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121. 发明申请

US20100025620A1 PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3- TETRAFLUOROPROPENE 失效
标题翻译：包含2,3,3,3-四氢呋喃和/或1,2,3,3-四氢呋喃的生产和组合物的方法
公开(公告)号：US20100025620A1
公开(公告)日：2010-02-04
申请号：US12442952
申请日：2007-10-31
申请人： Mario Joseph Nappa , Velliyur Mallikarjuna Nott Rao , Allen Capron Sievert
发明人： Mario Joseph Nappa , Velliyur Mallikarjuna Nott Rao , Allen Capron Sievert
IPC分类号： C09K5/00 , C07C17/23
CPC分类号： C07C21/18 , C07C17/23 , C07C17/25 , C07C17/278 , C09K3/30 , C09K5/045 , C09K2205/126 , C07C19/10
摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF═CFCHF2. The process involves contacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a catalyst including a catalytically effective amount of palladium supported on a support of alumina, fluorided alumina and/or aluminum fluoride, to produce a product mixture including CH2═CFCF3 (and when CCl2FCF2CClF2 is present, CHF═CFCHF2); recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture; and optionally, separating at least a portion of any CHF═CFCHF2 in the product mixture from the CH2═CFCF3 in the product mixture. The mole ratio of H2 to the total of CCl3CF2CF3 and CCl2FCF2CClF2 fed to the reaction zone is between about 1:1 and about 5:1. The present invention also provides another process for making CH2═CFCF3 or mixtures thereof with CHF═CFCHF2 This process involves (a) reacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 (and when CCl2FCF2CClF2 is present, CH2FCF2CHF2); (b) dehydrofluorinating CH3CF2CF3 and optionally any CH2FCF2CHF2 from (a) to form a product mixture including CH2═CFCF3, and if CH2FCF2CHF2 is present, CHF═CFCHF2; (c) recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture formed in (b); and optionally (d) separating at least a portion of any CHF═CFCHF2 in the product mixture formed in (b) from the CH2═CFCF3 in the product mixture formed in (b).The present invention also provides compositions involving CH2═CFCF3 and/or CHF═CFCHF2, including compositions useful as refrigerants, foam blowing agents, cleaning agents and aerosols and azeotropic compositions involving (a) CF2HCF═CFH and (b) HF.
摘要翻译：公开了制备CF 3 CF-CH 2或其与CHF-CFCHF 2的混合物的方法。该方法包括在催化剂存在下使CCl 3 CF 2 CF 3和任选的CCl 2 CFF 2 CClF 2与H 2接触，所述催化剂包括负载在氧化铝，氟化氧化铝和/或氟化铝的载体上的催化有效量的钯，以产生包含CH 2 -CFCF 3的产物混合物 CCl 2 CFF 2 CClF 2，CHF-CFCHF 2）; 从产物混合物中回收CH2-CFCF3或其与CHF-CFCHF2的混合物; 并且任选地，将产物混合物中的任何CHF-CFCHF 2的至少一部分与产物混合物中的CH 2 -CFCF 3分离。供给到反应区的H 2与CCl 3 CF 2 CF 3和CCl 2 FCF 2 CClF 2的总量的摩尔比为约1:1至约5:1。本发明还提供另外一种制备CH2-CFCF3或其与CHF-CFCHF2的混合物的方法。该方法包括（a）在催化有效量的氢化催化剂存在下使CCl 3 CF 2 CF 3和任选的CCl 2 FCF 2 CClF 2与H 2反应以形成CH 3 CF 2 CF 3 CCl 2 FCF 2 CClF 2存在，CH 2 CFF 2 CHF 2）; （b）从（a）中将CH 3 CF 2 CF 3和任选的任何任何CH 2 CFF 2 CHF 3脱氟氟化，形成包含CH2-CFCF3的产物混合物，如果存在CH 2 CF 2 CHF 2，则CHF-CFCHF 2; （c）从（b）中形成的产物混合物中回收CH 2 CFCF 3或其与CHF-CFCHF 2的混合物; 和任选地（d）将（b）中形成的产物混合物中的任何CHF-CFCHF 2的至少一部分与（b）中形成的产物混合物中的CH 2 -CFCF 3分离。本发明还提供了包含CH 2 -CFCF 3和/或CHF-CFCHF 2的组合物，包括可用作制冷剂的组合物，泡沫发泡剂，清洁剂和气溶胶以及涉及（a）CF 2 HCF-CFH和（b）HF的共沸组合物。

