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101. 发明授权

US08968931B2 Crystalline mesoporous titanium dioxide and the use thereof in electrochemical devices 有权
标题翻译：结晶介孔二氧化钛及其在电化学装置中的应用
公开(公告)号：US08968931B2
公开(公告)日：2015-03-03
申请号：US13508529
申请日：2010-11-08
申请人： Palani Balaya , Ananthanarayanan Krishnamoorthy , Saravanan Kuppan
发明人： Palani Balaya , Ananthanarayanan Krishnamoorthy , Saravanan Kuppan
IPC分类号： H01M4/50 , B01J21/06 , C01G23/08 , H01M4/02 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/03 , H01G9/20 , H01M4/133 , H01M4/1393 , H01M4/485 , H01M4/58 , H01M4/62 , H01M10/0525 , C01G23/053
CPC分类号： C01G23/08 , B01J21/063 , B01J35/0013 , B01J35/0026 , B01J35/004 , B01J35/023 , B01J35/1019 , B01J35/1061 , B01J37/036 , C01G23/053 , C01P2002/60 , C01P2002/72 , C01P2002/78 , C01P2004/03 , C01P2004/04 , C01P2004/62 , C01P2006/11 , C01P2006/12 , C01P2006/16 , C01P2006/40 , H01G9/2031 , H01M4/133 , H01M4/1393 , H01M4/485 , H01M4/5825 , H01M4/624 , H01M10/0525 , H01M2004/021 , Y02E10/542 , Y02E60/122
摘要： The present invention relates to the preparation of a mesoporous substantially pure anatase titanium oxide (meso-TiO2) and its use in electrochemical devices, in particular lithium-ion batteries.
摘要翻译：本发明涉及介孔基本上纯的锐钛矿型氧化钛（meso-TiO2）的制备及其在电化学装置，特别是锂离子电池中的应用。

102. 发明授权

US08952248B2 Dye-sensitized solar cell module and method of fabricating the same 有权
标题翻译：染料敏化太阳能电池模块及其制造方法
公开(公告)号：US08952248B2
公开(公告)日：2015-02-10
申请号：US12962199
申请日：2010-12-07
申请人： Sung Hoon Joo , Seong Kee Park , Seung Hoon Ryu , Noh Jin Myung , So Mi Jeong
发明人： Sung Hoon Joo , Seong Kee Park , Seung Hoon Ryu , Noh Jin Myung , So Mi Jeong
IPC分类号： H01G9/20
CPC分类号： H01G9/2031 , H01G9/2068 , Y02E10/542 , Y02P70/521
摘要： A dye-sensitized solar cell module is disclosed. The dye-sensitized solar cell module includes a solution capable of being selectively printed on only a desired region and used in the formation of a metal oxide film. The solution for the metal oxide film formation can be selectively printed on only the surface of metal oxide nano-particle without affecting the electrical conductivity of the electrode and a sealant interposed between transparent electrodes. Therefore, the dye-sensitized solar cell module can greatly improve the output efficiency. Moreover, the dye-sensitized solar cell module can prevent the output efficiency deterioration at an enlarged size.
摘要翻译：公开了染料敏化太阳能电池模块。染料敏化太阳能电池模块包括能够仅选择性地印刷在所需区域上并用于形成金属氧化物膜的溶液。用于金属氧化物膜形成的溶液可以仅选择性地印刷在金属氧化物纳米颗粒的表面上，而不影响电极的导电性和介于透明电极之间的密封剂。因此，染料敏化太阳能电池模块可以大大提高输出效率。此外，染料敏化太阳能电池模块可以防止放大的输出效率恶化。

