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111. 发明授权

US5886183A Naphthalenelactamimide fluorescence dyes 失效
标题翻译：萘酰胺酰亚胺荧光染料
公开(公告)号：US5886183A
公开(公告)日：1999-03-23
申请号：US729124
申请日：1996-10-11
申请人： Heinz Langhals , Petra Christa von Unold
发明人： Heinz Langhals , Petra Christa von Unold
IPC分类号： C07D221/14 , B41M5/26 , C07D471/06 , C09B57/08 , C09K9/02 , C09K11/06 , C07D221/00 , C07D471/02
CPC分类号： C07D471/06 , C09B57/08 , C09K11/06
摘要： Naphthalenelactamimides of the formula I ##STR1## in which, for example, R.sub.1 and R.sub.2 are 2,5-di-tert-butylphenyl and m and n are 0, are novel dyes which have the distinctive features of pronounced fluorescence as a solid and in solvents and a good light-fastness. They are therefore suitable, for example, for mass dyeing of high molecular weight organic material, as laser dyes and for the preparation of printing toners, colour filters, organic photoreceptors, electroluminescent and photoluminescent elements, optical information storage media or solar collectors. The compounds of the the formula I can be prepared by reaction of the corresponding naphthalenetetracarboxylic acid bisimides with a base.
摘要翻译：其中例如R 1和R 2为2,5-二叔丁基苯基且m和n为0的式I（I）的萘内酰胺酰胺是具有显着荧光的独特特征的新颖染料，固体和溶剂，耐光性好。因此，它们适用于例如用于高分子量有机材料的大量染色，作为激光染料和用于制备印刷调色剂，滤色器，有机感光体，电致发光和光致发光元件，光学信息存储介质或太阳能收集器。式I的化合物可以通过相应的萘四羧酸双酰亚胺与碱的反应来制备。