122. 发明申请

US20100010277A1 Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3-Pentafluoropropene 失效
标题翻译： 1,2,3,3,3-五氟丙烯的E和Z异构体之间的催化异构化
公开(公告)号：US20100010277A1
公开(公告)日：2010-01-14
申请号：US12373588
申请日：2007-07-11
申请人： Mario Joseph Nappa , Donald J. Toton
发明人： Mario Joseph Nappa , Donald J. Toton
IPC分类号： C07C19/08
CPC分类号： B01J27/12 , B01J27/135 , C07C17/358 , C07C21/18
摘要： A process is disclosed to increase the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF3 or carbon, wherein the catalyst is selected from the group consisting of SbClwF5-w, TiClxF4-x, SnClyF4-y and TaCl2F5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is increased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in the starting material.A process is also disclosed to decrease the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF3 or carbon, wherein the catalyst is selected from the group consisting of SbClwF5-w, TiClxF4-x, SnClyF4-y and TaClzF5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is decreased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in the starting material.
摘要翻译：公开了提高1,2,3,3,3-五氟丙烯的Z / E比的方法。该方法包括使包含1,2,3,3,3-五氟丙烯的起始材料与AlF 3或碳上的催化剂接触，其中催化剂选自SbClwF5-w，TiClxF4-x，SnClyF4-y和TaCl2F5 -z其中w为0至4，x为0至3，y为0至3，z为0至4，得到其Z / E比为1,2,3,3， 3-五氟丙烯相对于起始原料中1,2,3,3,3-五氟丙烯的Z / E比增加。还公开了降低1,2,3,3,3-五氟丙烯的Z / E比的方法。该方法包括将包含1,2,3,3,3-五氟丙烯的原料与AlF 3或碳上的催化剂接触，其中催化剂选自SbClwF5-w，TiClxF4-x，SnClyF4-y和TaClzF5 -z其中w为0至4，x为0至3，y为0至3，z为0至4，得到其Z / E比为1,2,3,3， 3-五氟丙烯相对于起始原料中1,2,3,3,3-五氟丙烯的Z / E比降低。

123. 发明申请

US20090306438A1 1,2,3,3,3-PENTAFLUOROPROPENE PRODUCTION PROCESSES 有权
标题翻译： 1,2,3,3,3-苯甲酮生产工艺
公开(公告)号：US20090306438A1
公开(公告)日：2009-12-10
申请号：US12440046
申请日：2007-09-05
申请人： Allen Capron Sievert , Mario Joseph Nappa , Barry Asher Mahler
发明人： Allen Capron Sievert , Mario Joseph Nappa , Barry Asher Mahler
IPC分类号： C07C17/23
CPC分类号： C07C17/25 , Y02P20/582 , C07C21/18
摘要： The present disclosure relates to a new and efficient manufacturing process for the production of HFC-1225ye. The process involves contacting at least one hexafluoropropane selected from the group consisting of 1,1,1,2,2,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane with a suitable catalyst in a reactor to obtain a product mixture containing HFC-1225ye (1,2,3,3,3-pentafluoropropene) where the pressure in the reactor ranges from about 0.5 psig to about 100 psig.
摘要翻译：本公开涉及用于生产HFC-1225ye的新的和有效的制造方法。该方法包括将至少一种选自1,1,1,2,2,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷的六氟丙烷与合适的催化剂在反应器中接触以获得含有HFC-1225ye（1,2,3,3,3-五氟丙烯）的产物混合物，其中反应器中的压力为约0.5psig至约100psig。

