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111. 发明授权

US09045381B2 Ruthenium complexes and their uses in processes for formation and/or hydrogenation of esters, amides and derivatives thereof 有权
标题翻译：钌络合物及其在酯，酰胺和衍生物的形成和/或氢化方法中的用途
公开(公告)号：US09045381B2
公开(公告)日：2015-06-02
申请号：US13880328
申请日：2011-10-11
申请人： David Milstein , Ekambaram Balaraman , Chidambaram Gunanathan , Boopathy Gnanaprakasam , Jing Zhang
发明人： David Milstein , Ekambaram Balaraman , Chidambaram Gunanathan , Boopathy Gnanaprakasam , Jing Zhang
IPC分类号： B01J31/18 , C07B41/08 , C07C29/136 , C07C29/149 , C07C29/17 , C07C41/16 , C07C45/00 , C07C51/23 , C07C67/00 , C07C67/03 , C07C209/62 , C07C213/00 , C07C231/02 , C07C231/10 , C07D207/08 , C07D213/38 , C07D241/08 , C07D241/12 , C07D295/023 , C07D307/14 , C07D307/33 , C07D307/83 , C07D309/30 , C07D487/14 , C07F9/58 , C07F15/00 , C08G69/00 , C07C51/02 , C07C51/295 , C07B41/02 , C07B41/12 , C07B43/06 , C07C209/00 , C07C213/02 , C07F9/6558 , C07K1/00
CPC分类号： C07K5/12 , B01J31/18 , B01J31/189 , B01J31/2404 , B01J31/2409 , B01J31/248 , B01J31/2485 , B01J2231/40 , B01J2231/49 , B01J2231/643 , B01J2231/763 , B01J2531/0244 , B01J2531/821 , C07B41/02 , C07B41/08 , C07B41/12 , C07B43/04 , C07B43/06 , C07C29/136 , C07C29/149 , C07C29/177 , C07C41/16 , C07C41/26 , C07C45/002 , C07C45/006 , C07C51/00 , C07C51/02 , C07C51/23 , C07C51/295 , C07C67/00 , C07C67/03 , C07C67/297 , C07C209/00 , C07C209/62 , C07C213/00 , C07C213/02 , C07C231/02 , C07C231/10 , C07C2601/08 , C07C2601/10 , C07C2601/14 , C07D207/06 , C07D207/08 , C07D211/12 , C07D213/38 , C07D241/08 , C07D241/12 , C07D295/023 , C07D295/027 , C07D295/185 , C07D305/06 , C07D307/14 , C07D307/33 , C07D307/44 , C07D307/52 , C07D307/83 , C07D309/30 , C07D487/14 , C07F9/58 , C07F9/65583 , C07F15/0046 , C07F15/0053 , C07K1/00 , C08G69/00 , Y02P20/52 , C07C233/05 , C07C235/06 , C07C233/07 , C07C235/16 , C07C235/14 , C07C235/10 , C07C211/27 , C07C211/07 , C07C211/35 , C07C211/46 , C07C211/10 , C07C215/28 , C07C217/58 , C07C69/14 , C07C69/24 , C07C31/125 , C07C31/12 , C07C49/78 , C07C49/04 , C07C49/10 , C07C49/08 , C07C49/403 , C07C31/205 , C07C31/202 , C07C31/04 , C07C31/08 , C07C33/20 , C07C33/22 , C07C31/1355 , C07C31/10 , C07C43/13 , C07C69/78 , C07C69/75 , C07C53/124 , C07C53/126 , C07C59/125 , C07C57/32 , C07C61/08 , C07C57/30 , C07C65/21 , C07C63/08 , C07C63/06
摘要： The present invention relates to novel Ruthenium catalysts and related borohydride complexes, and the use of such catalysts, inter alia, for (1) hydrogenation of amides (including polyamides) to alcohols and amines; (2) preparing amides from alcohols with amines (including the preparation of polyamides (e.g., polypeptides) by reacting dialcohols and diamines and/or by polymerization of amino alcohols); (3) hydrogenation of esters to alcohols (including hydrogenation of cyclic esters (lactones) or cyclic di-esters (di-lactones) or polyesters); (4) hydrogenation of organic carbonates (including polycarbonates) to alcohols and hydrogenation of carbamates (including polycarbamates) or urea derivatives to alcohols and amines; (5) dehydrogenative coupling of alcohols to esters; (6) hydrogenation of secondary alcohols to ketones; (7) amidation of esters (i.e., synthesis of amides from esters and amines); (8) acylation of alcohols using esters; (9) coupling of alcohols with water to form carboxylic acids; and (10) dehydrogenation of beta-amino alcohols to form pyrazines. The present invention further relates to the novel uses of certain pyridine Ruthenium catalysts.
摘要翻译：本发明涉及新的钌催化剂和相关的硼氢化物络合物，以及这种催化剂的用途，特别是（1）将酰胺（包括聚酰胺）氢化成醇和胺; （2）由醇与胺制备酰胺（包括通过使二醇和二胺反应和/或通过氨基醇的聚合反应制备聚酰胺（例如多肽）; （3）将酯氢化成醇（包括环酯（内酯）或环状二酯（二内酯）或聚酯）的氢化）; （4）将有机碳酸酯（包括聚碳酸酯）氢化成醇，并将氨基甲酸酯（包括聚氨基甲酸酯）或脲衍生物氢化成醇和胺; （5）醇与酯的脱氢偶联; （6）将仲醇醇化成酮类; （7）酯的酰胺化（即从酯和胺合成酰胺）; （8）使用酯酰化醇; （9）将醇与水偶联以形成羧酸; 和（10）β-氨基醇脱氢形成吡嗪。本发明还涉及某些吡啶钌催化剂的新用途。