112. 发明授权

US4578469A Benzo[de]pyrano[3,2-g]isoquinoline derivatives useful as dyestuffs 失效
标题翻译：苯并[de]吡喃并[3,2-g]异喹啉衍生物，可用作染料
公开(公告)号：US4578469A
公开(公告)日：1986-03-25
申请号：US655307
申请日：1984-09-26
申请人： Hans-Matthias Deger , Rudiger Erckel , Horst Fruhbeis
发明人： Hans-Matthias Deger , Rudiger Erckel , Horst Fruhbeis
IPC分类号： C07D491/06 , C07D493/06 , C09B57/02 , C09B57/08 , C07D471/04
CPC分类号： C07D491/06 , C07D493/06 , C09B57/02 , C09B57/08
摘要： Coumarin compounds of the general formula (1) ##STR1## in which A denotes an oxygen atom or a grouping >N--R in which R represents a hydrogen atom or an alkyl radical of 1 to 18 carbon atoms which may be substituted by fluorine, chlorine or bromine atoms or by alkoxy.sub.C.sbsb.1.sub.-C.sbsb.4, dialkyl.sub.C.sbsb.1.sub.-C.sbsb.4 -amino, --SO.sub.2 --N(alkyl.sub.C.sbsb.1.sub.-C.sbsb.4).sub.2 or cyano groups or a cycloaliphatic, aromatic or heterocyclic radical which may be substituted by fluorine, chlorine or bromine atoms or by alkyl.sub.C.sbsb.1.sub.-C.sbsb.4, alkoxy.sub.C.sbsb.1.sub.-C.sbsb.4, hydroxyl, cyano, sulfonamide or --SO.sub.2 --N--(alkyl.sub.C.sbsb.1.sub.-C.sbsb.4).sub.2 groups, X denotes an oxygen atom or a grouping .gtoreq.N--R' in which R' represents a hydrogen atom or an alkyl.sub.C.sbsb.1.sub.-C.sbsb.18 carbonyl, alkoxy.sub.C.sbsb.1.sub.-C.sbsb.4 carbonyl, alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 carbamoyl or alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 sulfonyl group or an aryl, arylcarbonyl, arylcarbamoyl or arylsulfonyl radical which may be substituted by fluorine, chlorine or bromine atoms or by alkyl or alkoxy groups of 1 to 4 carbon atoms each or by cyano groups, Y denotes a hydrogen atom or a cyano or an alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 carboxylate group, an aryl, arylsulfonyl or --CO--O--aryl radical which may be substituted by fluorine, chlorine or bromine atoms or by alkyl or alkoxy groups of 1 to 4 carbon atoms, or by nitro, methylenedioxy, amino, monoalkyl.sub.C.sbsb.1.sub.-C.sbsb.4 amino or dialkyl.sub.C.sbsb.1.sub.-C.sbsb.4 amino groups or by a benzoxazolyl radical, or a heterocyclic radical which may be quaternized and which may be substituted by fluorine, chlorine or bromine atoms or by alkyl or alkoxy groups of 1 to 4 carbon atoms, or by nitro, phenyl, alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 phenyl, alkoxy.sub.C.sbsb.1.sub.-C.sbsb.4 phenyl, cyano, methylenedioxy or alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 carboxylate groups, and Z denotes a hydrogen atom or an alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 carboxylate or cyano group, a process for their preparation, and their use for dyeing or printing synthetic fiber materials, in particular polyester fibers.
摘要翻译：通式（1）的香豆素化合物其中A表示氧原子或基团> NR，其中R表示氢原子或可被氟取代的1至18个碳原子的烷基，氯或溴原子或烷氧基C 1 -C 4，二烷基C 1 -C 4 - 氨基，-SO 2 -N（烷基C 1 -C 4）2或氰基或可被氟，氯或溴原子取代的脂环族，芳族或杂环基团，或通过烷基C 1 -C 4，烷氧基C 1 -C 4，羟基，氰基，磺酰胺或-SO 2 -N-（烷基C 1 -C 4）2基团，X表示氧原子或其中R'表示氢原子或> NR = 烷基C 1 -C 18羰基，烷氧基C 1 -C 4羰基，烷基C 1 -C 4氨基甲酰基或烷基C 1 -C 4磺酰基或芳基，芳基羰基，芳基氨基甲酰基或芳基磺酰基，其可以被氟，氯或溴原子取代或被1至4个碳原子的烷基或烷氧基取代各自或由氰基组成，Y表示氢原子或氰基或烷基C 1 -C 4羧酸酯基团可被氟，氯或溴原子取代的芳基，芳基磺酰基或-CO-O-芳基，或被1至4个碳原子的烷基或烷氧基取代，或被硝基，亚甲二氧基，氨基，单烷基C 1 -C 4氨基或二烷基C 1 或可以被季铵化并且可以被氟，氯或溴原子取代或通过1-4个碳原子的烷基或烷氧基取代的杂环基，或被硝基，苯基，烷基C1- C4苯基，烷氧基C1-C4苯基，氰基，亚甲二氧基或烷基C1-C4羧酸酯基，Z表示氢原子或烷基C1-C4羧酸酯或氰基，其制备方法及其用于染色或印刷合成纤维材料的用途特定的聚酯纤维。

