/03 , C08L63/02
CPC分类号： C08G59/4071 , C08G59/12 , C08G59/304 , H05K1/0326
摘要： The invention relates to a phosphorus-modified epoxy resin having an epoxide value of from 0.05 to 0.6 mol/100 g comprising structural units derived from(A) polyepoxide compounds having at least two epoxide groups per molecule and(B) phosphorus-containing dicarboxylic acids or phosphorus-containing carboxylic anhydrides,to a process for their preparation and to their use.
摘要翻译：本发明涉及环氧化物值为0.05-0.6mol / 100g的磷改性环氧树脂，其包含衍生自（A）每分子具有至少两个环氧基团的聚环氧化物化合物的结构单元和（B）含磷二羧酸或含磷羧酸酐，其制备方法及其用途。

137. 发明授权

US5847184A Process for preparing phosphorus-containing dicarboxylic acids 失效
标题翻译：制备含磷二羧酸的方法
公开(公告)号：US5847184A
公开(公告)日：1998-12-08
申请号：US532114
申请日：1995-09-22
申请人： Hans-Jerg Kleiner
发明人： Hans-Jerg Kleiner
IPC分类号： C07F9/6574 , C07F9/50 , C07F9/53 , C07F9/6571 , C08K5/53 , C08K5/5357 , C07F9/141 , C08G63/692
CPC分类号： C07F9/657172 , C07F9/5304
摘要： The present invention relates to a process for preparing of phosphorus-containing dicarboxylic acids of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are identical or different and are each a straight-chain or branched alkyl radical having from 1 to 8 carbon atoms, a cycloaliphatic radical having 5 or 6 carbon atoms in the ring, an unsubstituted or substituted aryl radical having from 6 to 10 carbon atoms, or R.sup.1 and R.sup.2 form, with inclusion of the phosphorus atom, a ring having from 5 to 8 members, and m and n are each, independently of one another 0 or 1, by reacting a compound of the formula (II) ##STR2## where R.sup.1, R.sup.2 and m are as defined above, with fumaric acid, maleic acid or itaconic acid in the presence of a saturated aliphatic monocarboxylic acid having a total of from 1 to 5 carbon atoms as solvent at from 100.degree. to 200.degree. C. under atmospheric pressure or superatmospheric pressure.
摘要翻译：本发明涉及制备式（I）的含磷二羧酸的方法，其中R 1和R 2相同或不同，并且各自是直链或支链的烷基，其具有1至 8个碳原子，环中具有5或6个碳原子的脂环族基团，未取代或取代的具有6至10个碳原子的芳基，或R 1和R 2形成，包括磷原子，具有5至 8个成员，m和n各自彼此独立地为0或1，其中R1，R2和m如上所定义的式（II）化合物（II）与富马酸，马来酸在饱和脂肪族单羧酸的存在下，在大气压或超大气压下，在100〜200℃下，在总共1〜5个碳原子的溶剂存在下，使用酸或衣康酸。

138. 发明授权

US5801291A Process for the preparation of aldehydes by means of a catalyst system comprising rhodium and substituted diphenyldiphospines 失效
标题翻译：通过包含铑和取代的二苯基二磷的催化剂体系制备醛的方法
公开(公告)号：US5801291A
公开(公告)日：1998-09-01
申请号：US813877
申请日：1997-03-07
申请人： Helmut Bahrmann , Hans-Jerg Kleiner , Dieter Regnat
发明人： Helmut Bahrmann , Hans-Jerg Kleiner , Dieter Regnat
IPC分类号： B01J31/24 , B01J31/28 , B01J31/40 , C07B61/00 , C07C45/50 , C07C45/78 , C07C47/02
CPC分类号： B01J31/04 , B01J31/2409 , B01J31/2414 , B01J31/2452 , B01J31/4046 , B01J31/4061 , C07C45/50 , C07C45/786 , B01J2231/321 , B01J2531/822 , B01J2540/40 , B01J2540/42 , Y02P20/584
摘要： The present invention relates to a process for the preparation of aldehydes, which comprises reacting an olefinic compound having 2 to 20 carbon atoms with carbon monoxide and hydrogen, in the presence or absence of a solvent, in the presence of a catalyst comprising rhodium and a compound or a mixture of compounds of the formula (I) ##STR1## in which R.sup.1 is H or an alkyl radical having 1 to 12 carbon atoms, R.sup.2 is a straight-chain alkylene radical having 1 to 8 carbon atoms, an oxygen-containing alkylene radical having 2 to 4 carbon atoms, a radical of the formula (II) or (III) ##STR2## or a cycloalkylene radical having 3 to 10 carbon atoms, R.sup.3 is an alkyl radical having 1 to 25 carbon atoms or an aryl radical having 6 to 10 carbon atoms, A is a radical --COO.sup.- or --SO.sub.3.sup.- and x=0, y=1, m=1 and n=1, or x=0.1, y=1, m=(1 or 2) and n=(1 or 2), or, if R.sup.2 is a radical of the formula (II) or (III), x=1, y=0, m=(0 or 1) and n=(0 or 1), at a temperature from 50.degree. to 190.degree. C. and under a pressure from 0.1 to 45 MPa, and separating the reaction product off from the catalyst.
摘要翻译：本发明涉及醛的制备方法，其包括在存在或不存在溶剂的情况下，使含有2-20个碳原子的烯属化合物与一氧化碳和氢反应，在包含铑和化合物或其中R 1为H或具有1至12个碳原子的烷基的式（I）化合物（I）的化合物，R 2为具有1至8个碳原子的直链亚烷基，具有2至4个碳原子的含氧亚烷基，式（II）或（III）的基团（III）或具有3至10个碳原子的亚环烷基，R 3是具有1至25个碳原子的烷基或具有6至10个碳原子的芳基，A是基团-COO-或-SO 3 - ，x = 0，y = 1，m = 1和n = 1，或x = 0.1，y = 1，m =（1或2）和n =（1或2），或者如果R2是式（II）或（III）的基团，x = 1，y = 0，m = （0或1）和n =（0或1），在50°至190℃的温度下并在0.1至45MPa的压力下，将反应产物与催化剂分离。

