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121. 发明授权

US4959419A Polymeric emulsifiers based on aminotelechelic oligomers I 失效
标题翻译：基于氨基扑耳低聚物的聚合乳化剂I
公开(公告)号：US4959419A
公开(公告)日：1990-09-25
申请号：US133517
申请日：1987-12-16
申请人： Adolf Schmidt , Udo W. Hendricks , Bruno Bomer , Karl H. Ott , Herbert Eichenauer , Alfred Pischtschan
发明人： Adolf Schmidt , Udo W. Hendricks , Bruno Bomer , Karl H. Ott , Herbert Eichenauer , Alfred Pischtschan
IPC分类号： B01F17/00 , B01F17/52 , C07C67/00 , C07C231/00 , C07C233/05 , C07C233/09 , C07C233/36 , C07C233/38 , C07C233/58 , C07C233/62 , C07C233/65 , C08F2/26 , C08F8/00 , C08F8/46 , C08F36/04
CPC分类号： C08F8/46 , B01F17/005 , C08F2/26 , C08F36/04 , C08F8/00
摘要： Polycarboxylic acids and their salts corresponding to the following general formula[X]--(NHOC--Y--COO M).sub.n (I)in whichX is the residue of a hydrophobic, linear or branched vinyl oligomer having an average molecular weight M.sub.n of from 200 to 5000 and preferably from 300 to 3000,Y is the 1,2-vinylene, 1,2-ethylene, 1,3-propylene, 1,2-phenylene, 1,2-cyclohexen-4-ylene or 1,2-cyclohexylene group,n is a number of from 1.4 to 3.0 and preferably from 1.6 to 2.3 andM is hydrogen, an alkali metal, an ammonium, C.sub.1 -C.sub.4 alkylammonium or C.sub.2 -C.sub.3 hydroxyalkylammonium group, which are useful as surfactants and emulsifiers in aqueous systems.
摘要翻译：对应于以下通式[X] - （NHOC-Y-COO M）n（I）的多元羧酸及其盐，其中X是疏水性，直链或支链乙烯基低聚物的残基，其平均分子量＆ 200至5000，优选300至3000，Y为1,2-亚乙烯基，1,2-亚乙基，1,3-亚丙基，1,2-亚苯基，1,2-环己烯-4-基或1， 2-亚环己基，n为1.4〜3.0，优选为1.6〜2.3，M为氢，碱金属，铵，C1-C4烷基铵或C2-C3羟烷基铵，可用作表面活性剂和乳化剂在水系统中。

122. 发明授权

US4885337A Process for the preparation of thermoplastic moulding compositions 失效
标题翻译：制备热塑性模塑组合物的方法
公开(公告)号：US4885337A
公开(公告)日：1989-12-05
申请号：US69967
申请日：1987-07-06
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08F279/04 , C08F2/22 , C08F279/00 , C08F279/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/00 , C08L55/02
CPC分类号： C08L25/12 , C08F279/02 , C08L51/04
摘要： Process for the preparation of a thermoplastic moulding composition of 10 to 65% by weight of at least one graft polymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, in the presence of at least one rubber base, and the weight ratio of monomers employed to rubber polymer employed being 20:80 to 70:30, and 90 to 35% by weight of a copolymer of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50, it being possible for all or some of the styrene to be replaced by .alpha.-methylstyrene or methyl methacrylate, wherein, to prepare the graft polymer, the grafting monomers and 0.05 to 1.00 part by weight (per 100 parts by weight of grafting monomer) of a mercaptan are added stepwise to the latex of the rubber base over a period of time, the part amount of the monomer added in each time interval .DELTA.t.sub.n+1 being 0.30 to 0.95 times the amount of monomer added in the preceding time interval .DELTA.t.sub.n at least in the first half of the period of time, and the total period of time comprising n time intervals where n=3 to 30, and each time interval .DELTA.t being 5 to 100 minutes long.
摘要翻译：用于制备10至65重量％的至少一种接枝聚合物的热塑性模塑组合物的方法，所述接枝聚合物可以通过苯乙烯和丙烯腈的重量比为90:10至50:50的乳液聚合而获得，所有这些都可能或由至少一个橡胶基团存在下由α-甲基苯乙烯或甲基丙烯酸甲酯代替的一些苯乙烯，并且所用单体与橡胶聚合物的重量比为20:80至70:30和90至35 重量比为90:10至50:50的苯乙烯和丙烯腈的共聚物的重量比，可以用α-甲基苯乙烯或甲基丙烯酸甲酯代替全部或一些苯乙烯，其中制备接枝物聚合物，接枝单体和0.05至1.00重量份（每100重量份接枝单体）硫醇在一段时间内逐步添加到橡胶基料的胶乳上，每次加入单体的部分量时间间隔DELTA tn + 1 bei ng至少在上述时间段的前半部分中，在上述时间间隔DELTA tn中添加的单体量的0.30〜0.95倍，n = 3〜30的n个时间间隔的总时间，以及每个时间间隔长达5到100分钟。