103. 发明申请

US20150024539A1 FORMULATION OF COLLOIDAL TITANIUM-OXIDE SOLUTIONS COMPOSITION FOR COATING AND PRINTING METHODS, AND IMPROVEMENT OF THE OUTPUT AND LIFESPAN OF ORGANIC P-I-N/N-I-P PHOTOVOLTAIC CELLS 有权
标题翻译：用于涂料和印刷方法的胶体钛氧化物溶液组合物的制备和有机P-I-N / N-I-P光伏电池的输出和活性物质的改进
公开(公告)号：US20150024539A1
公开(公告)日：2015-01-22
申请号：US14345381
申请日：2012-09-12
申请人： Luc René Roger Brohan , Arkadiusz Michal Karpinski , Mireille Richard-Plouet , Solenn Berson , Stéphane Guillerez , Mickaël Barret , Jérôme Mourao
发明人： Luc René Roger Brohan , Arkadiusz Michal Karpinski , Mireille Richard-Plouet , Solenn Berson , Stéphane Guillerez , Mickaël Barret , Jérôme Mourao
IPC分类号： H01L31/18 , C01G23/08 , H01L31/032 , C09D11/30
CPC分类号： H01L31/18 , B82Y30/00 , C01G23/053 , C01G23/08 , C01P2004/62 , C01P2004/64 , C01P2006/22 , C01P2006/40 , C09D11/30 , H01G9/2031 , H01G9/2059 , H01L31/032 , Y02E10/542 , Y02P70/521
摘要： The invention relates to a method for preparing a colloidal nanoparticle solution, including: (a) dissolving a titanium-oxide precursor, referred to as a precursor, in one or more solvents, referred to as precursor solvents; and (b) chemically converting, preferably by means of hydrolysis, said titanium-oxide precursor and said precursor solvent into a colloidal-solution solvent so as to form titanium-oxide nanoparticles that are dispersed in the colloidal-solution solvent, said colloidal solution having a dynamic viscosity of between 4 and 54 cP at 20° C. and 101,325 Pa.The invention also relates to a colloidal titanium-oxide nanoparticle solution containing a dispersion of titanium-oxide nanoparticles in a solvent or system of solvents, the viscosity of which is between 4 and 54 cP, said solution being particularly obtainable according to the method of the invention, as well as to the uses thereof, in particular for preparing photovoltaic cells. The invention also relates to a method for generating power using a semiconductor prepared from said solution.
摘要翻译：本发明涉及一种制备胶体纳米颗粒溶液的方法，包括：（a）将被称为前体的氧化钛前体溶解在称为前体溶剂的一种或多种溶剂中; 和（b）优选通过水解将所述氧化钛前体和所述前体溶剂化学转化成胶体溶剂，以形成分散在胶体溶液中的氧化钛纳米颗粒，所述胶体溶液具有在20℃和101,325Pa下动态粘度在4和54cP之间。本发明还涉及一种胶体二氧化钛纳米颗粒溶液，其中含有氧化钛纳米颗粒在溶剂或溶剂体系中的分散体，其粘度在4和54cP之间，所述溶液是特别可根据本发明的方法获得的，以及其用途，特别是用于制备光伏电池。本发明还涉及一种使用由所述解决方案制备的半导体发电的方法。

104. 发明授权

US08933329B2 Maleimide-based compound, and tautomer or stereoisomer thereof, dye for photoelectric conversion, and semiconductor electrode, photoelectric conversion element and photoelectrochemical cell using the same 有权
标题翻译：马来酰亚胺类化合物及其互变异构体或立体异构体，光电转换用染料，半导体电极，光电转换元件及使用其的光电化学电池
公开(公告)号：US08933329B2
公开(公告)日：2015-01-13
申请号：US13697974
申请日：2011-05-16
申请人： Katsumi Maeda , Shin Nakamura , Kentaro Nakahara
发明人： Katsumi Maeda , Shin Nakamura , Kentaro Nakahara
IPC分类号： H01L51/00 , C07D409/04 , C07D495/04 , C09B57/00 , H01G9/20
CPC分类号： C07D409/04 , C07D495/04 , C09B57/008 , H01G9/2031 , H01G9/2059 , H01L51/0059 , Y02E10/542
摘要： It is an object to provide a maleimide-based compound having excellent photoelectric conversion characteristics, and a tautomer or a stereoisomer thereof, a dye for photoelectric conversion, a semiconductor electrode, a photoelectric conversion element, and a photoelectrochemical cell. In order to accomplish the above-described objects, a dye for photoelectric conversion including at least one compound represented by the following general formula (1) is provided. (In the formula (1), R1 represents a direct bond, or a substituted or unsubstituted alkylene group. X represents an acidic group. D represents an organic group containing an electron-donating substituent. Z represents a linking group that has at least one hydrocarbon group selected from aromatic rings or heterocyclic rings).
摘要翻译：本发明的目的是提供具有优异光电转换特性的马来酰亚胺基化合物及其互变异构体或立体异构体，用于光电转换的染料，半导体电极，光电转换元件和光电化学电池。为了实现上述目的，提供了包含至少一种由以下通式（1）表示的化合物的光电转换用染料。（式（1）中，R 1表示直接键或取代或未取代的亚烷基，X表示酸性基团，D表示含有供电子基团的有机基团，Z表示具有至少1个选自芳环或杂环的烃基）。