124. 发明申请

US20090156869A1 PROCESSES FOR THE SYNTHESIS OF 2-CHLORO-1,1,1,3,3,4,4,4-HEPTAFLUORO-2-BUTENE AND HEXAFLUORO-2-BUTYNE 失效
标题翻译：合成2-氯代-1,1,1,3,3,4,4,4-二氢-2-丁烯和十六烷基-2-丁基的方法
公开(公告)号：US20090156869A1
公开(公告)日：2009-06-18
申请号：US12334873
申请日：2008-12-15
申请人： Mario Joseph Nappa
发明人： Mario Joseph Nappa
IPC分类号： C07C17/23
CPC分类号： C07C17/23 , C07C17/278 , C07C17/354 , C07C21/18 , C07C21/22 , C07C19/10
摘要： Disclosed is a process comprising reacting CF3CCl2CF2CF3 (CFC-318ma) with hydrogen in the presence of a dehalogenation catalyst to produce CF3CCl=CFCF3(CFC-1317mx). Also disclosed is a process comprising reacting CF3CCl═CFCF3 (CFC-1317mx) with hydrogen in the presence of a dehalogenation catalyst to produce CF3C≡CCF3 (hexafluoro-2-butyne). Hexafluoro-2-butyne can be used to produce CF3CH═CHCF2CF3 (1,1,1,4,4,5,5,5-octafluoro-2-pentene).
摘要翻译：公开了一种方法，其包括在脱卤催化剂存在下使CF 3 CCl 2 CF 2 CF 3（CFC-318ma）与氢气反应以产生CF 3 CCl = CFCF 3（CFC-1317mx）。还公开了包括在脱卤催化剂存在下使CF 3 CCl-CFCF 3（CFC-1317mx）与氢反应以产生CF 3C≡CCF3（六氟-2-丁炔）的方法。六氟-2-丁炔可用于制备CF 3 CH-CHCF 2 CF 3（1,1,1,4,4,5,5,5-八氟-2-戊烯）。

125. 发明申请

US20080315149A1 HEAT TRANSFER AND REFRIGERANT COMPOSITIONS COMPRISING 3,3,4,4,5,5,6,6,6-NONAFLUORO-1-HEXENE AND A HYDROCARBON 审中-公开
标题翻译：包含3,3,4,4,5,5,6,6,6-壬二醇-1-异丙苯和氢氯化物的热交换器和制冷剂组合物
公开(公告)号：US20080315149A1
公开(公告)日：2008-12-25
申请号：US12193282
申请日：2008-08-18
申请人： Mario Joseph Nappa , Barbara Haviland Minor , Velliyur Nott Mallikarjuna Rao
发明人： Mario Joseph Nappa , Barbara Haviland Minor , Velliyur Nott Mallikarjuna Rao
IPC分类号： C09K5/04 , C11D7/50
CPC分类号： C11D7/5072 , C09K5/045 , C09K2205/12
摘要： The present invention relates to:Disclosed herein are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene compositions for use in refrigeration and air conditioning systems, particularly in centrifugal compressor systems. Also disclosed are 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene in combination with hydrocarbons, which are azeotropic or near azeotropic.
摘要翻译：本发明涉及：本文公开了用于制冷和空调系统中的3,3,4,4,5,5,6,6,6-九氟-1-己烯组合物，特别是在离心式压缩机系统中。还公开了3,3,4,4,5,5,6,6,6-九氟-1-己烯与烃共沸，它们是共沸的或接近共沸的。

