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111. 发明授权

US08563761B2 Boron or aluminum complexes 有权
标题翻译：硼或铝络合物
公开(公告)号：US08563761B2
公开(公告)日：2013-10-22
申请号：US12736195
申请日：2009-03-19
申请人： Michel Armand , Jean-Marie Tarascon , Nadir Recham , Sylvie Grugeon , Stephane Laruelle , Shanmukaraj Devaraj
发明人： Michel Armand , Jean-Marie Tarascon , Nadir Recham , Sylvie Grugeon , Stephane Laruelle , Shanmukaraj Devaraj
IPC分类号： C07F5/06 , C07F5/02 , C01G49/02
CPC分类号： C07F5/022 , C07F5/025 , C07F5/069 , H01M10/052 , H01M10/0567
摘要： The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.
摘要翻译：本发明涉及硼和铝络合物，其制备方法及其用于增溶离子化合物的用途。所述络合物具有下式之一：其中D表示B或Al; R1表示R，RF，NO2，CN，C（= O）OR，RSO2或RFSO2; -X1-，-X2-，-X3-和X4各自表示二价基团> C = O，> C = NC = N，> C = C（C = N）2，> CR2R3或> SO2; -Y2-，-Y2-和-Y3-各自表示二价基团-O - ，> N（C = N），> N（CORF），> N（SO 2 R 4），NR 4，N（COR 4） N（SO2RF）; R，R 2和R 3各自表示H，烷基，芳基，烷基芳基，芳烷基，氧杂烷基或烯基; R4表示烷基，芳基，烷基芳基，杂芳基，芳基烷基，氧杂烷基，烯基或RFCH2-基团; RF是全氟烷基，部分氟化烷基或部分或全部氟化苯基; R'2和R'3各自表示R或F.

112. 发明申请

US20120135311A1 Li4Ti5O12, Li(4-alpha)ZalphaTi5O12 OR Li4ZbetaTi(5-beta)O12 PARTICLES, PROCESSES FOR OBTAINING SAME AND USE AS ELECTROCHEMICAL GENERATORS 有权
标题翻译： Li4Ti5O12，Li（4-α）ZalphaTi5O12或Li4ZbetaTi（5-beta）O12颗粒，其获得方法和用作电化学发生器
公开(公告)号：US20120135311A1
公开(公告)日：2012-05-31
申请号：US13360173
申请日：2012-01-27
申请人： Karim ZAGHIB , Michel Gauthier , Fernand Brochu , Abdelbast Guerfi , Monique Massé , Michel Armand
发明人： Karim ZAGHIB , Michel Gauthier , Fernand Brochu , Abdelbast Guerfi , Monique Massé , Michel Armand
IPC分类号： H01M4/131 , H01G9/155 , C01D15/02 , H01B1/08 , B82Y40/00 , B82Y30/00
CPC分类号： H01M4/485 , B82Y30/00 , C01G23/003 , C01G23/005 , C01P2002/77 , C01P2002/88 , C01P2004/03 , C01P2004/64 , C01P2006/40 , H01G9/155 , H01G11/04 , H01G11/46 , H01M4/02 , H01M4/0471 , H01M4/131 , H01M4/136 , H01M4/366 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/623 , H01M4/625 , H01M4/661 , H01M4/745 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2300/004 , H01M2300/0082 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02P70/54 , Y10T428/2982
摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, preferably having a spinel structure, wherein β is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), α representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.
摘要翻译： Li4Ti5O12，Li（4-α）ZαTi5O12或Li4Z＆bgr; Ti（5-＆bgr））O12的新颗粒的合成方法，优选具有尖晶石结构，其中＆bgr; 大于0且小于或等于0.5（优选具有尖晶石结构），α表示大于零且小于或等于0.33的数，Z表示至少一种金属的来源，优选选自所制成的组 Mg，Nb，Al，Zr，Ni，Co这些颗粒被涂覆了一层碳，特别表现出电化学特性，作为电化学发生器中阳极和/或阴极的组分是特别有意义的。

113. 发明授权

US07998617B2 Cathode materials for secondary (rechargeable) lithium batteries 有权
公开(公告)号：US07998617B2
公开(公告)日：2011-08-16
申请号：US11647899
申请日：2006-12-29
申请人： Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
发明人： Michel Armand , John B. Goodenough , Akshaya K. Padhi , Kirakodu S. Nanjundaswamy , Christian Masquelier
IPC分类号： H01M4/58 , H01M4/13
CPC分类号： H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要： The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivineor the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.