105. 发明授权

US08927757B2 Process for the preparation of perfluoroalkylcyano- or perfluoroalkylcyanofluoroborates 有权
标题翻译：制备全氟烷基氰基或全氟烷基氰基氟硼酸盐的方法
公开(公告)号：US08927757B2
公开(公告)日：2015-01-06
申请号：US13522526
申请日：2011-01-12
申请人： Nikolai (Mykola) Ignatyev , Michael Schulte , Jan Sprenger , Maik Finze , Walter Frank
发明人： Nikolai (Mykola) Ignatyev , Michael Schulte , Jan Sprenger , Maik Finze , Walter Frank
IPC分类号： C07F5/02 , H01M10/052 , H01M10/0568 , H01G9/20
CPC分类号： C07F9/5442 , C07D233/58 , C07D233/60 , C07D295/037 , C07F1/005 , C07F5/02 , C07F5/027 , H01G9/2004 , H01G9/2013 , H01G9/2031 , H01G9/2059 , H01G11/60 , H01G11/62 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , Y02E60/122
摘要： The invention relates to a process for the preparation of salts having perfluoroalkyltricyano- or perfluoroalkylcyanofluoroborate anions, ((per)fluoro)phenyltricyano- or ((per)fluoro)phenylcyanofluoroborate anions, phenyltricyanoborate anions which are mono- or disubstituted by perfluoroalkyl groups having 1 to 4C atoms or phenylcyanofluoroborate anions which are mono- or disubstituted by perfluoroalkyl groups having 1 to 4C atoms, by reaction of alkali metal trifluoroperfluoroalkylborate with trialkylsilyl cyanide and a subsequent salt-exchange reaction or by direct reaction of an organic trifluoroperfluoroalkyl borate with trialkylsilyl cyanide.
摘要翻译：本发明涉及一种制备具有全氟烷基三氰基或全氟烷基氰基氟硼酸根阴离子，（（全）氟）苯基三氰基或（（全）氟）苯基氰基氟硼酸根阴离子的苯基三氰基硼酸阴离子的盐的方法，所述苯基三氰基硼酸阴离子被全氟烷基单 - 或二 - 4C原子或苯基氰基氟硼酸阴离子，其通过碱金属三氟全氟烷基硼酸酯与三烷基甲硅烷基氰反应或通过有机三氟全氟烷基硼酸盐与三烷基甲硅烷基氰直接反应，由具有1-4个原子的全氟烷基单 - 或二 - 二取代。

106. 发明申请

US20140345676A1 METHOD FOR PRODUCING THREE-DIMENSIONAL MESOPOROUS TITANIUM DIOXIDE ELECTRODE USING ORGANIC/INORGANIC HYBRID SUPPORT AND DYE-SENSITIZED SOLAR CELL USING THE SAME 有权
标题翻译：使用有机/无机混合支持和使用其的透明的太阳能电池生产三维多孔二氧化钛电极的方法
公开(公告)号：US20140345676A1
公开(公告)日：2014-11-27
申请号：US14239421
申请日：2012-12-18
申请人： Jong-Hak Kim , Jung-Tae Park , Harim Jeon , Sang Jin Kim
发明人： Jong-Hak Kim , Jung-Tae Park , Harim Jeon , Sang Jin Kim
IPC分类号： H01G9/20 , H01L31/18
CPC分类号： H01L31/042 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2004/03 , C01P2004/64 , C01P2006/12 , H01G9/2031 , H01L31/18 , Y02E10/542
摘要： Disclosed is a method for producing a mesoporous titanium dioxide thin film from a titanium precursor by using a polymer-grafted alumina composite as a support. The porous titanium dioxide thin film is obtained by using the polymer-grafted hybrid alumina composite as a support for sol-gel reaction, and thus it has a mesoporous structure and high surface area, thereby providing a high dye adsorption ratio. Therefore, a dye-sensitized solar cell using the mesoporous titanium dioxide thin film as a photoelectrode material has high energy conversion efficiency. In addition, it is possible to improve the long-term stability of a dye-sensitized solar cell through efficient infiltration of high-viscosity polymer and solid electrolyte as well as liquid electrolyte.
摘要翻译：公开了一种通过使用聚合物接枝氧化铝复合材料作为载体从钛前体制备介孔二氧化钛薄膜的方法。通过使用聚合物接枝的杂化氧化铝复合物作为溶胶 - 凝胶反应的载体，获得多孔二氧化钛薄膜，因此其具有介孔结构和高表面积，从而提供高的染料吸附比。因此，使用介孔二氧化钛薄膜作为光电极材料的染料敏化太阳能电池具有高的能量转换效率。此外，通过高粘度聚合物和固体电解质以及液体电解质的有效渗透，可以提高染料敏化太阳能电池的长期稳定性。