126. 发明授权

US07423188B2 Azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof 有权
标题翻译：包含E-1,3,3,3-四氟丙烯和氟化氢的共沸组合物及其用途
公开(公告)号：US07423188B2
公开(公告)日：2008-09-09
申请号：US11590343
申请日：2006-10-30
申请人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Ralph Newton Miller , Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/00 , C07C17/38
CPC分类号： C07C21/18 , C01B7/191 , C01B7/196 , C07C17/25 , C07C17/38 , C07C17/383
摘要： Disclosed herein are azeotrope and near-azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride. These azeotrope and near-azeotrope compositions are useful in processes to produce E-1,3,3,3-tetrafluoropropene and in processes to purify E-1,3,3,3-tetrafluoropropene from mixtures of E-1,3,3,3-tetrafluoropropene with 1,1,1,3,3-pentafluoropropane and/or with hydrogen fluoride.
摘要翻译：本文公开了包含E-1,3,3,3-四氟丙烯和氟化氢的共沸物和近共沸组合物。这些共沸物和近共沸组合物可用于生产E-1,3,3,3-四氟丙烯的方法和在E-1,3,3,3-四氟丙烯的混合物中纯化E-1,3,3,3-四氟丙烯的方法，三氟丙烯与1,1,1,3,3-五氟丙烷和/或氟化氢。

127. 发明授权

US5969074A Reaction of perfluoroolefins with Bis (Silyl) ethers to produce fluorinated compounds 失效
标题翻译：全氟烯烃与双（甲硅烷基）醚的反应生成氟化物
公开(公告)号：US5969074A
公开(公告)日：1999-10-19
申请号：US64575
申请日：1993-05-21
申请人： William Brown Farnham , Mario Joseph Nappa
发明人： William Brown Farnham , Mario Joseph Nappa
IPC分类号： C07C43/13 , C07C43/17 , C07C43/192 , C07C43/247 , C07D323/00 , C07F7/18 , C08F20/14 , C08F214/18 , C08G65/00 , C08G65/336 , C08G65/34 , C08G67/00 , C07D317/16 , C07D321/00 , C07D319/12
CPC分类号： C07C43/17 , C07C43/137 , C07C43/192 , C07C43/247 , C07D323/00 , C07F7/1852 , C08F20/14 , C08F214/186 , C08G65/007 , C08G65/336 , C08G65/34 , C07C2101/04 , C07C2101/06
摘要： A reaction of perfluoroolefins with bis(silyl) ethers to produce novel partially fluorinated and perfluorinated copolymers and macrocyclic compounds is disclosed.
摘要翻译：公开了全氟烯烃与双（甲硅烷基）醚的反应以产生新的部分氟化和全氟化的共聚物和大环化合物。

128. 发明授权

US5866728A Use of alkali metal halides in the manufacture of 1, 1-difluoroethane 失效
标题翻译：在制备1,1-二氟乙烷时使用碱金属卤化物
公开(公告)号：US5866728A
公开(公告)日：1999-02-02
申请号：US583331
申请日：1996-01-05
申请人： Mario Joseph Nappa , William Robert Williams
发明人： Mario Joseph Nappa , William Robert Williams
IPC分类号： C07C17/21 , C07C17/08
CPC分类号： C07C17/21
摘要： A process is disclosed for the selective and high yield preparation of 1,1-difluoroethane (HFC-152a). The process comprises contacting chloroethene with anhydrous hydrogen fluoride in a liquid phase at a temperature from about 50.degree. C. and 95.degree. C. while in the presence of a tin(IV) catalyst and an alkali metal halide.
摘要翻译：公开了1,1-二氟乙烷（HFC-152a）的选择性和高产率制备方法。该方法包括在约50℃和95℃的温度下，在锡（IV）催化剂和碱金属卤化物存在下，将氯乙烯与无水氟化氢在液相中接触。

129. 发明授权

US09724684B2 Selective catalytical dehydrochlorination of hydrochlorofluorocarbons 有权
公开(公告)号：US09724684B2
公开(公告)日：2017-08-08
申请号：US13397956
申请日：2012-02-16
申请人： Mario Joseph Nappa
发明人： Mario Joseph Nappa
IPC分类号： C07C17/25 , B01J35/10 , B01J23/26 , B01J37/26 , B01J27/132
CPC分类号： B01J35/1014 , B01J23/26 , B01J27/132 , B01J37/26 , C07C17/25 , C07C21/18
摘要： A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.