113. 发明授权

US4443226A Process for dyeing textile sheet-like structures made of polyester fibers for use as warning protective clothing 失效
标题翻译：染色由聚酯纤维制成的织物片状结构用作警示防护服的方法
公开(公告)号：US4443226A
公开(公告)日：1984-04-17
申请号：US464527
申请日：1983-02-07
申请人： Helmut Rohser
发明人： Helmut Rohser
IPC分类号： C09B57/08 , C09B57/14 , D06P3/54 , D06P1/16
CPC分类号： C09B57/08 , C09B57/14 , D06P3/54 , Y10S534/01 , Y10S8/922
摘要： Work clothing, having an optical warning effect, which has been dyed in specific, prescribed color shades and is not coated with plastics is desired by the authorities. Thioindigo and/or derivatives of the red and pink series of thioindigo, as the base dyestuff, in combination with specific yellow disperse dyestuffs have proved usable, for dyeings on polyester fibers or polyester/cotton fiber mixtures, which are in the required shade of fluorescent orange-red and meet the requirements regarding color point, luminance and fastness to light. Both the exhaustion process and the thermosol process can be used to produce these dyeings.
摘要翻译：具有光学警告效果的工作服，被特定的规定的色调染色并且没有被塑料涂覆。作为基础染料的红色和粉红色系列的硫靛红和/或衍生物与特定的黄色分散染料组合已被证明可用于聚酯纤维或聚酯/棉纤维混合物上的染色，其在所需的荧光色素橙红色，符合色点，亮度和耐光性要求。耗尽过程和热溶胶过程都可用于生产这些染色。

114. 发明授权

US4310359A Pigment compositions 失效
标题翻译：颜料组成
公开(公告)号：US4310359A
公开(公告)日：1982-01-12
申请号：US235556
申请日：1981-02-18
申请人： Shigeyuki Ehashi , Junichi Tsuchida , Kenichi Kakimoto , Hiromitsu Katsura
发明人： Shigeyuki Ehashi , Junichi Tsuchida , Kenichi Kakimoto , Hiromitsu Katsura
IPC分类号： C07C67/00 , C07C301/00 , C07C311/00 , C09B1/00 , C09B3/60 , C09B5/16 , C09B5/20 , C09B5/48 , C09B5/62 , C09B7/10 , C09B19/02 , C09B29/01 , C09B29/08 , C09B29/15 , C09B29/20 , C09B29/44 , C09B29/50 , C09B48/00 , C09B57/08 , C09B57/12 , C09B67/22 , C09C3/00 , C09C3/08 , C09D7/00 , C09D7/12 , C09D11/00 , C09D11/02
CPC分类号： C09B1/005 , C09B19/02 , C09B29/0003 , C09B29/0836 , C09B29/10 , C09B29/20 , C09B29/3643 , C09B29/366 , C09B3/60 , C09B48/00 , C09B5/16 , C09B5/20 , C09B5/48 , C09B5/62 , C09B57/08 , C09B57/12 , C09B67/0033 , C09B7/10
摘要： A pigment composition is disclosed which includes a pigment and a coloring compound of the general formula (I), ##STR1## wherein Q represents a residue of a coloring compound other than phthalocyanine, X represents --SO.sub.2 -- or --CO--, m and n represent, respectively, an integer of from 1 to 4 and an integer of from 1 to 6, R represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms or an alkenyl group having from 2 to 20 carbon atoms, and R.sub.1 and R.sub.2 represent, independently, a hydrogen atom, a substituted or unsubstituted alkyl group having from 1 to 20 carbon atoms or a substituted or unsubstituted alkenyl group having from 2 to 20 carbon atoms, or R.sub.1 and R.sub.2 together form a heterocyclic ring which contains a nitrogen, oxygen or sulfur atom therein.
摘要翻译：公开了一种颜料组合物，其包含颜料和通式（I）的着色化合物，其中Q表示除酞菁以外的着色化合物的残基，X表示-SO 2 - 或-CO-， m和n分别表示1〜4的整数和1〜6的整数，R表示氢原子，碳原子数1〜20的烷基或碳原子数2〜20的烯基，R 1和R 2分别独立地表示氢原子，取代或未取代的碳原子数1〜20的烷基或取代或未取代的碳原子数2〜20的烯基，或者R 1和R 2一起形成杂环其中含有氮，氧或硫原子。

