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    • 123. 发明授权
    • Pi-conjugated organoboron polymers in thin-film organic electronic devices
    • 在薄膜有机电子器件中的π共轭有机硼聚合物
    • US08097348B2
    • 2012-01-17
    • US12293372
    • 2007-03-19
    • Silvia DeVito LuebbenShawn Sapp
    • Silvia DeVito LuebbenShawn Sapp
    • H01L51/54
    • H01L51/0035C08G79/08C08G2261/94C09K11/06C09K2211/1425C09K2211/1433C09K2211/1466C09K2211/1475C09K2211/1483H01L51/0039H01L51/004H01L51/0043H01L51/008H01L51/0541H01L51/0545H01L51/4246H01L51/4253H01L51/5012H05B33/14Y02E10/549Y10S428/917
    • Pi-conjugated organoboron polymers for use in thin-film organic polymer electronic devices. The polymers contain aromatic and or unsaturated repeat units and boron atoms. Pi-conjugated organoboron polymers which are end capped, derivatized with solubilizing groups or both exhibit improved solubility and handling properties beneficial for the formation of thin films useful for device fabrication. The vacant p-orbital of the boron atoms conjugate with the pi-conjugated orbital system of the aromatic or unsaturated monomer units extending the pi-conjugation length of the polymer across the boron atoms. The pi-conjugated organoboron polymers are electron-deficient and, therefore, exhibit n-type semiconducting properties, photoluminescence, and electroluminescence. The invention provides thin-film organic polymer electronic devices, such as organic photovoltaic cells (OPVs), organic diodes, organic photodiodes, organic thin-film transistors (TFTs), organic field-effect transistors (OFETs), printable or flexible electronics, such as radio-frequency identification (RFID) tags, electronic papers, and printed circuit elements, organic light-emitting diodes (OLEDs), polymer light-emitting diodes (PLEDs), and energy storage devices employing the pi-conjugated organoboron polymers. In OLED and PLED applications these materials are used as the electron transport layer (ETL) to improve device efficiency. The polymers which exhibit photo- and electroluminescence are also useful as light-emitting material in PLEDs.
    • 用于薄膜有机聚合物电子器件的Pi共轭有机硼聚合物。 聚合物含有芳族和/或不饱和的重复单元和硼原子。 末端封端,用增溶基团衍生的P 2共轭有机硼聚合物表现出改善的溶解度和处理性能,有利于形成用于器件制造的薄膜。 与芳族或不饱和单体单元的π-共轭轨道体系共轭的硼原子的空位p轨道将聚合物的π-共轭长度延伸穿过硼原子。 π共轭有机硼聚合物是电子缺陷的,因此表现出n型半导体性质,光致发光和电致发光。 本发明提供薄膜有机聚合物电子器件,例如有机光伏电池(OPV),有机二极管,有机光电二极管,有机薄膜晶体管(TFT),有机场效应晶体管(OFET),可印刷或柔性电子器件 作为射频识别(RFID)标签,电子纸和印刷电路元件,有机发光二极管(OLED),聚合物发光二极管(PLED)和使用π-共轭有机硼聚合物的储能装置。 在OLED和PLED应用中,这些材料用作电子传输层(ETL)以提高器件效率。 显示光致发光和电致发光的聚合物也可用作PLED中的发光材料。
    • 128. 发明申请
    • ORGANIC ELECTROLUMINESCENT ELEMENT AND METHOD FOR PRODUCING THE SAME
    • 有机电致发光元件及其制造方法
    • US20110186833A1
    • 2011-08-04
    • US13060785
    • 2009-08-14
    • Masataka Iwasaki
    • Masataka Iwasaki
    • H01L51/54H01L51/56
    • H01L51/5012H01L51/0026H01L51/0036H01L51/0038H01L51/004H01L51/56
    • The problem to be solved by the present invention is to prolong the luminance half life of an organic EL element. A means for solving the problem is a method for producing an organic electroluminescent element comprising a first electrode that is formed first, a second electrode that is formed later, and a light-emitting layer that is formed between the first electrode and the second electrode, the method comprising the steps of applying a solution containing a light-emitting organic material to a surface of a layer located below to form an applied film; calcining the applied film in an inert gas atmosphere or in a vacuum atmosphere to form a light-emitting layer; holding the surrounding of the formed light-emitting layer in an inert gas atmosphere or in a vacuum atmosphere; and forming a layer located on the light-emitting layer in an inert gas atmosphere or in a vacuum atmosphere.
    • 本发明要解决的问题是延长有机EL元件的亮度半衰期。 用于解决问题的方法是一种生产有机电致发光元件的方法,该有机电致发光元件包括首先形成的第一电极,稍后形成的第二电极和形成在第一电极和第二电极之间的发光层, 该方法包括以下步骤:将含有发光有机材料的溶液施加到位于下面的层的表面以形成涂布膜; 在惰性气体气氛或真空气氛中煅烧涂膜以形成发光层; 将所形成的发光层的周围保持在惰性气体气氛或真空气氛中; 以及在惰性气体气氛或真空气氛中形成位于发光层上的层。