139. 发明授权

US5789623A Process for the preparation of hydroxybiarylphosphines and novel compounds of this group of substances 失效
标题翻译：制备羟基联芳基膦的方法和该组物质的新化合物
公开(公告)号：US5789623A
公开(公告)日：1998-08-04
申请号：US661629
申请日：1996-06-11
申请人： Dieter Regnat , Hans-Jerg Kleiner
发明人： Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07C45/50 , C07F9/50 , C07F9/6568 , C07F9/52
CPC分类号： C07F9/65683 , C07C45/505 , C07F9/5022 , C07F9/5068 , C07F9/5081
摘要： The present invention relates to a hydroxybiarylphosphines of the formula ##STR1## in which Ar-Ar is biphenyl, 1-phenyinaphthyl or 1,1'-binaphthyl, R.sup.1 and R.sup.2 are identical or different and are F or alkoxy having in each case 1 to 8 carbon atoms or are substituted or unsubstituted aryl, a and b are identical or different and are an integer from 0 to 4, in which R.sup.3 and R.sup.4 are identical or different and are alkyl having 1 to 8 carbon atoms, cycloalkyl having 4 to 10 carbon atoms, alkaryl having 7 to 9 carbon atoms, Ar.sup.3 --(R.sup.5).sub.n, in which A.sup.3 is an aryl radical having 6 to 10 carbon atoms, R.sup.5 is CF.sub.3, dialkylamino having a total of 2 to 8 carbon atoms or --CH.sub.2 N(alkyl).sub.2 having 1 to 3 carbon atoms per alkyl and n is an integer from 0 to 5, or --R.sup.3 --R.sup.4 -- forms a chain of 3 to 5 members to which one or two aromatic rings or ring systems having 6 to 10 carbon atoms are optionally fused together with the P atom, forms a ring having 4 to 6 members, with the proviso that Ar.sup.3 --(R.sup.5).sub.n is not phenyl or a phenyl substituted by halogen, alkyl or alkoxy each having 1 to 8 carbon atoms, if Ar-Ar is bipohenyl or 1,1'-binaphthyl and a.dbd.b.dbd.0 and R.sup.3 and R.sup.4 are identical in each case.
摘要翻译：本发明涉及下式的羟基联芳基膦：其中Ar-Ar为联苯基，1-苯基萘基或1,1'-联萘，R 1和R 2相同或不同，为各自为F或烷氧基 1至8个碳原子或为取代或未取代的芳基，a和b相同或不同，为0至4的整数，其中R 3和R 4相同或不同，为具有1至8个碳原子的烷基，环烷基具有 4至10个碳原子，具有7至9个碳原子的烷芳基，Ar 3 - （R 5）n，其中A 3是具有6至10个碳原子的芳基，R 5是CF 3，具有2至8个碳原子的二烷基氨基或每个烷基具有1至3个碳原子的-CH 2 N（烷基）2，n是0至5的整数，或-R 3 -R 4形成3至5个成员的链，其中一个或两个芳环或环系具有6个至10个碳原子任选地与P原子稠合在一起形成具有4至6个成员的环，条件是Ar 3 - （R 5）n不是苯基或phe 如果Ar-Ar是二苯基或1,1'-联萘，并且a = b = 0，并且R 3和R 4在每种情况下相同，则被卤素，烷基或烷氧基各自具有1至8个碳原子取代。

140. 发明授权

US5773556A Low-flammability polyamide molding materials 失效
标题翻译：低可燃性聚酰胺成型材料
公开(公告)号：US5773556A
公开(公告)日：1998-06-30
申请号：US806479
申请日：1997-02-27
申请人： Hans-Jerg Kleiner , Winfried Budzinsky , Gunther Kirsch
发明人： Hans-Jerg Kleiner , Winfried Budzinsky , Gunther Kirsch
IPC分类号： C08K5/5313 , C08K7/14 , C08L77/00 , C08G69/42 , C08G79/02 , C08K5/53
CPC分类号： C08K5/5313 , B29L2031/3493
摘要： Low-flammability polyamide molding materials are obtained by admixing calcium or aluminum phosphinates. These salts confer improved flame protection on polyamides compared with other metal salts.
摘要翻译：通过混合钙或铝次膦酸盐获得低可燃性聚酰胺成型材料。与其他金属盐相比，这些盐赋予聚酰胺更好的火焰保护作用。

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