114. 发明申请

US20110086273A1 ELECTRODE MATERIALS WITH HIGH SURFACE CONDUCTIVITY 有权
标题翻译：具有高表面电导率的电极材料
公开(公告)号：US20110086273A1
公开(公告)日：2011-04-14
申请号：US12899067
申请日：2010-10-06
申请人： NATHALIE RAVET , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
发明人： NATHALIE RAVET , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
IPC分类号： H01M4/583 , H01M4/525 , H01M4/505 , H01M4/485
CPC分类号： H01M4/136 , H01B1/24 , H01G9/042 , H01G9/155 , H01M4/364 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要： The present invention concerns electrode materials capable of redox reactions by electrons and alkali ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要翻译：本发明涉及能够通过电子和碱离子与电解质交换的氧化还原反应的电极材料。应用领域是超级电容器类型的初级（电池）或二级电化学发生器，超级电容器和光调制系统。

115. 发明授权

US07897674B2 Polymer electrolyte with high stability, its use in electrochemical systems 有权
标题翻译：聚合物电解质具有高稳定性，其在电化学系统中的应用
公开(公告)号：US07897674B2
公开(公告)日：2011-03-01
申请号：US10501844
申请日：2003-01-15
申请人： Karim Zaghib , Michel Perrier , Abdelbast Guerfi , Elisabeth Dupuis , Patrick Charest , Francois Allaire , Michel Armand
发明人： Karim Zaghib , Michel Perrier , Abdelbast Guerfi , Elisabeth Dupuis , Patrick Charest , Francois Allaire , Michel Armand
IPC分类号： C08L1/00
CPC分类号： H01G9/038 , C08F283/00 , C08F290/062 , C08G65/2609 , C08G65/33348 , C08L33/12 , C08L71/02 , C09D133/12 , H01G11/56 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2300/0091 , Y02E60/13 , C08L2666/04
摘要： Polymer electrolyte for an electrochemical generator based on at least a four branched polymer, at least a poly(vinylyldienefluoride), a poly(vinyldiene fluoro-co-hexafluoropropene copolymer), a poly(tetrafluoroethylene), a poly(ethylene-co-propylene-co-5-methylene-2-norbornene) or an ethylene propylene-diene copolymer, a polyol, a poly(methylmethacrylate, a poly(acrylonitrile), SiO2Al2O3, or nano TiO2 non coated or coated with an organic material. This electrolyte allows to prepare electrolytic compositions that can be used in high performance electrochemical devices.
摘要翻译：至少四种支链聚合物，至少一种聚（乙烯基二氟化物），聚（乙烯基二烯氟 - 共 - 六氟丙烯共聚物），聚（四氟乙烯），聚（乙烯 - 共 - 丙烯 - 共聚-5-亚甲基-2-降冰片烯）或乙烯丙烯 - 二烯共聚物，多元醇，聚（甲基丙烯酸甲酯，聚（丙烯腈），SiO 2 Al 2 O 3或纳米TiO 2），未涂覆或涂覆有机材料，该电解质允许制备可用于高性能电化学装置的电解质组合物。

116. 发明授权

US07815819B2 Electrode materials with high surface conductivity 有权
标题翻译：电极材料表面电导率高
公开(公告)号：US07815819B2
公开(公告)日：2010-10-19
申请号：US12033636
申请日：2008-02-19
申请人： Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
发明人： Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
IPC分类号： H01B1/08
CPC分类号： H01M4/136 , H01B1/24 , H01G9/042 , H01G9/155 , H01M4/364 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要： The present invention concerns electrode materials capable of redox reactions by electrons and alkali ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要翻译：本发明涉及能够通过电子和碱离子与电解质交换的氧化还原反应的电极材料。应用领域是超级电容器类型的初级（电池）或二级电化学发生器，超级电容器和光调制系统。

