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    • 124. 发明申请
    • METHOD OF PRODUCING NANO-SCALED GRAPHENE AND INORGANIC PLATELETS AND THEIR NANOCOMPOSITES
    • 生产纳米尺度石墨和无机薄板及其纳米复合材料的方法
    • US20110190435A1
    • 2011-08-04
    • US12983947
    • 2011-01-04
    • Bor Z. JangAruna Zhamu
    • Bor Z. JangAruna Zhamu
    • C08K3/20C09K3/00B82Y30/00
    • B82Y40/00B82Y30/00C01B32/15C01B32/22C01B32/225C01B32/23C01B33/40C01B2204/04C01P2004/24C09C1/44C09C1/46
    • Disclosed is a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm, and often between 0.34 nm and 1.02 nm. The method comprises: (a) subjecting the layered material in a powder form to a halogen vapor at a first temperature above the melting point or sublimation point of the halogen at a sufficient vapor pressure and for a duration of time sufficient to cause the halogen molecules to penetrate an interlayer space of the layered material, forming a stable halogen-intercalated compound; and (b) heating the halogen-intercalated compound at a second temperature above the boiling point of the halogen, allowing halogen atoms or molecules residing in the interlayer space to exfoliate the layered material to produce the platelets. Alternatively, rather than heating, step (a) is followed by a step of dispersing the halogen-intercalated compound in a liquid medium which is subjected to ultrasonication for exfoliating the halogen-intercalated compound to produce the platelets, which are dispersed in the liquid medium. The halogen can be readily captured and re-used, thereby significantly reducing the impact of halogen to the environment. The method can further include a step of dispersing the platelets in a polymer or monomer solution or suspension as a precursor step to nanocomposite fabrication.
    • 公开了一种剥离层状材料(例如石墨和氧化石墨)以产生厚度小于100nm,通常小于10nm,通常在0.34nm和1.02nm之间的纳米级片晶的方法。 该方法包括:(a)在高于卤素的熔点或升华点的第一温度下以足够的蒸汽压将粉末形式的层状材料经受卤素蒸气,持续足以引起卤素分子 穿透层状材料的层间空间,形成稳定的卤素插层化合物; 和(b)在高于卤素沸点的第二温度下加热卤素插层的化合物,使得驻留在层间空间中的卤素原子或分子剥离层状材料以产生血小板。 或者,步骤(a)不是加热,而是将卤素插入化合物分散在液体介质中的步骤,该液体介质经过超声波处理以使卤素插层化合物剥离以产生分散在液体介质中的血小板 。 可以容易地捕获和重新使用卤素,从而显着降低卤素对环境的影响。 该方法还可以包括将血小板分散在聚合物或单体溶液或悬浮液中作为前体步骤的纳米复合制备的步骤。
    • 125. 发明授权
    • Method of producing nano-scaled graphene and inorganic platelets and their nanocomposites
    • 生产纳米级石墨烯和无机血小板及其纳米复合材料的方法
    • US07892514B2
    • 2011-02-22
    • US11709274
    • 2007-02-22
    • Bor Z. JangAruna Zhamu
    • Bor Z. JangAruna Zhamu
    • C01B31/00
    • B82Y40/00B82Y30/00C01B32/15C01B32/22C01B32/225C01B32/23C01B33/40C01B2204/04C01P2004/24C09C1/44C09C1/46
    • Disclosed is a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm, and often between 0.34 nm and 1.02 nm. The method comprises: (a) subjecting the layered material in a powder form to a halogen vapor at a first temperature above the melting point or sublimation point of the halogen at a sufficient vapor pressure and for a duration of time sufficient to cause the halogen molecules to penetrate an interlayer space of the layered material, forming a stable halogen-intercalated compound; and (b) heating the halogen-intercalated compound at a second temperature above the boiling point of the halogen, allowing halogen atoms or molecules residing in the interlayer space to exfoliate the layered material to produce the platelets. Alternatively, rather than heating, step (a) is followed by a step of dispersing the halogen-intercalated compound in a liquid medium which is subjected to ultrasonication for exfoliating the halogen-intercalated compound to produce the platelets, which are dispersed in the liquid medium. The halogen can be readily captured and re-used, thereby significantly reducing the impact of halogen to the environment. The method can further include a step of dispersing the platelets in a polymer or monomer solution or suspension as a precursor step to nanocomposite fabrication.
    • 公开了一种剥离层状材料(例如石墨和氧化石墨)以产生厚度小于100nm,通常小于10nm,通常在0.34nm和1.02nm之间的纳米级片晶的方法。 该方法包括:(a)在高于卤素的熔点或升华点的第一温度下以足够的蒸汽压将粉末形式的层状材料经受卤素蒸气,持续足以引起卤素分子 穿透层状材料的层间空间,形成稳定的卤素插层化合物; 和(b)在高于卤素沸点的第二温度下加热卤素插层的化合物,使得驻留在层间空间中的卤素原子或分子剥离层状材料以产生血小板。 或者,步骤(a)不是加热,而是将卤素插入化合物分散在液体介质中的步骤,该液体介质经过超声波处理以使卤素插层化合物剥离以产生分散在液体介质中的血小板 。 可以容易地捕获和重新使用卤素,从而显着降低卤素对环境的影响。 该方法还可以包括将血小板分散在聚合物或单体溶液或悬浮液中作为前体步骤的纳米复合制备的步骤。