123. 发明授权

US4865917A Thermoplastic silicone rubber graft polymers (I) 失效
标题翻译：热塑性硅橡胶接枝聚合物（I）
公开(公告)号：US4865917A
公开(公告)日：1989-09-12
申请号：US203988
申请日：1988-06-08
申请人： Christian Lindner , Herbert Eichenauer , Dieter Wittmann , Volker Damrath
发明人： Christian Lindner , Herbert Eichenauer , Dieter Wittmann , Volker Damrath
IPC分类号： C08F283/12 , C08F285/00
CPC分类号： C08F285/00 , Y10S525/902 , Y10T428/2998 , Y10T428/31536
摘要： Thermoplastic particulate graft polymers comprising particles of a core (A) of an organic resin-like polymer of olefinically unsaturated monomers having softening temperatures (glass temperatures) above 30.degree. C., a shell polymer (B) or ogranopolysiloxane and a polymer (C) of at least one .alpha.,.beta.-unsaturated olefinic monomer grafted onto the particles consisting of A and B and their use as thermoplastic molding compositions.
摘要翻译：包含软化温度（玻璃温度）高于30℃的烯属不饱和单体的有机树脂状聚合物的芯（A），壳聚合物（B）或聚异氰酸聚硅氧烷和聚合物（C））的颗粒的热塑性颗粒接枝聚合物，的至少一种接枝到由A和B组成的颗粒上的α，β-不饱和烯烃单体及其作为热塑性模塑组合物的用途。

124. 发明授权

US4839421A Antistatic, thermoplastic moulding compound based on polycarbonates and aromatic vinyl polymers 失效
标题翻译：基于聚碳酸酯和芳族乙烯基聚合物的抗静电，热塑性模塑料
公开(公告)号：US4839421A
公开(公告)日：1989-06-13
申请号：US151288
申请日：1988-02-01
申请人： Hans-Josef Buysch , Norbert Schon , Herbert Eichenauer , Hans-Jurgen Kress , Josef Buekers
发明人： Hans-Josef Buysch , Norbert Schon , Herbert Eichenauer , Hans-Jurgen Kress , Josef Buekers
IPC分类号： C08L51/00 , C08L69/00 , C08L71/02
CPC分类号： C08L69/00
摘要： Thermoplastic moulding compounds consisting of 99.8-95% by weight of a mixture consisting of an aromatic polycarbonate, a graft polymer and optionally a thermoplastic vinyl polymer and/or the usual additives and 0.2 to 5% by weight of a polyalkylene ether which has been modified by a radical former.
摘要翻译：由99.8-95重量％的由芳族聚碳酸酯，接枝聚合物和任选的热塑性乙烯基聚合物组成的混合物和/或通常的添加剂和0.2-5重量％已经改性的聚亚烷基醚组成的热塑性模塑料由激进的前者。

125. 发明授权

US4772668A Sulphur-containing graft products 失效
标题翻译：含硫移植产品
公开(公告)号：US4772668A
公开(公告)日：1988-09-20
申请号：US827390
申请日：1986-02-10
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08L51/00 , C08F2/38 , C08F279/00 , C08F279/02 , C08F291/02 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/04 , C08L55/00 , C08L55/02
CPC分类号： C08F279/02 , C08F291/02
摘要： Sulphur-containing elastic-thermoplastic graft products of styrene, .alpha.-methyl styrene, p-methyl styrene, vinyl toluene, acrylonitrile or methyl methacrylate or mixtures thereof on a particle-like rubber with an average particle diameter (d.sub.50) of from 0.05 to 20.0 .mu.m and a glass temperature .ltoreq.10.degree. C. with a total rubber content of from 1 to 80% by weight, whereby the graft products have a sulphur content of from 1.15 to 3.95% by weight and the thermoplast proportion of the polymerized monomers on the particle-like rubber has a limiting viscosity of from 2 to 15 ml/g (measured in dimethyl formamide at 25.degree. C.) and in which at least 90% by weight of the incorporated sulphur is present as a constituent of terminal C1-18-thioalkyl groups.
摘要翻译：苯乙烯，α-甲基苯乙烯，对甲基苯乙烯，乙烯基甲苯，丙烯腈或甲基丙烯酸甲酯或其混合物在平均粒径（d50）为0.05至20.0的颗粒状橡胶上的含硫弹性 - 热塑性接枝产物微米，玻璃温度为10℃，总橡胶含量为1〜80重量％，由此接枝产物的硫含量为1.15〜3.95重量％，聚合物的热塑性比例颗粒状橡胶上的单体的特性粘度为2至15ml / g（在25℃的二甲基甲酰胺中测量），并且其中至少90重量％的引入的硫作为末端的成分存在 C 1-18 - 硫烷基。