112. 发明授权

US08802904B2 Processes for making ethanol from acetic acid 有权
标题翻译：从乙酸制备乙醇的方法
公开(公告)号：US08802904B2
公开(公告)日：2014-08-12
申请号：US13826859
申请日：2013-05-17
申请人： Celanese International Corporation
发明人： Victor J. Johnston , Laiyuan Chen , Barbara F. Kimmich , Josefina T. Chapman , James H. Zink , Heiko Weiner , John L. Potts , Radmilla Wollrab
IPC分类号： C07C29/136
CPC分类号： B01J23/6567 , B01J21/08 , B01J21/14 , B01J23/02 , B01J23/626 , B01J37/0207 , B01J37/08 , C07C1/24 , C07C29/149 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C31/08
摘要： A process for selective formation of ethanol from acetic acid by hydrogenating acetic acid in the presence of first metal, a silicaceous support, and at least one support modifier. Preferably, the first metal is selected from the group consisting of copper, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, zinc, chromium, rhenium, molybdenum, and tungsten. In addition the catalyst may comprise a second metal preferably selected from the group consisting of copper, molybdenum, tin, chromium, iron, cobalt, vanadium, tungsten, palladium, platinum, lanthanum, cerium, manganese, ruthenium, rhenium, gold, and nickel.
摘要翻译：通过在第一金属，硅质载体和至少一种载体改性剂存在下氢化乙酸，从乙酸中选择性形成乙醇的方法。优选地，第一金属选自铜，铁，钴，镍，钌，铑，钯，锇，铱，铂，钛，锌，铬，铼，钼和钨。此外，催化剂可以包含优选选自铜，钼，锡，铬，铁，钴，钒，钨，钯，铂，镧，铈，锰，钌，铼，金和镍的第二金属。