117. 发明授权

US07601318B2 Method for synthesis of carbon-coated redox materials with controlled size 有权
标题翻译：用于合成具有受控尺寸的碳涂覆的氧化还原材料的方法
公开(公告)号：US07601318B2
公开(公告)日：2009-10-13
申请号：US10362763
申请日：2001-09-21
申请人： Michel Armand , Michel Gauthier , Jean-Francois Magnan , Nathalie Ravet
发明人： Michel Armand , Michel Gauthier , Jean-Francois Magnan , Nathalie Ravet
IPC分类号： H01B1/08 , H01M4/58 , C01B17/96
CPC分类号： H01G9/155 , C01B17/96 , C01B25/37 , C01B25/45 , C01B33/20 , C01P2004/03 , C01P2004/04 , C01P2004/50 , C01P2004/80 , H01M4/136 , H01M4/366 , H01M4/485 , H01M4/525 , H01M4/5825 , H01M4/625 , H01M10/052 , H01M10/0525 , Y02E60/13 , Y10T428/2982 , Y10T428/2991 , Y10T428/30
摘要： A method for the synthesis of compounds of the formula C—LixM1−yM′y(XO4)n, where C represents carbon cross-linked with the compound LixM1−yM′y(XO4)n, in which x, y and n are numbers such as 0≦x≦2, 0≦y≦0.6, and 1≦n≦1.5, M is a transition metal or a mixture of transition metals from the first period of the periodic table, M′ is an element with fixed valency selected among Mg2+, Ca2+, Al3+, Zn2+ or a combination of these same elements and X is chosen among S, P and Si, by bringing into equilibrium, in the required proportions, the mixture of precursors, with a gaseous atmosphere, the synthesis taking place by reaction and bringing into equilibrium, in the required proportions, the mixture of the precursors, the procedure comprising at least one pyrolysis step of the carbon source compound in such a way as to obtain a compound in which the electronic conductivity measured on a sample of powder compressed at a pressure of 3750 Kg·cm−2 is greater than 10−8 S·cm−1. The materials obtained have excellent electrical conductivity, as well a very improved chemical activity.
摘要翻译：用于合成式C-LixM1-yM'y（XO4）n的化合物的方法，其中C表示与化合物LixM1-yM'y（XO4）n交联的碳，其中x，y和n为数字如0 <= x <= 2,0 <= y <= 0.6，1 <= n <= 1.5，M是过渡金属或来自周期表第一周期的过渡金属的混合物，M' 是选自Mg2 +，Ca2 +，Al3 +，Zn2 +或这些相同元素的组合的固定化合价元素，X选自S，P和Si，通过以所需比例以所需比例将前体混合物与通过反应进行合成，并以所需比例使所述前体的混合物达到平衡，所述前体的混合物以包含至少一个碳源化合物的热解步骤的方式得到其中在压力为3750Kg·cm-2压缩的粉末样品上测量的电子电导率大于10-8Scm-1。获得的材料具有优异的导电性，以及非常改进的化学活性。

118. 发明申请

US20070281215A1 Cathode materials for secondary (rechargeable) lithium batteries 审中-公开
标题翻译：二次（可充电）锂电池的阴极材料
公开(公告)号：US20070281215A1
公开(公告)日：2007-12-06
申请号：US11890130
申请日：2007-08-03
申请人： Michel Armand , John Goodenough , Akshaya Padhi , Kirakodu Nanjundaswamy , Christian Masquelier
发明人： Michel Armand , John Goodenough , Akshaya Padhi , Kirakodu Nanjundaswamy , Christian Masquelier
IPC分类号： H01M4/58 , C01B25/45
CPC分类号： H01M4/136 , C01B25/45 , G02F1/155 , H01M4/049 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M2004/028 , H01M2300/0068 , Y10T29/49108
摘要： The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
摘要翻译：本发明涉及用作碱离子二次（可再充电）电池，特别是锂离子电池中的电极的材料。本发明提供了具有有序橄榄石，改性橄榄石或菱方NASICON结构的过渡金属化合物和作为至少一种成分的聚阴离子（PO 3 SO 3）3 - 用作碱电池可充电电池的电极材料。