115. 发明授权

US4238386A Process for the mass pigmenting of rigid polyvinyl chloride and polyolefins 失效
标题翻译：刚性聚氯乙烯和聚烯烃的大量着色方法
公开(公告)号：US4238386A
公开(公告)日：1980-12-09
申请号：US37799
申请日：1979-05-10
申请人： Fridolin Babler
发明人： Fridolin Babler
IPC分类号： C08L23/00 , C08K5/34 , C08K5/3437 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/02 , C08L27/00 , C08L27/06 , C08L101/00 , C09B5/62 , C09B57/08
CPC分类号： C09B5/62 , C08K5/3437
摘要： A process for pigmenting polyolefins and rigid polyvinyl chloride, which comprises the use of perylenetetracarboxylic acid diimide pigments of the formula ##STR1## wherein R.sub.1 represents an aliphatic or cycloaliphatic radical of at least 12 carbon atoms and R.sub.2 represents hydrogen or an aliphatic or cycloaliphatic radical. These pigments are exceptionally suitable for pigmenting polyolefins and rigid polyvinyl chloride.
摘要翻译：用于着色聚烯烃和刚性聚氯乙烯的方法，其包括使用下式的苝四羧酸二酰亚胺颜料：其中R 1表示至少12个碳原子的脂族或脂环族基团，R 2表示氢或脂族或脂环族基团。这些颜料特别适用于着色聚烯烃和刚性聚氯乙烯。

116. 发明授权

US4220777A Naphthalimide derivatives 失效
标题翻译：邻苯二甲酰亚胺衍生物
公开(公告)号：US4220777A
公开(公告)日：1980-09-02
申请号：US961485
申请日：1978-11-17
申请人： Jochen Karg , Manfred Patsch , Walter Himmele
发明人： Jochen Karg , Manfred Patsch , Walter Himmele
IPC分类号： C09B57/08 , C07D221/14
CPC分类号： C07D221/14
摘要： Naphthalimide derivatives of the general formula ##STR1## where R.sup.1 is hydrogen or C.sub.1 - to C.sub.4 -alkyl,R.sup.2 is nitrile or a radical containing a carbonyl group or an acetalized carbonyl group andR.sup.3 and R.sup.4 are unsubstituted or substituted alkyl.The compounds are excellent optical brighteners, especially for synthetic fibers.
摘要翻译：其中R 1为氢或C 1〜C 4 - 烷基，R 2为腈或含有羰基或缩醛化羰基的基团，R 3和R 4为未取代或取代的烷基的通式为“IMAGE”的萘二甲酰亚胺衍生物。这些化合物是优异的荧光增白剂，特别是合成纤维。

117. 发明授权

US4200752A 4-Disubstituted amino, N-substituted naphthalimide dyestuffs 失效
标题翻译： 4-取代氨基，N-取代萘二甲酰亚胺染料
公开(公告)号：US4200752A
公开(公告)日：1980-04-29
申请号：US878395
申请日：1978-02-16
申请人： Robert C. Bertelson
发明人： Robert C. Bertelson
IPC分类号： C07D221/14 , C09B57/08
CPC分类号： C07D221/14 , C09B57/08
摘要： The present disclosure is directed to novel quenchable, fluorescent dyestuffs which are substantially soluble in low surface tension, substantially non-polar oily solvents, e.g., refined kerosene, and are trisubstituted 4-aminonaphthalimides having the structure formula: ##STR1## wherein R.sub.1 is a member selected from the group consisting of:(a) alkyl groups having from two to twelve carbon atoms,(b) substituted akyl groups having at least two carbon atoms,(c) phenylalkyl groups whose alkyl moiety has from one to four carbon atoms and(d) alicyclic rings having from five to six carbon atoms in the alicyclic ring;R.sub.2 and R.sub.3 are members selected from the group consisting of:(a) alkyl groups having from one to twenty-two carbon atoms,(b) phenylalkyl groups whose alkyl moiety has from one to four carbon atoms,(c) alicyclic groups having up to twelve carbon atoms,(d) tetrahydrofuranylmethyl and(e) a single alkylene chain forming a single heterocyclic ring with the amino nitrogen;with the provisos that the total number of carbon atoms in R.sub.1, R.sub.2 and R.sub.3 is at least nine, and the total number of carbon atoms in R.sub.2 and R.sub.3 is at least four.
摘要翻译：本公开涉及新颖的可淬灭的荧光染料，其基本上可溶于低表面张力，基本上非极性油性溶剂，例如精制煤油，并且是具有以下结构式的三取代的4-氨基萘二酰亚胺：其中R1是选自以下的成员：（a）具有2至12个碳原子的烷基，（b）具有至少2个碳原子的取代的烷基，（c）烷基部分具有1至4个碳原子的苯基烷基和（d）脂环中具有5-6个碳原子的脂环; R 2和R 3是选自以下的成员：（a）具有1-22个碳原子的烷基，（b）烷基部分具有1-4个碳原子的苯基烷基，（c）具有上述脂环族基团（d）四氢呋喃基甲基和（e）与氨基氮形成单个杂环的单个亚烷基链; 条件是R1，R2和R3中的碳原子总数至少为9，R2和R3中的碳原子总数至少为4。