107. 发明申请

US20140338749A1 PHOTOCATALYTIC MATERIAL AND GLAZING OR PHOTOVOLTAIC CELL COMPRISING SAID MATERIAL 审中-公开
标题翻译：光化学材料和玻璃或光伏电池，包含材料
公开(公告)号：US20140338749A1
公开(公告)日：2014-11-20
申请号：US14344558
申请日：2012-09-12
申请人： Rosiana Aguiar
发明人： Rosiana Aguiar
IPC分类号： H01G9/20 , C03C17/34
CPC分类号： H01G9/2031 , B01J21/063 , B01J37/0238 , B01J37/0244 , B01J37/349 , C03C17/3417 , C03C2217/71 , C03C2217/77 , C03C2218/1525 , C23C16/0272 , C23C16/405
摘要： A material includes a glass or glass-ceramic sheet provided on at least one portion of one of its faces with a photocatalytic coating based on titanium oxide deposited on a silica-based sublayer deposited by combustion chemical vapor deposition, the roughness Ra of which is between 4 and 30 nm, limits included.
摘要翻译：一种材料包括玻璃或玻璃陶瓷片，其设置在其一个面的至少一部分上，所述玻璃或玻璃陶瓷片基于沉积在通过燃烧化学气相沉积沉积的二氧化硅基底层上的氧化钛的光催化涂层，其沉积Ra在 4和30 nm，包括限制。

108. 发明授权

US08884029B2 Dye for photoelectric conversion device and photoelectric conversion device 有权
标题翻译：用于光电转换装置和光电转换装置的染料
公开(公告)号：US08884029B2
公开(公告)日：2014-11-11
申请号：US13062136
申请日：2009-09-09
申请人： Junji Tanabe , Atsushi Monden , Masahiro Shinkai , Mitsuhiro Okada , Toru Yano , Yohei Aoyama , Yusuke Kubota
发明人： Junji Tanabe , Atsushi Monden , Masahiro Shinkai , Mitsuhiro Okada , Toru Yano , Yohei Aoyama , Yusuke Kubota
IPC分类号： C07D403/06 , C07D417/06 , C07D413/06 , C07D421/06 , C09B23/01 , C09B23/08 , H01L51/00 , C09B23/02 , H01M14/00 , H01G9/20
CPC分类号： H01G9/2059 , C07D403/06 , C07D413/06 , C07D417/06 , C07D421/06 , C09B23/0058 , C09B23/0066 , C09B23/02 , C09B23/083 , H01G9/2013 , H01G9/2031 , H01L51/0064 , H01M14/005 , Y02E10/542
摘要： A photoelectric conversion device capable of improving conversion efficiency is provided. The photoelectric conversion device includes a work electrode, an opposed electrode, and an electrolyte-containing layer. In the work electrode, a metal oxide semiconductor layer supporting a dye is provided. The dye contains a cyanine compound that has a methine chain, an indolenine skeleton bonded with both ends of the methine chain, and anchor groups introduced to a nitrogen atom included in the indolenine skeleton. Electron injection efficiency to the metal oxide semiconductor layer is improved, and the dye is hardly exfoliated from the metal oxide semiconductor layer.
摘要翻译：提供了能够提高转换效率的光电转换装置。光电转换装置包括工作电极，相对电极和含电解质层。在工作电极中，提供了支撑染料的金属氧化物半导体层。染料含有具有次甲基链的花青化合物，与次甲基两端两端键合的吲哚宁骨架，以及引入到吲哚宁骨架中的氮原子的锚定基团。对金属氧化物半导体层的电子注入效率提高，并且染料几乎不从金属氧化物半导体层剥离。