113. 发明申请

US20100324343A1 PROCESS FOR THE PREPARATION OF HYDROXYTYROSOL 失效
标题翻译：制备羟肟酸的方法
公开(公告)号：US20100324343A1
公开(公告)日：2010-12-23
申请号：US12528554
申请日：2008-02-28
申请人： Manfred Breuninger , Marcel Joray
发明人： Manfred Breuninger , Marcel Joray
IPC分类号： C07C39/11 , C07C29/136 , C07C39/10
CPC分类号： C07C45/64 , C07C37/002 , C07C39/11 , C07C45/46 , C07C45/80 , C07C45/81 , C07C49/825 , C07C49/82
摘要： Process for the preparation of hydroxytyrosol, characterized by reacting 4-chloroacetyl-catechol with a metal formate and formic acid in an aqueous solvent optionally containing a lower alkanol and catalytically hydrogenating the 4-hydroxyacetyl-catechol obtained in the presence of a precious metal, preferably on a carrier.
摘要翻译：羟基酪醇的制备方法，其特征在于使4-氯乙酰基邻苯二酚与金属甲酸盐和甲酸在含有低级链烷醇的水性溶剂中反应，并在贵金属存在下催化氢化得到的4-羟基乙酰基邻苯二酚在运营商

114. 发明申请

US20100280273A1 HYDROGENATION OF ESTERS WITH RU/BIDENTATE LIGANDS COMPLEXES 有权
标题翻译：用RU / BIDENTATE LIGANDS复合物加成酯
公开(公告)号：US20100280273A1
公开(公告)日：2010-11-04
申请号：US12839787
申请日：2010-07-20
申请人： Lionel Saudan , Philippe Dupau , Jean-Jacques Riedhauser , Patrick Wyss
发明人： Lionel Saudan , Philippe Dupau , Jean-Jacques Riedhauser , Patrick Wyss
IPC分类号： C07C29/136 , C07C41/18 , C07C213/00
CPC分类号： C07B41/02 , B01J31/189 , B01J2231/643 , B01J2531/0255 , B01J2531/821 , C07C29/149 , C07C41/26 , C07C213/00 , C07C2601/14 , C07C2601/16 , C07C2602/10 , C07C2602/28 , C07D307/33 , C07D307/88 , C07D307/92 , C07D307/94 , C07D309/30 , C07F9/5004 , C07F9/5022 , C07F9/5407 , C07F9/58 , C07F15/0053 , C07C215/68 , C07C33/14 , C07C33/22 , C07C35/36 , C07C35/08 , C07C31/20 , C07C31/137 , C07C33/20 , C07C31/1355 , C07C31/125 , C07C33/46 , C07C43/23
摘要： The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Ru complexes with bidentate ligands, having one amino or imino coordinating group and one phosphino coordinating group, in hydrogenation processes for the reduction of esters or lactones into the corresponding alcohol or diol respectively.
摘要翻译：本发明涉及催化氢化领域，更具体地说，涉及在具有一个氨基或亚氨基配位基团和一个膦配位基团的二齿配位体上使用Ru络合物，在用于还原酯或内酯的氢化方法中相应的醇或二醇。

115. 发明申请

US20100179356A1 PROCESSES FOR PRODUCING ETHYLENE GLYCOL FROM OXALATE(S) 有权
标题翻译：用于生产乙酸甘油酯的方法（S）
公开(公告)号：US20100179356A1
公开(公告)日：2010-07-15
申请号：US12642621
申请日：2009-12-18
申请人： Juntao LIU , Weimin Yang , Fengxia Sun , Siqing Zhong , Wanmin Wang
发明人： Juntao LIU , Weimin Yang , Fengxia Sun , Siqing Zhong , Wanmin Wang
IPC分类号： C07C29/136
CPC分类号： B01J35/0006 , B01J21/08 , B01J23/72 , B01J23/745 , B01J23/78 , B01J23/80 , B01J23/868 , B01J23/8892 , B01J37/0201 , C07C29/149 , Y02P20/52 , C07C31/202
摘要： Provided are processes for producing ethylene glycol from oxalate(s), wherein two or more reaction zones in series are used, and oxalate feedstock is fed stagewise, or hydrogen feedstock and optionally a solvent are fed stagewise. The present processes achieve higher selectivity for the product and improved stability of catalysts.
摘要翻译：提供了从草酸生产乙二醇的方法，其中使用串联的两个或更多个反应区，并且草酸进料进料阶段，或者氢原料和任选的溶剂进料阶段进料。本发明方法对产物获得更高的选择性并提高催化剂的稳定性。