126. 发明授权

US4764557A Moulding compositions of uniform particle size and improved thermal stability 失效
标题翻译：均匀粒径和改善热稳定性的成型组合物
公开(公告)号：US4764557A
公开(公告)日：1988-08-16
申请号：US827639
申请日：1986-02-10
申请人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
发明人： Herbert Eichenauer , Alfred Pischtschan , Karl-Heinz Ott
IPC分类号： C08J3/12 , C08F8/34 , C08F279/02 , C08J3/00 , C08J3/16 , C08L55/00 , C08L55/02 , C08L39/04 , C08L51/04
CPC分类号： C08J3/005 , C08F279/04
摘要： Elastic-thermoplastic and thermoplastic powder-form moulding compositions of uniform particle size and improved thermal stability at made by incorporating a sulphur containing polymer.
摘要翻译：具有均匀粒径的弹性热塑性和热塑性粉末成型成型组合物，并且通过掺入含硫聚合物制成的热稳定性得到改善。

127. 发明授权

US4699972A Aliphatic polyesters containing sulphur, and their use as stabilizers for polymers 失效
标题翻译：含硫的脂肪族聚酯及其作为聚合物稳定剂的用途
公开(公告)号：US4699972A
公开(公告)日：1987-10-13
申请号：US899506
申请日：1986-08-22
申请人： Heinz Hammer , Herbert Eichenauer , Ernst Roos , Eberhard Jurgens
发明人： Heinz Hammer , Herbert Eichenauer , Ernst Roos , Eberhard Jurgens
IPC分类号： C08G63/00 , C08G63/68 , C08G63/688 , C08L101/00 , C08G63/04
CPC分类号： C08G63/6886 , C08L101/00
摘要： Aliphatic polyesters containing sulphur, which contain the sulphur as structural units in the form of sulphide or disulphide groups in both the acid component and the diol component, a process for the preparation of these polyesters, and also polymers containing these polyesters.
摘要翻译：含有硫的脂肪族聚酯，其含有硫作为酸组分和二醇组分中硫化物或二硫键形式的结构单元，制备这些聚酯的方法，以及含有这些聚酯的聚合物。

128. 发明授权

US4622363A Thermoplastic moulding compositions with an improved heat distortion point 失效
标题翻译：具有改善的热变形点的热塑性成型组合物
公开(公告)号：US4622363A
公开(公告)日：1986-11-11
申请号：US778882
申请日：1985-09-23
申请人： Herbert Eichenauer , Hans-Jurgen Kress , Karl-Heinz Ott , Horst Peters , Josef Buekers
发明人： Herbert Eichenauer , Hans-Jurgen Kress , Karl-Heinz Ott , Horst Peters , Josef Buekers
IPC分类号： C08L51/00 , C08L7/00 , C08L21/00 , C08L25/00 , C08L25/02 , C08L25/04 , C08L25/12 , C08L25/16 , C08L33/00 , C08L33/02 , C08L51/02 , C08L51/04 , C08L69/00
CPC分类号： C08L69/00
摘要： The present invention relates to the use of a copolymer with an Mw of 2.times.10.sup.6 to 1.times.10.sup.7 in amounts of 0.5 to 5 parts by weight for improving the heat distortion point of thermoplastic mixtures containing polycarbonates, graft polymers and copolymers, and the thermoplastic mixtures correspondingly rendered dimensionally stable under the influence of heat.
摘要翻译：本发明涉及使用0.5〜5重量份的2×10 6〜1×10 7的共聚物，其用量为0.5〜5重量份，以改善含有聚碳酸酯，接枝聚合物和共聚物的热塑性混合物的热变形点，在热的影响下尺寸稳定。

129. 发明授权

US4617358A Process for the production of high molecular weight thermoplastic resins 失效
标题翻译：生产高分子量热塑性树脂的方法
公开(公告)号：US4617358A
公开(公告)日：1986-10-14
申请号：US739280
申请日：1985-05-30
申请人： Herbert Eichenauer , Karl-Heinz Ott
发明人： Herbert Eichenauer , Karl-Heinz Ott
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/38 , C08F12/08
CPC分类号： C08F2/26
摘要： A process for the production of uncross-linked vinyl polymers in two steps, a mixture of vinyl monomer, aliphatic hydroxyl compound, water and initiator being prepolymerized in step (A) and polymerization being completed in step (B) after the addition of more vinyl monomer and an emulsifier.
摘要翻译：在步骤（A）中预聚合乙烯基单体，脂族羟基化合物，水和引发剂的混合物和步骤（B）中完成的步骤（B）中完成乙烯基单体，脂族羟基化合物，水和引发剂的混合物，单体和乳化剂。

130. 发明授权

US4612347A Polymer mixtures with a mat surface 失效
标题翻译：具有垫表面的聚合物混合物
公开(公告)号：US4612347A
公开(公告)日：1986-09-16
申请号：US698781
申请日：1985-02-06
申请人： Herbert Eichenauer , Joachim Doring , Karl-Heinz Ott , Ludwig Bottenbruch
发明人： Herbert Eichenauer , Joachim Doring , Karl-Heinz Ott , Ludwig Bottenbruch
IPC分类号： C08L39/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L57/00 , C08L101/00 , C08L39/08
CPC分类号： C08L51/04 , C08L57/00
摘要： The invention relates to polymer mixtures with a mat surface, based on graft polymers with acid functions and thermoplastic resins with basic functions.
摘要翻译：本发明涉及具有垫表面的聚合物混合物，其基于具有酸性功能的接枝聚合物和具有基本功能的热塑性树脂。

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