119. 发明申请

US20070185293A1 FLUOROSULPHONATED ELASTOMERS WITH LOW GLASS TRANSITION BASED OF VINYLIDENE FLUORIDE 审中-公开
标题翻译：基于氟乙烯的低玻璃化转变的氟化弹性体
公开(公告)号：US20070185293A1
公开(公告)日：2007-08-09
申请号：US11670826
申请日：2007-02-02
申请人： Bruno AMEDURI , Michel Armand , Mario Boucher , Abdellatif Manseri
发明人： Bruno AMEDURI , Michel Armand , Mario Boucher , Abdellatif Manseri
IPC分类号： C08F16/24
CPC分类号： C08F214/222 , C08F14/22 , C08F216/1408 , Y10T428/139 , C08F2/04
摘要： The present invention describes the synthesis of new sulforated fluorinated elastomers having very low glass transition temperatures (Tg), a good resistance to bases, oils and fuels and good properties of workability. These elastomers contain, by way of example, from 80 to 60 mole % of vinylidene fluoride (VDF) and 20 to 40 mole % of perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride (PFSO2F). In this case, they are prepared by radical copolymerisation of VDF and PFSO2F in the presence of different organic initiators, for example, peroxides, peresters or diazo compounds.
摘要翻译：本发明描述了具有非常低的玻璃化转变温度（Tg）的良好耐碱性，油和燃料的良好性能以及良好的可加工性能的新型磺化氟化弹性体的合成。这些弹性体例如含有80至60摩尔％的偏二氟乙烯（VDF）和20至40摩尔％的全氟（4-甲基-3,6-二氧杂辛-7-烯）磺酰氟（PFSO _{2F）。在这种情况下，它们通过在不同的有机引发剂例如过氧化物，过酸酯或重氮化合物的存在下，通过VDF和PFSO 2 F F的自由基共聚来制备。}

120. 发明申请

US20060166093A1 Electrode coated with a film obtained from an aqueous solution comprising a water-soluble binder, production method thereof and uses of same 有权
标题翻译：用由包含水溶性粘合剂的水溶液获得的膜涂覆的电极，其制备方法和用途
公开(公告)号：US20060166093A1
公开(公告)日：2006-07-27
申请号：US10534697
申请日：2003-11-13
申请人： Karim Zaghib , Michel Armand , Abdelbast Guerfi , Michel Perrier , Elisabeth Dupuis , Patrick Charest
发明人： Karim Zaghib , Michel Armand , Abdelbast Guerfi , Michel Perrier , Elisabeth Dupuis , Patrick Charest
IPC分类号： H01M4/62 , B05D5/12 , H01M4/74 , H01M4/66
CPC分类号： H01M4/0404 , H01G11/06 , H01G11/24 , H01G11/28 , H01G11/30 , H01G11/32 , H01G11/42 , H01G11/46 , H01G11/86 , H01M2/145 , H01M2/1653 , H01M4/04 , H01M4/0409 , H01M4/0471 , H01M4/133 , H01M4/136 , H01M4/139 , H01M4/1391 , H01M4/1393 , H01M4/1397 , H01M4/366 , H01M4/5825 , H01M4/587 , H01M4/621 , H01M4/622 , H01M4/623 , H01M4/625 , H01M4/66 , H01M4/661 , H01M10/0525 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2004/027 , H01M2004/028 , H01M2300/0028 , H01M2300/0037 , H01M2300/004 , H01M2300/0042 , H01M2300/0082 , Y02E60/122 , Y02E60/13 , Y02P70/54
摘要： The invention relates to a method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.
摘要翻译：本发明涉及一种制备电化学电极的方法，其部分或全部被膜覆盖，所述膜通过在电极上铺展包含水溶性粘合剂的水溶液并随后干燥而获得。由此获得的电极的生产成本降低，并且其表面孔隙率与期望的电阻值相关联。

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