116. 发明申请

US20100168440A1 Homogeneous Asymmetric Hydrogenation Process 有权
公开(公告)号：US20100168440A1
公开(公告)日：2010-07-01
申请号：US12703053
申请日：2010-02-09
申请人： Hideo SHIMIZU , Daisuke Igarashi , Wataru Kuriyama , Yukinori Yusa
发明人： Hideo SHIMIZU , Daisuke Igarashi , Wataru Kuriyama , Yukinori Yusa
IPC分类号： C07D209/48 , C07C5/03 , C07C35/08 , C07C35/18 , C07C29/136 , C07D307/44 , C07C67/02 , C07C69/76 , C07C45/62
CPC分类号： C07C29/145 , B01J31/2409 , B01J31/2452 , B01J31/2457 , B01J2231/643 , B01J2531/0266 , B01J2531/16 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C29/175 , C07C41/26 , C07C45/62 , C07C67/303 , C07C231/12 , C07C2601/14 , C07C2601/16 , C07D209/08 , C07D307/46 , C07F9/5045 , C07F9/65517 , C07C49/403 , C07C69/612 , C07C69/24 , C07C233/47 , C07C43/196 , C07C31/125 , C07C33/18 , C07C33/22 , C07C35/08 , C07C35/18
摘要： Provide that a useful catalyst for homogeneous hydrogenation, particularly a catalyst for homogeneous asymmetric hydrogenation for hydrogenation, particularly asymmetric hydrogenation, which is obtainable with comparative ease and is excellent in economically and workability, and a process for producing a hydrogenated compound of an unsaturated compound, particularly an optically active compound using said catalyst with a high yield and optical purity.

117. 发明授权

US07678947B2 Method for producing halogen-substituted benzenedimethanol 失效
标题翻译：制备卤素取代苯二甲醇的方法
公开(公告)号：US07678947B2
公开(公告)日：2010-03-16
申请号：US11572505
申请日：2005-08-02
申请人： Koji Hagiya
发明人： Koji Hagiya
IPC分类号： C07C33/28 , C07C29/136
CPC分类号： C07C29/147 , C07C33/46
摘要： A method for producing a halogen-substituted benzenedimethanol represented by the formula (2): wherein X1 to X4 are the same or different and independently represent a halogen atom or the like, provided that at least one of X1 to X4 is a halogen atom, by reacting a halogen-substituted terephthalic acid diester represented by the formula (1): wherein R1 and R2 are the same or different and independently represent a C1-C20 alkyl group which may have a substitutent or substituents, and X1 to X4 is the same as defined above, with a borohydride compound in the presence of an alcohol which comprises adding the alcohol into a mixture of the halogen-substituted terephthalic acid diester represented by the formula (1), the borohydride compound and a solvent.
摘要翻译：由式（2）表示的卤素取代的苯二甲醇的制备方法：其中X1至X4相同或不同，并且独立地表示卤素原子等，条件是X1至X4中的至少一个为卤素原子，通过使由式（1）表示的卤素取代的对苯二甲酸二酯：其中R 1和R 2相同或不同并且独立地表示可以具有取代基的C 1 -C 20烷基，并且X 1至X 4相同在醇的存在下与硼氢化合物反应，该醇包括将醇加入由式（1）表示的卤素取代的对苯二甲酸二酯，硼氢化合物和溶剂的混合物中。