118. 发明授权

US4089836A Process for the coloration of polyamides with pigments derived from carboxyamido-polyimides 失效
标题翻译：用衍生自羧酰氨基 - 聚酰亚胺的颜料着色聚酰胺的方法
公开(公告)号：US4089836A
公开(公告)日：1978-05-16
申请号：US601960
申请日：1975-08-04
申请人： Philippe Yves Edouard Gangneux
发明人： Philippe Yves Edouard Gangneux
IPC分类号： C07D471/06 , C07D487/04 , C08G69/02 , C08G73/14 , C08K5/3437 , C09B5/62 , C09B57/08 , C08K5/34
CPC分类号： C07D487/04 , C07D471/06 , C08G69/02 , C08G73/14 , C08K5/3437 , C09B5/62 , C09B57/08
摘要： Linear polyamides are colored with pigments of the formula: ##STR1## wherein R represents the tetravalent residue of a substituted mono- or poly-cyclic aromatic hydrocarbon or a substituted or unsubstituted perinone, R.sub.1 represents a substituted or unsubstituted aliphatic, benzene, naphthalene or heterocyclic radical, R.sub.2 represents a substituted or unsubstituted aliphatic, aromatic or heterocyclic radical and Y represents an amino or haloformyl group. A copolycondensate results.
摘要翻译：线性聚酰胺用下式的颜料着色：其中R表示取代的单环或多环芳族烃或取代或未取代的卤代酮的四价残基，R 1表示取代或未取代的脂族，苯，萘或杂环基，R 2表示取代或未取代的脂族，芳族或杂环基，Y表示氨基或卤代甲酰基。共缩聚的结果。