109. 发明申请

US20140311574A1 Self-Aligned Deposition of Silica Layers for Dye-Sensitized Solar Cells 审中-公开
标题翻译：用于染料敏化太阳能电池的二氧化硅层的自对准沉积
公开(公告)号：US20140311574A1
公开(公告)日：2014-10-23
申请号：US14357065
申请日：2012-11-19
申请人： President and Fellows of Harvard College
发明人： Roy Gerald Gordon
IPC分类号： H01G9/20 , H01G9/00
CPC分类号： H01G9/2031 , C09B23/005 , C09B23/0058 , C09B57/008 , C09B69/008 , H01G9/0029 , H01G9/2036 , H01L51/0064 , Y02E10/542
摘要： The application is directed to improved dye-sensitized solar cells and methods for making the same. In accordance with certain embodiments, dye-sensitized anodes are exposed to a vapor including at least one chemical that reacts with the catalytically active material of the anode to deposit a silica layer only on regions that are not covered with the dyes. The resulting self-aligned silica layers provide increased efficiency for dye-sensitized solar cells by reducing the leakage current from the anode to the electrolyte.
摘要翻译：本申请涉及改进的染料敏化太阳能电池及其制备方法。根据某些实施方案，染料敏化阳极暴露于包含至少一种与阳极的催化活性材料反应的化学物质的蒸汽，仅在没有被染料覆盖的区域上沉积二氧化硅层。所得到的自对准二氧化硅层通过减少从阳极到电解质的泄漏电流来提高染料敏化太阳能电池的效率。

110. 发明申请

US20140275602A1 Tunable Photoactive Compounds 有权
标题翻译：可调光活性化合物
公开(公告)号：US20140275602A1
公开(公告)日：2014-09-18
申请号：US13869325
申请日：2013-04-24
申请人： Michael D. Irwin , Jerred A. Chute , Robert D. Maher, III
发明人： Michael D. Irwin , Jerred A. Chute , Robert D. Maher, III
IPC分类号： H01L51/00
CPC分类号： H01L51/0058 , H01G9/2031 , H01G9/2059 , H01L51/006 , H01L51/0061 , H01L51/0071 , H01L51/0074 , Y02E10/542 , Y02E10/549
摘要： Photoactive compositions of matter, methods for their design and synthesis, and various applications of such compositions of matter are disclosed. Such photoactive compositions may, for example, include any one or more of the following: a core moiety; a primary electron donor moiety; an electron-withdrawing moiety; and an alkyl tail. Some photoactive compositions may further include multiple additional electron donor moieties, electron-withdrawing moieties, and alkyl tails. Methods for designing such photoactive compositions may include selecting a core moiety; selecting an electron-withdrawing moiety to add to the core moiety in order to modify the composition's electronic properties; selecting a primary electron donor moiety to be added in order to further modify the composition's electronic properties; selecting a second electron donor moiety to be added in order to modify the composition's electronic properties even further, if necessary; and synthesizing the designed composition.
摘要翻译：公开了物质的光活性组合物，其设计和合成方法以及这种物质组合物的各种应用。这样的光活性组合物可以例如包括以下中的任何一个或多个：芯部分; 初级电子给体部分; 吸电子部分; 和烷基尾。一些光活性组合物还可以包括多个另外的电子给体部分，吸电子部分和烷基尾部。设计这种光活性组合物的方法可包括选择核心部分; 选择吸电子部分以加入核心部分以改变组合物的电子性质; 选择要添加的主要电子体部分以进一步改变组合物的电子性质; 选择要加入的第二电子给体部分，以便在需要时进一步改变组合物的电子性质; 并合成设计的组合物。

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