118. 发明申请

US20090082599A1 ACCELERATED AMIDE AND ESTER REDUCTIONS WITH AMINE BORANES AND ADDITIVES 有权
标题翻译：加速的酰胺和降解与氨基硼烷和添加剂
公开(公告)号：US20090082599A1
公开(公告)日：2009-03-26
申请号：US11859377
申请日：2007-09-21
申请人： Elizabeth Burkhardt , Alex J. Attlesey , Christopher P. Sutton , Karl Matos
发明人： Elizabeth Burkhardt , Alex J. Attlesey , Christopher P. Sutton , Karl Matos
IPC分类号： C07C209/30 , C07C209/24 , C07C29/136
CPC分类号： C07C29/147 , C07C29/143 , C07C209/48 , C07C209/50 , C07C209/52 , C07C31/12 , C07C33/22
摘要： In a process for the accelerated reduction of organic substrates, selected from the group consisting of esters, amides, nitriles, acids, ketones, imines or mixtures thereof, they are reacted with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing either Lewis acidic or Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl or nitrile or imine group of the substrate or the Lewis basic site can coordinate with the borane.
摘要翻译：在加速还原有机底物的方法中，选自酯，酰胺，腈，酸，酮，亚胺或其混合物，它们与胺硼烷，硫化硼烷或醚硼烷络合物作为硼烷源反应在其结构中含有路易斯酸性或路易斯碱性位点的有机促进剂化合物的存在下，其中路易斯酸性位点可以与底物的羰基或腈或亚胺基团或路易斯碱性位点配位，可与硼烷配位。

119. 发明授权

US07408087B2 Process for making unsaturated coconut and/or palm nut fatty alcohols 有权
标题翻译：制备不饱和椰子和/或棕榈仁脂肪醇的方法
公开(公告)号：US07408087B2
公开(公告)日：2008-08-05
申请号：US09874899
申请日：2001-06-05
申请人： Stephan Heck , Norbert Klein , Horst-Dieter Komp , Christiane Boehr , Norbert Huebner , Alfred Westfechtel
发明人： Stephan Heck , Norbert Klein , Horst-Dieter Komp , Christiane Boehr , Norbert Huebner , Alfred Westfechtel
IPC分类号： C07C29/147 , C07C29/136
CPC分类号： C07C29/149 , C07C31/125 , C07C33/02 , C07C33/025
摘要： Unsaturated coconut and/or palm nut fatty alcohols having an iodine number in the range from 65 to 85, which essentially comprise unsaturated fatty alcohols and mixtures of saturated fatty alcohols of the formula (I): R1OH (I) in which R1 is a saturated or unsaturated, linear or branched alkyl radical having 12 to 20 carbon atoms, obtainable by fractionating coconut and/or palm nut fatty acid methyl esters to obtain a fraction containing predominantly C16-C18 portions, fractionating the C16-C18 fatty acid methyl ester fraction into a predominantly saturated distillate and a predominantly unsaturated bottom product, and hydrogenating the bottom product with retention of the double bonds to give the corresponding alcohols; are disclosed.
摘要翻译：具有65至85的碘值的不饱和椰子和/或棕榈仁脂肪醇，其基本上包含不饱和脂肪醇和式（I）的饱和脂肪醇的混合物：<β在线配方描述=“ 在线公式“end =”lead“？> R 1 OH（I）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中R 可以通过将椰子和/或棕榈仁脂肪酸甲酯分级得到主要为C 16的级分，可获得具有12至20个碳原子的饱和或不饱和的直链或支链烷基将C 16 -C 18脂肪酸甲酯部分分馏成主要饱和的馏出物，主要是不饱和底物，并保留双键氢化底物，得到相应的醇; 被披露。

120. 发明授权

US06930213B1 Process for the hydrogenation of acetone 有权
标题翻译：丙酮氢化方法
公开(公告)号：US06930213B1
公开(公告)日：2005-08-16
申请号：US09618044
申请日：2000-07-17
申请人： Werner Pompetzki , Joachim Schuler , Dietrich Maschmeyer
发明人： Werner Pompetzki , Joachim Schuler , Dietrich Maschmeyer
IPC分类号： C07B61/00 , C07C29/145 , C07C31/10 , C07C29/136 , C07C29/143
CPC分类号： C07C29/145 , C07C31/10
摘要： Acetone is hydrogenated by a process comprising, conducting the liquid-phase hydrogenation of acetone in at least two hydrogenation process stages, thereby preparing isopropanol product with a high selectivity and in high purity.
摘要翻译：丙酮通过包括在至少两个氢化工艺阶段中进行丙酮的液相氢化的方法氢化，从而以高选择性和高纯度制备异丙醇产物。

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