119. 发明授权

US4055565A Optical brightening agents of naphthalimide derivatives 失效
标题翻译：萘二甲酰亚胺衍生物的荧光增白剂
公开(公告)号：US4055565A
公开(公告)日：1977-10-25
申请号：US385578
申请日：1973-08-03
申请人： Seiji Hotta , Takashi Akamatsu
发明人： Seiji Hotta , Takashi Akamatsu
IPC分类号： C07D221/14 , C09B26/02 , C09B57/08 , D06L3/12 , C07D217/24
CPC分类号： C07D221/14 , C09B26/02 , C09B57/08 , D06L3/12
摘要： A naphthalimide derivative having the formula ##STR1## wherein R is an alkyl, or cycloalkyl, an aralkyl, a haloalkyl, an alkoxyalkyl, a hydroxyalkyl, an N,N-dialkylaminoalkyl, an unsubstituted or halogen-, alkyl-, alkoxy- or hydroxy-substituted aryl, or an ammoniumalkyl; X is a group of the formula, ##STR2## wherein A is ##STR3## or an unsubstituted or halogen-substituted arylene, or a group of the formula, ##STR4## wherein R.sub.1 is hydrogen, an alkyl, phenyl, a hydroxyalkyl, or an alkoxyalkyl; Y is --CO--, --COO--, --CONR.sub.3 -- (where R.sub.3 is hydrogen or an alkyl), or --SO.sub.2 --; R.sub.2 is hydrogen, an alkyl, a cycloalkyl, an aralkyl, a haloalkyl, an alkyl- or aryl-substituted amino-alkyl, an unsubstituted or halogen-, alkyl-, alkoxy-, hydroxy-, amino- or alkylamino-substituted aryl, a group of the formula, ##STR5## (where R, R.sub.1 and Y are as defined above and R.sub.4 is a bivalent group), or a group of the formula,--R.sub.5 --Q.sup.+ ..alpha.--(where R.sub.5 is direct linkage or a bivalent group; Q.sup.+ is a substituted ammonium, a cycloammonium or a hydrazinium; and .alpha..sup.- is an anion),Which is useful for optically brightening an organic polymer material.
摘要翻译：具有下式的萘酰亚胺衍生物，其中R是烷基或环烷基，芳烷基，卤代烷基，烷氧基烷基，羟基烷基，N，N-二烷基氨基烷基，未取代或卤素，烷基 - ，烷氧基 - 或羟基取代的芳基或铵烷基; X是下式的基团，其中A是<或者未取代的或卤素取代的亚芳基，或下式的基团，其中R 1是氢，烷基，苯基，羟基烷基或烷氧基烷基; Y是-CO - ， - COO - ， - CONR 3 - （其中R 3是氢或烷基）或-SO 2 - ; R 2是氢，烷基，环烷基，芳烷基，卤代烷基，烷基或芳基取代的氨基 - 烷基，未取代或卤素，烷基 - ，烷氧基 - ，羟基 - ，氨基或烷基氨基取代的芳基，式中的基团（其中R，R 1和Y如上定义，R 4是二价基团）或式-R 5 -Q +的基团。

120. 发明授权

US4039545A Pigmentary imido-perinones 失效
标题翻译：色素亚胺素
公开(公告)号：US4039545A
公开(公告)日：1977-08-02
申请号：US589222
申请日：1975-06-23
申请人： Philippe Yves Edouard Gangneux
发明人： Philippe Yves Edouard Gangneux
IPC分类号： C07D471/22 , C08K5/3465 , C09B5/62 , C09B57/08
CPC分类号： C07D471/22 , C08K5/3465 , C09B5/62 , C09B57/08
摘要： Imido-perinones falling within one of the formulae: ##STR1## wherein R.sub.1 represents the tetravalent residue of a substituted or unsubstituted aromatic hydrocarbon, R.sub.2 represents a substituted or unsubstituted aliphatic or aromatic radical and X represents a primary amino, carboxy or hydroxy group, process for the preparation of such imido perinones which comprises condensing a tetracid of the formula: ##STR2## or the corresponding anhydride with 4,5-diamino-1,8-naphthalic anhydride at the rate of at least two moles of diamine per mole of tetracid and then condensing the perinone dianhydride thus obtained with an amine of the formula:H.sub.2 N -- R.sub.2 -- Xwherein R.sub.1, R.sub.2 and X have the same significance as in claim 1, at the rate of at least two moles of amine, per mole of perinone, and the use of such imido-perinones in the coloration of lacquers, plastic materials or synthetic fibres.
摘要翻译：其中R1表示取代或未取代的芳族烃的四价残基，R2表示取代或未取代的脂族或芳族基团，X表示伯氨基，羧基或羟基组合的方法，其包括将下式的四酸缩合：（II）或其相应的酐与4,5-二氨基-1,8-萘二甲酸酐以至少两摩尔的速率的二胺，然后将由此获得的perinone二酐与下式的胺缩合：

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