130. 发明授权

US09174896B2 Catalytical synthesis of internal fluorobutenes and internal fluoropentenes 有权
标题翻译：内部氟代内酯和内部氟代戊烯的催化合成
公开(公告)号：US09174896B2
公开(公告)日：2015-11-03
申请号：US13988111
申请日：2011-11-07
申请人： Mario Joseph Nappa , Ekaterina N Swearingen
发明人： Mario Joseph Nappa , Ekaterina N Swearingen
IPC分类号： C07C17/25 , C07C17/20 , C07C21/18
CPC分类号： C07C17/25 , C07C17/206 , C07C21/18
摘要： A vapor phase process is disclosed for making internal fluorobutenes. The process involves contacting a halobutane starting material selected from the group consisting of CF2HCHClCH2CCl2H, CF2HCHClCH2CCl3, CF3CHClCH2CCl2H, CF3CHClCH2CCl3, CF3CHClCHClCCl2H, CF3CHClCHClCCl3, CF3CCl2CH2CCl2H, CF3CCl2CH2CCl3, CF3CCl2CHClCCl2H, CF3CCl2CHClCCl3, CF3CClFCHClCCl2H, CF3CClFCHClCCl3, CF3CClFCH2CCl2H, CF3CClFCH2CCl3, CF3CClFCHFCCl2H, CF3CClFCHFCCl3, CF3CClHCHFCCl2H and CF3CClHCHFCCl3, with HF in a reaction zone in the presence of a chromium oxyfluoride catalyst to produce a product mixture comprising an internal fluorobutene. Another vapor phase process is disclosed for making internal fluoropentenes. The process involves contacting a halopentane starting material selected from the group consisting of CF2HCHXCH2CX2CX3, CF3CHXCH2CX2CX3, CF3CHXCHXCX2CX3, CF3CX2CH2CX2CX3, CF3CX2CHXCX2CX3 and CF3CHXCHFCX2CX3, with HF in a reaction zone in the presence of a chromium oxyfluoride catalyst to produce a product mixture comprising an internal fluoropentene, wherein each X is independently selected from the group consisting of F, Cl and Br, provided that not all X are fluorines.
摘要翻译：公开了一种用于制备内部氟代异丁烯的气相方法。该方法包括接触选自CF2HCHClCH2CCl2H，CF2HCHClCH2CCl3，CF3CHClCH2CCl2H，CF3CHClCH2CCl3，CF3CHClCHClCCl2H，CF3CHClCHClCCl3，CF3CCl2CH2CCl2H，CF3CCl2CH2CCl3，CF3CCl2CHClCCl2H，CF3CCl2CHClCCl3，CF3CClFCHClCCl2H，CF3CClFCHClCCl3，CF3CClFCH2CCl2H，CF3CClFCH2CCl3，CF3CClFCHFCCl2H，CF3CClFCHFCCl3，CF3CClHCHFCCl2H和CF3CClHCHFCCl3的组中选择的halobutane起始材料在HF反应区中，在氟氧化铬催化剂的存在下制备包含内部氟代丁烯的产物混合物。公开了制备内部氟代戊烯的另一种气相方法。该方法包括在氟氧化铬催化剂存在下，在反应区中将选自CF2HCHXCH2CX2CX3，CF3CHXCH2CX2CX3，CF3CHXCHXCX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CHXCX2CX3与CF3CHXCHFCX2CX3的卤代戊烷起始材料与HF接触，制备包含内部氟代戊烯的产物混合物，其中每个X独立地选自F，Cl和Br，条件是不是全部X是氟。

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